NASICON型无机固态锂离子电解质的研究进展
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摘要
无机固体电解质由于其安全性能高,机械强度大等特点在锂离子电池行业潜力巨大,其中NASICON型无机锂离子电解质因电导率较高、稳定性好、种类繁多的优势备受研究者关注。主要从NASICON型锂离子电解质材料的晶体结构、制备工艺和掺杂改性方面综述了其目前的研究进展,对其未来的发展做出展望。
Inorganic solid electrolyte has great potential in lithium-ion battery industry,due to its high safety performance,high mechanical strength and other characteristics.NASICON inorganic lithium ion electrolyte has attracted much attention because of its advantages such as high conductivity,good stability and wide variety.The crystal structure,preparation process and doping modification of NASICON lithium ion electrolyte material were focus on.And the current research progress and future development of NASICON were reviewed.
Inorganic solid electrolyte has great potential in lithium-ion battery industry,due to its high safety performance,high mechanical strength and other characteristics.NASICON inorganic lithium ion electrolyte has attracted much attention because of its advantages such as high conductivity,good stability and wide variety.The crystal structure,preparation process and doping modification of NASICON lithium ion electrolyte material were focus on.And the current research progress and future development of NASICON were reviewed.
引文
[1] Nuernberg R B,Rodrigues A C M.A new NASICON lithium ion-conducting glass-ceramic of the Li1+xCrx(GeyTi1-y)2-x(PO4)3system[J].Solid State Ionics,2017,301:1-9.
[2] Yuan C F.All-solid-state lithium ion battery:research and industrial prospects[J].Acta Chimica Sinica,2013,71(1):869-878.
[3] Sun C W,Liu J,Gong Y D,et al.Recent advances in all-solidstate rechargeable lithium batteries[J].Nano Energy,2017,33:363-386.
[4] Tatsumisago M,Takano R,Tadanaga K,et al.Preparation of Li3BO3-Li2SO4glass-ceramic electrolytes for all-oxide lithium batteries[J].Journal of Power Sources,2014,270(4):603-607.
[5] Anantharamulu N,Rao K K,Rambabu G,et al.A wide-ranging review on nasicon type materials[J].Journal of Materials Science,2011,46(9):2821-2837.
[6] Hagman L O,Kierkegaard P,Karvonen P,et al.The crystal structure of NaMeⅣ(PO4)3;MeⅣ=Ge,Ti,Zr[J].Acta Chemica Scandinavica,1968,22:1822-1832.
[7] Goodenough J B,Hong Y P,Kafalas J A.Fast Na+-ion transport in skeleton structures[J].Materials Research Bulletin,1976,11(2):203-220.
[8]张舒,王少飞,凌仕刚,等.锂离子电池基础科学问题(Ⅹ)——全固态锂离子电池[J].储能科学与技术,2014,3(4):376-394.
[9] Vijayan L,Govindaraj G.Structural and electrical properties of high-energy ball-milled NASICON type Li1.3 Ti1.7 Al0.3(PO4)2.9(VO4)0.1ceramics[J].Journal of Physics&Chemistry of Solids,2011,72(6):613-619.
[10]李杨,连芳,周国治.应用于锂离子电池的无机晶态固体电解质导电性能研究进展[J].硅酸盐学报,2013,27(7):950-958.
[11] Knauth P.Inorganic solid Li ion conductors:an overview[J].Solid State Ionics,2009,180(14-16):911-916.
[12] Takada K,Tansho M,Yanase I,et al.Lithium ion conduction in LiTi2(PO4)3[J].Solid State Ionics,2001,139(3-4):241-247.
[13] Arbi K,Bucheli W,Jiménez R,et al.High lithium ion conducting solid electrolytes based on NASICON Li1+x AlxM2-x(PO4)3,materials(M=Ti,Ge and 0≤x≤0.5)[J].Journal of the European Ceramic Society,2015,35(5):1477-1484.
[14]柳红东,胡忠利,阮海波.无机固体电解质Li7La3Zr2O12的制备及掺杂改性研究进展[J].材料导报,2016,30(13):71-75.
[15] Tamura S,Araki K I,Imanaka N.Trivalent gallium ion conduction in NASICON-type solid[J].Journal of Asian Ceramic Societies,2016,4(4):390-393.
[16] Xu X P,Yang T C,Shui M,et al.The preparation and lithium mobility of zinc based NASICON-type solid electrolyte Li1+2x+2yAlxZnyTi2-x-ySixP3-xO12[J].Ceramics International,2014,40(2):3819-3822.
[17] Ramakumar S,Deviannapoorani C,Dhivya L,et al.Lithium garnets:synthesis,structure,Li+conductivity,Li+dynamics and applications[J].Progress in Materials Science,2017,88:325-411.
[18] Chung H,Kang B.Increase in grain boundary ionic conductivity of Li1.5Al0.5Ge1.5(PO4)3by adding excess lithium[J].Solid State Ionics,2014,263(263):125-130.
[19]何海亮,吴显明,陈上,等.锂离子固体电解质Li1.3Al0.3Ti1.7(PO4)3的合成与表征[J].人工晶体学报,2015,44(1):195-199.
[20] Bucharsky E C,Schell K G,Hintennach A,et al.Preparation and characterization of sol-gel derived high lithium ion conductive NZP-type ceramics Li1+xAlxTi2-x(PO4)3[J].Solid State Ionics,2015,274(2):77-82.
[21] Yadav P,Bhatnagar M C.Structural studies of NASICON material of different compositions by sol-gel method[J].Ceramics International,2012,38(2):1731-1735.
[22] Kim K M,Dong O S,Lee Y G.Effects of preparation conditions on the ionic conductivity of hydrothermally synthesized Li1+xAlxTi2-x(PO4)3solid electrolytes[J].Electrochimica Acta,2015,176:1364-1373.
[23] Xu X X,Wen Z Y,Wu J G,et al.Preparation and electrical properties of NASICON-type structured Li1.4 Al0.4 Ti1.6(PO4)3glass-ceramics by the citric acid-assisted sol-gel method[J].Solid State Ionics,2007,178(1-2):29-34.
[24]吴显明,刘金练,李润秀,等.Li3PO4助熔剂添加对Li1.3Al0.3Ti1.7(PO4)3性质的影响[J].精细化工,2011,28(6):573-577.
[25] Huang L Z,Wen Z Y,Wu M F,et al.Electrochemical properties of Li1.4Al0.4Ti1.6(PO4)3,synthesized by a co-precipitation method[J].Journal of Power Sources,2011,196(16):6943-6946.
[26] Yang B,Li X H,Guo H J,et al.Preparation and properties of Li1.3Al0.3Ti1.7(PO4)3,by spray-drying and post-calcining method[J].Journal of Alloys&Compounds,2015,643:181-185.
[27] Bogusz W,Krok F,Jakubowski W.Influence of doping on some physical properties of NASICON[J].Solid State Ionics,1983,9(12):803-807.
[28] Ma F R,Zhao E Q,Zhu S Y,et al.Preparation and evaluation of high lithium ion conductivity Li1.3Al0.3Ti1.7(PO4)3,solid electrolyte obtained using a new solution method[J].Solid State Ionics,2016,295:7-12.
[29] Kuwano J,Sato N,Kato M,et al.Ionic conductivity of LiM2(PO4)3,(M=Ti,Zr,Hf)and related compositions[J].Solid State Ionics,1994,70-71(8):332-336.
[30] Kotobuki M,Hoshina K,Isshiki Y,et al.Preparation of Li1.5Al0.5Ge1.5(PO4)3solid electrolyte by sol-gel method[J].Phosphorus Research Bulletin,2011,25:61-63.
[31] Huang L Z,Wen Z Y,Jin J,et al.Preparation and characterization of PEO-LATP/LAGP ceramic composite electrolyte membrane for lithium batteries[J].Journal of Inorganic Materials,2012,27(3):249-252.
[32] Ortiz G F,López M C,Lavela P,et al.Improved lithium-ion transport in NASICON-type lithium titanium phosphate by calcium and iron doping[J].Solid State Ionics,2014,262(9):573-577.
[33] Kotobuki M,Koishi M.Preparation of Li1.5Al0.5Ti1.5(PO4)3,solid electrolyte via a sol-gel route using various Al sources[J].Ceramics International,2013,39(4):4645-4649.
[34] Shang X F,Nemori H,Mitsuoka S,et al.High lithium-ion conducting NASICON-type Li1+x-yAlxNbyTi2-x-y(PO4)3,solid electrolytes[J].Solid State Ionics,2016,297:43-48.
[35] Zhang P,Wang H,Si Q,et al.High lithium ion conductivity solid electrolyte of chromium and aluminum co-doped NASICON-type LiTi2(PO4)3[J].Solid State Ionics,2015,272:101-106.
[36] Kothari D H,Kanchan D K.Effect of doping of trivalent cations Ga3+,Sc3+,Y3+in Li1.3Al0.3Ti1.7(PO4)3(LATP)system on Li+ion conductivity[J].Physica B Condensed Matter,2016,501:90-94.
[37] Zhang P,Matsui M,Hirano A,et al.Water-stable lithium ion conducting solid electrolyte of the Li1.4 Al0.4 Ti1.6-x Gex(PO4)3,system(x=0-1.0)with NASICON-type structure[J].Solid State Ionics,2013,253(12):175-180.
[38] Pérez-Estébanez M,Isasi-Marín J,T9bbens D M,et al.A systematic study of nasicon-type Li1+x MxTi2-x(PO4)3,(M:Cr,Al,Fe)by neutron diffraction and impedance spectroscopy[J].Solid State Ionics,2014,266:1-8.
[39] Du X Y,He W,Zhang X D,et al.Low temperature biosynthesis of Li2O-MgO-P2O5-TiO2nanocrystalline glass with mesoporous structure exhibiting fast lithium ion conduction[J].Materials Science&Engineering C Materials for Biological Applications,2013,33(3):1592.
[40] Lu X J,Xu Y H.Study of inorganic solid lithium ion conductor with mixed degrees of sintering[J].Solid State Ionics,2016,287:17-21.
[41] Li Y T,Liu M J,Liu K,et al.High Li+conduction in NASICON-type Li1+xYxZr2-x(PO4)3at room temperature[J].Journal of Power Sources,2013,240(240):50-53.
[42]刘美景,魏红康,汪长安.NASICON型电解质材料Li1+x ErxZr2-x(PO4)3(0.1≤x≤0.2)的制备与性能[J].稀有金属材料与工程,2015,44(S1):113-115.
[43] Kumar S,Balaya P.Improved ionic conductivity in NASICONtype Sr2+doped LiZr2(PO4)3[J].Solid State Ionics,2016,296:1-6.
[44] Feng J K,Lu L,Lai M O.Lithium storage capability of lithium ion conductor Li1.5Al0.5Ge1.5(PO4)3[J].Journal of Alloys&Compounds,2010,501(2):255-258.
[45] Zhang M,Huang Z,Cheng J F,et al.Solid state lithium ionic conducting thin film Li1.4Al0.4Ge1.6(PO4)3,prepared by tape casting[J].Journal of Alloys&Compounds,2014,590(590):147-152.
[46] Xu X X,Wen Z Y,Gu Z H,et al.High lithium conductivity in Li1.3Cr0.3Ge1.7(PO4)3 glass-ceramics[J].Materials Letters,2004,58(27-28):3428-3431.
[47] Illbeigi M,Fazlali A,Kazazi M,et al.Effect of simultaneous addition of aluminum and chromium on the lithium ionic conductivity of LiGe2(PO4)3 NASICON-type glass-ceramics[J].Solid State Ionics,2016,289:180-187.
[48] Norhaniza R,Subban R H Y,Mohamed N S,et al.Chromium substituted LiSn2P3O12 solid electrolyte[J].International Journal of Electrochemical Science,2012,7(10):10254-10265.
[49] Kothari D H,Kanchan D K.Study of Li+conduction in Li1.3Al0.3-xScxTi1.7(PO4)3(x=0.01,0.03,0.05and 0.07)NASICON ceramic compound[J].Physica B Condensed Matter,2016,494:20-25.
[50] Xie H,Goodenough J B,Li Y T.Li1.2Zr1.9Ca0.1(PO4)3,a room-temperature Li-ion solid electrolyte[J].Journal of Power Sources,2011,196(196):7760-7762.
[51] Best A S,Newman P J,Macfarlane D R,et al.Characterisation and impedance spectroscopy of substituted Li1.3Al0.3Ti1.7(PO4)3-x(ZO4)x(Z=V,Nb)ceramics[J].Solid State Ionics,1999,126(1-2):191-196.
[52]彭会芬,高美伶,王明芳,等.SiO4-4对Li3Sc2(PO4)3快离子导体的阴离子替代效果研究[J].无机化学学报,2011,27(10):1969-1974.
[53] Geng S X,Yang Y G,Zhang Y G,et al.Effect of[VO4]3-substitution for[PO4]3-on electrical conductivity in the nasicon Li3Sc2(PO4)3compound[J].Electrochimica Acta,2015,176:327-333.
[54] Fu J.Fast Li+ion conduction in Li2O-Al2O3-TiO2-SiO2-P2O2glass-ceramics[J].Journal of the American Ceramic Society,2005,80(7):1901-1903.
[55] Goharian P,Yekta B E,Aghaei A R,et al.Lithium ion-conducting glass-ceramics in the system Li2O-TiO2-P2O5-Cr2O3-SiO2[J].Journal of Non-Crystalline Solids,2015,409:120-125.
[56] Xu X P,Yang T C,Shui M,et al.The preparation and lithium mobility of zinc based NASICON-type solid electrolyte Li1+2x+2yAlxZnyTi2-x-ySixP3-xO12[J].Ceramics International,2014,40(2):3819-3822.
[57] Lu X J,Xiao H N.Improving ionic conductivity of polycrystalline lithium ion conductors by interacting with mesoporous materials[J].Materials Letters,2016,177:50-53.
[58]郑卫东,水淼,任政娟,等.高岭土掺杂NASICON固体电解质及全固态电池性能[J].浙江大学学报工学版,2012,46(2):237-242.
[2] Yuan C F.All-solid-state lithium ion battery:research and industrial prospects[J].Acta Chimica Sinica,2013,71(1):869-878.
[3] Sun C W,Liu J,Gong Y D,et al.Recent advances in all-solidstate rechargeable lithium batteries[J].Nano Energy,2017,33:363-386.
[4] Tatsumisago M,Takano R,Tadanaga K,et al.Preparation of Li3BO3-Li2SO4glass-ceramic electrolytes for all-oxide lithium batteries[J].Journal of Power Sources,2014,270(4):603-607.
[5] Anantharamulu N,Rao K K,Rambabu G,et al.A wide-ranging review on nasicon type materials[J].Journal of Materials Science,2011,46(9):2821-2837.
[6] Hagman L O,Kierkegaard P,Karvonen P,et al.The crystal structure of NaMeⅣ(PO4)3;MeⅣ=Ge,Ti,Zr[J].Acta Chemica Scandinavica,1968,22:1822-1832.
[7] Goodenough J B,Hong Y P,Kafalas J A.Fast Na+-ion transport in skeleton structures[J].Materials Research Bulletin,1976,11(2):203-220.
[8]张舒,王少飞,凌仕刚,等.锂离子电池基础科学问题(Ⅹ)——全固态锂离子电池[J].储能科学与技术,2014,3(4):376-394.
[9] Vijayan L,Govindaraj G.Structural and electrical properties of high-energy ball-milled NASICON type Li1.3 Ti1.7 Al0.3(PO4)2.9(VO4)0.1ceramics[J].Journal of Physics&Chemistry of Solids,2011,72(6):613-619.
[10]李杨,连芳,周国治.应用于锂离子电池的无机晶态固体电解质导电性能研究进展[J].硅酸盐学报,2013,27(7):950-958.
[11] Knauth P.Inorganic solid Li ion conductors:an overview[J].Solid State Ionics,2009,180(14-16):911-916.
[12] Takada K,Tansho M,Yanase I,et al.Lithium ion conduction in LiTi2(PO4)3[J].Solid State Ionics,2001,139(3-4):241-247.
[13] Arbi K,Bucheli W,Jiménez R,et al.High lithium ion conducting solid electrolytes based on NASICON Li1+x AlxM2-x(PO4)3,materials(M=Ti,Ge and 0≤x≤0.5)[J].Journal of the European Ceramic Society,2015,35(5):1477-1484.
[14]柳红东,胡忠利,阮海波.无机固体电解质Li7La3Zr2O12的制备及掺杂改性研究进展[J].材料导报,2016,30(13):71-75.
[15] Tamura S,Araki K I,Imanaka N.Trivalent gallium ion conduction in NASICON-type solid[J].Journal of Asian Ceramic Societies,2016,4(4):390-393.
[16] Xu X P,Yang T C,Shui M,et al.The preparation and lithium mobility of zinc based NASICON-type solid electrolyte Li1+2x+2yAlxZnyTi2-x-ySixP3-xO12[J].Ceramics International,2014,40(2):3819-3822.
[17] Ramakumar S,Deviannapoorani C,Dhivya L,et al.Lithium garnets:synthesis,structure,Li+conductivity,Li+dynamics and applications[J].Progress in Materials Science,2017,88:325-411.
[18] Chung H,Kang B.Increase in grain boundary ionic conductivity of Li1.5Al0.5Ge1.5(PO4)3by adding excess lithium[J].Solid State Ionics,2014,263(263):125-130.
[19]何海亮,吴显明,陈上,等.锂离子固体电解质Li1.3Al0.3Ti1.7(PO4)3的合成与表征[J].人工晶体学报,2015,44(1):195-199.
[20] Bucharsky E C,Schell K G,Hintennach A,et al.Preparation and characterization of sol-gel derived high lithium ion conductive NZP-type ceramics Li1+xAlxTi2-x(PO4)3[J].Solid State Ionics,2015,274(2):77-82.
[21] Yadav P,Bhatnagar M C.Structural studies of NASICON material of different compositions by sol-gel method[J].Ceramics International,2012,38(2):1731-1735.
[22] Kim K M,Dong O S,Lee Y G.Effects of preparation conditions on the ionic conductivity of hydrothermally synthesized Li1+xAlxTi2-x(PO4)3solid electrolytes[J].Electrochimica Acta,2015,176:1364-1373.
[23] Xu X X,Wen Z Y,Wu J G,et al.Preparation and electrical properties of NASICON-type structured Li1.4 Al0.4 Ti1.6(PO4)3glass-ceramics by the citric acid-assisted sol-gel method[J].Solid State Ionics,2007,178(1-2):29-34.
[24]吴显明,刘金练,李润秀,等.Li3PO4助熔剂添加对Li1.3Al0.3Ti1.7(PO4)3性质的影响[J].精细化工,2011,28(6):573-577.
[25] Huang L Z,Wen Z Y,Wu M F,et al.Electrochemical properties of Li1.4Al0.4Ti1.6(PO4)3,synthesized by a co-precipitation method[J].Journal of Power Sources,2011,196(16):6943-6946.
[26] Yang B,Li X H,Guo H J,et al.Preparation and properties of Li1.3Al0.3Ti1.7(PO4)3,by spray-drying and post-calcining method[J].Journal of Alloys&Compounds,2015,643:181-185.
[27] Bogusz W,Krok F,Jakubowski W.Influence of doping on some physical properties of NASICON[J].Solid State Ionics,1983,9(12):803-807.
[28] Ma F R,Zhao E Q,Zhu S Y,et al.Preparation and evaluation of high lithium ion conductivity Li1.3Al0.3Ti1.7(PO4)3,solid electrolyte obtained using a new solution method[J].Solid State Ionics,2016,295:7-12.
[29] Kuwano J,Sato N,Kato M,et al.Ionic conductivity of LiM2(PO4)3,(M=Ti,Zr,Hf)and related compositions[J].Solid State Ionics,1994,70-71(8):332-336.
[30] Kotobuki M,Hoshina K,Isshiki Y,et al.Preparation of Li1.5Al0.5Ge1.5(PO4)3solid electrolyte by sol-gel method[J].Phosphorus Research Bulletin,2011,25:61-63.
[31] Huang L Z,Wen Z Y,Jin J,et al.Preparation and characterization of PEO-LATP/LAGP ceramic composite electrolyte membrane for lithium batteries[J].Journal of Inorganic Materials,2012,27(3):249-252.
[32] Ortiz G F,López M C,Lavela P,et al.Improved lithium-ion transport in NASICON-type lithium titanium phosphate by calcium and iron doping[J].Solid State Ionics,2014,262(9):573-577.
[33] Kotobuki M,Koishi M.Preparation of Li1.5Al0.5Ti1.5(PO4)3,solid electrolyte via a sol-gel route using various Al sources[J].Ceramics International,2013,39(4):4645-4649.
[34] Shang X F,Nemori H,Mitsuoka S,et al.High lithium-ion conducting NASICON-type Li1+x-yAlxNbyTi2-x-y(PO4)3,solid electrolytes[J].Solid State Ionics,2016,297:43-48.
[35] Zhang P,Wang H,Si Q,et al.High lithium ion conductivity solid electrolyte of chromium and aluminum co-doped NASICON-type LiTi2(PO4)3[J].Solid State Ionics,2015,272:101-106.
[36] Kothari D H,Kanchan D K.Effect of doping of trivalent cations Ga3+,Sc3+,Y3+in Li1.3Al0.3Ti1.7(PO4)3(LATP)system on Li+ion conductivity[J].Physica B Condensed Matter,2016,501:90-94.
[37] Zhang P,Matsui M,Hirano A,et al.Water-stable lithium ion conducting solid electrolyte of the Li1.4 Al0.4 Ti1.6-x Gex(PO4)3,system(x=0-1.0)with NASICON-type structure[J].Solid State Ionics,2013,253(12):175-180.
[38] Pérez-Estébanez M,Isasi-Marín J,T9bbens D M,et al.A systematic study of nasicon-type Li1+x MxTi2-x(PO4)3,(M:Cr,Al,Fe)by neutron diffraction and impedance spectroscopy[J].Solid State Ionics,2014,266:1-8.
[39] Du X Y,He W,Zhang X D,et al.Low temperature biosynthesis of Li2O-MgO-P2O5-TiO2nanocrystalline glass with mesoporous structure exhibiting fast lithium ion conduction[J].Materials Science&Engineering C Materials for Biological Applications,2013,33(3):1592.
[40] Lu X J,Xu Y H.Study of inorganic solid lithium ion conductor with mixed degrees of sintering[J].Solid State Ionics,2016,287:17-21.
[41] Li Y T,Liu M J,Liu K,et al.High Li+conduction in NASICON-type Li1+xYxZr2-x(PO4)3at room temperature[J].Journal of Power Sources,2013,240(240):50-53.
[42]刘美景,魏红康,汪长安.NASICON型电解质材料Li1+x ErxZr2-x(PO4)3(0.1≤x≤0.2)的制备与性能[J].稀有金属材料与工程,2015,44(S1):113-115.
[43] Kumar S,Balaya P.Improved ionic conductivity in NASICONtype Sr2+doped LiZr2(PO4)3[J].Solid State Ionics,2016,296:1-6.
[44] Feng J K,Lu L,Lai M O.Lithium storage capability of lithium ion conductor Li1.5Al0.5Ge1.5(PO4)3[J].Journal of Alloys&Compounds,2010,501(2):255-258.
[45] Zhang M,Huang Z,Cheng J F,et al.Solid state lithium ionic conducting thin film Li1.4Al0.4Ge1.6(PO4)3,prepared by tape casting[J].Journal of Alloys&Compounds,2014,590(590):147-152.
[46] Xu X X,Wen Z Y,Gu Z H,et al.High lithium conductivity in Li1.3Cr0.3Ge1.7(PO4)3 glass-ceramics[J].Materials Letters,2004,58(27-28):3428-3431.
[47] Illbeigi M,Fazlali A,Kazazi M,et al.Effect of simultaneous addition of aluminum and chromium on the lithium ionic conductivity of LiGe2(PO4)3 NASICON-type glass-ceramics[J].Solid State Ionics,2016,289:180-187.
[48] Norhaniza R,Subban R H Y,Mohamed N S,et al.Chromium substituted LiSn2P3O12 solid electrolyte[J].International Journal of Electrochemical Science,2012,7(10):10254-10265.
[49] Kothari D H,Kanchan D K.Study of Li+conduction in Li1.3Al0.3-xScxTi1.7(PO4)3(x=0.01,0.03,0.05and 0.07)NASICON ceramic compound[J].Physica B Condensed Matter,2016,494:20-25.
[50] Xie H,Goodenough J B,Li Y T.Li1.2Zr1.9Ca0.1(PO4)3,a room-temperature Li-ion solid electrolyte[J].Journal of Power Sources,2011,196(196):7760-7762.
[51] Best A S,Newman P J,Macfarlane D R,et al.Characterisation and impedance spectroscopy of substituted Li1.3Al0.3Ti1.7(PO4)3-x(ZO4)x(Z=V,Nb)ceramics[J].Solid State Ionics,1999,126(1-2):191-196.
[52]彭会芬,高美伶,王明芳,等.SiO4-4对Li3Sc2(PO4)3快离子导体的阴离子替代效果研究[J].无机化学学报,2011,27(10):1969-1974.
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