金包覆的核壳结构纳米材料的制备进展
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摘要
金、银等贵金属纳米材料具有独特的光学、电学和催化性能以及良好的生物兼容性,其在化学、物理、生物和医学等领域具有广泛的应用。以贵金属纳米金作为核或壳,制备成核壳结构复合纳米材料,这样的核壳材料同时具有核和壳的性质以及其他优越的性能,因此受到研究者的广泛青睐。金包覆纳米颗粒制备核壳结构的方法众多,主要对金包覆所形成的核壳型纳米材料的制备方法进行综述。
Au,Ag and other precious metal nanomaterials(NPs) have been widely used in the fields of chemistry,physics,biology and medicine due to their unique optical,electrical,catalytic properties and good biocompatibility.Au NPs are employed as core or shell to prepare core-shell type of composite NPs,which are widely favored by researchers.Such core-shell NPs endow with both the performance of core and shell,as well as other superior properties,there are many methods for preparing core-shell structure with Au coating NPs.The methods for preparing core-shell NPs with Au coating was reviewed.
Au,Ag and other precious metal nanomaterials(NPs) have been widely used in the fields of chemistry,physics,biology and medicine due to their unique optical,electrical,catalytic properties and good biocompatibility.Au NPs are employed as core or shell to prepare core-shell type of composite NPs,which are widely favored by researchers.Such core-shell NPs endow with both the performance of core and shell,as well as other superior properties,there are many methods for preparing core-shell structure with Au coating NPs.The methods for preparing core-shell NPs with Au coating was reviewed.
引文
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[6]吴睿,张强,刘存芳.纳米金的应用[J].贵金属,2017,38(1):139-148.
[7]吴睿,张强,郝亮.金核壳结构复合纳米颗粒在生物医学中的应用[J].贵金属,2018,39(2):69-75.
[8]寇莹莹,任相浩.GSH和CTAB功能纳米金比色法快速检测Pb2+的研究[J].贵金属,2017,39(12):1 301-1 304.
[9]杨爽,吴学,金艳花,等.亲和素引发金纳米粒子聚集的影响因素研究[J].贵金属,2018,40(8):721-724.
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[17]XU F G,CUI K,SUN Y J,et al.Facile synthesis of urchin-like gold submicrostructures for nonenzymatic glucose sensing[J].Talanta,2010,82(5):1 845-1 852.
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[23]WU Z M,TANG M,LI X Y,et al.Surface faceting and compositional evolution of Pd@Au core-shell nanocrystals during in situ annealing[J]. Phys. Chem. Chem.Phys.,2019,21(6):3 134-3 139.
[24]TIRUVALAM R C,PRITCHARD J C,DIMITRATOS N.Aberration corrected analytical electron microscopy studies of sol-immobilized Au,Pd,Au{Pd}and Pd{Au}catalysts used for benzyl alcohol oxidation and hydrogen peroxide production[J]. Faraday Discuss.,2011,152(5):63-86.
[25]ZHANG H J,OKUNI J,TOSHIMA N.One-pot synthesis of Ag-Au bimetallic nanoparticles with Au shell and their high catalytic activity for glucose oxidation[J]. J.Collid.Interf.Sci.,2011,354(1):131-138.
[26]KUMAR G V P. Surface-enhanced Raman scattering studies of carbon nanotubes using Ag-core Au-shell nanoparticles[J]. J. Raman Spectrosc.,2009,40(12):2 069-2 073.
[27]QI G,ZHANG Y H.Synthesis of Ni@Au core-shell nanoparticles and its applications in ullmann reaction as a synergistic catalyst[J]. Chin. J. Struct. Chem.,2011,30(8):1 122-1 126.
[28]NADAGOUDA M N,VARMA R S.A greener synthesis of core(Fe,Cu)-shell(Au,Pt,Pd,and Ag)nanocrystals using aqueous vitamin[J].Cryst.Growth Des.,2007,7(12):2 582-2 587.
[29]SOM T,KARMAKAR B.Core-shell Au-Ag nanoparticles in dielectric nanocomposites with plasmon-enhanced fluorescence:a new paradigm in antimony glasses[J].Nano Res.,2009,2(8):607-616.
[30]MAO K,YANG Z G,LI J R,et al.A novel colorimetric biosensor based on non-aggregated Au@Ag core-shell nanoparticles for methamphetamine and cocaine detection[J].Talanta,2017,175(1):338-346.
[31]YU J W,MA Y N,YANG C X.SERS-active composite based on r GO and Au/Ag core-shell nanorods for analytical applications[J].Sensor.Actuat.B:Chem.,2018,254:182-188.
[32]ANH D T N,SINGH P,SHANKAR C,et al. Chargetransfer-induced suppression of galvanic replacement and synthesis of(Au@Ag)@Au double shell nanoparticles for highly uniform,robust and sensitive bioprobes[J].Appl.Phys.Lett.,2011,99(7):73 107-73 110.
[33]SHAHJAMALI M M,BOSMAN M,CAO S W,et al.Gold coating of silver nanoprisms[J]. Adv. Funct. Mater.,2012,22(4):849-854.
[34]SUDHEENDRA L,ORTALAN V,DEY S,et al.Plasmonic enhanced emissions from cubic Na YF4∶Yb∶Er/Tm nanophosphors[J].Chem. Mater.,2011,23(11):2 987-2 993.
[35]LOAIZA O A,JUBETE E,OCHOTECO E,et al. Gold coated ferric oxide nanoparticles based disposable magnetic genosensors for the detection of DNA hybridization processes[J]. Biosens. Bioelectron.,2011,26(5):2 194-2 200.
[36]LIU N,QIN W P,QIN G S,et al. Highly plasmon-enhanced upconversion emissions from Au@b-NaYF4∶Yb,Tm hybrid nanostructures[J]. Chem. Commun.,2011,47(27):7 671-7 673.
[37]ZHOU T,WU B Y,XING D.Bio-modified Fe3O4core/Au shell nanoparticles for targeting and multimodal imaging of cancer cells[J]. J. Mater. Chem.,2012,22(2):470-477.
[38]LI Z Q,LI X D,LIU Q Q,et al. Core/shell structured Na YF4∶Yb3+/Er3+/Gd3+nanorods with Au nanoparticles or shells for flexible amorphous silicon solar cells[J].Nanotechnology,2012,23(2):25 402-25 410.
[39]FUJII M,NAKANO T,IMAKITA K,et al.Upconversion luminescence of Er and Yb Codoped Na YF4nanoparticles with metal shells[J]. J. Phys. Chem. C,2013,117(2):1 113-1 120.
[40]WANG Z J,WU L N,LIANG H J,et al. Controllable synthesis of bifunctional Na YF4∶Yb3+/Ho3+@Si O2/Au nanoparticles with upconversion luminescence and high X-ray attenuation[J]. J. Alloy. Compd.,2011,509(37):9 144-9 149.
[41]LI Z Q,WANG L M,WANG Z Y.Modification of Na YF4∶Yb,Er@Si O2nanoparticles with gold nanocrystals for tunable green-to-red upconversion emissions[J].J.Phys.Chem.C,2011,115(8):3 291-3 296.
[42]RASCH M R,SOKOLOV K V,KORGEL B A. Limitations on the optical tunability of small diameter gold nanoshells[J].Langmuir,2009,25(19):11 777-11 785.
[43]PRIYAM A,IDRISA N M,ZHANG Y. Gold nanoshell coated Na YF4nanoparticles for simultaneously enhanced upconversion fluorescence and darkfield imaging[J]. J.Mater.Chem.,2012,22(3):960-965.
[44]WANG L Y,BAI J W,LI Y J,et al.Multifunctional nanoparticles displaying magnetization and Near-IR absorption[J]. Angew. Chem. Int. Ed.,2008,47(13):2 439-2 442.
[45]ZHANG H,LI Y J,IVANOV I A,et al.Plasmonic modulation of the upconversion fluorescence in Na YF4∶Yb/Tm hexaplate nanocrystals using gold nanoparticles or nanoshells[J]. Angew. Chem. Int. Ed.,2010,49(16):2 865-2 868.
[46]XIE H Y,ZHEN R,WANG B,et al. Fe3O4/Au core/shell nanoparticles modified with Ni2+-nitrilotriacetic acid specific to histidine-tagged proteins[J]. J. Phys.Chem.C,2010,114(11):4 825-4 830.
[47]LOU L,YU K,ZHANG Z L,et al. Facile methods for synthesis of core-shell structured and heterostructured Fe3O4@Au nanocomposites[J]. Appl. Surf. Sci.,2012,258(22):8 521-8 526.
[48]WANG Y,SHEN Y H,XIE A J.A simple method to construct bifunctional Fe3O4/Au hybrid nanostructures and tune their optical properties in the near-infrared region[J].J.Phys.Chem.C,2010,114(32):4 297-4 301.
[2]WANG Y,HERRON N. Nanometer-sized semiconductor clusters:materials synthesis,quantum size effects,and photophysical properties[J]. J. Phys. Chem. C,1991,95(2):525-532.
[3]ZHANG N,LIU S Q,XU Y J. Recent progress on metal core@semiconductor shell nanocomposites as a promising type of photocatalyst[J]. Nanoscale,2012,4(7):2 227-2 238.
[4]MULVANEY P,LUIS M,MARZAN L. Rational material design using Au core-shell nanocrystals[J]. Top. Curr.Chem.,2003,226(12):225-246.
[5]赵灵芝,张成孝.基于纳米金的比色法在生理活性分子分析中的应用进展[J].化学试剂,2014,36(9):801-805.
[6]吴睿,张强,刘存芳.纳米金的应用[J].贵金属,2017,38(1):139-148.
[7]吴睿,张强,郝亮.金核壳结构复合纳米颗粒在生物医学中的应用[J].贵金属,2018,39(2):69-75.
[8]寇莹莹,任相浩.GSH和CTAB功能纳米金比色法快速检测Pb2+的研究[J].贵金属,2017,39(12):1 301-1 304.
[9]杨爽,吴学,金艳花,等.亲和素引发金纳米粒子聚集的影响因素研究[J].贵金属,2018,40(8):721-724.
[10]HAO X L,YUAN Z,YI S H,et al. DNA zyme cross linked hydrogel:a new platform for visual detection of metal ions[J]. Chem. Commun.,2011,47(33):9 312-9 314.
[11]BASTUS N G,COMENGE J,PUNTES V. Kinetically controlled seeded growth synthesis of citrate-stabilized gold nanoparticles of up to 200 nm:size focusing versus ostwald ripening[J]. Langmuir,2011,27(17):11 098-11 105.
[12]ZIEGLER C,EYCHMULLER A.Seeded growth synthesis of uniform gold nanoparticles with diameters of 15~300nm[J].J.Phys.Chem.C,2011,115(11):4 502-4 506.
[13]SAJANLAL P R,SREEPRASAD T S,NAIR A S,et al.Wires,plates,flowers,needles,and core-shells:diverse nanostructures of gold using polyaniline templates[J].Langmuir,2008,24(9):4 607-4 614.
[14]XIE J P,ZHANG Q B,LEE J Y,et al.The synthesis of SERS-active gold nanoflower tags for in vivo applications[J].ACS Nano,2008,2(12):2 473-2 480.
[15]ZHAO L L,JI X H,SUN X J,et al.Formation and stability of gold nanoflowers by the seeding approach:the effect of intraparticle ripening[J]. J. Phys. Chem. C,2009,113(38):16 645-16 651.
[16]GOBIN A M,WATKINS E M,QUEVEDO E,et al.Nearinfrared-resonant gold/gold sulfide nanoparticles as a photothermal cancer therapeutic agent[J]. Small,2010,6(6):745-752.
[17]XU F G,CUI K,SUN Y J,et al.Facile synthesis of urchin-like gold submicrostructures for nonenzymatic glucose sensing[J].Talanta,2010,82(5):1 845-1 852.
[18]DANIEL M C,ASTRUC D. Gold nanoparticles:assembly, supramolecular chemistry, quantum-size-related properties,and applications toward biology,catalysis,and nanotechnology[J].Chem.Rev.,2004,104(1):293-346.
[19]SAHA K,AGASTI S S,KIM C,et al.Gold nanoparticles in chemical and biological sensing[J]. Chem. Rev.,2012,112(5):2 739-2 779.
[20]LIU X Y,LIU M H,LUO Y C,et al.Strong metal-support interactions between gold nanoparticles and Zn O nanorods in CO oxidation[J]. J. Am. Chem. Soc.,2012,134(24):10 251-10 258.
[21]YANG L B,SHEN Y H,XIE A J.Synthesis of controllable-size core-shell Se@Ag and Se@Au nanoparticles in UV-irradiated TSA solution[J]. Eur. J. Inorg. Chem.,2010,2 007(8):1 128-1 134.
[22]LIN N,ZHANG W X,KOSHEL B M,et al. Spatially modulated two-photon luminescence from Si-Au coreshell nanowires[J]. J. Phys. Chem. C,2011,115(8):3 198-3 202.
[23]WU Z M,TANG M,LI X Y,et al.Surface faceting and compositional evolution of Pd@Au core-shell nanocrystals during in situ annealing[J]. Phys. Chem. Chem.Phys.,2019,21(6):3 134-3 139.
[24]TIRUVALAM R C,PRITCHARD J C,DIMITRATOS N.Aberration corrected analytical electron microscopy studies of sol-immobilized Au,Pd,Au{Pd}and Pd{Au}catalysts used for benzyl alcohol oxidation and hydrogen peroxide production[J]. Faraday Discuss.,2011,152(5):63-86.
[25]ZHANG H J,OKUNI J,TOSHIMA N.One-pot synthesis of Ag-Au bimetallic nanoparticles with Au shell and their high catalytic activity for glucose oxidation[J]. J.Collid.Interf.Sci.,2011,354(1):131-138.
[26]KUMAR G V P. Surface-enhanced Raman scattering studies of carbon nanotubes using Ag-core Au-shell nanoparticles[J]. J. Raman Spectrosc.,2009,40(12):2 069-2 073.
[27]QI G,ZHANG Y H.Synthesis of Ni@Au core-shell nanoparticles and its applications in ullmann reaction as a synergistic catalyst[J]. Chin. J. Struct. Chem.,2011,30(8):1 122-1 126.
[28]NADAGOUDA M N,VARMA R S.A greener synthesis of core(Fe,Cu)-shell(Au,Pt,Pd,and Ag)nanocrystals using aqueous vitamin[J].Cryst.Growth Des.,2007,7(12):2 582-2 587.
[29]SOM T,KARMAKAR B.Core-shell Au-Ag nanoparticles in dielectric nanocomposites with plasmon-enhanced fluorescence:a new paradigm in antimony glasses[J].Nano Res.,2009,2(8):607-616.
[30]MAO K,YANG Z G,LI J R,et al.A novel colorimetric biosensor based on non-aggregated Au@Ag core-shell nanoparticles for methamphetamine and cocaine detection[J].Talanta,2017,175(1):338-346.
[31]YU J W,MA Y N,YANG C X.SERS-active composite based on r GO and Au/Ag core-shell nanorods for analytical applications[J].Sensor.Actuat.B:Chem.,2018,254:182-188.
[32]ANH D T N,SINGH P,SHANKAR C,et al. Chargetransfer-induced suppression of galvanic replacement and synthesis of(Au@Ag)@Au double shell nanoparticles for highly uniform,robust and sensitive bioprobes[J].Appl.Phys.Lett.,2011,99(7):73 107-73 110.
[33]SHAHJAMALI M M,BOSMAN M,CAO S W,et al.Gold coating of silver nanoprisms[J]. Adv. Funct. Mater.,2012,22(4):849-854.
[34]SUDHEENDRA L,ORTALAN V,DEY S,et al.Plasmonic enhanced emissions from cubic Na YF4∶Yb∶Er/Tm nanophosphors[J].Chem. Mater.,2011,23(11):2 987-2 993.
[35]LOAIZA O A,JUBETE E,OCHOTECO E,et al. Gold coated ferric oxide nanoparticles based disposable magnetic genosensors for the detection of DNA hybridization processes[J]. Biosens. Bioelectron.,2011,26(5):2 194-2 200.
[36]LIU N,QIN W P,QIN G S,et al. Highly plasmon-enhanced upconversion emissions from Au@b-NaYF4∶Yb,Tm hybrid nanostructures[J]. Chem. Commun.,2011,47(27):7 671-7 673.
[37]ZHOU T,WU B Y,XING D.Bio-modified Fe3O4core/Au shell nanoparticles for targeting and multimodal imaging of cancer cells[J]. J. Mater. Chem.,2012,22(2):470-477.
[38]LI Z Q,LI X D,LIU Q Q,et al. Core/shell structured Na YF4∶Yb3+/Er3+/Gd3+nanorods with Au nanoparticles or shells for flexible amorphous silicon solar cells[J].Nanotechnology,2012,23(2):25 402-25 410.
[39]FUJII M,NAKANO T,IMAKITA K,et al.Upconversion luminescence of Er and Yb Codoped Na YF4nanoparticles with metal shells[J]. J. Phys. Chem. C,2013,117(2):1 113-1 120.
[40]WANG Z J,WU L N,LIANG H J,et al. Controllable synthesis of bifunctional Na YF4∶Yb3+/Ho3+@Si O2/Au nanoparticles with upconversion luminescence and high X-ray attenuation[J]. J. Alloy. Compd.,2011,509(37):9 144-9 149.
[41]LI Z Q,WANG L M,WANG Z Y.Modification of Na YF4∶Yb,Er@Si O2nanoparticles with gold nanocrystals for tunable green-to-red upconversion emissions[J].J.Phys.Chem.C,2011,115(8):3 291-3 296.
[42]RASCH M R,SOKOLOV K V,KORGEL B A. Limitations on the optical tunability of small diameter gold nanoshells[J].Langmuir,2009,25(19):11 777-11 785.
[43]PRIYAM A,IDRISA N M,ZHANG Y. Gold nanoshell coated Na YF4nanoparticles for simultaneously enhanced upconversion fluorescence and darkfield imaging[J]. J.Mater.Chem.,2012,22(3):960-965.
[44]WANG L Y,BAI J W,LI Y J,et al.Multifunctional nanoparticles displaying magnetization and Near-IR absorption[J]. Angew. Chem. Int. Ed.,2008,47(13):2 439-2 442.
[45]ZHANG H,LI Y J,IVANOV I A,et al.Plasmonic modulation of the upconversion fluorescence in Na YF4∶Yb/Tm hexaplate nanocrystals using gold nanoparticles or nanoshells[J]. Angew. Chem. Int. Ed.,2010,49(16):2 865-2 868.
[46]XIE H Y,ZHEN R,WANG B,et al. Fe3O4/Au core/shell nanoparticles modified with Ni2+-nitrilotriacetic acid specific to histidine-tagged proteins[J]. J. Phys.Chem.C,2010,114(11):4 825-4 830.
[47]LOU L,YU K,ZHANG Z L,et al. Facile methods for synthesis of core-shell structured and heterostructured Fe3O4@Au nanocomposites[J]. Appl. Surf. Sci.,2012,258(22):8 521-8 526.
[48]WANG Y,SHEN Y H,XIE A J.A simple method to construct bifunctional Fe3O4/Au hybrid nanostructures and tune their optical properties in the near-infrared region[J].J.Phys.Chem.C,2010,114(32):4 297-4 301.