硫化矿捕收剂的研究进展
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摘要
综述了硫化矿捕收剂的合成及浮选应用,混合捕收剂与组合用药的应用现状,捕收剂在硫化矿表面的作用机理。研究捕收剂分子结构和它们与矿物表面的作用机理,为硫化矿物新药剂的分子设计、开发与应用提供了理论指导。
The synthesis and application of the new sulphide ore collectors were reviewed,the application of mixed collectors and combined usage of reagents,the surface interaction mechanism of ores and collectors.Research on the collectors molecular structure and interaction on mineral surface provide theoretical guidance for the development and application of new collectors.
The synthesis and application of the new sulphide ore collectors were reviewed,the application of mixed collectors and combined usage of reagents,the surface interaction mechanism of ores and collectors.Research on the collectors molecular structure and interaction on mineral surface provide theoretical guidance for the development and application of new collectors.
引文
[1]Alijanianzadeh M,Saboury A A,Mansuri-torshizi H,et al.The inhibitory effect of some new synthesized xanthates onmushroom tyrosinase activities[J].Journal of Enzyme In-hibition and Medicinal Chemistry,2007,22(2):239-246.
[2]黄军.一种丁基黄原酸钠的合成工艺:CN,102050769A[P].2011-05-11.
[3]王永斌.胺基乙基黄原酸氰乙酯化合物和制备方法及其捕收剂:CN,102464600A[P].2012-05-23.
[4]谭鑫.乙硫氨酯合成的新工艺研究[D].长沙:中南大学,2011.
[5]袁露,钟宏,刘广义,等.N,N’-二乙氧羰基-O,O’-烷基二硫氨酯的合成及表征[J].高等学校化学学报,2011,32(7):1541-1544.
[6]李文风,陈雯.一种新型硫化矿捕收剂——二甲基二硫代氨基甲酸丙烯腈酯的合成及应用[J].金属矿山,2010,39(7):55-56,86.
[7]秦磊.新型硫化矿捕收剂P1Q1的研制与应用[D].武汉:武汉理工大学,2010.
[8]薛丁帅.新型酰肼二硫代甲酸类浮选剂在金川镍矿中的应用[D].兰州:兰州大学,2008.
[9]王彩虹.用酯105浮选酒钢桦树沟铜矿石的试验研究[J].金属矿山,2011(6):101-103.
[10]朱一民.异丁基铵黑药的合成及浮选效果[J].金属矿山,2010,39(9):68-70.
[11]朱一民.浮选药剂的同分异构原理在研究硫醇捕收剂中的应用[J].有色金属:选矿部分,2011(2):57-59.
[12]Huang Hongjun,Sun Wei.Effect of 2-aminothiophenol onthe separation of jamesonite and marmatite[J].Journal ofChina University of Mining Science and Technology,2010,20(3):425-427.
[13]程传杰,杨江明,申亮,等.一锅法合成三硫代碳酸酯[J].合成化学,2010,18(2):242-243.
[14]欧阳素勤.广西环江某高硫铅锌矿浮选工艺及杂质影响的量子化学研究[D].南宁:广西大学,2010.
[15]刘凤霞,韦根远,陈建华,等.新型捕收剂C08在六梅金矿的应用[J].黄金,2009,30(3):47-50.
[16]苏建芳,孙伟,黄红军,等.云南某复杂铅锌银硫化矿综合回收试验研究[J].有色金属:选矿部分,2011(6):8-12.
[17]彭会清,王江巍.安徽某多金属锌矿选矿工艺研究[J].湖南有色金属,2011,27(6):7-9,36.
[18]王晓慧,刘厚明,陈晓青.某多金属矿石选矿试验及新药剂作用机理研究[J].金属矿山,2011(10):99-104.
[19]McFadzean B,Castelyn D G,O’Connor C T.The effect ofmixed thiol collectors on the flotation of galena[J/OL].http://dx.doi.org/10.1016/j.mineng,2012-03-27.
[20]吕宏芝.某铅锌矿适宜选锌捕收剂的试验研究[J].采矿技术,2011,11(2):94-96.
[21]Makanza A T,Vermaak M K G,Davidtz J C.The flotationof auriferous pyrite with a mixture of collectors[J].Inter-national Journal of Mineral Processing,2008(86):85-93.
[22]Liu Guangyi,Zhong Hong,Xia Liuyin,et al.Improvingcopper flotation recovery from a refractory copper porphyryore by using ethoxycarbonyl thiourea as a collector[J].Minerals Engineering,2011(24):817-824.
[23]陈玉平,曾科,何名飞.使用MA捕收剂提高白牛厂铅锌矿浮选指标的研究[J].矿冶工程,2009,29(5):43-45.
[24]Caroline C Sui,Stephane H R Brienne,Zheng Hexu,et al.Xanthate adsorption on Pb contaminated pyrite[J].Inter-national Journal of Mineral Processing,1997(40):207-221.
[25]Li Weizhong,Qin Wenqing,Sun Wei,et al.Electrodeposi-tion of dixanthogen(TETD)on pyrite surface[J].Trans-actions of Nonferrous Metals Society of China,2007,17(1):154-158.
[26]Mukendi Kongolo,Mostafa Benzaazoua,Philippe de Do-nato,et al.The comparison between amine thioacetate andamyl xanthate collector performances for pyrite flotationand its application to tailings desulphurization[J].Miner-als Engineering,2004(17):505-515.
[27]Liu Runqing,Sun Wei,Hu Yuehua,et al.Surface chemi-cal study of the selective separation of chalcopyrite andmarmatite[J].Journal of China University of Mining Sci-ence and Technology,2010,20(4):542-545.
[28]Nagaraj D R,Brinen J S.SIMS Study of adsorption of col-lectors on pyrite[J].International Journal of Mineral Pro-cessing,2001(63):45-57.
[29]Bulu T G,Atak S.Role of dixanthogen on pyrite flotation:solubility,adsorption studies and Eh,FTIR measurements[J].Minerals&Mentallurgical Processing,2002,19(2):81-86.
[30]Zhang Qin,Hu Yuehua,Xu Jing,et al.FTIR spectroscop-ic study of electrochemical flotation of jamesonite-diethyl-dithiocarbamate system[J].Transactions of NonferrousMetals Society of China,2006,16(2):493-496.
[31]Pecina E T,Uribe A,Finch J A,et al.Mechanism of di-isobutyl dithiophosphinate adsorption onto galena and py-rite[J].Minerals Engineering,2006(19):904-911.
[32]Pecina E T,Uribe A,Nava F,et al.The role of copper andlead in the activation of pyrite in xanthate and non-xan-thate systems[J].Minerals Engineering,2006(19):172-179.
[33]Pecina-Trevifio E T,Uribe-Salas A,Nava-Alonso F,et al.On the sodium-diisobutyl dithiophosphinate(Aerophine3418A)interaction with activated and unactivated galenaand pyrite[J].International Journal of Mineral Process-ing,2003(71):201-217.
[34]孙伟,杨帆,胡岳华,等.前线轨道在黄铜矿捕收剂开发中的应用[J].中国有色金属学报,2009,19(8):1524-1532.
[35]Liu Guangyi,Zeng Hongbo,Lu Qingye,et al.Adsorption ofmercaptobenzoheterocyclic compounds on sulfide mineralsurfaces:A density functional theory study of structure-re-activity relations[J].Colloids and Surfaces A:Physico-chem Eng Aspects,2012(409):1-9.
[36]Bag B,Das B,Mishra B K.Geometrical optimization ofxanthate collectors with copper ions and their response toflotation[J].Minerals Engineering,2011(24):760-765.
[2]黄军.一种丁基黄原酸钠的合成工艺:CN,102050769A[P].2011-05-11.
[3]王永斌.胺基乙基黄原酸氰乙酯化合物和制备方法及其捕收剂:CN,102464600A[P].2012-05-23.
[4]谭鑫.乙硫氨酯合成的新工艺研究[D].长沙:中南大学,2011.
[5]袁露,钟宏,刘广义,等.N,N’-二乙氧羰基-O,O’-烷基二硫氨酯的合成及表征[J].高等学校化学学报,2011,32(7):1541-1544.
[6]李文风,陈雯.一种新型硫化矿捕收剂——二甲基二硫代氨基甲酸丙烯腈酯的合成及应用[J].金属矿山,2010,39(7):55-56,86.
[7]秦磊.新型硫化矿捕收剂P1Q1的研制与应用[D].武汉:武汉理工大学,2010.
[8]薛丁帅.新型酰肼二硫代甲酸类浮选剂在金川镍矿中的应用[D].兰州:兰州大学,2008.
[9]王彩虹.用酯105浮选酒钢桦树沟铜矿石的试验研究[J].金属矿山,2011(6):101-103.
[10]朱一民.异丁基铵黑药的合成及浮选效果[J].金属矿山,2010,39(9):68-70.
[11]朱一民.浮选药剂的同分异构原理在研究硫醇捕收剂中的应用[J].有色金属:选矿部分,2011(2):57-59.
[12]Huang Hongjun,Sun Wei.Effect of 2-aminothiophenol onthe separation of jamesonite and marmatite[J].Journal ofChina University of Mining Science and Technology,2010,20(3):425-427.
[13]程传杰,杨江明,申亮,等.一锅法合成三硫代碳酸酯[J].合成化学,2010,18(2):242-243.
[14]欧阳素勤.广西环江某高硫铅锌矿浮选工艺及杂质影响的量子化学研究[D].南宁:广西大学,2010.
[15]刘凤霞,韦根远,陈建华,等.新型捕收剂C08在六梅金矿的应用[J].黄金,2009,30(3):47-50.
[16]苏建芳,孙伟,黄红军,等.云南某复杂铅锌银硫化矿综合回收试验研究[J].有色金属:选矿部分,2011(6):8-12.
[17]彭会清,王江巍.安徽某多金属锌矿选矿工艺研究[J].湖南有色金属,2011,27(6):7-9,36.
[18]王晓慧,刘厚明,陈晓青.某多金属矿石选矿试验及新药剂作用机理研究[J].金属矿山,2011(10):99-104.
[19]McFadzean B,Castelyn D G,O’Connor C T.The effect ofmixed thiol collectors on the flotation of galena[J/OL].http://dx.doi.org/10.1016/j.mineng,2012-03-27.
[20]吕宏芝.某铅锌矿适宜选锌捕收剂的试验研究[J].采矿技术,2011,11(2):94-96.
[21]Makanza A T,Vermaak M K G,Davidtz J C.The flotationof auriferous pyrite with a mixture of collectors[J].Inter-national Journal of Mineral Processing,2008(86):85-93.
[22]Liu Guangyi,Zhong Hong,Xia Liuyin,et al.Improvingcopper flotation recovery from a refractory copper porphyryore by using ethoxycarbonyl thiourea as a collector[J].Minerals Engineering,2011(24):817-824.
[23]陈玉平,曾科,何名飞.使用MA捕收剂提高白牛厂铅锌矿浮选指标的研究[J].矿冶工程,2009,29(5):43-45.
[24]Caroline C Sui,Stephane H R Brienne,Zheng Hexu,et al.Xanthate adsorption on Pb contaminated pyrite[J].Inter-national Journal of Mineral Processing,1997(40):207-221.
[25]Li Weizhong,Qin Wenqing,Sun Wei,et al.Electrodeposi-tion of dixanthogen(TETD)on pyrite surface[J].Trans-actions of Nonferrous Metals Society of China,2007,17(1):154-158.
[26]Mukendi Kongolo,Mostafa Benzaazoua,Philippe de Do-nato,et al.The comparison between amine thioacetate andamyl xanthate collector performances for pyrite flotationand its application to tailings desulphurization[J].Miner-als Engineering,2004(17):505-515.
[27]Liu Runqing,Sun Wei,Hu Yuehua,et al.Surface chemi-cal study of the selective separation of chalcopyrite andmarmatite[J].Journal of China University of Mining Sci-ence and Technology,2010,20(4):542-545.
[28]Nagaraj D R,Brinen J S.SIMS Study of adsorption of col-lectors on pyrite[J].International Journal of Mineral Pro-cessing,2001(63):45-57.
[29]Bulu T G,Atak S.Role of dixanthogen on pyrite flotation:solubility,adsorption studies and Eh,FTIR measurements[J].Minerals&Mentallurgical Processing,2002,19(2):81-86.
[30]Zhang Qin,Hu Yuehua,Xu Jing,et al.FTIR spectroscop-ic study of electrochemical flotation of jamesonite-diethyl-dithiocarbamate system[J].Transactions of NonferrousMetals Society of China,2006,16(2):493-496.
[31]Pecina E T,Uribe A,Finch J A,et al.Mechanism of di-isobutyl dithiophosphinate adsorption onto galena and py-rite[J].Minerals Engineering,2006(19):904-911.
[32]Pecina E T,Uribe A,Nava F,et al.The role of copper andlead in the activation of pyrite in xanthate and non-xan-thate systems[J].Minerals Engineering,2006(19):172-179.
[33]Pecina-Trevifio E T,Uribe-Salas A,Nava-Alonso F,et al.On the sodium-diisobutyl dithiophosphinate(Aerophine3418A)interaction with activated and unactivated galenaand pyrite[J].International Journal of Mineral Process-ing,2003(71):201-217.
[34]孙伟,杨帆,胡岳华,等.前线轨道在黄铜矿捕收剂开发中的应用[J].中国有色金属学报,2009,19(8):1524-1532.
[35]Liu Guangyi,Zeng Hongbo,Lu Qingye,et al.Adsorption ofmercaptobenzoheterocyclic compounds on sulfide mineralsurfaces:A density functional theory study of structure-re-activity relations[J].Colloids and Surfaces A:Physico-chem Eng Aspects,2012(409):1-9.
[36]Bag B,Das B,Mishra B K.Geometrical optimization ofxanthate collectors with copper ions and their response toflotation[J].Minerals Engineering,2011(24):760-765.