铼的分析方法研究进展
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摘要
铼做为一种贵重的战略金属,已广泛应用于航空航天、石油化工和电子科技等领域,近年来其需求量持续增长。精确测定各类样品中的铼含量一直是项艰难的工作。光度法是最经典的铼测定方法之一,一直有学者对其改进,以提高其准确度和精密度;精密仪器如ICP-MS、XRF等,由于样品处理简单、准确度高正逐渐成为主要检测手段;铼的测定新方法如HPLC、RRS等,都有不同程度的研究进展。文章介绍了2009年~2013年以来国内外铼的分析测定方法研究进展,综述了各种铼分析测定方法的使用特点和范围。展望了铼分析方法的发展方向,并指出经济实用的痕量铼测定是今后研究的焦点。
Rhenium as a kind of precious strategic metal was widely used in Aerospace Industry,Petrochemical Industry,Electronics Technologyand so on,and its demand was outstripping supply in recent years. Accurate determination of rhenium in various types of samples always are difficult tasks. Spectrophotometry was one of the most classic methods for rhenium determination,so many researchers had improved the accuracy and precision of this method all the time. The method that would be a major way for rhenium determination by precision instruments such as ICP- MS and XRF,was getting more and more attention because of its higher accuracy and simpler pretreatment. In addition,some new methods such as HPLC and RRS were springing up and progressing steadily. A description is made of the method for rhenium determination published from 2009 to 2013. In this study,the characteristics of different methods and their applications were reviewed. The development direction on determination of rhenium was prospected. Moreover,the accurate and green method on the determination of trace rhenium should be focus on in future.
Rhenium as a kind of precious strategic metal was widely used in Aerospace Industry,Petrochemical Industry,Electronics Technologyand so on,and its demand was outstripping supply in recent years. Accurate determination of rhenium in various types of samples always are difficult tasks. Spectrophotometry was one of the most classic methods for rhenium determination,so many researchers had improved the accuracy and precision of this method all the time. The method that would be a major way for rhenium determination by precision instruments such as ICP- MS and XRF,was getting more and more attention because of its higher accuracy and simpler pretreatment. In addition,some new methods such as HPLC and RRS were springing up and progressing steadily. A description is made of the method for rhenium determination published from 2009 to 2013. In this study,the characteristics of different methods and their applications were reviewed. The development direction on determination of rhenium was prospected. Moreover,the accurate and green method on the determination of trace rhenium should be focus on in future.
引文
[1]Paul J Fink,Joshua L Miller,Douglas G Konitzer.Rhenium reduction-alloy design using an economically strategic element[J].JOM,2010,62(1):55-57.
[2]宾智勇,刘景槐,冉俊铭.铼的生产、应用与市场[J].湖南有色金属,2005,21(3)7-10.
[3]程挺宇,熊宁,彭楷元,杨海兵,殷晶川.铼及铼合金的应用现状及制造技术[J].稀有金属材料与工程,2009,38(2)373-376.
[4]骆宇时,刘世忠,孙凤礼.铼在单晶高温合金中强化机理的研究现状[J].材料导报,2005,19(8):55-58.
[5]Monya B.Radioactive bacteria attack cancer[EB/OL].http://www.nature.com/news/radioactivebacteria-attack-cancer-1,12841,2013-4-22.
[6]Serikbayeva A K,Telegusova N,Bekentayev B B.Recovery of valuable metals from industrial wastes.[J].Metalurgija,2013,52(4):515-517.
[7]邓桂春,腾洪辉,刘国杰,侯松嵋,张渝阳,王鑫,臧树良.铼的分离与分析研究进展[J].稀有金属,2004,28(4):771-775.
[8]Evdokimova O V,Pechishcheva N V,Shunyaev K.Yu.Up to Date Methods for the Determination of Rhenium[J].Journal of Analytical Chemistry,2012,67(9):741-753.
[9]邱朝辉,钟宏,曹占芳,姚禛.铼的分离分析方法研究进展[J].稀有金属与硬质合金,2010,38(1):56-59.
[10]冯宝奇,郭金亮,马高峰,王伟,白宏斌,田莎莎,谢亚宁,王子川.铼的分离提取技术研究[J].中国钼业,2013,37(1):12-15.
[11]邓桂春,吕改芳,鞠政楠,叶琳琳.催化动力学分光光度法测定钼冶炼烟尘吸收液中铼[J].理化检验.化学分册.2012(48):1137-1139.
[12]Tzvetkova Christina,Bozhkov Ognyan.Study of Rhenium Phytoaccumulation in White Clover(Trifolium Repens)and Water Fern(Salvinia Natans L)[C]//Proceedings of the 7th International Conference on ENVIRONMENT,ECOSYSTEMS and DEVELOPMENT.Spain:Tenerife,2009:123-126.
[13]周恺,孙宝莲,李波,张磊.高含量铼的紫外分光光度法测定研究[J].中国无机分析化学,2011,1(3):46-49.
[14]周煜,谭艳山,朱利亚牛春林,汤云正,李玉仙,李美菊,万仲建,王前会.硫脲光度法测定粗铼酸钾中铼时钼干扰的消除[J].冶金分析2013,33(9):57-60.
[15]牟婉君,刘国平,李兴亮,魏洪源.聚乙二醇双水相萃取光度法测定铼[J].化学研究与应用,2012,24(9):1402-1404.
[16]Plevaka A V,Troshkina I D,Zemskova L A,Voit A V,Rhenium sorption by fibrous chitosan-carbon materials[J].Russ J Inorg Chem,2009,(54)7:1168-1171.
[17]李亚男,王秀琴.砂岩型铀矿地质样品中铼的测定[J].铀矿地质,1997,13(5):30.
[18]魏良江.电感耦合等离子体原子发射光谱分析研究进展[J].广东微量元素科学,2010,17(4):1-8.
[19]杨金辉,杨江柳,胡鄂明,邓喆,柳建祥.电感耦合等离子体发射光谱法(ICP-AES)测定铀矿石中微量钪、硒、铼[J].南华大学学报,2004,18(4):83-85.
[20]冯艳秋,白文娟.ICP-AES法测定单晶高温合金中徕元素的分析方法研究[J].现代科学仪器,2009,5(10):97-100.
[21]张永中,杨则恒,戚月花,张晓天.ICP-AES法快速测定铜冶炼废酸中铼、钼、硒含量的研究[J].安徽化工,2011,37(3):72-74.
[22]赵庆令,李清彩.电感耦合等离子体发射光谱法测定钼矿石和铜矿石中的铼[J].岩矿测试,2009,28(6):593-594.
[23]张磊,李波,孙宝莲,周恺.电感耦合等离子体原子发射光谱标准加入法测定钼精矿及烟道灰中的铼[J].分析化学,2011,39(8):1291-1292.
[24]Manshilin V I,Vinokourov E K,Kapelyushny S A.Determination of Pt,Pd,Rh in the samples of spent catalyst by atomic emission spectrometry with inductively coupled plasma[J].Methods and objects of chemical analysis,2009,4(1):97-100.
[25]罗善霞,焦圣兵.地质样品中铼的分离和测定方法研究进展[J].冶金分析,2013,33(2):22-27.
[26]Hu Zhaochu,Liu Yongsheng,Li Ming,Gao Shan,Zhao Laishi,Applications of LA-ICP-MS in the elemental analyses of geological samples[J].Chinese Science Bulletin,2013,58(32):3863-3878.
[27]Tagami K,Uchida S.Rhenium Contents in Japanese River Waters Measured by Isotope Dilution ICP-MS and the Relationship of Re with Some Chemical Components[J].J Nucl Sci Technol,2008,Supplment 6:128-132.
[28]Hu Zhaochu,Liu Yongsheng,Li Ming,Gao Shan,Zhao Laishi,Results for Rarely Determined Elements in MPI-DING,USGS and NIST SRM Glasses Using Laser Ablation ICP-MS[J].Geo Standards and Geoanalyticak Research,2009,33(3):319-335.
[29]张然,王学田.ICP-MS法测定地质样品中铼含量[J].江西化工,2011,(1):125-128.
[30]苟体忠,钟宏,漆亮,冷成彪,吴孔文,任涛.地质样品中痕量铼的异戊醇萃取研究[J].分析测试学报,2009,28(9):1027-1030.
[31]Li Jie,Zhong Lifeng,Tu Xianglin,Liang Xirong,Xu Jifeng.Determination of rhenium content in molybdenite by ICP–MS after separation of the major matrix by solvent extraction with N-benzoyl-N-phenylhydroxalamine[J].Talanta,2010,8(3):954-958.
[32]Palesskii S V,Nikolaeva I V,Koz’menko O A,Anoshin G N.Determination of platinum-group elements and rhenium in standard geological samples by isotope dilution with mass-spectrometric ending[J].Journal of Analytical Chemistry,2009,64(3):272–276.
[33]程秀花,黎卫亮.电感耦合等离子体质谱法测定钼矿石和钼精矿中铼[J].冶金分析,2013,33(1):54-58.
[34]任志海,夏照明,李树强.电感耦合等离子体质谱法(ICP-MS)测定钼矿石中的铼[J].中国无机分析化学,2013,3(3):27-29.
[35]李超,屈文俊,王登红,陈郑辉,杜安道,张长青.沥青样品铼-锇同位素分析溶解实验研究[J].岩矿测试,2011,30(6):688-694.
[36]Pearce C R,Cohen A S,and Parkinson I J.Quantitative Separation of Molybdenum and Rhenium from Geological Materials for Isotopic Determination by MCICP-MS[J].Geo Standards and Geoanalyticak Research,2009,33(2):219-229.
[37]Tao Yan,Li Chusi,Hu Ruizhong,Qi Liang,Qu Wenjun,Du Andao.Re–Os isotopic constraints on the genesis of the Limahe Ni–Cu deposit in the Emeishan large igneous province,SW China[J].Lithos,2010,119(2):P137–146.
[38]Chopabaeva N N,Ergozhin E E,Tasmagambet A T,Nikitin A I.Sorption of perrhenate anions by lignin anion exchangers[J].Solid Fuel Chemistry,2009,43(2):99-102.
[39]宋如晟,钟鸣,涂建球.安徽省金寨县沙坪沟钼矿中贵重分散元素铼的分析[J].安徽地质,2011,21(1):32-34.
[40]田建平,戈润滔,华磊.催化极谱法测定矿石中微量铼方法改进[J].云南地质,2011.30(2):204-207.
[41]Wang Shengmian,Wen Guiqing,Li Tingsheng,Liao Xianjiu,Liang Aihui,Jiang Zhiliang.A Simple and Selective Nanocatalytic Resonance Rayleigh Scattering Spectral Method for the Determination of Trace Re[J/OL].Journal of Spectroscopy.2013,2013:5.http://www.hindawi.com/journals/jspec/2013/646050/ref/
[42]Borisova L V,Demin Yu V,Gatinskaya N G,Ermakov V V,Ryabukhin V A,Bozhkov O D.Determination of rhenium in plant materials[J].J Anal Chem,2005,60(1):86-91.
[43]Kolpakova N A,Buinovskii A S,Mel’nikova I A.Determination of rhenium in gold-containing ores by Xray fluorescence spectrometry[J].J Anal Chem,2009,64(2):144-148.
[44]Mladenov M,Jordanov J.Preparation of secondary standards for X-ray fluorescence analysis in proudction of molybdenum concentrat[J].Journal of the University of Chemical Technology and Metallurgy,2012,47(1):103-108.
[45]牟婉君,刘国平,熊小玲.反相高效液相色谱同时测定铼与钼的方法研究[J].分析测试技术与仪器,2009,15(1):26-29.
[2]宾智勇,刘景槐,冉俊铭.铼的生产、应用与市场[J].湖南有色金属,2005,21(3)7-10.
[3]程挺宇,熊宁,彭楷元,杨海兵,殷晶川.铼及铼合金的应用现状及制造技术[J].稀有金属材料与工程,2009,38(2)373-376.
[4]骆宇时,刘世忠,孙凤礼.铼在单晶高温合金中强化机理的研究现状[J].材料导报,2005,19(8):55-58.
[5]Monya B.Radioactive bacteria attack cancer[EB/OL].http://www.nature.com/news/radioactivebacteria-attack-cancer-1,12841,2013-4-22.
[6]Serikbayeva A K,Telegusova N,Bekentayev B B.Recovery of valuable metals from industrial wastes.[J].Metalurgija,2013,52(4):515-517.
[7]邓桂春,腾洪辉,刘国杰,侯松嵋,张渝阳,王鑫,臧树良.铼的分离与分析研究进展[J].稀有金属,2004,28(4):771-775.
[8]Evdokimova O V,Pechishcheva N V,Shunyaev K.Yu.Up to Date Methods for the Determination of Rhenium[J].Journal of Analytical Chemistry,2012,67(9):741-753.
[9]邱朝辉,钟宏,曹占芳,姚禛.铼的分离分析方法研究进展[J].稀有金属与硬质合金,2010,38(1):56-59.
[10]冯宝奇,郭金亮,马高峰,王伟,白宏斌,田莎莎,谢亚宁,王子川.铼的分离提取技术研究[J].中国钼业,2013,37(1):12-15.
[11]邓桂春,吕改芳,鞠政楠,叶琳琳.催化动力学分光光度法测定钼冶炼烟尘吸收液中铼[J].理化检验.化学分册.2012(48):1137-1139.
[12]Tzvetkova Christina,Bozhkov Ognyan.Study of Rhenium Phytoaccumulation in White Clover(Trifolium Repens)and Water Fern(Salvinia Natans L)[C]//Proceedings of the 7th International Conference on ENVIRONMENT,ECOSYSTEMS and DEVELOPMENT.Spain:Tenerife,2009:123-126.
[13]周恺,孙宝莲,李波,张磊.高含量铼的紫外分光光度法测定研究[J].中国无机分析化学,2011,1(3):46-49.
[14]周煜,谭艳山,朱利亚牛春林,汤云正,李玉仙,李美菊,万仲建,王前会.硫脲光度法测定粗铼酸钾中铼时钼干扰的消除[J].冶金分析2013,33(9):57-60.
[15]牟婉君,刘国平,李兴亮,魏洪源.聚乙二醇双水相萃取光度法测定铼[J].化学研究与应用,2012,24(9):1402-1404.
[16]Plevaka A V,Troshkina I D,Zemskova L A,Voit A V,Rhenium sorption by fibrous chitosan-carbon materials[J].Russ J Inorg Chem,2009,(54)7:1168-1171.
[17]李亚男,王秀琴.砂岩型铀矿地质样品中铼的测定[J].铀矿地质,1997,13(5):30.
[18]魏良江.电感耦合等离子体原子发射光谱分析研究进展[J].广东微量元素科学,2010,17(4):1-8.
[19]杨金辉,杨江柳,胡鄂明,邓喆,柳建祥.电感耦合等离子体发射光谱法(ICP-AES)测定铀矿石中微量钪、硒、铼[J].南华大学学报,2004,18(4):83-85.
[20]冯艳秋,白文娟.ICP-AES法测定单晶高温合金中徕元素的分析方法研究[J].现代科学仪器,2009,5(10):97-100.
[21]张永中,杨则恒,戚月花,张晓天.ICP-AES法快速测定铜冶炼废酸中铼、钼、硒含量的研究[J].安徽化工,2011,37(3):72-74.
[22]赵庆令,李清彩.电感耦合等离子体发射光谱法测定钼矿石和铜矿石中的铼[J].岩矿测试,2009,28(6):593-594.
[23]张磊,李波,孙宝莲,周恺.电感耦合等离子体原子发射光谱标准加入法测定钼精矿及烟道灰中的铼[J].分析化学,2011,39(8):1291-1292.
[24]Manshilin V I,Vinokourov E K,Kapelyushny S A.Determination of Pt,Pd,Rh in the samples of spent catalyst by atomic emission spectrometry with inductively coupled plasma[J].Methods and objects of chemical analysis,2009,4(1):97-100.
[25]罗善霞,焦圣兵.地质样品中铼的分离和测定方法研究进展[J].冶金分析,2013,33(2):22-27.
[26]Hu Zhaochu,Liu Yongsheng,Li Ming,Gao Shan,Zhao Laishi,Applications of LA-ICP-MS in the elemental analyses of geological samples[J].Chinese Science Bulletin,2013,58(32):3863-3878.
[27]Tagami K,Uchida S.Rhenium Contents in Japanese River Waters Measured by Isotope Dilution ICP-MS and the Relationship of Re with Some Chemical Components[J].J Nucl Sci Technol,2008,Supplment 6:128-132.
[28]Hu Zhaochu,Liu Yongsheng,Li Ming,Gao Shan,Zhao Laishi,Results for Rarely Determined Elements in MPI-DING,USGS and NIST SRM Glasses Using Laser Ablation ICP-MS[J].Geo Standards and Geoanalyticak Research,2009,33(3):319-335.
[29]张然,王学田.ICP-MS法测定地质样品中铼含量[J].江西化工,2011,(1):125-128.
[30]苟体忠,钟宏,漆亮,冷成彪,吴孔文,任涛.地质样品中痕量铼的异戊醇萃取研究[J].分析测试学报,2009,28(9):1027-1030.
[31]Li Jie,Zhong Lifeng,Tu Xianglin,Liang Xirong,Xu Jifeng.Determination of rhenium content in molybdenite by ICP–MS after separation of the major matrix by solvent extraction with N-benzoyl-N-phenylhydroxalamine[J].Talanta,2010,8(3):954-958.
[32]Palesskii S V,Nikolaeva I V,Koz’menko O A,Anoshin G N.Determination of platinum-group elements and rhenium in standard geological samples by isotope dilution with mass-spectrometric ending[J].Journal of Analytical Chemistry,2009,64(3):272–276.
[33]程秀花,黎卫亮.电感耦合等离子体质谱法测定钼矿石和钼精矿中铼[J].冶金分析,2013,33(1):54-58.
[34]任志海,夏照明,李树强.电感耦合等离子体质谱法(ICP-MS)测定钼矿石中的铼[J].中国无机分析化学,2013,3(3):27-29.
[35]李超,屈文俊,王登红,陈郑辉,杜安道,张长青.沥青样品铼-锇同位素分析溶解实验研究[J].岩矿测试,2011,30(6):688-694.
[36]Pearce C R,Cohen A S,and Parkinson I J.Quantitative Separation of Molybdenum and Rhenium from Geological Materials for Isotopic Determination by MCICP-MS[J].Geo Standards and Geoanalyticak Research,2009,33(2):219-229.
[37]Tao Yan,Li Chusi,Hu Ruizhong,Qi Liang,Qu Wenjun,Du Andao.Re–Os isotopic constraints on the genesis of the Limahe Ni–Cu deposit in the Emeishan large igneous province,SW China[J].Lithos,2010,119(2):P137–146.
[38]Chopabaeva N N,Ergozhin E E,Tasmagambet A T,Nikitin A I.Sorption of perrhenate anions by lignin anion exchangers[J].Solid Fuel Chemistry,2009,43(2):99-102.
[39]宋如晟,钟鸣,涂建球.安徽省金寨县沙坪沟钼矿中贵重分散元素铼的分析[J].安徽地质,2011,21(1):32-34.
[40]田建平,戈润滔,华磊.催化极谱法测定矿石中微量铼方法改进[J].云南地质,2011.30(2):204-207.
[41]Wang Shengmian,Wen Guiqing,Li Tingsheng,Liao Xianjiu,Liang Aihui,Jiang Zhiliang.A Simple and Selective Nanocatalytic Resonance Rayleigh Scattering Spectral Method for the Determination of Trace Re[J/OL].Journal of Spectroscopy.2013,2013:5.http://www.hindawi.com/journals/jspec/2013/646050/ref/
[42]Borisova L V,Demin Yu V,Gatinskaya N G,Ermakov V V,Ryabukhin V A,Bozhkov O D.Determination of rhenium in plant materials[J].J Anal Chem,2005,60(1):86-91.
[43]Kolpakova N A,Buinovskii A S,Mel’nikova I A.Determination of rhenium in gold-containing ores by Xray fluorescence spectrometry[J].J Anal Chem,2009,64(2):144-148.
[44]Mladenov M,Jordanov J.Preparation of secondary standards for X-ray fluorescence analysis in proudction of molybdenum concentrat[J].Journal of the University of Chemical Technology and Metallurgy,2012,47(1):103-108.
[45]牟婉君,刘国平,熊小玲.反相高效液相色谱同时测定铼与钼的方法研究[J].分析测试技术与仪器,2009,15(1):26-29.