摘要
对铝硅活塞合金用Al-P系列晶种合金的制备方法、组织特点、应用原理和细化作用等方面进行了系统介绍。在介绍铝硅活塞用Al-P晶种合金研究进展的同时,提出了面临的挑战和机遇,从而进一步推动该领域内晶种合金的发展。
This paper systematically introduces the fabrication methods, typical structures, applied principles and refining effects of Al-P series master alloys which have extensive applications in Al-Si piston alloys. Meanwhile, the confronted challenges and opportunities at current situations are put forward for driving the development of master alloys in this field.
引文
[1]李言祥.材料加工原理[M].北京:清华大学出版社,2005.LI Yan-xiang.Principle of Material Processing[M].Beijing:Tsinghua University Press,2005.
[2]《铸造有色金属及其熔炼》联合编写组.铸造有色合金及其熔炼[M].北京:国防工业出版社,1980.“Casting Nonferrous Metals and their Smelting”Joint Compiling Group.Casting Nonferrous Metals and Their Smelting[M].Beijing:National Defence Industry Press,1980.
[3]张俊红,任智森,赵群,等.变质工艺影响过共晶Al-Si合金初晶硅细化的研究[J].轻合金,2006(10):62-65.ZHANG Jun-hong,REN Zhi-sen,ZHAO Qun,et al.Effect of Modification Process on the Refinement of Primary Si in Hypereutectic Al-Si Alloy[J].Light Metals,2006(10):62-65.
[4]赵爱民,毛卫民,甄子胜,等.冷却速度对过共晶铝硅合金凝固组织和耐磨性能的影响[J].中国有色金属学报,2001,11(5):827-832.ZHAO Ai-min,MAO Wei-min,ZHEN Zi-sheng,et al.Effect of Cooling Rate on the Solidification Structure and Wear Resistance of Hypereutectic Al-Si Alloy[J].Chinese Journal of Nonferrous Metals,2001,11(5):827-832.
[5]张蓉,黄太文,刘林.过共晶Al-Si合金熔体中初生硅生长特性[J].中国有色金属学报,2004,14(2):262-266.ZHANG Rong,HUANG Tai-wen,LIU Lin.Growth Characterization of Primary Si in Hypereutectic Al-Si alloy[J].Chinese Journal of Nonferrous Metals,2004,14(2):262-266.
[6]HERNáNDEZ F C Robles,SOKOLOWSKI J H.Comparison Among Chemical and Electromagnetic Stirring and Vibration Melt Treatments for Al-Si Hypereutectic Alloys[J].Journal of Alloys and Compounds,2006,426(1/2):205-212.
[7]JIANG Q C,XU C L,LU M,et al.Effect of New Al-P-Ti-Ti C-Y Modifier on Primary Silicon in Hypereutectic Al-Si Alloys[J].Materials Letters,2005,59(6):624-628.
[8]MAENG D Y,LEE J H,WON C W,et al.The Effects of Processing Parameters on the Microstructure and Mechanical Properties of Modified B390 Alloy in Direct Squeeze Casting[J].Journal of Materials Processing Technology,2000,105(1/2):196-203.
[9]YOON S C,HONG S J,HONG S I,et al.Mechanical Properties of Equal Channel Angular Pressed Powder Extrudates of a Rapidly Solidified Hypereutectic Al-20 wt%Si Alloy[J].Materials Science and Engineering A,2007,449/450/451:966-970.
[10]APAYDIN N,SMITH R W.Microstructural Characterization of Rapid Solidified Al-Si Alloys[J].Materials Science and Engineering,1988,98:149-152.
[11]UZUN O,KARAASLAN T,GOGEBAKAN M,et al.Handness and Microstructural Characteristics of Rapidly Solidified Al-8-16wt.%Si Alloys[J].Journal of Alloys and Compounds,2004,376(1/2):149-157.
[12]MATSUURA K,KUDOH M,KINOSHITA H,et al.Precipitation of Si Particles in a Super-rapidly Solidified Al-Si Hypereutectic Alloy[J].Materials Chemistry and Physics,2003,81(2/3):393-395.
[13]FENG H K,YU S R,LI Y L,et al.Effect of Ultrasonic Treatment on Microstructures of Hypereutectic Al-Si Alloy.Journal of Materials Processing Technology,2008,208(1/2/3):330-335.
[14]LU D H,JIANG Y H,GUAN G S,et al.Refinement of Primary Si in Hypereutectic Al-Si alloy by Electromagnetic Stirring[J].Journal of Materials Processing Technology,2007,189(1/2/3):13-18.
[15]ABU-DHEIR N,KHRAISHEH M,SAITO K,et al.Silicon Morphology Modification in the Eutectic Al-Si Alloy Using Mechanical Mold Vibration[J].Materials Science and Engineering A,2005,393(1/2):109-117.
[16]ADDAMIANO A.On the Preparation of the Phosphides of Aluminum,Gallium and Indium[J].Journal of the American Chemical Society,1960,82(7):1537-1540.
[17]HO C R,CANTOR B.Heterogeneous Nucleation of Solidification of Si in Al-Si and Al-Si-P Alloys[J].Acta Metallurgica et Materialia,1995,43(8):3231-3246.
[18]CANTOR B.Impurity Effects on Heterogeneous Nucleation[J].Materials Science and Engineering A,1997,226/227/228:151-156.
[19]杨伏良,甘卫平,陈招科.高硅铝合金几种常见制备方法及其细化机理[J].材料导报,2005,19(5):42-45.YANG Fu-liang,GAN Wei-ping,CHEN Zhao-ke.Several Preparation Methods and Refinement Mechanism of High-Si Aluminium Alloys[J].Materials Review,2005,19(5):42-45.
[20]王泽华,毛协民,张金龙,等.Sr-PM复合变质过共晶铝硅合金[J].特种铸造及有色合金,2005,25(4):241-243.WANG Ze-hua,MAO Xie-min,ZHANG Jin-long,et al.Complex Modification of Hypereutectic Al-Si Alloy by Sr-PM[J].Special Casting&Nonferrous Alloys,2005,25(4):241-243.
[21]ZHANG H H,DUAN H L,SHAO G J,et al.Microstructure and Mechanical Properties of Hypereutectic Al-Si Alloy Modified with Cu-P[J].Rare Metals,2008,27(1):59-63.
[22]武玉英,刘相法,刘相俊,等.低熔点Cu-P基中间合金及其变质效果[J].特种铸造及有色合金,2004(3):69-70.WU Yu-ying,LIU Xiang-fa,LIU Xiang-jun,et al.A Low Melting Point Cu-P Based Master Alloy and Its Modification Efficiency[J].Special Casting&Nonferrous Alloys,2004(3):69-70.
[23]WOLFGANG S.A New Method for the Refinement of Primary Si of Hypereutectic Al-Si Alloys in Direct Chill and Ingot Casting[J].Light Metals,1993:815-820.
[24]赵永治,高泽生.过共晶Al-Si合金连续铸造中初晶硅细化的新方法[J].轻合金加工技术,1995,23(10):5-8.ZHAO Yong-zhi,GAO Ze-sheng.A New Method for Refinement of Silicon in the Continuous Casting of Eutectic Al-Si Alloy[J].Light Alloy Fabrication Technology,1995,23(10):5-8.
[25]王德满,郑子樵,石春生,等.熔铸法生产的磷变质剂对过共晶铝-硅合金组织和性能的影响[J].轻合金加工技术,1995,23(9):9-12.WANG De-man,ZHENG Zi-qiao,SHI Chun-sheng,et al.The Influence of Phosphorus Metamorphic Agent on the Microstructure and Properties of Eutectic Al-Si Alloy[J].Light Alloy Fabrication Technology,1995,23(9):9-12.
[26]王德满,赵海英,孙兆霞,等.一种新型过共晶Al-Si合金变质剂[J].轻金属,1997(7):50-53.WANG De-man,ZHAO Hai-ying,SUN Zhao-xia,et al.A New Modifier for Hypereutectic Al-Si Alloy[J].Light Metals,1997(7):50-53.
[27]KYFFIN W J,RAINFORTH W M,JONES H.The Formation of Aluminum Phosphide in Aluminum Melt Treated with an Al-Fe-P Inoculant Addition[J].Zeitschrift für Metallkunde,2001,92(4):396-398.
[28]KYFFIN W J,RAINFORTH W M,JONES H.Effect of Phosphorus Additions on the Spacing between Primary Silicon Particles in a Bridgman Solidified Hypereutectic Al-Si Alloy[J].Journal of Materials Science,2001,36(11):2667-2672.
[29]刘相法,齐广慧,韩延峰,等.Al-P中间合金变质剂在Al-Si活塞合金中的应用[J].内燃机配件,2001(6):14-17.LIU Xiang-fa,QI Guang-hui,HAN Yan-feng,et al.Application of Al-P Master Alloy in Al-Si Piston Alloy[J].Internal Combustion Engine Parts,2001(6):14-17.
[30]QIN J Y,ZUO Min,GU T,et al.The Featured Local Structural Units in Liquid Al80Si15P5 Alloy and Their Relationship with Si Modification[J].Journal of Alloys and Compounds,2010,492(1/2):525-528.
[31]朱向镇.Al-Si-X-P熔体中Al-P团簇演变行为与化学稳定性的研究[D].济南:山东大学,2016.ZHU Xiang-zhen.Study of Evolution and Chemistry Stability of Al-P Clusters in Al-Si-X-P melt[D].Jinan:Doctoral Dissertation of Shandong University,2009.
[32]ZHU X,JIANG W,LI M,et al.The Effect of Mg Adding Order on the Liquid Structure and Solidified Microstructure of the Al-Si-Mg-P Alloy:An Experiment and ab Initio Study[J].Metals,2015,5(1):40-51.
[33]乔进国.Al-P-Si中间合金及其变质处理技术的研究[D].济南:山东大学,2005.QIAO Jin-guo.Study of Al-P-Si Master Alloy and Its Modification Treatment[D].Jinan:Master's Dissertation of Shandong University,2005.
[34]ZUO Min,LIU Xiang-fa.Twin Growth Mechanism of Al P Hexagonal Platelets in an Al-Si Melt[J].Crystal Growth&Design,2010,10:2443-2446.
[35]刘相法,侯静,李冲,等.一种铝-镁-磷中间合金及其制备方法:中国,ZL201110264218.4[P].LIU Xiang-fa,HOU Jing,LI Chong,et al.An Al-Mg-PIntermediate Alloy and Its Preparation Method:China,ZL201110264218.4[P].
[36]侯静.Al-P中间合金对含Si镁合金细化与变质行为的研究[D].济南:山东大学,2012.HOU Jing.Study of Refinement and Modification Effect of Al-P Master Alloy on Magnesium Alloy with Si Containing[D].Jinan:Master's Dissertation of Shandong University,2012.
[37]刘相法,左敏,姜琨,等.一种铝-锆-磷中间合金及其制备方法:中国,ZL200910016834.0[P].LIU Xiang-fa,ZUO Min,JIANG Kun,et al.An Al-Zr-PIntermediate Alloy and Its Preparation Method:China,ZL200910016834.0[P].
[38]ZUO Min,JIANG Kun,LIU Xiang-fa.Refinement of Hypereutectic Al-Si Alloy by a New Al-Zr-P Master Alloy[J].Journal of Alloys and Compounds,2010,503(2):26-30.
[39]包国菊.Zr(RE)P在铝熔体中的反应合成与演变机制[D].济南:山东大学,2013.BAO Guo-ju.Reaction Synthesis and Evolution Mechanism of Zr(RE)P in Aluminum Melt[D].Jinan:Master's Dissertation of Shandong University,2013.
[40]ZHOU X L,WU Y Y,LI Y F,et al.Absorbing Formation Mechanism of Al P on Ti B2 Substrate and Their Application as High-efficiency Nucleating Agent in Al-45Si alloy[J].Journal of Alloys and Compounds,2017,693:853-858.
[41]XU C L,YANG Y F.Effect of Al-P-Ti-Ti C-Nd2O3Modifier on the Microstructure and Mechanical Properties of Hypereutectic Al-20 wt.%Si Alloy[J].Materials Science&Engineering A,2007,452/453(24):341-346.
[42]戴洪尚.超高硅铝合金中硅相的细化与界面性质研究[D].济南:山东大学,2009.DAI Hong-shang.Study on the Properties of Silicon Phase and Interfacial Properties of High Silicon Aluminum Alloys[D].Jinan:Doctoral Dissertation of Shandong University,2009.
[43]TEBIB M,SAMUEL A M,AJERSCH F,et al.Effect of P and Sr Additions on the Microstructure of Hypereutectic Al-15Si-14Mg-4Cu Alloy[J].Materials Characterization,2014,89:112-123.
[44]LIU G,LI G,CAI A,et al.The Influence of Strontium Addition on Wear Properties of Al-20 wt%Si Alloys under Dry Reciprocating Sliding Condition[J].Materials&Design,2011,32(1):121-126.
[45]VIJEESH V,NARAYAN PRABHU K.Review of Microstructure Evolution in Hypereutectic Al-Si Alloys and Its Effect on Wear Properties[J].Trans Indian Inst Met,2014,67(1):1-18.
[46]陈亮宇.过共晶铝硅合金之初晶硅细化效果研究[D].台湾:大同大学材料工程学系所,2011.CHEN Liang-yu.Study of Refinement of Primary Si in Hypereutectic Al-Si Alloy[D].Taiwan:Dissertation,Department of Material Engineering,Datong University,2011.
[47]卢绍龙,马幼平.过共晶Al-Si合金变质处理研究进展[J].轻合金加工技术,2009,37(8):5-8.LU Shao-long,MA You-ping.Research Progress of Modification of Hypereutectic Al-Si Alloy[J].Light Alloy Fabrication Technology,2009,37(8):5-8.