黏土基催化剂的制备及在处理难降解有机废水中的研究进展
|
摘要
黏土因一系列优异性能而被广泛应用于黏土基吸附剂及催化剂的制备,并用于废水中难降解有机物的降解研究。系统总结了黏土基非均相催化剂的制备方法,阐述了黏土基非均相催化剂在难降解废水处理领域的研究现状。其中黏土基非均相催化剂的分离、催化剂形貌的控制、活性组分的浸出问题、难降解有机物降解过程动力学及机理等方面的问题仍然是今后研究的重点。
Clay has been widely used in the preparation of clay supported adsorbents and catalysts due to a serious of excellent properties.Those clay products have been widely applied to the degradation of refractory organic wastewater.The preparation methods of heterogeneous catalysts based on clay were systematically summarized,and the research status of refractory wastewater degradation based clay heterogeneous catalysts was introduced.The separation of heterogeneous clay-catalysts,control of the morphology,leaching of the active components,kinetics and mechanism of degradation of refractory organic wastewater were still the focus of future research.
Clay has been widely used in the preparation of clay supported adsorbents and catalysts due to a serious of excellent properties.Those clay products have been widely applied to the degradation of refractory organic wastewater.The preparation methods of heterogeneous catalysts based on clay were systematically summarized,and the research status of refractory wastewater degradation based clay heterogeneous catalysts was introduced.The separation of heterogeneous clay-catalysts,control of the morphology,leaching of the active components,kinetics and mechanism of degradation of refractory organic wastewater were still the focus of future research.
引文
[1]Muthuvel I,Krishnakumar B,Swaminathan M.Solar active fire clay based hetero-fenton catalyst over a wide pH range for degradation of acid violet 7[J].Journal of Environmental Science,2012,24(3):529-535.
[2]Herney-Ramirez J,Vicente M A,Madeira L M.Heterogeneous photo-fenton oxidation with pillared clay-based catalysts for wastewater treatment:a review[J].Applied Catalysis B Environmental,2010,98(1-2):10-26.
[3]Hassan H,Hameed B H.Fe-clay as effective heterogeneous fenton catalyst for the decolorization of reactive blue 4[J].Chemical Engineering Journal,2011,171(3):912-918.
[4]Ramirez J H,Costa C A,Madeira L M,et al.Fenton-like oxidation of orangeⅡsolutions using heterogeneous catalysts based on saponite clay[J].Applied Catalysis B Environmental,2007,71(1-2):44-56.
[5]Navalon S,Alvaro M,Garcia H,et al.Heterogeneous fenton catalysts based on clays,silicas and zeolites[J].Cheminform,2010,99(1-2):1-26.
[6]Yadav G D,Bisht P M,Lande S V.Regioselective nitration of o-xylene by using a novel clay-based shape-selective acid catalyst[J].Catalysis Today,2009,141(1-2):56-60.
[7]Espantaleón A G,Nieto J A,Fernndez M,et al.Use of activated clays in the removal of dyes and surfactants from tannery waste waters[J].Applied Clay Science,2003,24(1-2):105-110.
[8]Gonzalez-Olmos R,Martin M J,Georgi A,et al.Fe-zeolites as heterogeneous catalysts in solar fenton-like reactions at neutral pH[J].Applied Catalysis B Environmental,2012,125(3):51-58.
[9]Zhang A,Wang N,Zhou J,et al.Heterogeneous fenton-like catalytic removal of p-nitrophenol in water using acid-activated fly ash[J].Journal of Hazardous Materials,2012,s201-202(1):68-73.
[10]Ji F,Li C,Zhang J,et al.Heterogeneous photo-fenton decolorization of methylene blue over LiFe(WO4)2catalyst[J].Journal of Hazardous Materials,2011,186(2-3):1979.
[11]Liu T,You H,Chen Q W.Heterogeneous photo-fenton degradation of polyacrylamide in aqueous solution over Fe(Ⅲ)-SiO2catalyst[J].Journal of Hazardous Materials,2009,162(2-3):860-865.
[12]Tian S H,Tu Y T,Chen D S,et al.Degradation of acid orangeⅡat neutral pH using Fe2(MoO4)3,as a heterogeneous fenton-like catalyst[J].Chemical Engineering Journal,2011,169(1-3):31-37.
[13]刘杰,赵志伟,王威,等.以磁性Fe3O4-MnO2核壳结构复合材料为Fenton催化剂氧化去除水中4-氯酚[J].水处理技术,2014,40(7):20-23.
[14]郭冬雪,宗海伦,吴一泓,等.蒸汽相水解法制备磁性光催化剂Fe3O4/SiO2/TiO2及其光催化性能[J].中国科技论文,2014(6):637-641.
[15]Roulia M,Vassiliadis A A.Clay-catalyzed phenomena of cationic-dye aggregation and hydroxo-chromium oligomerization[J].Microporous&Mesoporous Materials,2009,122(1):13-19.
[16]Garrido-Ramírez E G,Theng B K G,Mora M L.Clays and oxide minerals as catalysts and nanocatalysts in Fenton-like reactions-a review[J].Applied Clay Science,2010,47(3-4):182-192.
[17]洪新,唐克.NaY分子筛的改性及吸附脱氮性能[J].燃料化学学报,2015,43(2):214-220.
[18]魏健,王璠,徐东耀,等.离子交换法处理含Mn2+废水的研究[J].中国锰业,2009,27(4):25-29.
[19]戴玉锦,张敏艳,徐珏.离子交换法提取橙皮果胶的研究[J].江苏农业科学,2005(2):103-106.
[20]罗晋朝,路程,孙琪娟,等.铁镍铝柱撑蒙脱土协同过氧化氢降解模拟染料废水[J].广州化工,2016,44(1):98-99.
[21]谌刚,寿瑾枫,任洁琼.Ti柱撑黏土负载CrCe催化剂用于低温NH3-SCR脱硝性能研究[J].广东化工,2015,42(20):77-79.
[22]陆光.柱层黏土催化剂上丙烯选择还原NO反应的研究[D].大连:大连理工大学,2011.
[23]张占梅,何世德,周富春.超声辐射浸渍法制备Fe-Ni-Mn/Al2O3催化剂及性能研究[J].环境工程学报,2012,6(1):173-177.
[24]赵晓媛,张亚平,仲佳鑫,等.超声波浸渍法制备MnO/TiO催化剂低温选择性催化还原NO[J].东南大学学报:自然科学版,2011,41(6):1225-1230.
[25]童晶,夏晓丹,左树锋.AlMn复合柱撑黏土负载CrCe催化剂用于氯苯催化降解性能初探[J].中国稀土学报,2015,33(2):156-164.
[26]王红琴,刘勇健.非均相Fenton和非均相US-Fenton体系中甲基橙降解动力学[J].环境工程学报,2012,6(10):3673-3678.
[27]Azmi N H M,Ayodele O B,Vadivelu V M,et al.Fe-modified local clay as effective and reusable heterogeneous photo-fenton catalyst for the decolorization of acid green 25[J].Journal of the Taiwan Institute of Chemical Engineers,2014,45(4):1459-1467.
[28]孙剑秋,宫璐,沈静,等.溶胶-凝胶法制备多孔晶体材料C12A7-Cl-[J].物理化学学报,2010,26(3):795-798.
[29]徐鑫,王晓静,胡中华,等.溶胶-凝胶和浸渍-水热制备方法对TiO2/AC光催化剂结构和性能的影响[J].物理化学学报,2010,26(1):79-86.
[30]田桂英.凝胶色谱分析法在测定β-内酰胺类抗生素高分子聚合物中的应用[J].天津药学,2010,22(3):65-67.
[31]武改美.K-Co-Mo/clay催化剂的制备、结构及CO加氢合成醇性能研究[D].合肥:中国科学技术大学,2015.
[32]Belver C,Bedia J,lvarez-Montero M A,et al.Solar photocatalytic purification of water with Ce-doped TiO2/clay heterostructures[J].Catalysis Today,2016,266:36-45.
[33]Belver C,Han C,Rodriguez J J,et al.Innovative W-doped titanium dioxide anchored on clay for photocatalytic removal of atrazine[J].Catalysis Today,2016,280:21-28.
[34]Hadjltaief H B.Photocatalytic degradation of methyl green dye in aqueous solution over natural clay-supported ZnOTiO2catalysts[J].Journal of Photochemistry&Photobiology A Chemistry,2016,315:25-33.
[35]Hadjltaief H B,Galvez M E,Zina M B,et al.TiO2/clay as a heterogeneous catalyst in photocatalytic/photochemical oxidation of anionic reactive blue 19[J].Arabian Journal of Chemistry,2014,http://dx.doi.org/10.1016/j.arabjc.
[36]Akkari M,Aranda P,Rhaiem H B,et al.ZnO/clay nanoarchitectures:synthesis,characterization and evaluation as photocatalysts[J].Applied Clay Science,2015,131:131-139.
[37]王鹤.Cu/TiO2/改性凹凸棒石复合光催化剂的制备及其光催化性能研究[D].武汉:武汉理工大学,2012.
[38]朱鹏飞,刘梅,曾静,等.La-N-TiO2/硅藻土的制备及光催化降解染料废水性能研究[J].非金属矿,2013,36(6):60-62.
[39]王艳.逆负载型CoO2/CuO催化剂与CuO/CeO2催化剂CO优先氧化性能及活性位的研究[D].呼和浩特:内蒙古大学,2013.
[40]李志林,孙艳.负载CaSO4/TiO2复合材料的制备及染料废水处理研究[J].科学技术与工程,2012,12(15):3792-3796.
[41]张莉莉,吕伏建,刘建全,等.凹凸棒黏土-SnO2-TiO2复合材料的制备及其光催化性能[J].应用化学,2010,27(1):63-68.
[2]Herney-Ramirez J,Vicente M A,Madeira L M.Heterogeneous photo-fenton oxidation with pillared clay-based catalysts for wastewater treatment:a review[J].Applied Catalysis B Environmental,2010,98(1-2):10-26.
[3]Hassan H,Hameed B H.Fe-clay as effective heterogeneous fenton catalyst for the decolorization of reactive blue 4[J].Chemical Engineering Journal,2011,171(3):912-918.
[4]Ramirez J H,Costa C A,Madeira L M,et al.Fenton-like oxidation of orangeⅡsolutions using heterogeneous catalysts based on saponite clay[J].Applied Catalysis B Environmental,2007,71(1-2):44-56.
[5]Navalon S,Alvaro M,Garcia H,et al.Heterogeneous fenton catalysts based on clays,silicas and zeolites[J].Cheminform,2010,99(1-2):1-26.
[6]Yadav G D,Bisht P M,Lande S V.Regioselective nitration of o-xylene by using a novel clay-based shape-selective acid catalyst[J].Catalysis Today,2009,141(1-2):56-60.
[7]Espantaleón A G,Nieto J A,Fernndez M,et al.Use of activated clays in the removal of dyes and surfactants from tannery waste waters[J].Applied Clay Science,2003,24(1-2):105-110.
[8]Gonzalez-Olmos R,Martin M J,Georgi A,et al.Fe-zeolites as heterogeneous catalysts in solar fenton-like reactions at neutral pH[J].Applied Catalysis B Environmental,2012,125(3):51-58.
[9]Zhang A,Wang N,Zhou J,et al.Heterogeneous fenton-like catalytic removal of p-nitrophenol in water using acid-activated fly ash[J].Journal of Hazardous Materials,2012,s201-202(1):68-73.
[10]Ji F,Li C,Zhang J,et al.Heterogeneous photo-fenton decolorization of methylene blue over LiFe(WO4)2catalyst[J].Journal of Hazardous Materials,2011,186(2-3):1979.
[11]Liu T,You H,Chen Q W.Heterogeneous photo-fenton degradation of polyacrylamide in aqueous solution over Fe(Ⅲ)-SiO2catalyst[J].Journal of Hazardous Materials,2009,162(2-3):860-865.
[12]Tian S H,Tu Y T,Chen D S,et al.Degradation of acid orangeⅡat neutral pH using Fe2(MoO4)3,as a heterogeneous fenton-like catalyst[J].Chemical Engineering Journal,2011,169(1-3):31-37.
[13]刘杰,赵志伟,王威,等.以磁性Fe3O4-MnO2核壳结构复合材料为Fenton催化剂氧化去除水中4-氯酚[J].水处理技术,2014,40(7):20-23.
[14]郭冬雪,宗海伦,吴一泓,等.蒸汽相水解法制备磁性光催化剂Fe3O4/SiO2/TiO2及其光催化性能[J].中国科技论文,2014(6):637-641.
[15]Roulia M,Vassiliadis A A.Clay-catalyzed phenomena of cationic-dye aggregation and hydroxo-chromium oligomerization[J].Microporous&Mesoporous Materials,2009,122(1):13-19.
[16]Garrido-Ramírez E G,Theng B K G,Mora M L.Clays and oxide minerals as catalysts and nanocatalysts in Fenton-like reactions-a review[J].Applied Clay Science,2010,47(3-4):182-192.
[17]洪新,唐克.NaY分子筛的改性及吸附脱氮性能[J].燃料化学学报,2015,43(2):214-220.
[18]魏健,王璠,徐东耀,等.离子交换法处理含Mn2+废水的研究[J].中国锰业,2009,27(4):25-29.
[19]戴玉锦,张敏艳,徐珏.离子交换法提取橙皮果胶的研究[J].江苏农业科学,2005(2):103-106.
[20]罗晋朝,路程,孙琪娟,等.铁镍铝柱撑蒙脱土协同过氧化氢降解模拟染料废水[J].广州化工,2016,44(1):98-99.
[21]谌刚,寿瑾枫,任洁琼.Ti柱撑黏土负载CrCe催化剂用于低温NH3-SCR脱硝性能研究[J].广东化工,2015,42(20):77-79.
[22]陆光.柱层黏土催化剂上丙烯选择还原NO反应的研究[D].大连:大连理工大学,2011.
[23]张占梅,何世德,周富春.超声辐射浸渍法制备Fe-Ni-Mn/Al2O3催化剂及性能研究[J].环境工程学报,2012,6(1):173-177.
[24]赵晓媛,张亚平,仲佳鑫,等.超声波浸渍法制备MnO/TiO催化剂低温选择性催化还原NO[J].东南大学学报:自然科学版,2011,41(6):1225-1230.
[25]童晶,夏晓丹,左树锋.AlMn复合柱撑黏土负载CrCe催化剂用于氯苯催化降解性能初探[J].中国稀土学报,2015,33(2):156-164.
[26]王红琴,刘勇健.非均相Fenton和非均相US-Fenton体系中甲基橙降解动力学[J].环境工程学报,2012,6(10):3673-3678.
[27]Azmi N H M,Ayodele O B,Vadivelu V M,et al.Fe-modified local clay as effective and reusable heterogeneous photo-fenton catalyst for the decolorization of acid green 25[J].Journal of the Taiwan Institute of Chemical Engineers,2014,45(4):1459-1467.
[28]孙剑秋,宫璐,沈静,等.溶胶-凝胶法制备多孔晶体材料C12A7-Cl-[J].物理化学学报,2010,26(3):795-798.
[29]徐鑫,王晓静,胡中华,等.溶胶-凝胶和浸渍-水热制备方法对TiO2/AC光催化剂结构和性能的影响[J].物理化学学报,2010,26(1):79-86.
[30]田桂英.凝胶色谱分析法在测定β-内酰胺类抗生素高分子聚合物中的应用[J].天津药学,2010,22(3):65-67.
[31]武改美.K-Co-Mo/clay催化剂的制备、结构及CO加氢合成醇性能研究[D].合肥:中国科学技术大学,2015.
[32]Belver C,Bedia J,lvarez-Montero M A,et al.Solar photocatalytic purification of water with Ce-doped TiO2/clay heterostructures[J].Catalysis Today,2016,266:36-45.
[33]Belver C,Han C,Rodriguez J J,et al.Innovative W-doped titanium dioxide anchored on clay for photocatalytic removal of atrazine[J].Catalysis Today,2016,280:21-28.
[34]Hadjltaief H B.Photocatalytic degradation of methyl green dye in aqueous solution over natural clay-supported ZnOTiO2catalysts[J].Journal of Photochemistry&Photobiology A Chemistry,2016,315:25-33.
[35]Hadjltaief H B,Galvez M E,Zina M B,et al.TiO2/clay as a heterogeneous catalyst in photocatalytic/photochemical oxidation of anionic reactive blue 19[J].Arabian Journal of Chemistry,2014,http://dx.doi.org/10.1016/j.arabjc.
[36]Akkari M,Aranda P,Rhaiem H B,et al.ZnO/clay nanoarchitectures:synthesis,characterization and evaluation as photocatalysts[J].Applied Clay Science,2015,131:131-139.
[37]王鹤.Cu/TiO2/改性凹凸棒石复合光催化剂的制备及其光催化性能研究[D].武汉:武汉理工大学,2012.
[38]朱鹏飞,刘梅,曾静,等.La-N-TiO2/硅藻土的制备及光催化降解染料废水性能研究[J].非金属矿,2013,36(6):60-62.
[39]王艳.逆负载型CoO2/CuO催化剂与CuO/CeO2催化剂CO优先氧化性能及活性位的研究[D].呼和浩特:内蒙古大学,2013.
[40]李志林,孙艳.负载CaSO4/TiO2复合材料的制备及染料废水处理研究[J].科学技术与工程,2012,12(15):3792-3796.
[41]张莉莉,吕伏建,刘建全,等.凹凸棒黏土-SnO2-TiO2复合材料的制备及其光催化性能[J].应用化学,2010,27(1):63-68.