浆态床甲烷化工艺和Ni基催化剂的研究进展
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摘要
综述了浆态床合成气甲烷化工艺技术发展现状,重点介绍了浆态床甲烷化Ni基催化剂的制备方法、助剂、载体、焙烧条件和镍盐前体等影响因素的研究进展,提出了浆态床甲烷化工艺和催化剂技术面临的机遇和挑战。
The development status of process for the methanation of synthesis gas in a slurry bed is reviewed.Research progress in the preparation method,promoter,supporter,calcination conditions and precursor of Ni based catalyst for methanation in a slurry bed are introduced,and the opportunities and challenges faced by the slurry bed methanation process and catalyst technology are put forward.
The development status of process for the methanation of synthesis gas in a slurry bed is reviewed.Research progress in the preparation method,promoter,supporter,calcination conditions and precursor of Ni based catalyst for methanation in a slurry bed are introduced,and the opportunities and challenges faced by the slurry bed methanation process and catalyst technology are put forward.
引文
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[19]张俊峰,白云星,张清德,等.Zr改性Ni/γ-Al2O3催化剂用于浆态相合成气的低温甲烷化[J].燃料化学学报,2013,41(8):966-971.
[20]Meng F,Li Z,Ji F,et al.Effect of Zr O2on catalyst structure and catalytic methanation performance over Ni-based catalyst in slurrybed reactor[J].International Journal of Hydrogen Energy,2015,40(29):8833-8843.
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[22]吴秀,辜冬梅,余镇重,等.焙烧温度对共沉淀法合成Ni/Al2O3甲烷化催化剂性能的影响[J].工业催化,2015,23(4):282-288.
[23]贺龙,王永刚,公维博,等.焙烧温度对浆态床甲烷化催化剂的影响[J].煤炭转化,2012,35(4):72-76.
[24]莫文龙,肖艳,马凤云,等.焙烧条件对浆态床CO甲烷化NiAl2O3催化剂性能的影响[J].燃料化学学报,2018,46(1):84-91.
[25]钟朋展,孟凡会,崔晓曦,等.镍盐前体对Ni-Fe/γ-Al2O3催化剂甲烷化性能的影响[J].化工进展,2013,32(8):1845-1849.
[26]莫文龙,肖艳,马凤云,等.Ni含量和还原温度对浆态床CO甲烷化Ni-Al2O3催化剂结构和性能的影响[J].应用化工,2018,47(5):896-904.
[2]Kopyscinski J,Schildhauer T J,Biollaz S M A.Production of synthetic natural gas(SNG)from coal and dry biomass-A technology review from 1950 to 2009[J].Fuel,2010,89(8):1763-1783.
[3]宋鹏飞,姚辉超,侯建国,等.一种浆态床与固定床结合的甲烷化方法:CN,104212507A[P].2014-12-17.
[4]张庆庚,崔晓曦,范辉,等.一种浆态床甲烷化合成天然气的工艺及装置:CN,102952596A[P].2013-03-06.
[5]范辉,李晓,崔晓曦,等.利用整体催化剂进行浆态床甲烷化的工艺及装置:CN,104164265A[P].2014-11-26.
[6]张庆庚,李忠,闫少伟,等.一种煤制合成气进行甲烷化合成天然气的工艺:CN,101979476A[P].2011-02-23.
[7]韩怡卓,谭猗生,解红娟,等.一种合成气合成甲烷的工艺:CN,102690157A[P].2012-09-26.
[8]Meng F,Song Y,Li X,et al.Catalytic methanation performance in a low-temperature slurry-bed reactor over Ni-ZrO2catalyst:Effect of the preparation method[J].Journal of Sol-Gel Science and Technology,2016,80(3):759-768.
[9]吉可明.燃烧法制备Ni基催化剂及其浆态床甲烷化性能的研究[D].太原:太原理工大学,2015.
[10]宋燕.柠檬酸-凝胶法制备Ni-Zr O2催化剂及其低温浆态床甲烷化性能研究[D].太原:太原理工大学,2016.
[11]邹梦,马凤云,莫文龙,等.机械化学法制备甲烷化Ni/Al2O3催化剂性能研究[J].应用化工,2017,46(12):2314-2319.
[12]刘军,孟凡会,钟朋展,等.载体织构对Ni-Fe/γ-Al2O3催化剂结构和甲烷化活性的影响[J].天然气化工:C1化学与化工,2013,38(04):6-10.
[13]秦晋钰.Ni/MCM-41催化剂的制备及其浆态床CO甲烷化性能研究[D].太原:太原理工大学,2015.
[14]崔晓曦,孟凡会,何忠,等.助剂对Ni基催化剂结构及甲烷化性能的影响[J].无机化学学报,2014,30(2):277-283.
[15]孟凡会,崔晓曦,何忠,等.Ni/Al2O3及La改性Ni/Al2O3催化CO浆态床甲烷化性能[J].稀土,2014,35(6):1-6.
[16]孟凡会,常慧蓉,李忠.Ni-Mn/Al2O3催化剂在浆态床中CO甲烷化催化性能[J].化工学报,2014,65(8):2997-3003.
[17]Meng F,Zhong P,Li Z,et al.Surface structure and catalytic performance of Ni-Fe catalyst for low-temperature CO hydrogenation[J].Journal of Chemistry,2014,2014(5):1-7.
[18]孟凡会,刘军,李忠,等.Ce含量对Ni-Ce/Al2O3催化剂结构及浆态床CO甲烷化性能的影响[J].燃料化学学报,2014,42(2):231-237.
[19]张俊峰,白云星,张清德,等.Zr改性Ni/γ-Al2O3催化剂用于浆态相合成气的低温甲烷化[J].燃料化学学报,2013,41(8):966-971.
[20]Meng F,Li Z,Ji F,et al.Effect of Zr O2on catalyst structure and catalytic methanation performance over Ni-based catalyst in slurrybed reactor[J].International Journal of Hydrogen Energy,2015,40(29):8833-8843.
[21]Zhang J,Bai Y,Zhang Q,et al.Low-temperature methanation of syngas in slurry phase over Zr-doped Ni/γ-Al2O3catalysts prepared using different methods[J].Fuel,2014,132:211-218.
[22]吴秀,辜冬梅,余镇重,等.焙烧温度对共沉淀法合成Ni/Al2O3甲烷化催化剂性能的影响[J].工业催化,2015,23(4):282-288.
[23]贺龙,王永刚,公维博,等.焙烧温度对浆态床甲烷化催化剂的影响[J].煤炭转化,2012,35(4):72-76.
[24]莫文龙,肖艳,马凤云,等.焙烧条件对浆态床CO甲烷化NiAl2O3催化剂性能的影响[J].燃料化学学报,2018,46(1):84-91.
[25]钟朋展,孟凡会,崔晓曦,等.镍盐前体对Ni-Fe/γ-Al2O3催化剂甲烷化性能的影响[J].化工进展,2013,32(8):1845-1849.
[26]莫文龙,肖艳,马凤云,等.Ni含量和还原温度对浆态床CO甲烷化Ni-Al2O3催化剂结构和性能的影响[J].应用化工,2018,47(5):896-904.