Cobalt and nitrogen codoped porous carbon as superior bifunctional electrocatalyst for oxygen reduction and hydrogen evolution reaction in alkaline medium

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英文篇名：Cobalt and nitrogen codoped porous carbon as superior bifunctional electrocatalyst for oxygen reduction and hydrogen evolution reaction in alkaline medium 作者：Xiaoxia ; Chen ; Xiangjun ; Zhen ; Hongyu ; Gong ; Le ; Li ; Jianwei ; Xiao ; Zhi ; Xu ; Deyue ; Yan ; Guyu ; Xiao ; Ruizhi ; Yang 英文作者：Xiaoxia Chen;Xiangjun Zhen;Hongyu Gong;Le Li;Jianwei Xiao;Zhi Xu;Deyue Yan;Guyu Xiao;Ruizhi Yang;School of Chemistry and Chemical Engineering,State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University;College of Physics, Optoelectronics and Energy & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University; 英文关键词：Carbon;;Cobalt and nitrogen;;Doped;;Oxygen reduction reaction;;Hydrogen evolution reaction 中文刊名：FXKB 英文刊名：中国化学快报(英文版) 机构：School of Chemistry and Chemical Engineering,State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University;College of Physics, Optoelectronics and Energy & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University; 出版日期：2019-03-15 出版单位：Chinese Chemical Letters 年：2019 期：v.30 基金：supported by the National Natural Science Foundation of China(Nos.21774073,51690151,21404071,and 21320102006);; the National Basic Research Program (No. 2016YFA0201500) 语种：英文; 页：FXKB201903033 页数：5 CN：03 ISSN：11-2710/O6 分类号：169-173

摘要

Cobalt and nitrogen codoped carbon materials(Co-N-C) were fabricated by pyrolysis of the mixture of poly(4-vinylpyridine) and cobalt chloride using SiO_2 nanoparticles as hard template, which were the first transition metal/nitrogen-codoped carbon bifunctional electrocatalyst derived from noncarbonizable polymer for ORR and HER. The as-made Co-N-C possessed hierarchical pore structure and high specific surface area, achieving excellent electrocatalytic performances for ORR and HER. Its ORR catalytic performances were comparable to those of Pt/C catalyst and its HER catalytic performances were superior to those of most doped carbon catalysts in KOH electrolyte. Moreover, its bifunctional electrocatalytic performances for ORR and HER were better than those of most bifunctional doped carbon catalysts in alkaline electrolyte.
        Cobalt and nitrogen codoped carbon materials(Co-N-C) were fabricated by pyrolysis of the mixture of poly(4-vinylpyridine) and cobalt chloride using SiO_2 nanoparticles as hard template, which were the first transition metal/nitrogen-codoped carbon bifunctional electrocatalyst derived from noncarbonizable polymer for ORR and HER. The as-made Co-N-C possessed hierarchical pore structure and high specific surface area, achieving excellent electrocatalytic performances for ORR and HER. Its ORR catalytic performances were comparable to those of Pt/C catalyst and its HER catalytic performances were superior to those of most doped carbon catalysts in KOH electrolyte. Moreover, its bifunctional electrocatalytic performances for ORR and HER were better than those of most bifunctional doped carbon catalysts in alkaline electrolyte.

引文

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