冷喷涂自敏发光高铝青铜复合涂层及其摩擦磨损性能
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摘要
利用冷空气动力喷涂(冷喷涂)工艺在(45)~#钢基材上分别制备高铝青铜涂层、SrAl_2O_4掺杂和SiO_2包覆SrAl_2O_4掺杂高铝青铜自敏发光复合涂层。采用SEM分析复合涂层表面、界面组织结构;采用HT-1000型高温摩擦磨损试验机对涂层进行常温干摩擦试验。研究SrAl_2O_4掺杂和SiO_2包覆SrAl_2O_4掺杂分别对高铝青铜冷喷涂涂层沉积特性、显微组织以及摩擦磨损性能的影响,并检测了自敏发光复合涂层的宏观指示效应。结果表明:溶胶-凝胶法能够制备具有核-壳结构SiO_2-SrAl_2O_4包覆粉体,形成的SiO_2壳层结构较好地改善了粉体表面形貌,使得包覆粉体表面较为平整圆润,硬度增大;SiO_2包覆SrAl_2O_4掺杂高铝青铜涂层表面平整,具有最优的摩擦磨损性能,发光指示效应较明显。
High aluminum bronze(Cu-14 Al-X) coating, SrAl_2O_4 doped and SiO_2 coated SrAl_2O_4 doped high aluminum bronze self sensitized luminescence composite coatings were prepared on the (45)~# steel substrate by cold spraying technique. The surface and interface structure of the composite coatings were analyzed by SEM, and the dry friction test of the coatings was carried out by HT-1000 type high temperature friction and wear tester. Consequently, the effects of SrAl_2O_4 doping and SiO_2 coated SrAl_2O_4 doping on the deposition characteristics, coating micro-structure and tribological properties of high aluminum bronze coating were investigated, and the macro indicator effect of the self sensitized luminescent composite coating was detected. The results indicate that the SiO_2 shell structure prepared by sol-gel method can optimize the surface morphology of the SiO_2-SrAl_2O_4 coating powders for more smooth and round shape, and increases the hardness of composite coating. The surface of SiO_2 coated SrAl_2O_4 doped high aluminum bronze coating also has the best friction and wear properties, and the luminous indication effect is more obvious.
High aluminum bronze(Cu-14 Al-X) coating, SrAl_2O_4 doped and SiO_2 coated SrAl_2O_4 doped high aluminum bronze self sensitized luminescence composite coatings were prepared on the (45)~# steel substrate by cold spraying technique. The surface and interface structure of the composite coatings were analyzed by SEM, and the dry friction test of the coatings was carried out by HT-1000 type high temperature friction and wear tester. Consequently, the effects of SrAl_2O_4 doping and SiO_2 coated SrAl_2O_4 doping on the deposition characteristics, coating micro-structure and tribological properties of high aluminum bronze coating were investigated, and the macro indicator effect of the self sensitized luminescent composite coating was detected. The results indicate that the SiO_2 shell structure prepared by sol-gel method can optimize the surface morphology of the SiO_2-SrAl_2O_4 coating powders for more smooth and round shape, and increases the hardness of composite coating. The surface of SiO_2 coated SrAl_2O_4 doped high aluminum bronze coating also has the best friction and wear properties, and the luminous indication effect is more obvious.
引文
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[21]YIN S,SUO X K,SU J Q,GUO ZW,LIAO H L,WANG XF.Effects of substrate hardness and spray angle on the deposition behavior of cold-sprayed Ti particles[J].Journal of Thermal Spray Technology,2014,23(1/2):76-83.
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[23]巫湘坤,周香林,崔华,张济山.多颗粒沉积模型预测铜和铝冷喷涂层微观形貌[J].北京科技大学学报,2012,34(12):1391-1399.WU Xiang-kun,ZHOU Xiang-lin,CUI Hua,ZHANGJi-shan.Morphology prediction of cold-sprayed Cu and Al coatings through multi-parti-cles deposition simulation[J].Journal of University of Science and Technology Beijing,2012,34(12):1391-1399.
[24]李文生.新型高铝青铜的研制及其摩擦磨损腐蚀磨损机理研究[D].兰州:兰州理工大学,2006.LI Wen-sheng.Preparation wear and corrosive wear properties of a novel aluminum bronze[D].Lanzhou:Lanzhou University of Technology,2006.
[25]LI Y,NGAI T L,XIA W.Mechanical,friction and wear behaviors of a novel high-strength wear-resisting aluminum bronze[J].Wear,1996,197(1/2):130-136.
[26]赫罗绍夫M M,巴比契夫M A.金属的磨损[M].胡绍衣.北京:机械工业出版社,1966:96-101.KHRUSHEV M M,BABITCHEV M A.Wear of metals[M].HU Shao-yi.Beijing:China Machine Press,1996:96-101.
[27]李渊,伍方,赵文杰,李赫,金谷,乌学东,薛群基.微纳米二氧化硅颗粒协同改性丙烯酸树脂的摩擦学性能[J].润滑与密封,2015,40(11):11-18.LI Yuan,WU Fang,ZHAO Wen-jie,LI HE,JIN Gu,WUXue-dong,XUE Qun-ji.Tribological performance of acrylic resin coatings modified by micro/nano-Si O2 particles[J].Lubrication Engineering,2015,40(11):11-18.
[28]SHI H,LIU F,YANG L,HAN E.Characterization of protective performance of epoxy reinforced with nanometer-sized Ti O2 and SiO2[J].Progress in Organic Coatings,2008,62(4):359-368.
[29]KANG Y K,CHEN X H,SONG S Y,YU L G,ZHANG P Y.Friction and wear behavior of nanosilica-filled epoxy resin composite coatings[J].Applied Surface Science,2012,258(17):6384-6390.
[30]孙文周,陈宇红.燃烧法制备SrAl2O4:Eu2+,Dy3+长余辉发光粉体的有机包覆研究[J].化工新型材料,2016,44(7):133-135.SUNG Wen-zhou,CHENG Yu-hong.Surface organic encapsulation on SrAl2O4:Eu2+,Dy3+long persistence phosphor synthesized by combustion synthesis method[J].New Chemical Materials,2016,44(7):133-135.
[2]BARIK R C,WHARTON J A,WOOD R J K,TAN K S,STOKES K R.Erosion and erosion-corrosion performance of cast and thermally sprayed nickel-aluminium bronze[J].Wear,2005,259(1/6):230-242.
[3]刘舒婕,李文生,杨效田,何玲,王大锋,何艳艳.热扩散对高铝青铜等离子喷焊层组织及摩擦性能的影响[J].中国有色金属报,2016,26(7):1487-1497.LIU Shu-jie,LI Wen-sheng,YANG Xiao-tian,HE Ling,WANG Da-feng,HE Yan-yan.Effect of thermal diffusion on microstructure and wear behaviors of plasma spray welded high Al bronze coating[J].The Chinese Journal of Nonferrous Metals,2016,26(7):1487-1497.
[4]RAJAKUMAR S,BALASUBRAMAN-IAN V.Corrosion performance of friction surfaced nickel aluminium bronze(NAB)alloy under erosion corrosion and salt fog environment[J].Corrosion Engineering Science&Technology,2018,53(Sup1):1-6.
[5]何艳艳,李文生,吴学军,王大锋,杨效田,何玲.元素扩散对高铝青铜喷焊层显微组织及摩擦性能的影响[J].中国有色金属学报,2015,25(1):143-149.HE Yan-yan,LI Wen-sheng,WU Xue-jun,WANG Da-feng,YANG Xiao-tian,HE Ling.Effects of element diffusion on microstructure and friction behavior of high-aluminum bronze plasma spray coating[J].The Chinese Journal of Nonferrous Metals,2015,25(1):143-149.
[6]FELDSTEIN M D.Composite coatings with light-emitting properties[J].Metal Finishing,1999,97(2):87-90.
[7]何玲,李乾坤,李文生,崔帅.三基色镍基自敏复合涂层的制备及其性能研究[J].无机材料学报,2017,32(1):56-62.HE Ling,LI Qian-kun,LI Weng-sheng,CUI Shuai.Synthesis and properties of self-sensitization luminescent composite coatings[J].Journal of Inorganic Materials,2017,32(1):56-62.
[8]MURATORE C,CLARKE D R,JONES J G,VOEVODINCA A.Smart tribological coatings with wear sensing capability[J].Wear,2008,265(5/6):913-920.
[9]李文生,张咪娜,何玲,杨效田,吴学军.新型减摩耐磨自敏监测复合涂层及其发光性能[J].焊接学报,2016,37(4):73-76.LI Wen-sheng,ZHANG Mi-na,HE Ling,YANG Xian-tian,WU Xue-jun.Novel antifriction and wear-resistant composite coating with self-sensing detection and its luminescent properties[J].Transactions of the China Welding Institution,2016,37(4):73-76.
[10]HE L,WU X,LI W S,WANG S C,LI Q K.Metal contact quenching mechanism of sintered SrAl2O4:Eu2+,Dy3+composite coating[J].Journal of Materials Science Materials in Electronics,2017,28(9):14483-14488.
[11]闫旺,李文生,何玲,安国升,胡春霞.磷光粉表面包覆对铜基磷光复合材料发光及摩擦性能影响[J].材料导报,2016,30(22):26-30.YAN Wang,LI Wen-sheng,HE Ling,AN Guo-sheng,HUChun-xia.Enhanced luminescence and wear resistance of copper matrix phosphorescent composite with surface-coated phosphors[J].Materials Review,2016,30(22):26-30.
[12]周海滨,姚萍屏,肖叶龙,张忠义,陈凌寒,贡太敏,赵林,左晓婷.SiC颗粒强化铜基粉末冶金摩擦材料的表面形貌特征及磨损机理[J].中国有色金属学报,2014,24(9):2272-2279.ZHOU Hai-bin,YAO Ping-ping,XIAO Ye-long,ZHANGZhong-yi,CHEN Ling-han,GONG Tai-min,ZHAO Lin,ZUO Xiao-ting.Topographical characteristics and wear mechanism of copper-based powder metallurgy friction materials reinforced by SiC particle[J].The Chinese Journal of Nonferrous Metals,2014,24(9):2272-2279.
[13]IRISSOU E,LEGOUX J G,ARSENAULT B,MOREAU C.Investigation of Al-Al2O3 cold spray coating formation and properties[J].Journal of Thermal Spray Technology,2007,16(5/6):661-668.
[14]KOIVULUOTO H,VUORISTO P.Effect of powder type and composition on structure and mechanical properties of Cu+Al2O3 coatings prepared by using low-pressure cold spray process[J].Journal of Thermal Spray Technology,2010,19(5):1081-1092.
[15]MARZBANRAD B,JAHED H,TOYSERKANI E.On the evolution of substrate's residual stress during cold spray process A parametric study[J].Materials&Design,2018,138:90-102.
[16]TU D,XU C N,FUJIO Y,YOSHIDA A.Mechanism of mechanical quenching and mechanoluminescence in phosphorescent CaZnOS:Cu[J].Light:Science&Applications,2015,4(11):e356.
[17]TU D,XU C N.Lifetime-based measurement of mechanical load using mechanical-quenching of CaZnOS:Cu[J].JournalCeramic Society Japan,2017,125(6):438-440.
[18]WU Y,WU H R,WANG M L,SONG Q L,DING M X,HOUX Y.Metal-induced photoluminescence quenching in thin organic films originating from noncontact energy transfer between single molecule and atom[J].Applied Physics Letters,2007,90(15):154105.
[19]曹雨虹.基于量子点的荧光猝灭效应检测金属离子[D].保定:河北大学,2015.CAO Yu-hong.The detection of metal ions based on the fluorescence quenching of quantum dots[D].Baoding:Hebei University,2015.
[20]路阳,王智平,李文生,苏义祥,许建林,金玉花,朱小武.铝青铜合金及其制备方法:中国,CN1629350[P].2005-06-22.LU Yang,WANG Zhi-ping,LI Wen-sheng,SU Yi-xiang,XUJian-ling,JING Yu-hua,ZHU Xiao-wu.Aluminum bronze alloy and its preparation method:China,CN1629350[P].2005-06-22.
[21]YIN S,SUO X K,SU J Q,GUO ZW,LIAO H L,WANG XF.Effects of substrate hardness and spray angle on the deposition behavior of cold-sprayed Ti particles[J].Journal of Thermal Spray Technology,2014,23(1/2):76-83.
[22]周彤辉,阮文红,王跃林,容敏智,章明秋.原位接枝改性纳米二氧化硅/聚丙烯复合材料Ⅱ:性能测试[J].复合材料学报,2007,24(3):45-51.ZHOU Tong-hui,RUAN Wen-hong,WANG Yue-lin,RONGMin-zhi,ZHANG Ming-qiu.Polypropylene composites with nano-silicamodified by in-situ grafting polymerizationⅡ:Performance characterization[J].Acta Materiae Compositae Sinica,2007,24(3):45-51.
[23]巫湘坤,周香林,崔华,张济山.多颗粒沉积模型预测铜和铝冷喷涂层微观形貌[J].北京科技大学学报,2012,34(12):1391-1399.WU Xiang-kun,ZHOU Xiang-lin,CUI Hua,ZHANGJi-shan.Morphology prediction of cold-sprayed Cu and Al coatings through multi-parti-cles deposition simulation[J].Journal of University of Science and Technology Beijing,2012,34(12):1391-1399.
[24]李文生.新型高铝青铜的研制及其摩擦磨损腐蚀磨损机理研究[D].兰州:兰州理工大学,2006.LI Wen-sheng.Preparation wear and corrosive wear properties of a novel aluminum bronze[D].Lanzhou:Lanzhou University of Technology,2006.
[25]LI Y,NGAI T L,XIA W.Mechanical,friction and wear behaviors of a novel high-strength wear-resisting aluminum bronze[J].Wear,1996,197(1/2):130-136.
[26]赫罗绍夫M M,巴比契夫M A.金属的磨损[M].胡绍衣.北京:机械工业出版社,1966:96-101.KHRUSHEV M M,BABITCHEV M A.Wear of metals[M].HU Shao-yi.Beijing:China Machine Press,1996:96-101.
[27]李渊,伍方,赵文杰,李赫,金谷,乌学东,薛群基.微纳米二氧化硅颗粒协同改性丙烯酸树脂的摩擦学性能[J].润滑与密封,2015,40(11):11-18.LI Yuan,WU Fang,ZHAO Wen-jie,LI HE,JIN Gu,WUXue-dong,XUE Qun-ji.Tribological performance of acrylic resin coatings modified by micro/nano-Si O2 particles[J].Lubrication Engineering,2015,40(11):11-18.
[28]SHI H,LIU F,YANG L,HAN E.Characterization of protective performance of epoxy reinforced with nanometer-sized Ti O2 and SiO2[J].Progress in Organic Coatings,2008,62(4):359-368.
[29]KANG Y K,CHEN X H,SONG S Y,YU L G,ZHANG P Y.Friction and wear behavior of nanosilica-filled epoxy resin composite coatings[J].Applied Surface Science,2012,258(17):6384-6390.
[30]孙文周,陈宇红.燃烧法制备SrAl2O4:Eu2+,Dy3+长余辉发光粉体的有机包覆研究[J].化工新型材料,2016,44(7):133-135.SUNG Wen-zhou,CHENG Yu-hong.Surface organic encapsulation on SrAl2O4:Eu2+,Dy3+long persistence phosphor synthesized by combustion synthesis method[J].New Chemical Materials,2016,44(7):133-135.