典型清洁氧化剂在湿法冶金中材料制备方面的应用研究现状
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摘要
介绍了氧气、双氧水和臭氧这3种清洁氧化剂在湿法冶金领域中材料制备方面的研究应用现状。氧气氧化能力较弱,常用来制备铁化合物和锰化合物功能材料以及焦锑酸钠,利用氧气氧化时通常使用高温高压来增强氧化效果。双氧水的氧化能力较氧气较强,而且在液相中的传质效率较高,其在材料制备方面的应用与氧气相似,但是其应用范围较氧气较大,除了铁氧化物、焦锑酸钠的制备,还可用于其他功能材料的制备。臭氧的氧化能力极强,可以氧化较难氧化的银、钴、镍等离子,目前已有少量材料制备的研究报道。
The research status and application for oxygen,hydrogen peroxide and ozone in the preparation of materials in hydrometallurgy are introduced.Due to its mild oxidation ability,oxygen is used to prepare iron compounds,manganese compounds,functional materials and sodium pyroantimonate.When oxidated with oxygen,high temperature and pressure is used to enhance the oxidative effect.The oxidation ability of hydrogen peroxide is strong relatively to oxygen,and its mass transfer efficiency is higher.The application in preparation of materials is similar to oxygen,however the range of applications is larger,not only iron oxide,sodium pyroantimonate,but also for other functional materials.Ozone can oxidize silver,cobalt,nickel,which is difficult to be oxidized.At present,a small amount of research reports material prepared with ozone.
The research status and application for oxygen,hydrogen peroxide and ozone in the preparation of materials in hydrometallurgy are introduced.Due to its mild oxidation ability,oxygen is used to prepare iron compounds,manganese compounds,functional materials and sodium pyroantimonate.When oxidated with oxygen,high temperature and pressure is used to enhance the oxidative effect.The oxidation ability of hydrogen peroxide is strong relatively to oxygen,and its mass transfer efficiency is higher.The application in preparation of materials is similar to oxygen,however the range of applications is larger,not only iron oxide,sodium pyroantimonate,but also for other functional materials.Ozone can oxidize silver,cobalt,nickel,which is difficult to be oxidized.At present,a small amount of research reports material prepared with ozone.
引文
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26 Huang Lihua,Chen Shanhu,Zhu Yi,et al.Preparation of Ce0.65Zr0.35O2by co-precipitation:The role of hydrogen peroxide[J].J Rare Earths,2013,31,461
27 Zhang S,Xue H,Wu J.Photocatalytic active titania thin films through oxidation of metallic Ti in aqueous H2O2solutions containing various block copolymers[J].Rare Metal Mater Eng,2011,40(10):1703
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29 Taegyung Ko,Deok-Ki Hwang.Preparation of nanocrystalline lead zirconate powder by homogeneous precipitation using hydrogen peroxide and urea[J].Mater Lett,2003,57:2472
30 乐颂光.钴冶金[M].北京:冶金工业出版社,1987
31 Tian Q,Guo X,Yi Y,et al.Kinetics of oxidation-precipitation of cobalt(Ⅱ)from solution by ozone[J].Trans Nonferrous Met Soc,2010(20):s42
32 Luis E Calzado,Cesar O Gomez,James A Finch.Nickel recovered from solution by oxidation using ozone:Some physical properties[J].Miner Eng,2005,18:537
33 姬忠涛,张正富,周效峰.β-NiOOH的臭氧氧化法合成、表征及电化学性能[J].中国有色金属学报,2012(22):1326
34 银小兵.γ-NiOOH绿色合成工艺及其在无汞碱锰电池中的应用[D].重庆:重庆大学,2007
35 Zhang W,Cheng C.Manganese metallurgy review.PartⅡ:Manganese separation and recovery from solution[J].Hydrometallurgy,2007,89:160
36 Bolton G L,Sefton V B,Zubryckyj N.Removal of manganese and chloride ions from aqueous acidic zinc sulfate solutions for the recovery of zinc:US4379037[P].1983
37 Bolton G L,Sefton V B,Zubryckyj N.Removal of manganese ions from zinc and manganese containing solutions:US4290866[P].1981
38 Kijima N,Yasuda H,Sato T,et al.Preparation and characterization of open tunnel oxide a-MnO2precipitated by ozone oxidation[J].J Solid State Chem,2001,159:94
39 Martín R Cruz-Díaz,Yennifer Arauz-Torres,Francisco Caballero,et al.Recovery of MnO2from a spent alkaline battery leach solution via ozone treatment[J].J Power Sources,2015,274:839
40 Myoung-Jin Kim,Jerome Nriagu.Oxidation of arsenite in groundwater using ozone and oxygen[J].Sci Total Environ,2000,247:71
41 Nishimura T,Umetsu Y.Oxidative precipitation of arsenicⅢwith manganeseⅡand ironⅡin dilute acidic solution by ozone[J].Hydrometallurgy,2001,62:83
42 沈文宁,冯拉俊,孔珍珍.AgO超细粉末的制备及银的价态变化研究[J].稀有金属材料工程,2011,40(11):1961
2 Zhang W,Muir D M,Singh P.Iron(Ⅱ)oxidation by SO2/O2in acidic media[J].Hydrometallurgy,2000,58:117
3 杨喜云,龚竹青,彭长宏,等.空气氧化法制备Fe3O4的反应机理[J].中南大学学报:自然科学版,2008,39(3):454
4 张丽清,刘新锋,王雅静,等.利用工业废铁泥制备α-FeOOH[J].化工环保,2011,31(3):243
5 方敏,段学臣.空气氧化法制备纳米氧化铁黄[J].纳米粉体技术,2006(5):32
6 Lu Jianming,David Dreisinger.Pressure oxidation of ferrous ions by oxygen and hematite precipitation from concentrated solution of calcium,copper and iron chlorides[J].Hydrometallurgy,2013,140:59
7 刘娘,王鹏,周星辰,等.空气氧化法制备FePO4超细颗粒[J].中国粉体技术,2013,19(2):24
8 唐剑,邱运仁.空气-氧化剂联合氧化法制备聚合硫酸铁的研究[J].化学工程师,2010(7):17
9 谭柱中,梅光贵,等.锰冶金学[M].长沙:中南大学出版社,2004
10 施雯.软锰矿湿法还原制备四氧化三锰的研究[D].吉首:吉首大学,2012:43
11 邹兴,孙宁磊,王国承.用空气直接氧化游离二价锰离子制备高纯四氧化三锰[J].北京科技大学学报,2007,29(12):1250
12 戴艳阳,钟晖,钟海云.钨渣回收制备四氧化三锰新工艺[J].中国有色金属学报,2012,22(4):1242
13 朱伟长,吴小俊,高孝钱,等.由硫酸锰制备高纯四氧化三锰的研究[J].矿冶工程,2013,30(2):138
14 王志明,杨天足,王卫东,等.从锑精矿制备焦锑酸钠的工业试验[J].湖南冶金,2005,33(3):17
15 王志明,刘伟锋,王卫东,等.空气氧化法生产焦锑酸钠的设备改进[J].湖南有色金属,2005,21(3):14
16 杜新玲.焦锑酸钠生产工艺研究[J].湖南有色金属,2008,24(5):24
17 Zhang Duchao,Xiao Qingkai,Liu Weifeng,et al.Pressure oxidation of sodium thioantimonite solution to prepare sodium pyroantimonat[J].Hydrometallurgy,2015,151:91
18 张文钲.氧化钼研发进展[J].中国钼业,2006,30(1):7
19 李发伸,王涛,王颖.H2O2氧化法制备Fe3O4纳米颗粒及与共沉淀法制备该样品的比较[J].物理学报,2005,54(7):310
20 Li G,Jiang Y,Huang K,et al.Preparation and properties of magnetic Fe3O4-chitosan nanoparticles[J].J Alloys Compd,2008,466:451
21 周兴,黄雁,王玉棉,等.用黑铜泥制备砷酸钠和焦锑酸钠[J].甘肃冶金,2012,34(1):1
22 江名喜,杨天足,楚广,等.配合水热氧化法合成锑掺杂二氧化锡纳米粉末[J].中南大学学报:自然科学版,2006,37(2):247
23卫芝贤,范文浩,程尊华,等.氧化共沉淀制备Sb2O5掺杂的超细SnO2[J].过程工程学报,2002,2(2):151
24 Bas A D,Yazici E Y,et al.Recovery of silver from X-ray film processing effluents by hydrogen peroxide treatment[J].Hydrometallurgy,2012,121-124:22
25 李小忠,王连军,赵铭,等.离子交换-双氧水氧化法制备纳米CeO2晶体[J].无机化学学报,2006,122(1):79
26 Huang Lihua,Chen Shanhu,Zhu Yi,et al.Preparation of Ce0.65Zr0.35O2by co-precipitation:The role of hydrogen peroxide[J].J Rare Earths,2013,31,461
27 Zhang S,Xue H,Wu J.Photocatalytic active titania thin films through oxidation of metallic Ti in aqueous H2O2solutions containing various block copolymers[J].Rare Metal Mater Eng,2011,40(10):1703
28 黎先财,汪文娟,柯勇,等.H2O2氧化水热法制备超细WO3的研究[J].中国钨业,2005,20(3):27
29 Taegyung Ko,Deok-Ki Hwang.Preparation of nanocrystalline lead zirconate powder by homogeneous precipitation using hydrogen peroxide and urea[J].Mater Lett,2003,57:2472
30 乐颂光.钴冶金[M].北京:冶金工业出版社,1987
31 Tian Q,Guo X,Yi Y,et al.Kinetics of oxidation-precipitation of cobalt(Ⅱ)from solution by ozone[J].Trans Nonferrous Met Soc,2010(20):s42
32 Luis E Calzado,Cesar O Gomez,James A Finch.Nickel recovered from solution by oxidation using ozone:Some physical properties[J].Miner Eng,2005,18:537
33 姬忠涛,张正富,周效峰.β-NiOOH的臭氧氧化法合成、表征及电化学性能[J].中国有色金属学报,2012(22):1326
34 银小兵.γ-NiOOH绿色合成工艺及其在无汞碱锰电池中的应用[D].重庆:重庆大学,2007
35 Zhang W,Cheng C.Manganese metallurgy review.PartⅡ:Manganese separation and recovery from solution[J].Hydrometallurgy,2007,89:160
36 Bolton G L,Sefton V B,Zubryckyj N.Removal of manganese and chloride ions from aqueous acidic zinc sulfate solutions for the recovery of zinc:US4379037[P].1983
37 Bolton G L,Sefton V B,Zubryckyj N.Removal of manganese ions from zinc and manganese containing solutions:US4290866[P].1981
38 Kijima N,Yasuda H,Sato T,et al.Preparation and characterization of open tunnel oxide a-MnO2precipitated by ozone oxidation[J].J Solid State Chem,2001,159:94
39 Martín R Cruz-Díaz,Yennifer Arauz-Torres,Francisco Caballero,et al.Recovery of MnO2from a spent alkaline battery leach solution via ozone treatment[J].J Power Sources,2015,274:839
40 Myoung-Jin Kim,Jerome Nriagu.Oxidation of arsenite in groundwater using ozone and oxygen[J].Sci Total Environ,2000,247:71
41 Nishimura T,Umetsu Y.Oxidative precipitation of arsenicⅢwith manganeseⅡand ironⅡin dilute acidic solution by ozone[J].Hydrometallurgy,2001,62:83
42 沈文宁,冯拉俊,孔珍珍.AgO超细粉末的制备及银的价态变化研究[J].稀有金属材料工程,2011,40(11):1961