Determination of 13 Trace Elements in Anshun Thorn Pear (Rosa roxburghii) and Golden Thorn Pear (Rosa sterilis S.D.Shi) by ICP-MS
|
摘要
[Objectives] This study was conducted to establish an analytical method for the establishment of 13 trace elements in Anshun thorn pear(Rosa roxburghii) and golden thorn pear(Rosa sterilis S. D. Shi). [Methods] Nitric acid was used as the digestion system for microwave digestion. Inductively coupled plasma mass spectrometry(ICP-MS) was used to determine the trace elements in thorn pear and golden thorn pear. [Results] Be, Ti, V, Cr, Mn, Co, Ni, As, Sr, Mo, Cd, Sb and Hg were determined by ICP-MS method in thorn pear and golden thorn pear. The correlation coefficients of the regression equations of the elements were higher than 0.996; the precision RSD was lower than 2.87%; and the recovery ranged from 94.3% to 109.8%. [Conclusions] The method has the advantages of high sensitivity, good accuracy and simultaneous detection of multiple elements, and provides a reference method and theoretical basis for determining trace elements in thorn pear and golden thorn pear and other fruits.
[Objectives] This study was conducted to establish an analytical method for the establishment of 13 trace elements in Anshun thorn pear(Rosa roxburghii) and golden thorn pear(Rosa sterilis S. D. Shi). [Methods] Nitric acid was used as the digestion system for microwave digestion. Inductively coupled plasma mass spectrometry(ICP-MS) was used to determine the trace elements in thorn pear and golden thorn pear. [Results] Be, Ti, V, Cr, Mn, Co, Ni, As, Sr, Mo, Cd, Sb and Hg were determined by ICP-MS method in thorn pear and golden thorn pear. The correlation coefficients of the regression equations of the elements were higher than 0.996; the precision RSD was lower than 2.87%; and the recovery ranged from 94.3% to 109.8%. [Conclusions] The method has the advantages of high sensitivity, good accuracy and simultaneous detection of multiple elements, and provides a reference method and theoretical basis for determining trace elements in thorn pear and golden thorn pear and other fruits.
[Objectives] This study was conducted to establish an analytical method for the establishment of 13 trace elements in Anshun thorn pear(Rosa roxburghii) and golden thorn pear(Rosa sterilis S. D. Shi). [Methods] Nitric acid was used as the digestion system for microwave digestion. Inductively coupled plasma mass spectrometry(ICP-MS) was used to determine the trace elements in thorn pear and golden thorn pear. [Results] Be, Ti, V, Cr, Mn, Co, Ni, As, Sr, Mo, Cd, Sb and Hg were determined by ICP-MS method in thorn pear and golden thorn pear. The correlation coefficients of the regression equations of the elements were higher than 0.996; the precision RSD was lower than 2.87%; and the recovery ranged from 94.3% to 109.8%. [Conclusions] The method has the advantages of high sensitivity, good accuracy and simultaneous detection of multiple elements, and provides a reference method and theoretical basis for determining trace elements in thorn pear and golden thorn pear and other fruits.
引文
[1]DAI ZK,YU LM. Pharmacological action of Rosa roxbunghii[J]. China Pharmacy,2007,18(21):1668-1669.(in Chinese)
[2]Editorial Board of Flora of China,Chinese Academy of Sciences. Flora of China[M]. Beijing:Science Press,1998,37(2):452.(in Chinese)
[3]DAI TT,YANG XS. Advances in studies on chemical constituents and pharmacological activity of Rosa roxbunghii[J]. Journal of Guiyang College of Traditional Chinese Medicine,2015,37(4):93-97.(in Chinese)
[4]LIU W,LI S,HUANG X,et al. Inhibition of tumor growth in vitro by a combination of extracts from Rosa Roxburghii Tratt and Fagopyrum cymosum[J]. Asian Pacific Journal of Cancer Prevention,2012,13(5):2409-2414.
[5] MA Y X,ZHU Y,WANG C F,et al. The aging retarding effect of‘Long-Life Ci Li’[J]. Mech Ageing Dev,1997,96(1-3):171-180.
[6]SHI SD. A new taxonomic group of Guizhou Rosa plants[J]. Guizhou Science,1985(1):8-9.(in Chinese)
[7]JIAN CD. Advances in research on pharmacological effects of Rosa roxbunghii[J]. Guide of China Medicine,2011,9(29):38-40.(in Chinese)
[8]LU M,AN HM,ZHAO XH. Analysis of amino acids in Rosa sterilis and Rosa roxburghii fruits[J]. Food Science,2015,(14):118-121.(in Chinese)
[9]DU W,REN YQ. Content determination of trace element and total flavone in Cil[J]. Chinese Journal of Hospital Pharmacy,2003,23(9):530-532.(in Chinese)
[10]WANG ZW,ZHANG PP. Determination of mineral elements contents in Rosa roxburghii Tratt by microwave digestion and flame atomic absorption spectrometry[J]. Journal of Henan Agricultural Sciences,2015,44(6):125-127.(in Chinese)
[11]ZHANG YH,MA N. Quantitative determination of multiple elements in Rosa roxburghii and Rosa sterilis fruits using ICP-OES with microwave digestion[J]. Journal of Sun Yat-Sen University,2016,55(3):106-110.(in Chinese)
[12]CHI MY,LI GF,ZHOU W,et al. Determination of heavy metals in 10 kinds of traditional chinese medicine from Guizhou Province by ICP-MS[J]. Journal of Guizhou Medical University,2016,41(7):783-786.(in Chinese)
[13]ZU WC,WANG Y,LI BN. The application and development of elemental speciation analysis in foods by ICP-MS related hyphenated technique[J]. Journal of Chinese Mass Spectrometry Society,2013,34(4):247-256.(in Chinese)
[14]GUO HL,ZHANG S,LIU LY,et al. Determination of 13 kinds of metal elements in 10 common Chinese materia medica injection by ICPMS[J]. Chinese Traditional and Herbal Drugs,2015,46(17):2568-2572.(in Chinese)
[15]JIA GN. The harm and prevention of heavy metal pollution[J]. NonFerrous Mining and Metallurgy,2004,20(1):39-42.(in Chinese)
[2]Editorial Board of Flora of China,Chinese Academy of Sciences. Flora of China[M]. Beijing:Science Press,1998,37(2):452.(in Chinese)
[3]DAI TT,YANG XS. Advances in studies on chemical constituents and pharmacological activity of Rosa roxbunghii[J]. Journal of Guiyang College of Traditional Chinese Medicine,2015,37(4):93-97.(in Chinese)
[4]LIU W,LI S,HUANG X,et al. Inhibition of tumor growth in vitro by a combination of extracts from Rosa Roxburghii Tratt and Fagopyrum cymosum[J]. Asian Pacific Journal of Cancer Prevention,2012,13(5):2409-2414.
[5] MA Y X,ZHU Y,WANG C F,et al. The aging retarding effect of‘Long-Life Ci Li’[J]. Mech Ageing Dev,1997,96(1-3):171-180.
[6]SHI SD. A new taxonomic group of Guizhou Rosa plants[J]. Guizhou Science,1985(1):8-9.(in Chinese)
[7]JIAN CD. Advances in research on pharmacological effects of Rosa roxbunghii[J]. Guide of China Medicine,2011,9(29):38-40.(in Chinese)
[8]LU M,AN HM,ZHAO XH. Analysis of amino acids in Rosa sterilis and Rosa roxburghii fruits[J]. Food Science,2015,(14):118-121.(in Chinese)
[9]DU W,REN YQ. Content determination of trace element and total flavone in Cil[J]. Chinese Journal of Hospital Pharmacy,2003,23(9):530-532.(in Chinese)
[10]WANG ZW,ZHANG PP. Determination of mineral elements contents in Rosa roxburghii Tratt by microwave digestion and flame atomic absorption spectrometry[J]. Journal of Henan Agricultural Sciences,2015,44(6):125-127.(in Chinese)
[11]ZHANG YH,MA N. Quantitative determination of multiple elements in Rosa roxburghii and Rosa sterilis fruits using ICP-OES with microwave digestion[J]. Journal of Sun Yat-Sen University,2016,55(3):106-110.(in Chinese)
[12]CHI MY,LI GF,ZHOU W,et al. Determination of heavy metals in 10 kinds of traditional chinese medicine from Guizhou Province by ICP-MS[J]. Journal of Guizhou Medical University,2016,41(7):783-786.(in Chinese)
[13]ZU WC,WANG Y,LI BN. The application and development of elemental speciation analysis in foods by ICP-MS related hyphenated technique[J]. Journal of Chinese Mass Spectrometry Society,2013,34(4):247-256.(in Chinese)
[14]GUO HL,ZHANG S,LIU LY,et al. Determination of 13 kinds of metal elements in 10 common Chinese materia medica injection by ICPMS[J]. Chinese Traditional and Herbal Drugs,2015,46(17):2568-2572.(in Chinese)
[15]JIA GN. The harm and prevention of heavy metal pollution[J]. NonFerrous Mining and Metallurgy,2004,20(1):39-42.(in Chinese)