CO_2 sensing properties and mechanism of PrFeO_3 and NdFeO_3 thick film sensor
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摘要
The CO_2 sensing of PrFeO_3 and NdFeO_3 sensors were investigated. Experimental results show that the resistances for PrFeO_3 and NdFeO_3 in CO_2 gas are larger than those in air and the responses for PrFeO_3and NdFeO_3 sensors increase with an increase in room-temperature relative humidity. When exposed to1000 ppm CO_2, the response of PrFeO_3 thick film based on nano-powders annealed at 700℃can reach8.44 at 160℃for the background of wet air with 58%of room-temperature relative humidity (RH),which is much larger than the corresponding value (3.03) in wet air with 25%RH. The sensing response S of NdFeO_3 thick-film sensor based on nano-powders annealed at 600℃to 3000 ppm CO_2 at the operating temperature 200℃can reach 2.36 for the background of wet air with 72%RH, which is larger than the corresponding value (1.83) in the air with 25%RH. Compared with other CO_2 sensing materials, the PrFeO_3 sensor has larger response at lower operating temperature for CO_2 gas and may be used as a new CO_2 sensing material.
The CO_2 sensing of PrFeO_3 and NdFeO_3 sensors were investigated. Experimental results show that the resistances for PrFeO_3 and NdFeO_3 in CO_2 gas are larger than those in air and the responses for PrFeO_3 and NdFeO_3 sensors increase with an increase in room-temperature relative humidity. When exposed to1000 ppm CO_2, the response of PrFeO_3 thick film based on nano-powders annealed at 700 ℃ can reach8.44 at 160 ℃ for the background of wet air with 58% of room-temperature relative humidity(RH), which is much larger than the corresponding value(3.03) in wet air with 25% RH. The sensing response S of NdFeO_3 thick-film sensor based on nano-powders annealed at 600 ℃ to 3000 ppm CO_2 at the operating temperature 200 ℃ can reach 2.36 for the background of wet air with 72% RH, which is larger than the corresponding value(1.83) in the air with 25% RH. Compared with other CO_2 sensing materials, the PrFeO_3 sensor has larger response at lower operating temperature for CO_2 gas and may be used as a new CO_2 sensing material.
The CO_2 sensing of PrFeO_3 and NdFeO_3 sensors were investigated. Experimental results show that the resistances for PrFeO_3 and NdFeO_3 in CO_2 gas are larger than those in air and the responses for PrFeO_3 and NdFeO_3 sensors increase with an increase in room-temperature relative humidity. When exposed to1000 ppm CO_2, the response of PrFeO_3 thick film based on nano-powders annealed at 700 ℃ can reach8.44 at 160 ℃ for the background of wet air with 58% of room-temperature relative humidity(RH), which is much larger than the corresponding value(3.03) in wet air with 25% RH. The sensing response S of NdFeO_3 thick-film sensor based on nano-powders annealed at 600 ℃ to 3000 ppm CO_2 at the operating temperature 200 ℃ can reach 2.36 for the background of wet air with 72% RH, which is larger than the corresponding value(1.83) in the air with 25% RH. Compared with other CO_2 sensing materials, the PrFeO_3 sensor has larger response at lower operating temperature for CO_2 gas and may be used as a new CO_2 sensing material.
引文
1. Yu CH, Huang CH, Tan CS. A review of CO_2 capture by absorption and adsorption. Aerosol Air Qual Res. 2012;12(5):745.
2. Hansen J, Sato M, Kharecha P, Beerling D, Berner R, Masson-Delmotte V, et al.Target atmospheric CO_2:where should humanity aim? Open Atmos Sci J.2008;2:217.
3. Ong KG, Grimes CA. A carbon nanotube-based sensor for CO_2 monitoring.Sensors. 2001:1:193.
4. Ishihara T, Kometani K, Mizuhara Y, Takita Y. Mixed oxide capacitor of CuOBaTiO_3 as a new type CO_2 gas sensor. J Am Ceram Soc. 1992;75:613.
5. Ishihara T, Kometani K, Hashida M, Takita Y. Applications of mixed oxide capacitor to the selective carbon dioxide sensor. J Electrochem Soc. 1991;138:173.
6. Wang W, Lee KK, Kim TH, Park L, Yang SS. A novel wireless, passive CO_2 sensor incorporating a surface acoustic wave reflective delay line. Smart Mater Struct.2007;16:1382.
7. Nieuwenhuizen MS, Nederlof AJ. A SAW gas sensor for carbon dioxide and water. Preliminary experiments. Sens Actuators B Chem. 1990;2:97.
8. Maruyama T, Sasaki S, Saito Y. Potentiometric gas sensor for carbon dioxide using solid electrolytes. Solid State Ionics. 1987;23:107.
9. Miura N, Yao S, Shimizu Y, Yamazoe N. Carbon dioxide sensor using sodium ion conductor and binary carbonate auxiliary electrode. J Electrochem Soc.1992;139:1384.
10. Aono H, Sugimoto F, Sadaoka Y, Imanaka N,Adachi G. Ionic conductivity of solid electrolytes based on lithium titanium phosphate.J Electrochem Soc.1990;37:1023.
11. Shimizu Y, Yamashita N. Solid electrolyte CO_2 sensor using NASICON and perovskite-type oxide electrode. Sens Actuators B Chem. 2000;64:102.
12. Yao S, Hosohara S, Shimizu Y, Miura N, Futata H, Yamazoe N. Solid electrolyte CO_2 sensor using NASICON and Li-based binary carbonate electrode. Chem Lett.1991;11:2069.
13. Hong W, Chen Y, Feng X, Yan Y, Hu XB, Zhao BY, et al. Full-color C02 gas sensing by an inverse opal photonic hydrogel. Chem Commun. 2013;49:8229.
14. Chiang CJ, Tsai KT, Lee YH, Lin HW, Yang YL, Shiha CC, et al. In situ fabrication of conducting polymer composite film as a chemical resistive CO_2 gas sensor.Microelectron Eng. 2013;111:409.
15. Waghuley S, Yenorkar S, Yawale S, Yawale S. Application of chemically synthesized conducting polymer-polypyrrole as a carbon dioxide gas sensor. Sens Actuators B Chem. 2008;128:366.
16. Yaqub S, Mellon N, Shariff A. A review on robustness of covalent organic polymers for CO_2 capture. Appl Mech Mater. 2014;625:237.
17. Wang XF, Ma W, Sun KM, Hu JF, Qin HW. Nanocrystalline Gd_(1-x)Ca_xFeO_3 sensors for detection of methanol gas. J Rare Earths. 2017;35(7):690.
18. Zhang PP, Qin HW, Zhang H, Lv W, Hu JF. CO_2 gas sensors based on Yb1-xCaxFeO_3 nanocrystalline powders.J Rare Earths. 2017;35(6):602.
19. Chen YP, Qin HW, Shi CM, Li L, Hu JF. High temperature C02 sensing properties and mechanism of nanocrystalline LaCrO_3 with rhombohedral structure:experiments and ab initio calculations. RSC Adv. 2015;5(67):54710.
20. Marsal A, Dezanneau G, Cornet A, Morante JR. A new CO_2 gas sensing material.Sens Actuators B Chem. 2003;95:266.
21. Steiner K, Hoefer U, Kiihner G, Sulz G, Wagner E. Ca-and Pt-catalysed thin-film SnO_2 gas sensors for CO and CO_2 detection. Sens Actuators B Chem.1995:24-25:529.
22. Trung DD, Toan LD, Hong HS, Lam TD, Trung T, Hieu NV. Selective detection of carbon dioxide using LaOCl-functionalized SnO2 nanowires for air-quality monitoring. Talanta. 2012;88:152.
23. Krishnakumar T, Jayaprakash R, Prakash T, Sathyaraj D, Donato N, Licoccia S,et al. CdO-based nanostructures as novel CO_2 gas sensors. Nanotechnology.2011;22(32):325501.
24. Kim DH, Yoon JY, Park HC, Kim KH. CO_2-sensing characteristics of Sn02 thick film by coating lanthanum oxide. Sens Actuators B Chem. 2000;62:61.
25. Marsal A, Cornet A, Morante JR. Study of the CO and humidity interference in La doped tin oxide CO_2 gas sensor. Sens Actuators B Chem. 2003;94:324.
26. Diagne EHA, Lumbreras M. Elaboration and characterization of tin oxidelanthanum oxide mixed layers prepared by the electrostatic spray pyrolysis technique. Sens Actuators B Chem. 2001;78:98.
27.Yadav BC, Srivastava R, Dwivedi CD, Pramanik P. Moisture sensor based on ZnO nanomaterial synthesized through oxalate route. Sens Actuators B Chem.2008;131(1):216.
28. Wang DD, Chen YP, Liu ZX, Li L,Shi CM, Qin HW, et al. CO_2-sensing properties and mechanism of nano-SnO_2 thick-film sensor. Sens Actuators B Chem.2016;227:73.
29. Manoilova OV, Podkolzin SG, Tope B, Lercher J, Stangland EE, Goupil JM, et al.Surface acidity and basicity of La_2O_3, LaOCl, and LaCl_3 characterized by IR spectroscopy, TPD, and DFT calculations. J Phys Chem B. 2004;108(40):15770.
30. Delgado E, Michel CR. CO_2 and O_2 sensing behavior of nanostructured bariumdoped SmCo03. Mater Lett. 2006;60(13):1613.
31. Michel CR, Martinez AH, Huerta-Villalpando F, Moran-Lazaro JP. Carbon dioxide gas sensing behavior of nanostructured GdCoO_3 prepared by a solutionpolymerization method.J Alloys Compd. 2009;484(1):605.
32. Wang XF, Qin HW, Sun LH, Hu JF. CO_2 sensing properties and mechanism of nanocrystalline LaFeO_3 sensor. Sens Actuators B Chem. 2013;188:965.
33. Djerdj I, Haensch A, Koziej D, Pokhrel S, Barsan N, Weimar U, et al. Neodymium dioxide carbonate as a sensing layer for chemoresistive CO_2 sensing. Chem Mater. 2009;21:5375.
34. Wang XF, Chen YP, Qin HW, Li L, Shi CM, Liu L, et al. CO_2 sensing of La_(0.875)Ca_(0.125)FeO_3 in wet vapor:a comparison of experimental results and firstprinciples calculations. Phys Chem Chem Phys. 2015;17:13733.
35. Li L, Qin HW, Shi CM, Zhang L, Chen YP, Hu JF. CO_2 sensing properties of La_(1-x)Ba_xFeO_3 thick film-and packed powder-sensors. RSC Adv. 2015;5:103073.
36. Fan K, Qin HW, Wang L, Ju L, Hu JF. C02 gas sensors based on La_(1-x)Sr_xFeO_3nanocrystalline powders. Sens Actuators B Chem. 2013;177:265.
37. Haeusler A, Meyer JU. A novel thick film conductive type CO_2 sensor. Sens Actuators B Chem. 1996;34(1):388.
38. Lee MS, Meyer JU. A new process for fabricating CO_2-sensing layers based on BaTiO_3 and additives. Sens Actuators B Chem. 2000;68(1):293.
39. Prasad BV, Rao GN, Chen JW, Babu DS. Colossal dielectric constant in PrFeO_3semiconductor ceramics. Solid State Sci. 2012;14(2):225.
40. Wang XY, Cao SX, Wang YB, Yuan SJ, Kang BJ, Wu AH, et al. Crystal growth and characterization of the rare earth orthoferrite PrFeO_3.J Cryst Growth. 2013;362:216.
41. Chikhale L,Patil J, Rajgure A, Shaikh F, Mulla I, Suryavanshi S. Co-precipitation synthesis of nanocrystalline SnO_2:effect of Fe doping on structural, morphological and ethanol vapor response properties. Measurement.2014;57:46.
42. Yamazoe N, Fuchigami J, Kishikawa M, Seiyama T. Interactions of tin oxide surface with O_2, H_2O and H_2. Surf Sci. 1979;86:335.
43. Siemons M, Leifert A, Simon U. Preparation and gas sensing characteristics of nanoparticulate p-type semiconducting LnFeO_3 and LnCrO_3 materials. Adv Funct Mater. 2007;17:2189.
44. Chen G, Han BQ, Deng SJ, Wang Y, Wang YD. Lanthanum dioxide carbonate La_2O_2CO_3 nanorods as a sensing material for chemoresistive CO_2 gas sensor.Electrochim Acta. 2014;127:355.
45. Desai RR, Lakshminarayana D, Patel PB, Panchal CB. Indium sesquitelluride(In_2Te_3)thin film gas sensor for detection of carbon dioxide. Sens Actuators B Chem. 2005;107(2):523.
46. Chapelle A, El Younsi I, Vitale S, Thimont Y, Nelis Th, Presmanes L, et al.Improved semiconducting CuO/CuFe_2O_4 nanostructured thin films for CO_2 gas sensing. Sens Actuators B Chem. 2014;204:407.
2. Hansen J, Sato M, Kharecha P, Beerling D, Berner R, Masson-Delmotte V, et al.Target atmospheric CO_2:where should humanity aim? Open Atmos Sci J.2008;2:217.
3. Ong KG, Grimes CA. A carbon nanotube-based sensor for CO_2 monitoring.Sensors. 2001:1:193.
4. Ishihara T, Kometani K, Mizuhara Y, Takita Y. Mixed oxide capacitor of CuOBaTiO_3 as a new type CO_2 gas sensor. J Am Ceram Soc. 1992;75:613.
5. Ishihara T, Kometani K, Hashida M, Takita Y. Applications of mixed oxide capacitor to the selective carbon dioxide sensor. J Electrochem Soc. 1991;138:173.
6. Wang W, Lee KK, Kim TH, Park L, Yang SS. A novel wireless, passive CO_2 sensor incorporating a surface acoustic wave reflective delay line. Smart Mater Struct.2007;16:1382.
7. Nieuwenhuizen MS, Nederlof AJ. A SAW gas sensor for carbon dioxide and water. Preliminary experiments. Sens Actuators B Chem. 1990;2:97.
8. Maruyama T, Sasaki S, Saito Y. Potentiometric gas sensor for carbon dioxide using solid electrolytes. Solid State Ionics. 1987;23:107.
9. Miura N, Yao S, Shimizu Y, Yamazoe N. Carbon dioxide sensor using sodium ion conductor and binary carbonate auxiliary electrode. J Electrochem Soc.1992;139:1384.
10. Aono H, Sugimoto F, Sadaoka Y, Imanaka N,Adachi G. Ionic conductivity of solid electrolytes based on lithium titanium phosphate.J Electrochem Soc.1990;37:1023.
11. Shimizu Y, Yamashita N. Solid electrolyte CO_2 sensor using NASICON and perovskite-type oxide electrode. Sens Actuators B Chem. 2000;64:102.
12. Yao S, Hosohara S, Shimizu Y, Miura N, Futata H, Yamazoe N. Solid electrolyte CO_2 sensor using NASICON and Li-based binary carbonate electrode. Chem Lett.1991;11:2069.
13. Hong W, Chen Y, Feng X, Yan Y, Hu XB, Zhao BY, et al. Full-color C02 gas sensing by an inverse opal photonic hydrogel. Chem Commun. 2013;49:8229.
14. Chiang CJ, Tsai KT, Lee YH, Lin HW, Yang YL, Shiha CC, et al. In situ fabrication of conducting polymer composite film as a chemical resistive CO_2 gas sensor.Microelectron Eng. 2013;111:409.
15. Waghuley S, Yenorkar S, Yawale S, Yawale S. Application of chemically synthesized conducting polymer-polypyrrole as a carbon dioxide gas sensor. Sens Actuators B Chem. 2008;128:366.
16. Yaqub S, Mellon N, Shariff A. A review on robustness of covalent organic polymers for CO_2 capture. Appl Mech Mater. 2014;625:237.
17. Wang XF, Ma W, Sun KM, Hu JF, Qin HW. Nanocrystalline Gd_(1-x)Ca_xFeO_3 sensors for detection of methanol gas. J Rare Earths. 2017;35(7):690.
18. Zhang PP, Qin HW, Zhang H, Lv W, Hu JF. CO_2 gas sensors based on Yb1-xCaxFeO_3 nanocrystalline powders.J Rare Earths. 2017;35(6):602.
19. Chen YP, Qin HW, Shi CM, Li L, Hu JF. High temperature C02 sensing properties and mechanism of nanocrystalline LaCrO_3 with rhombohedral structure:experiments and ab initio calculations. RSC Adv. 2015;5(67):54710.
20. Marsal A, Dezanneau G, Cornet A, Morante JR. A new CO_2 gas sensing material.Sens Actuators B Chem. 2003;95:266.
21. Steiner K, Hoefer U, Kiihner G, Sulz G, Wagner E. Ca-and Pt-catalysed thin-film SnO_2 gas sensors for CO and CO_2 detection. Sens Actuators B Chem.1995:24-25:529.
22. Trung DD, Toan LD, Hong HS, Lam TD, Trung T, Hieu NV. Selective detection of carbon dioxide using LaOCl-functionalized SnO2 nanowires for air-quality monitoring. Talanta. 2012;88:152.
23. Krishnakumar T, Jayaprakash R, Prakash T, Sathyaraj D, Donato N, Licoccia S,et al. CdO-based nanostructures as novel CO_2 gas sensors. Nanotechnology.2011;22(32):325501.
24. Kim DH, Yoon JY, Park HC, Kim KH. CO_2-sensing characteristics of Sn02 thick film by coating lanthanum oxide. Sens Actuators B Chem. 2000;62:61.
25. Marsal A, Cornet A, Morante JR. Study of the CO and humidity interference in La doped tin oxide CO_2 gas sensor. Sens Actuators B Chem. 2003;94:324.
26. Diagne EHA, Lumbreras M. Elaboration and characterization of tin oxidelanthanum oxide mixed layers prepared by the electrostatic spray pyrolysis technique. Sens Actuators B Chem. 2001;78:98.
27.Yadav BC, Srivastava R, Dwivedi CD, Pramanik P. Moisture sensor based on ZnO nanomaterial synthesized through oxalate route. Sens Actuators B Chem.2008;131(1):216.
28. Wang DD, Chen YP, Liu ZX, Li L,Shi CM, Qin HW, et al. CO_2-sensing properties and mechanism of nano-SnO_2 thick-film sensor. Sens Actuators B Chem.2016;227:73.
29. Manoilova OV, Podkolzin SG, Tope B, Lercher J, Stangland EE, Goupil JM, et al.Surface acidity and basicity of La_2O_3, LaOCl, and LaCl_3 characterized by IR spectroscopy, TPD, and DFT calculations. J Phys Chem B. 2004;108(40):15770.
30. Delgado E, Michel CR. CO_2 and O_2 sensing behavior of nanostructured bariumdoped SmCo03. Mater Lett. 2006;60(13):1613.
31. Michel CR, Martinez AH, Huerta-Villalpando F, Moran-Lazaro JP. Carbon dioxide gas sensing behavior of nanostructured GdCoO_3 prepared by a solutionpolymerization method.J Alloys Compd. 2009;484(1):605.
32. Wang XF, Qin HW, Sun LH, Hu JF. CO_2 sensing properties and mechanism of nanocrystalline LaFeO_3 sensor. Sens Actuators B Chem. 2013;188:965.
33. Djerdj I, Haensch A, Koziej D, Pokhrel S, Barsan N, Weimar U, et al. Neodymium dioxide carbonate as a sensing layer for chemoresistive CO_2 sensing. Chem Mater. 2009;21:5375.
34. Wang XF, Chen YP, Qin HW, Li L, Shi CM, Liu L, et al. CO_2 sensing of La_(0.875)Ca_(0.125)FeO_3 in wet vapor:a comparison of experimental results and firstprinciples calculations. Phys Chem Chem Phys. 2015;17:13733.
35. Li L, Qin HW, Shi CM, Zhang L, Chen YP, Hu JF. CO_2 sensing properties of La_(1-x)Ba_xFeO_3 thick film-and packed powder-sensors. RSC Adv. 2015;5:103073.
36. Fan K, Qin HW, Wang L, Ju L, Hu JF. C02 gas sensors based on La_(1-x)Sr_xFeO_3nanocrystalline powders. Sens Actuators B Chem. 2013;177:265.
37. Haeusler A, Meyer JU. A novel thick film conductive type CO_2 sensor. Sens Actuators B Chem. 1996;34(1):388.
38. Lee MS, Meyer JU. A new process for fabricating CO_2-sensing layers based on BaTiO_3 and additives. Sens Actuators B Chem. 2000;68(1):293.
39. Prasad BV, Rao GN, Chen JW, Babu DS. Colossal dielectric constant in PrFeO_3semiconductor ceramics. Solid State Sci. 2012;14(2):225.
40. Wang XY, Cao SX, Wang YB, Yuan SJ, Kang BJ, Wu AH, et al. Crystal growth and characterization of the rare earth orthoferrite PrFeO_3.J Cryst Growth. 2013;362:216.
41. Chikhale L,Patil J, Rajgure A, Shaikh F, Mulla I, Suryavanshi S. Co-precipitation synthesis of nanocrystalline SnO_2:effect of Fe doping on structural, morphological and ethanol vapor response properties. Measurement.2014;57:46.
42. Yamazoe N, Fuchigami J, Kishikawa M, Seiyama T. Interactions of tin oxide surface with O_2, H_2O and H_2. Surf Sci. 1979;86:335.
43. Siemons M, Leifert A, Simon U. Preparation and gas sensing characteristics of nanoparticulate p-type semiconducting LnFeO_3 and LnCrO_3 materials. Adv Funct Mater. 2007;17:2189.
44. Chen G, Han BQ, Deng SJ, Wang Y, Wang YD. Lanthanum dioxide carbonate La_2O_2CO_3 nanorods as a sensing material for chemoresistive CO_2 gas sensor.Electrochim Acta. 2014;127:355.
45. Desai RR, Lakshminarayana D, Patel PB, Panchal CB. Indium sesquitelluride(In_2Te_3)thin film gas sensor for detection of carbon dioxide. Sens Actuators B Chem. 2005;107(2):523.
46. Chapelle A, El Younsi I, Vitale S, Thimont Y, Nelis Th, Presmanes L, et al.Improved semiconducting CuO/CuFe_2O_4 nanostructured thin films for CO_2 gas sensing. Sens Actuators B Chem. 2014;204:407.