Fe_3O_4纳米材料的改性研究及在锂离子电池负极中的应用
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摘要
四氧化三铁凭借其较高的比容量(926 mAh/g)、良好的导电性(σ=2×10~4 S/m)、成本低、自然丰度大、环境友好等优点,在锂离子电池负极材料的研究中占了举足轻重的地位.综述了四氧化三铁作为锂离子电池负极材料的研究情况,主要包括特殊形貌纳米材料及复合纳米材料,指出了对于四氧化三铁作为锂离子电池负极材料存在的问题、亟待解决的方法以及未来的发展方向。
With its high specific capacity(926 mAh/g), good electrical conductivity(σ=2×10~4 S/m), low cost, high natural abundance and environmental friendliness, ferroferric oxide is extensively used in lithium ion batteries. The research of anode material occupies the pivotal position. This paper reviews the research status of ferroferric oxide as the anode material of lithium ion battery, including the preparation of special morphology nanomaterials and composite nanomaterials. As for ferroferric oxide as a lithium ion battery anode material, problems, urgent solutions and future directions are also pointed out.
With its high specific capacity(926 mAh/g), good electrical conductivity(σ=2×10~4 S/m), low cost, high natural abundance and environmental friendliness, ferroferric oxide is extensively used in lithium ion batteries. The research of anode material occupies the pivotal position. This paper reviews the research status of ferroferric oxide as the anode material of lithium ion battery, including the preparation of special morphology nanomaterials and composite nanomaterials. As for ferroferric oxide as a lithium ion battery anode material, problems, urgent solutions and future directions are also pointed out.
引文
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[16] Xiong Q Q,Tu J P,Lu Y,et al.Synthesis of Hie-rarchical Hollow-structured Single-crystalline Magnetite (Fe3O4) Microspheres:The Highly Powerful Storage Versus Lithium as an Anode for Lithium Ion Batteries [J].J Phys Chem C,2012,116(10):6 495-6 502.
[17] Lim H S,Jung B Y,Sun Y K,et al.Hollow Fe3O4 Microspheres as Anode Materials for Lithium-ion Batteries [J].Electrochim Acta,2012,75(4):123-130.
[18] Zhang W M,Wu X L,Hu J S,et al.Carbon Coated Fe3O4 Nanospindles as a Superior Anode Material for Lithium-ion Batteries [J].Adv Funct Mater,2010,18(24):3 941-3 946.
[19] Lian P C,Zhu X F,Xiang H F,et al.Enhanced Cycling Performance of Fe3O4-graphene Nanocomposite as An Anode Material for Lithium-ion Batteries [J].Electrochim Acta,2010,56(2):834-840.
[20] Wang K X.Preparation of Hierarchical Porous Carbon Materials and Heterogeneous Fe3O4@Fe3C-C Yolk-shell Nanostructures for Enhanced Electrochemi-cal Performance [D].Zhengzhou:Zhengzhou University,2016.(王凯熙.多级孔碳和摇铃型 Fe3O4@Fe3C-C 异质结构的构筑及电化学性能优化[D].郑州:郑州大学.2016.)
[21] Jiang H,Hu Y J,Guo S J,et al.Rational Design of MnO/Carbon Nanopeapods with Internal Void Space for High-rate and Long-life Li-ion Batteries [J].ACS Nano,2014,8(6):6 038-6 046.
[22] Zhang J N,Guo S J,Wei J Y,et al.High-efficiency Encapsulation of Pt Nanoparticles into the Channel of Carbon Nanotubes as an Enhanced Electrocatalyst for Methanol Oxidation [J].Chem Eur J,2013,19(47):16 087-16 092.
[23] Luo J S,Liu J L,Zeng Z Y,et al.Three-dimensional Graphene Foam Supported Fe3O4 Lithium Battery Anodes with Long Cycle Life and High Rate Capability [J].Nano Lett,2013,13(12):6 136-6 143.
[24] He C N,Wu S,Zhao N Q,et al.Carbon-encapsulated Fe3O4 Nanoparticles as a High-rate Lithium Ion Battery Anode Material [J].ACS Nano,2013,7(5):4 459-4 469.
[25] Cheng J L,Wang B,Park C M,et al.CNT@ Fe3O4-@C Coaxial Nanocables:One-pot,Additive-free Synthesis and Remarkable Lithium Storage Behavior [J].Chem Eur J,2013,19(30):9 866-9 874.
[26] Huang X,Chen J,Lu Z Y,et al.Carbon Inverse Opal Entrapped with Electrode Active Nanoparticles as High-performance Anode for Lithium-ion Batteries [J].Sci Rep,2013,3:2 317-2 325.
[27] Li D,Wang K L,Tao H W,et al.Facile Synthesis of Fe3O4/FeO/Fe/C Composite as High-performance Anode for Lithium-ion Battery [J].Rsc Adv,2016,6(92).
[28] Wang Y K,Zhang H Y,Hu R Z,et al.Fe3O4/SnO2/rGO Ternary Composite as a High-performance Anode Material for Lithium-ion Batteries [J].J Alloys Compd,2017,693:1 174-1 179.
[2] Poizot P,Laruelle S,Grugeon S,et al.Nano-sized Transition-metal Oxides as Negative-electrode Materials for Lithium-ion Batteries [J].Nature,2000,407(6803):496-499.
[3] Zhang W,Guo M,Gu H,et al.A New Lithium-ion Battery:CuO Nanorod Array Anode Versus Spinel LiNi0.5Mn1.5O4,Cathode [J].J Power Sources,2015,273(273):561-565.
[4] Xiang J Y,Tu J P,Zhang L,et al.Self-assembled Synthesis of Hierarchical Nanostructured CuO with Various Morphologies and Their Application as Ano-des for Lithium Ion Batteries [J].J Power Sources,2010,195(1):313-319.
[5] Song Q F.Preparation and Surface Modification of Fe3O4 Nano-particles and the Effect in Magnetic Field [D].Shijiazhuang:Hebei Normal University,2008.(宋庆峰.纳米四氧化三铁的制备、修饰及磁场影响[D].石家庄:河北师范大学,2008.)
[6] Zhang W,Hou X,Shen J,et al.Magnetic PSA-Fe3O4@C 3D Mesoporous Microsphere as Anode for Lithium Ion Batteries [J].Electrochim Acta,2016,188:734-743.
[7] Wang S Q.Synthesis of Nano/Micro Composite Structured Copper/Ion/Vanadium Oxides and Their Applications for Lithium-ion Batteries [D].Hefei:University of Science and Technology of China,2010.(王素清.纳微复合结构的铜铁机氧化物电极材料的合成及性能表征[D].合肥:中国科学技术学院.2010.)
[8] Zhang Y.Synthesis and Characterizations of Fe3O4 Anode Materials for Li-ion Batteries [D].Jilin:Jilin University,2014.(张宇.锂离子电池负极材料Fe3O4的制备与性质研究[D].吉林:吉林大学,2014.)
[9] Geng H,Li S,Pan Y,et al.Porous Fe3O4 Hollow Spheres with Chlorine-doped-carbon Coating as Superior Anode Materials for Lithium Ion Batteries [J].Rsc Adv.,2015,5(65):52 993-52 997.
[10] Cui L F.Synthesis and electrochemical Properties of SnO@Ppy and FeO@C as Anode Materials for Lithium Ion Batteries [D].Tiangjing:Nankai University,2010.(崔立丰.锂离子电池负极材料SnO@PPy和FeO@C的制备及电化学性能研究[D].天津:南开大学,2010.)
[11] Tang Y P,Wang S M,Hou G Y,et al.Rearch Progress in Magnetite as Anode Material for Li-ion battery [J].Battery Bimon,2014,44(1):51-52.(唐谊平,王诗明,侯广亚.锂离子电池负极材料四氧化三铁的研究进展[J].电池,2014,44(1):51-52.)
[12] Geng H B.The Preparation and Modification of the Anode Materials for Li-ion Batteries [D].Suzhou:Soochow University,2014.(耿洪波.锂离子电池负极材料的制备及其改性研究[D].苏州:苏州大学.2014.)
[13] Wang X,Liu Y,Arandiyan H,et al.Uniform Fe3O4 Microflowers Hierarchical Structures Assembled with Porous Nanoplates as Superior Anode Materials for Lithium-ion Batteries [J].Appl Surf Sci,2016,389:240-246.
[14] Su D,Ahn H J,Wang G.One-dimensional Magnetite Fe3O4 Nanowires as Electrode Material for Li-ion Batteries with Improved Electrochemical Performance [J].J Power Sources,2013,244(4):742-746.
[15] Lee S H,Yu S H,Lee J E,et al.Self-assembled Fe3O4 Nanoparticle Clusters as High-performance Anodes for Lithium Ion Batteries Via Geometric Confinement [J].Nano Lett,2013,13(9):4 249-4 256.
[16] Xiong Q Q,Tu J P,Lu Y,et al.Synthesis of Hie-rarchical Hollow-structured Single-crystalline Magnetite (Fe3O4) Microspheres:The Highly Powerful Storage Versus Lithium as an Anode for Lithium Ion Batteries [J].J Phys Chem C,2012,116(10):6 495-6 502.
[17] Lim H S,Jung B Y,Sun Y K,et al.Hollow Fe3O4 Microspheres as Anode Materials for Lithium-ion Batteries [J].Electrochim Acta,2012,75(4):123-130.
[18] Zhang W M,Wu X L,Hu J S,et al.Carbon Coated Fe3O4 Nanospindles as a Superior Anode Material for Lithium-ion Batteries [J].Adv Funct Mater,2010,18(24):3 941-3 946.
[19] Lian P C,Zhu X F,Xiang H F,et al.Enhanced Cycling Performance of Fe3O4-graphene Nanocomposite as An Anode Material for Lithium-ion Batteries [J].Electrochim Acta,2010,56(2):834-840.
[20] Wang K X.Preparation of Hierarchical Porous Carbon Materials and Heterogeneous Fe3O4@Fe3C-C Yolk-shell Nanostructures for Enhanced Electrochemi-cal Performance [D].Zhengzhou:Zhengzhou University,2016.(王凯熙.多级孔碳和摇铃型 Fe3O4@Fe3C-C 异质结构的构筑及电化学性能优化[D].郑州:郑州大学.2016.)
[21] Jiang H,Hu Y J,Guo S J,et al.Rational Design of MnO/Carbon Nanopeapods with Internal Void Space for High-rate and Long-life Li-ion Batteries [J].ACS Nano,2014,8(6):6 038-6 046.
[22] Zhang J N,Guo S J,Wei J Y,et al.High-efficiency Encapsulation of Pt Nanoparticles into the Channel of Carbon Nanotubes as an Enhanced Electrocatalyst for Methanol Oxidation [J].Chem Eur J,2013,19(47):16 087-16 092.
[23] Luo J S,Liu J L,Zeng Z Y,et al.Three-dimensional Graphene Foam Supported Fe3O4 Lithium Battery Anodes with Long Cycle Life and High Rate Capability [J].Nano Lett,2013,13(12):6 136-6 143.
[24] He C N,Wu S,Zhao N Q,et al.Carbon-encapsulated Fe3O4 Nanoparticles as a High-rate Lithium Ion Battery Anode Material [J].ACS Nano,2013,7(5):4 459-4 469.
[25] Cheng J L,Wang B,Park C M,et al.CNT@ Fe3O4-@C Coaxial Nanocables:One-pot,Additive-free Synthesis and Remarkable Lithium Storage Behavior [J].Chem Eur J,2013,19(30):9 866-9 874.
[26] Huang X,Chen J,Lu Z Y,et al.Carbon Inverse Opal Entrapped with Electrode Active Nanoparticles as High-performance Anode for Lithium-ion Batteries [J].Sci Rep,2013,3:2 317-2 325.
[27] Li D,Wang K L,Tao H W,et al.Facile Synthesis of Fe3O4/FeO/Fe/C Composite as High-performance Anode for Lithium-ion Battery [J].Rsc Adv,2016,6(92).
[28] Wang Y K,Zhang H Y,Hu R Z,et al.Fe3O4/SnO2/rGO Ternary Composite as a High-performance Anode Material for Lithium-ion Batteries [J].J Alloys Compd,2017,693:1 174-1 179.