MCM-22分子筛催化烷基化反应的研究进展
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摘要
结合烷基化反应的催化机理,综述了MCM-22的孔道结构和表面酸性对芳烃烷基化反应的影响,总结了其应用于烷基化反应的优势与不足,进一步介绍了针对MCM-22特点适用的改性方法,及改性后分子筛的催化烷基化性能,最后对该方向研究提出了展望。
Combining with the catalytic mechanism of alkylation reaction,the effects of the porous structure and surface acidity of MCM-22 on the alkylation of aromatic hydrocarbons are reviewed.The advantages and disadvantages are summarized when MCM-22 is applied in alkylation.The modification methods suitable for the features of MCM-22 as well as the catalytic performance of modified MCM-22 in alkylation are further introduced.At last,a research prospect for this issue is proposed.
Combining with the catalytic mechanism of alkylation reaction,the effects of the porous structure and surface acidity of MCM-22 on the alkylation of aromatic hydrocarbons are reviewed.The advantages and disadvantages are summarized when MCM-22 is applied in alkylation.The modification methods suitable for the features of MCM-22 as well as the catalytic performance of modified MCM-22 in alkylation are further introduced.At last,a research prospect for this issue is proposed.
引文
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[17]Zhao F,Zhang Y,Jiang W J.Acid properties of MCM-36 molecular sieve and its catalytic behavior in benzene alkylation with propylene[J].Advanced Material Research,2014,1015:434-437.
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[23]Magar R R,Pawar G T,Arbad B R,et al.Fe-MCM-22:An efficient heterogeneous catalyst for one pot four component synthesis of 1Hpyrazolo[1,2-b]phthalazine-5,10-dione derivatives[J].Advanced Organic Chemistry Letters,2016,3(1):8-14.
[24]Zhang H L,Tang C J,Gao F,et al.Synthesis and catalytic activity of Fe-MCM-41 nanoparticles[J].Advanced Materials Research,2014,933:17-22.
[25]Shamzhy M V,Ochoa-Hernndez C,Kasneryk V I,et al.Direct incorporation of B,Al,and Ga into medium-pore ITH zeolite:Synthesis,acidic,and catalytic properties[J].Catalysis Today,2016,277:34-37.
[26]Mihlyi M R,Kollr M,Klébert S,et al.Transformation of ethylbenzene-m-xylene feed over MCM-22 zeolites with different acidities[J].Applied Catalysis A:General,2014,476:19-25.
[27]Kolev I,Mavrodinova V,Alexieva G,et al.Pore volume probing of boron-modified MCM-22 zeolite by quartz crystal microbalance assisted study of o-and p-xylene adsorption[J].Senors and Actuators B:Chemical,2010,149:389-394.
[28]Mihlyi M R,Kollr M,Kirly P,et al.Effect of extra-framework Al formed by successive steaming and acid leaching of zeolite MCM-22on its structure and catalytic performance[J].Applied Catalysis A:General,2012,417/418:76-86.
[2]曹志涛,邱志文,赵楠楠,等.烷基化工艺技术进展[J].精细石油化工进展,2016,17(4):34-37.
[3]闻振浩,杨大强,朱学栋.苯和甲醇烷基化反应机理及催化剂研究进展[J].现代化工,2017,37(1):41-46.
[4]Opanasenko M V,Roth W J,Cejka J.Two-dimantional zeolites in catalysis:Current status and perspectives[J].Catalysis and Science Technology,2016,6:2467-2484.
[5]Corma A,Martínez-Soria V,Schnoeveld E.Alkylation of benzene with short-chain olefins over MCM-22 zeolite:Catalytic behaviour and kinetic mechanism[J].Journal of Catalysis,2000,192:163-173.
[6]Zhang M,Jin K T,Zhang Y,et al.Static synthesis of MCM-22 and MCM-36 zeolites using piperidine as an organic template[J].Journal of Chemical Engineering of Chinese Universities,2015,29(4):939-947.
[7]Odedairo T,Al-Khattaf S.Comparative study of zeolite catalyzed alkylation of benzene with alcohols of different chain length:H-ZSM-5 versus mordenite[J].Catalysis Today,2013,204:73-84.
[8]Atanda L,Aitani A,Al-Khattf S.Experiental and kinetic studies of ethyltoluenesproduction via different alkylation reactions[J].Chemical Engineering Research and Design,2015,95:34-36.
[9]杨春雁,杨亚卫,凌凤香,等.MCM-22分子筛的合成、性质与催化应用[J].现代化工,2010,30(6):30-34.
[10]Palin L,Croce G,Viterbo D,et al.Monitoring the formation of HMCMC-22 by a combined XRPD and computational study of the decomposition of the structure directing agent[J].Chemistry of Materials,2011,23(22):4900-4909.
[11]Sastre G,Catlow A,Corma A,et al.Diffusion of benzene and propylene in MCM-22 zeolite:A molecular dynamics study[J].Journal of Physical Chemistry B,1999,103:5187-5196.
[12]丁春华,王祥生,郭新闻.氧化物改性MCM-22上甲苯与甲醇烷基化性能研究[J].石油学报:石油加工,2007,23(5):38-42.
[13]Laredo G C,Castillo J J,Navarrete-Bola1os J,et al.Benzene reduction in gasoline by alkylation with olefins:Comparison of Beta and MCM-22 catalysts[J].Applied Catalysis A:General,2012,413/414:140-148.
[14]Machado A,Rocha J,Carvalho A P,et al.Modification of MCM-22zeolite through sequential post-synthesis treatments.Implications on the acidic and catalytic behaviour[J].Applied Catalysis A:General,2012,47:329-338.
[15]Liu Kefeng,Xie Sujuan,Wei Huijuan,et al.Alkali-treatment of template-containing MCM-22 zeolite and itsapplication in alkylation and transalkylation reactions[J].Applied Catalysis A:General,2013,468:288-295.
[16]高宁宁,谢素娟,刘盛林,等.不同硅铝比的MCM-22分子筛的气相硅烷化处理[J].催化学报,2013,34(3):612-619.
[17]Zhao F,Zhang Y,Jiang W J.Acid properties of MCM-36 molecular sieve and its catalytic behavior in benzene alkylation with propylene[J].Advanced Material Research,2014,1015:434-437.
[18]田玲,李建伟,李英霞,等.磷改性MCM-22分子筛上苯与1-十二烯烷基化合成十二烷基苯[J].催化学报,2009,29(9):889-894.
[19]Hodala J L,Halgeri A B,Shanbhag G V.Phosphate modified ZSM-5for the shape-selective synthesis of para-diethylbenzene:Role of crystal size and acidity[J].Applied Catalysis A:General,2014,484:8-16.
[20]李永昕,马壮,薛冰,等.Mg O改性MCM-22分子筛催化乙苯与碳酸二乙酯的烷基化反应[J].石油化工,2010,39(4):391-395.
[21]Chen Jialing,Liang Tingyu,Li Junfen,et al.Regulation of framework aluminum siting and acid distribution in H-MCM-22 by boron incorporation and its effect on the catalytic performance in methanol to hydrocarbons[J].ACS Catalysis,2016,6:2299-2313.
[22]Liu Kefeng,Xie Sujuan,Liu Shenglin,et al.Catalytic role of different pore systems in MCM-49 zeolite for liquid alkylation of benzene with ethylene[J].Journal of Catalysis,2011,283(1):68-74.
[23]Magar R R,Pawar G T,Arbad B R,et al.Fe-MCM-22:An efficient heterogeneous catalyst for one pot four component synthesis of 1Hpyrazolo[1,2-b]phthalazine-5,10-dione derivatives[J].Advanced Organic Chemistry Letters,2016,3(1):8-14.
[24]Zhang H L,Tang C J,Gao F,et al.Synthesis and catalytic activity of Fe-MCM-41 nanoparticles[J].Advanced Materials Research,2014,933:17-22.
[25]Shamzhy M V,Ochoa-Hernndez C,Kasneryk V I,et al.Direct incorporation of B,Al,and Ga into medium-pore ITH zeolite:Synthesis,acidic,and catalytic properties[J].Catalysis Today,2016,277:34-37.
[26]Mihlyi M R,Kollr M,Klébert S,et al.Transformation of ethylbenzene-m-xylene feed over MCM-22 zeolites with different acidities[J].Applied Catalysis A:General,2014,476:19-25.
[27]Kolev I,Mavrodinova V,Alexieva G,et al.Pore volume probing of boron-modified MCM-22 zeolite by quartz crystal microbalance assisted study of o-and p-xylene adsorption[J].Senors and Actuators B:Chemical,2010,149:389-394.
[28]Mihlyi M R,Kollr M,Kirly P,et al.Effect of extra-framework Al formed by successive steaming and acid leaching of zeolite MCM-22on its structure and catalytic performance[J].Applied Catalysis A:General,2012,417/418:76-86.