无氯氧化剂在洁净固体推进剂中的应用
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摘要
为满足目前固体火箭推进剂在应用过程中产生的环境相容性要求,对几种无氯氧化剂在洁净固体推进剂中的应用进行了综述。针对固体推进剂燃烧产物中HCl对环境产生的危害,分析了几类推进剂的抑氯机理,并着重从氧化剂的角度介绍多种无氯高能氧化剂在固体推进剂中的应用,分析了无氯氧化剂的特点及在推进剂应用过程中面临的问题,提出了洁净固体推进剂的重点研究方向,促进洁净固体推进剂的广泛应用,降低HCl对环境的危害。
In order to meet the current requirements of the environmental compatibility occurred in the application process of solid rocket propellant, the applications of several chlorine-free oxidizers in the clean solid propellant are reviewed. Aiming at the harmfulness of HCl in the combustion products of the solid propellant to the environment, the chlorine inhibition mechanisms of several types of propellants are analyzed, and the applications of a variety of chlorine-free high energy oxidizers in the solid propellant are emphatically introduced from the aspect of the oxidizer. The characteristics of the chlorine-free oxidizer and the problems encountered in the application process of the propellant are analyzed. The key research directions of the clean propellant are put forward to promote the wide application of the clean solid propellant, and reduce the harmfulness of HCl to the environment.
In order to meet the current requirements of the environmental compatibility occurred in the application process of solid rocket propellant, the applications of several chlorine-free oxidizers in the clean solid propellant are reviewed. Aiming at the harmfulness of HCl in the combustion products of the solid propellant to the environment, the chlorine inhibition mechanisms of several types of propellants are analyzed, and the applications of a variety of chlorine-free high energy oxidizers in the solid propellant are emphatically introduced from the aspect of the oxidizer. The characteristics of the chlorine-free oxidizer and the problems encountered in the application process of the propellant are analyzed. The key research directions of the clean propellant are put forward to promote the wide application of the clean solid propellant, and reduce the harmfulness of HCl to the environment.
引文
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[29]NAYA T,KOHGA M.Thermal decomposition behaviors and burning characteristics of AN/nitramine-based composite propellant[J].Journal of Energetic Materials2015,33(2):73-90.
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[34]卫芝贤,王艳,龚磊,等.用于降低硝胺类推进剂压强指数的燃速催化剂:103212429A[P].2013-07-24.
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[36]侯斌,唐晓波,曹一林,等.AP/Al/SMX/HTPB四组元推进剂能量特性的理论研究[J].火炸药学报,2017,40(1):86-91.
[37]刘德辉,彭培根,王振芳,等.AP/HMX丁羟复合推进剂燃烧转爆轰研究[J].兵工学报,1994,15(1):32-36.
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[39]张超,赵凤起,金朋刚,等.p(BAMO-AMMO)热塑性高能推进剂燃烧转爆轰试验研究[J].火炸药学报,201639(4):92-96.
[40]KO Y-H,YEH J-Y,HE S-Y,et al.Flow visualization of combustion and liquid-nitrogen quenched surface in an energetic smoke-reduced propellant[J].Chung Cheng Ling Hsueh Pao/Journal of Chung Cheng Institute of Technology,2012,41(1):201-208.
[41]宋廷鲁.含HNIW的叠氮复合推进剂燃烧性能研究[D].北京:北京理工大学,2008.
[42]蔡如琳,胡伟,王敏,等.AP/HNIW混合体系的热分解研究[J].化学推进剂与高分子材料,2015,13(5):52-55.
[43]张杰,杨荣杰,邹彦文.HNIW的燃烧性能研究[J].固体火箭技术,2004,27(3):190-192.
[44]安红梅,刘云飞,李玉平,等.金属氧化物对HNIW单元推进剂燃烧的催化研究[J].火炸药学报,2000,23(4):27-28.
[45]张杰,邹彦文,贺俊.六硝基六氮杂异伍兹烷的性能及应用研究[J].飞航导弹,2005(8):54-59.
[46]WEISER V,EISENREICH N,ECKL W,et al.Burning behavior of CL-20/GAP and HMX/GAP rocket propellants[C]//Energetic materials-Analysis,diagnostics and testing;Proceeding of the 31st ICT International Conference.Germany:Karlsruhe,2000:144-151.
[47]胡荣祖,姚二岗,张海,等.自催化反应速率方程的导出途径及其在含能材料热行为研究中的应用[J].含能材料,2015,23(9):818-830.
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