纳米纤维素在可降解包装材料中的应用
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摘要
目的综述纳米纤维素在可降解包装材料中的应用研究。方法总结国内外纳米纤维素在包装领域的最新研究,简述纳米纤维素的制备方法与特性,详细介绍纳米纤维素在生物质薄膜材料、生物质发泡材料、缓释抗菌材料和纸张中的应用研究,以及纳米纤维素功能性材料在包装中的研究进展,并讨论纳米纤维素应用在食品包装中的安全问题。结果纳米纤维素性能优异、绿色环保,作为可降解包装材料的增强成分可以提高复合材料的力学性能和阻隔性能,并可赋予材料特殊的功能。结论纳米纤维素在包装领域有着巨大的应用潜力,利用农作物及其剩余物制备纳米纤维素拥有广阔的发展前景。
The work aims to review the research on the application of nano-cellulose in degradable packaging materials. The latest researches on the nano-cellulose applied in the field of packaging at home and abroad were summarized. The preparation methods and characteristics of nano-cellulose were briefly discussed. The researches on the nano-cellulose applied in biomass film materials, biomass foaming materials, slow release antibacterial materials and paper, as well as the research progress of nano-cellulose functional materials applied in packaging were introduced in details. The safety of nano-cellulose applied in food packaging was discussed. Nano-cellulose was environment friendly with excellent properties and it could improve the mechanical and barrier properties of composites as an enhanced component of degradable packaging materials, and it also could endow the materials with special functions. Nano-cellulose has huge potentials to be applied in the field of packaging. Preparation of nano-cellulose with crops and their leftovers has wide development prospects.
The work aims to review the research on the application of nano-cellulose in degradable packaging materials. The latest researches on the nano-cellulose applied in the field of packaging at home and abroad were summarized. The preparation methods and characteristics of nano-cellulose were briefly discussed. The researches on the nano-cellulose applied in biomass film materials, biomass foaming materials, slow release antibacterial materials and paper, as well as the research progress of nano-cellulose functional materials applied in packaging were introduced in details. The safety of nano-cellulose applied in food packaging was discussed. Nano-cellulose was environment friendly with excellent properties and it could improve the mechanical and barrier properties of composites as an enhanced component of degradable packaging materials, and it also could endow the materials with special functions. Nano-cellulose has huge potentials to be applied in the field of packaging. Preparation of nano-cellulose with crops and their leftovers has wide development prospects.
引文
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[2]宋孝周,吴清林,傅峰,等.农作物与其剩余物制备纳米纤维素研究进展[J].农业机械学报,2011,42(11):106—112.SONG Xiao-zhou,WU Qing-lin,FU Feng,et al.Research Progress of Nanocrystalline Cellulose Prepared from Crops and Agricultural Residues[J].Transactions of the Chinese Society for Agricultural Machinery,2011,42(11):106—112.
[3]付调坤,魏晓奕,李积华,等.热带农作物废弃物制备天然纳米纤维素的研究进展[J].纤维素科学与技术,2013,21(1):78—85.FU Diao-kun,WEI Xiao-yi,LI Ji-hua,et al.Development of Natural Nano-cellulose from Tropical Agricultural Products[J].Journal of Cellulose Science and Technology,2013,21(1):78—85.
[4]LI Y,LI G Z,ZOU Y L,et al.Preparation and Characterization of Cellulose Nanofibers from Partly Mercerized Cotton by Mixed Acid Hydrolysis[J].Cellulose,2014,21(1):301—309.
[5]HELOISA T,FRANCIELE M P,FLORENCIA C M.Cellulose Nanofibers Produced from Banana Peel by Chemical and Enzymatic Treatment[J].LWT-Food Science and Technology,2014,59(2):1311—1318.
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[7]LI W,YUE J Q,LIU S X.Preparation of Nanocrystalline Cellulose via Ultrasound and Its Reinforcement Capability for Poly(Vinyl Alcohol)Composites[J].Ultrasonics Sonochemistry,2012,19(3):479—485.
[8]SAVADEKAR N R,KARANDE V S,VIGNESHWARAN N,et al.Preparation of Cotton Linter Nanowhiskers by High-pressure Homogenization Process and Its Application in Thermoplastic Starch[J].Applied Nanoscience,2015,5(3):281—290.
[9]FENG J,HSIEH Y L.Chemically and Mechanically Isolated Nanocellulose and Their Self-assembled Structures[J].Carbohydrate Polymers,2013,95(1):32—40.
[10]CRISTIAN J G,FERNANDO G T,CLARA M G,et al.Development of Self-assembled Bacterial Cellulose–Starch Nanocomposites[J].Materials Science and Engineering C,2009,29(4):1098—1104.
[11]JANG K H,YU Y J,LEE Y H,et al.Antimicrobial Activity of Cellulose-based Nanofibers with Different Ag Phases[J].Materials Letters,2014,116(2):146—149.
[12]KHALIL A,BHAT A H,IREANA Y.Green Composites from Sustainable Cellulose Nanofibrils:A Review[J].Carbohydrate Polymers,2012,87(2):963—979.
[13]TIFFANY A,AMIT R,CAO Y F,et al.Nanocellulose,a Tiny Fiber with Huge Applications[J].Current Opinion in Biotechnology,2016,39(6):76—88.
[14]BAMDAD B,EMAD O,AFSANEH D M,et al.Mechanical,Physical and Tribological Characterization of Nano-cellulose Fibers Reinforced Bio-epoxy Composites:An Attempt to Fabricate and Scale the Green Composite[J].Carbohydrate Polymers,2016,147(8):282—293.
[15]FORTUNATIA E,PELTZERC M,ARMENTANO I,et al.Effects of Modified Cellulose Nanocrystals on the Barrier and Migration Properties of PLA Nano-biocomposites[J].Carbohydrate Polymers,2012,90(2):948—956.
[16]KHOO R Z,ISMAIL H,CHOW W S.Thermal and Morphological Properties of Poly(Lactic Acid)/Nanocellulose Nanocomposites[J].Procedia Chemistry,2016(1):788—794.
[17]ALI A,JABER H,ALIREZA A,et al.Preparation and Characterization of Modified Cellulose Nanofibers Reinforced Polylactic Acid Nanocomposite[J].Polymer Testing,2014,35(5):73—79.
[18]CHEN D,LAWTON D,THOMPSON M R,et al.Biocomposites Reinforced with Cellulose Nanocrystals Derived from Potato Peel Waste[J].Carbohydrate Polymers,2012,90(1):709—716.
[19]SAVADEKAR N R,MHASKE S T.Synthesis of Nano Cellulose Fibers and Effect on Thermoplastics Starch Based Films[J].Carbohydrate Polymers,2012,89(1):146—151.
[20]SURAKIT K,CHANCHAI T,ONUMA S.The Synthesis of Cellulose Nanofibers from Sesbania Javanica for Filler in Thermoplastic Starch[J].Energy Procedia,2014,56(1):318—325.
[21]母军,汤立秋,张瑞涵.纳米纤维素制备及壳聚糖/NCC复合膜的性能研究[J].化工新型材料,2015,43(2):83—85.MU Jun,TANG Li-qiu,ZHANG Rui-han.Preparation of Nano-cellulose and Performance of Chitosan/NCC Composite Film[J].New Chemical Materials,2015,43(2):83—85.
[22]周婧.壳聚糖/改性花生壳微晶纤维素可食膜的研究[D].吉林:吉林大学,2014.ZHOU Jing.Edible Films Based on Modified Peanut Shell Microcrystalline Cellulose and Chitosan[D].Jilin:Jilin University,2014.
[23]郭正旭,邱思,卢晓黎.海藻酸钙/纳米晶纤维素复合膜的制备及性能研究[J].食品工业科技,2012,33(24):174—176.GUO Zheng-xu,QIU Si,LU Xiao-li.Study on Preparation and Properties of Calcium Alginate/Nanocrystalline Cellulose Composite Films[J].Science and Technology of Food Industry,2012,33(24):174—176.
[24]刘翠云,高喜平,黄宇,等.NCC改性海藻酸钠可降解复合膜的制备及性能研究[J].化工新型材料,2015,43(6):80—82.LIU Cui-yun,GAO Xi-ping,HUANG Yu,et al.Preparation and Property of Nanocrystalline Cellulose/Modified Alginate Based Biodegradable Composite Film[J].New Chemical Materials,2015,43(6):80—82.
[25]李卫昌.胶原-纳米微晶纤维素复合材料的制备及性能研究[D].广州:暨南大学,2013.LI Wei-chang.Preparation and Property of Collagen-Nanometer Microcrystalline Cellulose Composites[D].Guangzhou:Jinan University,2013.
[26]卢天鸿.纳米纤维素/胶原蛋白复合材料的制备与性能[D].哈尔滨:东北林业大学,2014.LU Tian-hong.Preparation and Properties of Cellulose Nanofibers/Collagen Composite[D].Harbin:Northeast Forestry University,2014.
[27]陈观福寿.纤维素纳米纤维增强大豆分离蛋白透光复合材料的制备与性能研究[D].福州:福建师范大学,2009.CHEN Guan-fu-shou.Study on the Preparation and Properties of Cellulose Nanofiber Reinforced Soybean Protein Isolate(SPI)Transparent Composites[D].Fuzhou:Fujian Normal University,2009.
[28]YASUTOMO N,YOSHIHARU N,MASAHISA W,et al.Mechanical Properties of Silk Fibroin–Microcrystalline Cellulose Composite Films[J].Journal of Applied Polymer Science,2002,86(13):3425—3429.
[29]CHO S Y,LEE M E,CHOI Y,et al.Cellulose Nanofiber-Reinforced Silk Fibroin Composite Film with High Transparency[J].Fibers and Polymers,2014,15(2):215—219.
[30]陈翠.纳米纤维素作为纸张增强剂的应用[J].国际造纸,2014,33(5):27—31.CHEN Cui.The Potential Use of Nanocellulose as a Reinforcing Element in Paper[J].World Pulp and Paper,2014,33(5):27—31.
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