Enhanced gas separation performance of mixed matrix hollow fiber membranes containing post-functionalized S-MIL-53
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摘要
Mixed matrix hollow fiber membranes(MMHFMs)filled with metal-organic frameworks(MOFs)have great potential for energy-efficient gas separation processes,but the major hurdle is polymer/MOFs interfacial defects and membrane plasticization.Herein,lab-synthesized MIL-53 was post-functionalized by aminosilane grafting and subsequently incorporated into Ultem~?1000 polymer matrix to fabricate high performance MMHFMs.SEM,DLS,XRD and TGA were performed to characterize silane-modified MIL-53(S-MIL-53)and prepared MMHFMs.Moreover,the effect of MOFs loading was systematically investigated first;then gas separation performance of MMHFMs for pure and mixed gas was evaluated under different pressures.MMHFMs containing post-functionalized S-MIL-53 achieved remarkable gas permeation properties which was better than model predictions.Compared to pure HFMs,CO_2permeance of MMHFM loaded with 15%S-MIL-53 increased by 157%accompanying with 40%increase for CO_2/N_2selectivity,which outperformed the MMHFM filled with naked MIL-53.The pure and mixed gas permeation measurements with elevated feed pressure indicated that incorporation of S-MIL-53 also increased the resistance against CO_2plasticization.This work reveals that post-modified MOFs embedded in MMHFMs facilitate the improvement of gas separation performance and suppression of membrane plasticization.
Mixed matrix hollow fiber membranes(MMHFMs)filled with metal-organic frameworks(MOFs)have great potential for energy-efficient gas separation processes,but the major hurdle is polymer/MOFs interfacial defects and membrane plasticization.Herein,lab-synthesized MIL-53 was post-functionalized by aminosilane grafting and subsequently incorporated into Ultem~?1000 polymer matrix to fabricate high performance MMHFMs.SEM,DLS,XRD and TGA were performed to characterize silane-modified MIL-53(S-MIL-53)and prepared MMHFMs.Moreover,the effect of MOFs loading was systematically investigated first;then gas separation performance of MMHFMs for pure and mixed gas was evaluated under different pressures.MMHFMs containing post-functionalized S-MIL-53 achieved remarkable gas permeation properties which was better than model predictions.Compared to pure HFMs,CO_2permeance of MMHFM loaded with 15%S-MIL-53 increased by 157%accompanying with 40%increase for CO_2/N_2selectivity,which outperformed the MMHFM filled with naked MIL-53.The pure and mixed gas permeation measurements with elevated feed pressure indicated that incorporation of S-MIL-53 also increased the resistance against CO_2plasticization.This work reveals that post-modified MOFs embedded in MMHFMs facilitate the improvement of gas separation performance and suppression of membrane plasticization.
Mixed matrix hollow fiber membranes(MMHFMs)filled with metal-organic frameworks(MOFs)have great potential for energy-efficient gas separation processes,but the major hurdle is polymer/MOFs interfacial defects and membrane plasticization.Herein,lab-synthesized MIL-53 was post-functionalized by aminosilane grafting and subsequently incorporated into Ultem~?1000 polymer matrix to fabricate high performance MMHFMs.SEM,DLS,XRD and TGA were performed to characterize silane-modified MIL-53(S-MIL-53)and prepared MMHFMs.Moreover,the effect of MOFs loading was systematically investigated first;then gas separation performance of MMHFMs for pure and mixed gas was evaluated under different pressures.MMHFMs containing post-functionalized S-MIL-53 achieved remarkable gas permeation properties which was better than model predictions.Compared to pure HFMs,CO_2permeance of MMHFM loaded with 15%S-MIL-53 increased by 157%accompanying with 40%increase for CO_2/N_2selectivity,which outperformed the MMHFM filled with naked MIL-53.The pure and mixed gas permeation measurements with elevated feed pressure indicated that incorporation of S-MIL-53 also increased the resistance against CO_2plasticization.This work reveals that post-modified MOFs embedded in MMHFMs facilitate the improvement of gas separation performance and suppression of membrane plasticization.
引文
[1]Y.Peng,Y.Li,Y.Ban,H.Jin,W.Jiao,X.Liu,W.Yang,Science 346(2014)1356-1359.
[2]W.J.Koros,AICh E J.50(2004)2326-2334.
[3]A.Brunetti,F.Scura,G.Barbieri,E.Drioli,J.Membr.Sci.359(2010)115-125.
[4]D.F.Sanders,Z.P.Smith,R.Guo,L.M.Robeson,J.E.Mc Grath,D.R.Paul,B.D.Freeman,Polymer 54(2013)4729-4761.
[5]X.Jie,C.Duan,L.Wang,C.Jiang,H.Zheng,J.Liu,D.Liu,Y.Cao,Q.Yuan,Ind.Eng.Chem.Res.53(2014)4442-4452.
[6]T.-H.Bae,J.R.Long,Energy Environ.Sci.6(2013)3565-3569.
[7]H.Zhu,L.Wang,X.Jie,D.Liu,Y.Cao,ACS Appl.Mater.Interfaces 8(2016)22696-22704.
[8]L.M.Robeson,J.Membr.Sci.320(2008)390-400.
[9]M.A.Aroon,A.F.Ismail,T.Matsuura,M.M.Montazer-Rahmati,Sep.Purif.Technol.75(2010)229-242.
[10]L.Diestel,N.Wang,A.Schulz,F.Steinbach,J.Caro,Ind.Eng.Chem.Res.54(2015)1103-1112.
[11]Z.A.Jawad,A.L.Ahmad,S.C.Low,T.L.Chew,S.H.S.Zein,J.Membr.Sci.476(2015)590-601.
[12]X.Li,L.Ma,H.Zhang,S.Wang,Z.Jiang,R.Guo,H.Wu,X.Cao,J.Yang,B.Wang,J.Membr.Sci.479(2015)1-10.
[13]Y.Xiao,X.Guo,H.Huang,Q.Yang,A.Huang,C.Zhong,RSC Adv.5(2015)7253-7259.
[14]H.Zhu,X.Jie,L.Wang,G.Kang,D.Liu,Y.Cao,RSC Adv.6(2016)69124-69134.
[15]M.Shah,M.C.Mc Carthy,S.Sachdeva,A.K.Lee,H.-K.Jeong,Ind.Eng.Chem.Res.51(2012)2179-2199.
[16]H.B.Tanh Jeazet,C.Staudt,C.Janiak,Dalton Trans 41(2012)14003-14027.
[17]B.Li,H.Wang,B.Chen,Chem.Asian J.9(2014)1474-1498.
[18]S.Basu,A.Cano-Odena,I.F.J.Vankelecom,J.Membr.Sci.362(2010)478-487.
[19]M.Askari,T.-S.Chung,J.Membr.Sci.444(2013)173-183.
[20]R.Nasir,H.Mukhtar,Z.Man,D.F.Mohshim,Chem.Eng.Technol.36(2013)717-727.
[21]T.Yang,T.-S.Chung,J.Mater.Chem.A 1(2013)6081-6090.
[22]B.Zornoza,C.Tellez,J.Coronas,J.Gascon,F.Kapteijn,Microporous Mesoporous Mater 166(2013)67-78.
[23]T.-H.Bae,J.S.Lee,W.Qiu,W.J.Koros,C.W.Jones,S.Nair,Angew.Chem.,Int.Ed.49(2010)9863-9866.
[24]L.Cao,K.Tao,A.Huang,C.Kong,L.Chen,Chem.Commun.49(2013)8513-8515.
[25]M.J.C.Ordo?ez,K.J.Balkus,J.P.Ferraris,I.H.Musselman,J.Membr.Sci.361(2010)28-37.
[26]A.Car,C.Stropnik,K.-V.Peinemann,Desalination 200(2006)424-426.
[27]T.-S.Chung,L.Y.Jiang,Y.Li,S.Kulprathipanja,Prog.Polym.Sci.32(2007)483-507.
[28]Z.Wang,S.M.Cohen,J.Am.Chem.Soc.129(2007)12368-12369.
[29]S.M.Cohen,Chem.Sci.1(2010)32-36.
[30]S.Abednatanzi,A.Abbasi,M.Masteri-Farahani,J.Mol.Catal.A:Chem.399(2015)10-17.
[31]S.M.Cohen,Chem.Rev.112(2012)970-1000.
[32]B.Li,Y.Zhang,D.Ma,L.Li,G.Li,G.Li,Z.Shi,S.Feng,Chem.Commun.48(2012)6151-6153.
[33]Z.Wang,J.Liu,H.K.Arslan,S.Grosjean,T.Hagendorn,H.Gliemann,S.Brase,C.Woll,Langmuir 29(2013)15958-15964.
[34]A.M.Marti,D.Tran,K.J.Balkus,J.Porous Mater.22(2015)1275-1284.
[35]A.Huang,J.Caro,Angew.Chem.,Int.Ed.50(2011)4979-4982.
[36]Q.Xin,J.Ouyang,T.Liu,Z.Li,Z.Li,Y.Liu,S.Wang,H.Wu,Z.Jiang,X.Cao,ACSAppl.Mater.Interfaces 7(2015)1065-1077.
[37]X.Qian,B.Yadian,R.Wu,Y.Long,K.Zhou,B.Zhu,Y.Huang,Int.J.Hydrogen Energy 38(2013)16710-16715.
[38]T.Rodenas,M.van Dalen,P.Serra-Crespo,F.Kapteijn,J.Gascon,Microporous Mesoporous Mater 192(2014)35-42.
[39]S.Bourrelly,P.L.Llewellyn,C.Serre,F.Millange,T.Loiseau,G.Férey,J.Am.Chem.Soc.127(2005)13519-13521.
[40]T.Loiseau,C.Serre,C.Huguenard,G.Fink,F.Taulelle,M.Henry,T.Bataille,G.Férey,Chem.-Eur.J.10(2004)1373-1382.
[41]D.Himsl,D.Wallacher,M.Hartmann,Angew.Chem.,Int.Ed.48(2009)4639-4642.
[42]S.Saimani,A.Kumar,M.M.Dal-Cin,G.Robertson,J.Membr.Sci.374(2011)102-109.
[43]L.Hao,J.Zuo,T.-S.Chung,AICh E J.60(2014)3848-3858.
[44]X.-D.Do,V.-T.Hoang,S.Kaliaguine,Microporous Mesoporous Mater 141(2011)135-139.
[45]X.Liu,Q.Dai,L.Austin,J.Coutts,G.Knowles,J.Zou,H.Chen,Q.Huo,J.Am.Chem.Soc.130(2008)2780-2782.
[46]F.Dorosti,M.Omidkhah,R.Abedini,J.Nat.Gas Sci.Eng.25(2015)88-102.
[47]A.K.Zulhairun,B.C.Ng,A.F.Ismail,R.Surya Murali,M.S.Abdullah,Sep.Purif.Technol.137(2014)1-12.
[48]Q.Song,S.K.Nataraj,M.V.Roussenova,J.C.Tan,D.J.Hughes,W.Li,P.Bourgoin,M.A.Alam,A.K.Cheetham,S.A.Al-Muhtaseb,E.Sivaniah,Energy Environ.Sci.5(2012)8359-8369.
[49]C.Duan,X.Jie,D.Liu,Y.Cao,Q.Yuan,J.Membr.Sci.466(2014)92-102.
[50]J.Ma,Y.Ying,Q.Yang,Y.Ban,H.Huang,X.Guo,Y.Xiao,D.Liu,Y.Li,W.Yang,C.Zhong,Chem.Commun.51(2015)4249-4251.
[51]S.Husain,W.J.Koros,J.Membr.Sci.288(2007)195-207.
[52]Y.Dai,J.R.Johnson,O.Karvan,D.S.Sholl,W.J.Koros,J.Membr.Sci.401-402(2012)76-82.
[53]Z.Hu,K.Zhang,M.Zhang,Z.Guo,J.Jiang,D.Zhao,Chem Sus Chem 7(2014)2791-2795.
[54]S.Shahid,K.Nijmeijer,J.Membr.Sci.459(2014)33-44.
[2]W.J.Koros,AICh E J.50(2004)2326-2334.
[3]A.Brunetti,F.Scura,G.Barbieri,E.Drioli,J.Membr.Sci.359(2010)115-125.
[4]D.F.Sanders,Z.P.Smith,R.Guo,L.M.Robeson,J.E.Mc Grath,D.R.Paul,B.D.Freeman,Polymer 54(2013)4729-4761.
[5]X.Jie,C.Duan,L.Wang,C.Jiang,H.Zheng,J.Liu,D.Liu,Y.Cao,Q.Yuan,Ind.Eng.Chem.Res.53(2014)4442-4452.
[6]T.-H.Bae,J.R.Long,Energy Environ.Sci.6(2013)3565-3569.
[7]H.Zhu,L.Wang,X.Jie,D.Liu,Y.Cao,ACS Appl.Mater.Interfaces 8(2016)22696-22704.
[8]L.M.Robeson,J.Membr.Sci.320(2008)390-400.
[9]M.A.Aroon,A.F.Ismail,T.Matsuura,M.M.Montazer-Rahmati,Sep.Purif.Technol.75(2010)229-242.
[10]L.Diestel,N.Wang,A.Schulz,F.Steinbach,J.Caro,Ind.Eng.Chem.Res.54(2015)1103-1112.
[11]Z.A.Jawad,A.L.Ahmad,S.C.Low,T.L.Chew,S.H.S.Zein,J.Membr.Sci.476(2015)590-601.
[12]X.Li,L.Ma,H.Zhang,S.Wang,Z.Jiang,R.Guo,H.Wu,X.Cao,J.Yang,B.Wang,J.Membr.Sci.479(2015)1-10.
[13]Y.Xiao,X.Guo,H.Huang,Q.Yang,A.Huang,C.Zhong,RSC Adv.5(2015)7253-7259.
[14]H.Zhu,X.Jie,L.Wang,G.Kang,D.Liu,Y.Cao,RSC Adv.6(2016)69124-69134.
[15]M.Shah,M.C.Mc Carthy,S.Sachdeva,A.K.Lee,H.-K.Jeong,Ind.Eng.Chem.Res.51(2012)2179-2199.
[16]H.B.Tanh Jeazet,C.Staudt,C.Janiak,Dalton Trans 41(2012)14003-14027.
[17]B.Li,H.Wang,B.Chen,Chem.Asian J.9(2014)1474-1498.
[18]S.Basu,A.Cano-Odena,I.F.J.Vankelecom,J.Membr.Sci.362(2010)478-487.
[19]M.Askari,T.-S.Chung,J.Membr.Sci.444(2013)173-183.
[20]R.Nasir,H.Mukhtar,Z.Man,D.F.Mohshim,Chem.Eng.Technol.36(2013)717-727.
[21]T.Yang,T.-S.Chung,J.Mater.Chem.A 1(2013)6081-6090.
[22]B.Zornoza,C.Tellez,J.Coronas,J.Gascon,F.Kapteijn,Microporous Mesoporous Mater 166(2013)67-78.
[23]T.-H.Bae,J.S.Lee,W.Qiu,W.J.Koros,C.W.Jones,S.Nair,Angew.Chem.,Int.Ed.49(2010)9863-9866.
[24]L.Cao,K.Tao,A.Huang,C.Kong,L.Chen,Chem.Commun.49(2013)8513-8515.
[25]M.J.C.Ordo?ez,K.J.Balkus,J.P.Ferraris,I.H.Musselman,J.Membr.Sci.361(2010)28-37.
[26]A.Car,C.Stropnik,K.-V.Peinemann,Desalination 200(2006)424-426.
[27]T.-S.Chung,L.Y.Jiang,Y.Li,S.Kulprathipanja,Prog.Polym.Sci.32(2007)483-507.
[28]Z.Wang,S.M.Cohen,J.Am.Chem.Soc.129(2007)12368-12369.
[29]S.M.Cohen,Chem.Sci.1(2010)32-36.
[30]S.Abednatanzi,A.Abbasi,M.Masteri-Farahani,J.Mol.Catal.A:Chem.399(2015)10-17.
[31]S.M.Cohen,Chem.Rev.112(2012)970-1000.
[32]B.Li,Y.Zhang,D.Ma,L.Li,G.Li,G.Li,Z.Shi,S.Feng,Chem.Commun.48(2012)6151-6153.
[33]Z.Wang,J.Liu,H.K.Arslan,S.Grosjean,T.Hagendorn,H.Gliemann,S.Brase,C.Woll,Langmuir 29(2013)15958-15964.
[34]A.M.Marti,D.Tran,K.J.Balkus,J.Porous Mater.22(2015)1275-1284.
[35]A.Huang,J.Caro,Angew.Chem.,Int.Ed.50(2011)4979-4982.
[36]Q.Xin,J.Ouyang,T.Liu,Z.Li,Z.Li,Y.Liu,S.Wang,H.Wu,Z.Jiang,X.Cao,ACSAppl.Mater.Interfaces 7(2015)1065-1077.
[37]X.Qian,B.Yadian,R.Wu,Y.Long,K.Zhou,B.Zhu,Y.Huang,Int.J.Hydrogen Energy 38(2013)16710-16715.
[38]T.Rodenas,M.van Dalen,P.Serra-Crespo,F.Kapteijn,J.Gascon,Microporous Mesoporous Mater 192(2014)35-42.
[39]S.Bourrelly,P.L.Llewellyn,C.Serre,F.Millange,T.Loiseau,G.Férey,J.Am.Chem.Soc.127(2005)13519-13521.
[40]T.Loiseau,C.Serre,C.Huguenard,G.Fink,F.Taulelle,M.Henry,T.Bataille,G.Férey,Chem.-Eur.J.10(2004)1373-1382.
[41]D.Himsl,D.Wallacher,M.Hartmann,Angew.Chem.,Int.Ed.48(2009)4639-4642.
[42]S.Saimani,A.Kumar,M.M.Dal-Cin,G.Robertson,J.Membr.Sci.374(2011)102-109.
[43]L.Hao,J.Zuo,T.-S.Chung,AICh E J.60(2014)3848-3858.
[44]X.-D.Do,V.-T.Hoang,S.Kaliaguine,Microporous Mesoporous Mater 141(2011)135-139.
[45]X.Liu,Q.Dai,L.Austin,J.Coutts,G.Knowles,J.Zou,H.Chen,Q.Huo,J.Am.Chem.Soc.130(2008)2780-2782.
[46]F.Dorosti,M.Omidkhah,R.Abedini,J.Nat.Gas Sci.Eng.25(2015)88-102.
[47]A.K.Zulhairun,B.C.Ng,A.F.Ismail,R.Surya Murali,M.S.Abdullah,Sep.Purif.Technol.137(2014)1-12.
[48]Q.Song,S.K.Nataraj,M.V.Roussenova,J.C.Tan,D.J.Hughes,W.Li,P.Bourgoin,M.A.Alam,A.K.Cheetham,S.A.Al-Muhtaseb,E.Sivaniah,Energy Environ.Sci.5(2012)8359-8369.
[49]C.Duan,X.Jie,D.Liu,Y.Cao,Q.Yuan,J.Membr.Sci.466(2014)92-102.
[50]J.Ma,Y.Ying,Q.Yang,Y.Ban,H.Huang,X.Guo,Y.Xiao,D.Liu,Y.Li,W.Yang,C.Zhong,Chem.Commun.51(2015)4249-4251.
[51]S.Husain,W.J.Koros,J.Membr.Sci.288(2007)195-207.
[52]Y.Dai,J.R.Johnson,O.Karvan,D.S.Sholl,W.J.Koros,J.Membr.Sci.401-402(2012)76-82.
[53]Z.Hu,K.Zhang,M.Zhang,Z.Guo,J.Jiang,D.Zhao,Chem Sus Chem 7(2014)2791-2795.
[54]S.Shahid,K.Nijmeijer,J.Membr.Sci.459(2014)33-44.