石墨烯增强金属基复合材料制备方法的研究进展
|
摘要
石墨烯是一种新型的二维碳材料,具有优异的力学性能、电学性能以及导热性能,被视作理想的复合材料增强体之一。目前石墨烯/复合材料的制备与加工已经成为科研领域中非常重要的研究方向,同时石墨烯增强金属基复合材料在制备以及加工过程中已经取得很多进展。本文综述了石墨烯增强金属基复合材料的制备方法,归纳了粉末冶金法、电化学法以及其它多种方法的研究现状、应用现状以及未来的发展趋势。
Graphene is a new two-dimensional carbon material with excellent mechanical properties, electrical properties and thermal conductivity. It is considered as one of the ideal composite reinforcements. At present, the preparation and processing of graphene/composite materials has become a very important research direction in the field of scientific research. At the same time, many progress has been made in the preparation and processing of graphene reinforced metal matrix composites. In this paper, the preparation methods of graphene reinforced metal matrix composites are reviewed. The research status, application status and future development trend of powder metallurgy, electrochemical method and other methods are summarized.
Graphene is a new two-dimensional carbon material with excellent mechanical properties, electrical properties and thermal conductivity. It is considered as one of the ideal composite reinforcements. At present, the preparation and processing of graphene/composite materials has become a very important research direction in the field of scientific research. At the same time, many progress has been made in the preparation and processing of graphene reinforced metal matrix composites. In this paper, the preparation methods of graphene reinforced metal matrix composites are reviewed. The research status, application status and future development trend of powder metallurgy, electrochemical method and other methods are summarized.
引文
[1] Novoselov K,Geim A,Morozov S V,et al.Electric field effect in atomically thin carbon films[J].Science,2004,306(5696):666-669.
[2] Lee C,Wei X D,Kysar J W,et al.Measurement of the elastic properties and intrinsic strength of monolayer graphene[J].Science,2008,321(5887):385-388.
[3] Stankovich S,Dikin D A,Dommett G H B,et al.Graphene-based composite materials[J].Nature,2006,442(7100):282-286,
[4] Rafiee M A,Rafiee J,Wang Z,et al.Enhanced mechanical properties of nanocomposites at low graphene content[J].Acs Nano.2009,3(12):3884-3890.
[5] Ramanathan T,Abdala A A,Stankovich s,et al.Functionalized graphene sheets for polymer nanocomposites[J].Nature Nanotechnology,2008,3(6),327-331.
[6] Bartolucci S F,Paras J,Rafiee M A,et al.Graphene-aluminum nanocomposites[J].Materials Science Engineeering:A,2011,528(27),7933-7937.
[7] Koltsova T S,Nasibulina L I,Anoshkin I V,et al.New hybrid copper composite materials based on carbon nanostructures[J].Journal Materials Science and Engineering B,2012,2(4):240-246.
[8] Wang J Y,Li Z,Fan G,et al.Reinforcement with graphene nanosheets in aluminum matrix composites[J].Scripta Materialia,2012,66(8):594-597.
[9] 刘强,柯黎明,刘奋成,等.多壁碳纳米管增强铝基复合材料的高温力学性能[J].材料工程,2016,44(4):20-25.LIU Qiang,KE Li-ming,LIU Fen-cheng,et al.High temperature mechanical properties of aluminum matrix composites reinforced by multi-walled carbon nanotubes[J].Materials Engineering,2016,44(4):20-25.
[10] Kauling A P,Seefeldt A T,Pisoni D P,et al.The worldwide graphene flake production[J].Advanced Materials,2018,30(44):1-6.
[11] 张荻,张国定,李志强.金属基复合材料的现状与发展趋势[J].中国材料进展,2010,29(4):1-7.ZHANG Di,ZHANG Guo-ding,LI Zhi-qiang.Current status and development trend of metal matrix composites[J].Chinese Material Progress,2010,29(4):1-7.
[12] Bartolucci S F,Paras J,Rafiee M A,et al.Graphene-aluminum nanocomposites[J].Materials Science and Engineering A,2011,528(27):7933-7937.
[13] Wang J Y,Li Z Q,Fan G L,et al.Reinforcement with graphene nanosheets in aluminum matrix composites[J].Scripta Materialia,2012,66(8):594-597.
[14] Porwal H,Tatarko P,Grasso S,et al.Graphene reinforced alumina nano-composites[J].Carbon,2013,64:359-369.
[15] 高鑫.石墨烯增强铝基复合材料的制备方法及力学性能研究[D].哈尔滨:哈尔滨理工大学,2015.GAO Xin.Preparation and mechanical properties of graphene reinforced aluminum composites[D].Harbin:Harbin University of Science and Technology,2015.
[16] Kim J H,Lee S M,Oh Y S,et al.Unoxidized graphene/alumina nanocomposites:Fracture and wear resistance effects of graphene on alumina matrix[J].Scientific Reports,2014,4:1-10.
[17] Asgharzadeh H,Sedigh M.Synthesis and mechanical properties of Al matrix composites reinforced with few-layer graphene and graphene oxide[J].Journal of Alloys and Compounds,2017,728:47-62.
[18] Li Z,Guo Q,Li Z Q,et al.Enhanced mechanical properties of graphene (reduced graphene oxide)/aluminum composites with a bioinspired nanolaminated structure[J].Nano Letters,2015,15(12):8077-8083.
[19] Zhang Y Y,Li X D.Bioinspired graphene/Al2O3 doubly reinforced aluminum composites with high strength and toughness[J].Nano Letters,2017,11(17):6907-6915.
[20] Liu X H,Li J J,Sha J W,et al.In-situ synthesis of graphene nanosheets coated copper for preparing reinforced aluminum matrix composites[J].Materials Science and Engineering A,2018,709:65-71.
[21] Yang W S,Zhao Q,Xin L,et al.Microstructure and mechanical properties of graphene nanoplates reinforced pure Al matrix composites prepared by pressure infiltration method[J].Journal of Alloys and Compounds,2018,732:748-758.
[22] Dixit S,Mahata A,Mahapatra D R,et al.Multi-layer graphene reinforced aluminum-Manufacturing of high strength composite by friction stir alloying[J].Composites Part B,2018,136:63-71.
[23] 刘朋,闫翠霞,凌自成,等.镍含量对铜基复合材料力电性能的影响[J].稀有金属,2018,42(7):735-742.LIU Peng,YAN Cui-xia,LING Zi-cheng,et al.Strength and electrical properties of graphene reinforced copper matrix composites with different nickel contents[J].Rare Metal,2018,42(7):735-742.
[24] 李涛,闫翠霞,黄启祥,等.石墨烯-稀贵金属复合材料的制备及其研究进展[J].热加工工艺,2016,45(2):23-27.LI Tao,YAN Cui-xia,HUANG Qi-xiang,et al.Research progess and preparation of graphene-rare metal composite[J].Hot Working Technology,2016,45(2):23-27.
[25] Wang L D,Yang Z Y,Cui Y,et al.Graphene-copper composite with micro-layered grains and ultrahigh strength[J].Scientific Reports,2017,7:1-10.
[26] Hwang B,Kim W,Kim J,et al.Role of graphene in reducing fatigue damage in Cu/Gr nanolayered composite[J].Nano Letters,2017,17(8):4740-4745.
[27] 独涛.化学气相沉积法制备石墨烯铜复合材料[D].上海:上海交通大学,2015.DU Tao.Preparation of graphene copper composite by chemical vapoe[D].Shanghai:Shanghai Jiaotong University,2015.
[28] Chen F Y,Ying J M,Wang Y F,et al.Effects of graphene content on the microstructure and properties of copper matrix composites[J].Carbon,2016,96:836-842.
[29] Cao M,Xiong D B,Tan Z Q,et al.Aligning graphene in bulk copper:nacre-inspired nanolaminated architecture coupled with in-situ processing for enhanced mechanical properties and high electrical conductivity[J].Carbon,2017,117:65-74.
[30] Yang M,Weng L,Zhu H X,et al.Simultaneously enhancing the strength,ductility and conductivity of copper matrix composites with graphene nanoribbons[J].Carbon,2017,118:250-260.
[31] 匡达.石墨烯/镍基复合材料的制备和性能研究[D].上海:上海交通大学,2015.KUANG Da.Fabrication and properties of the nickel matrix graphene composites[D].Shanghai:Shanghai Jiaotong University,2012.
[32] 张兴普.石墨烯-纳米晶镍基复合材料的制备及性能研究[D].长春:吉林大学,2015.ZHANG Xing-pu.Fabrication and properties of graphene reinforced NC Ni matrix composites[D].Changchun:Jilin University,2015.
[33] Ren Z,Meng K,Shehzad K,et al.Mechanical properties of nickel-graphene composites synthesized by electrochemical deposition[J].Nanotechnology,2015,26(6):1-8.
[34] 杜金芳.石墨烯/镍基复合材料的原位制备与性能研究[D].兰州:兰州理工大学,2015.DU Jin-fang.In-situ fabrication and properties of graphene/nickel matrix composites[D].Lanzhou:Lanzhou University of Technology,2015.
[35] 吉传波,王晓峰,邹金文,等.石墨烯增强镍基粉末高温合金复合材料的力学性能[J].材料工程,2017,45(3):1-6.JI Chuan-bo,WANG Xiao-feng,ZOU Jin-wen,et al.Mechanical properties of graphene reinforced nickel-based P/M superalloy[J].Materials Engineering,2017,45(3):1-6.
[36] 张丽萍.体育器材用石墨烯镁基复合材料的制备与性能分析[J].热加工工艺,2015,44(12):140-142.ZHANG Li-ping.Properties analysis and preparation with grapheme magnesiummatrix composite in sports equipment[J].Hot Working Technology,2015,44(12):140-142.
[37] Rashad M,Pan F S,Hu H H,et al.Enhanced tensile properties of magnesium composites reinforced with graphene nanoplatelets[J].Materials Science and Engineering A,2015,630:36-44.
[38] Xiang S L,Gupta M,Wang X J,et al.Enhanced overall strength and ductility of magnesium matrix composites by low content of graphene nanoplatelets[J].Composites:Part A,2017,100:183-193.
[39] Du X,Du W B,Wang Z H,et al.Ultra-high strengthening efficiency of graphene nanoplatelets reinforced magnesium matrix composites[J].Materials Science and Engineering A,2018,711:633-642.
[40] 袁秋红,曾效舒,吴俊斌.石墨烯增强AZ91镁基复合材料的力学性能[J].机械工程材料,2016,40(8):43-48.YUAN Qiu-hong,ZENG Xiao-shu,WU Jun-bin,et al.Mechanical properties of graphene reinforced AZ91 Mg alloy based composite[J].Mechanical Engineering Materials,2016,40(8):43-48.
[2] Lee C,Wei X D,Kysar J W,et al.Measurement of the elastic properties and intrinsic strength of monolayer graphene[J].Science,2008,321(5887):385-388.
[3] Stankovich S,Dikin D A,Dommett G H B,et al.Graphene-based composite materials[J].Nature,2006,442(7100):282-286,
[4] Rafiee M A,Rafiee J,Wang Z,et al.Enhanced mechanical properties of nanocomposites at low graphene content[J].Acs Nano.2009,3(12):3884-3890.
[5] Ramanathan T,Abdala A A,Stankovich s,et al.Functionalized graphene sheets for polymer nanocomposites[J].Nature Nanotechnology,2008,3(6),327-331.
[6] Bartolucci S F,Paras J,Rafiee M A,et al.Graphene-aluminum nanocomposites[J].Materials Science Engineeering:A,2011,528(27),7933-7937.
[7] Koltsova T S,Nasibulina L I,Anoshkin I V,et al.New hybrid copper composite materials based on carbon nanostructures[J].Journal Materials Science and Engineering B,2012,2(4):240-246.
[8] Wang J Y,Li Z,Fan G,et al.Reinforcement with graphene nanosheets in aluminum matrix composites[J].Scripta Materialia,2012,66(8):594-597.
[9] 刘强,柯黎明,刘奋成,等.多壁碳纳米管增强铝基复合材料的高温力学性能[J].材料工程,2016,44(4):20-25.LIU Qiang,KE Li-ming,LIU Fen-cheng,et al.High temperature mechanical properties of aluminum matrix composites reinforced by multi-walled carbon nanotubes[J].Materials Engineering,2016,44(4):20-25.
[10] Kauling A P,Seefeldt A T,Pisoni D P,et al.The worldwide graphene flake production[J].Advanced Materials,2018,30(44):1-6.
[11] 张荻,张国定,李志强.金属基复合材料的现状与发展趋势[J].中国材料进展,2010,29(4):1-7.ZHANG Di,ZHANG Guo-ding,LI Zhi-qiang.Current status and development trend of metal matrix composites[J].Chinese Material Progress,2010,29(4):1-7.
[12] Bartolucci S F,Paras J,Rafiee M A,et al.Graphene-aluminum nanocomposites[J].Materials Science and Engineering A,2011,528(27):7933-7937.
[13] Wang J Y,Li Z Q,Fan G L,et al.Reinforcement with graphene nanosheets in aluminum matrix composites[J].Scripta Materialia,2012,66(8):594-597.
[14] Porwal H,Tatarko P,Grasso S,et al.Graphene reinforced alumina nano-composites[J].Carbon,2013,64:359-369.
[15] 高鑫.石墨烯增强铝基复合材料的制备方法及力学性能研究[D].哈尔滨:哈尔滨理工大学,2015.GAO Xin.Preparation and mechanical properties of graphene reinforced aluminum composites[D].Harbin:Harbin University of Science and Technology,2015.
[16] Kim J H,Lee S M,Oh Y S,et al.Unoxidized graphene/alumina nanocomposites:Fracture and wear resistance effects of graphene on alumina matrix[J].Scientific Reports,2014,4:1-10.
[17] Asgharzadeh H,Sedigh M.Synthesis and mechanical properties of Al matrix composites reinforced with few-layer graphene and graphene oxide[J].Journal of Alloys and Compounds,2017,728:47-62.
[18] Li Z,Guo Q,Li Z Q,et al.Enhanced mechanical properties of graphene (reduced graphene oxide)/aluminum composites with a bioinspired nanolaminated structure[J].Nano Letters,2015,15(12):8077-8083.
[19] Zhang Y Y,Li X D.Bioinspired graphene/Al2O3 doubly reinforced aluminum composites with high strength and toughness[J].Nano Letters,2017,11(17):6907-6915.
[20] Liu X H,Li J J,Sha J W,et al.In-situ synthesis of graphene nanosheets coated copper for preparing reinforced aluminum matrix composites[J].Materials Science and Engineering A,2018,709:65-71.
[21] Yang W S,Zhao Q,Xin L,et al.Microstructure and mechanical properties of graphene nanoplates reinforced pure Al matrix composites prepared by pressure infiltration method[J].Journal of Alloys and Compounds,2018,732:748-758.
[22] Dixit S,Mahata A,Mahapatra D R,et al.Multi-layer graphene reinforced aluminum-Manufacturing of high strength composite by friction stir alloying[J].Composites Part B,2018,136:63-71.
[23] 刘朋,闫翠霞,凌自成,等.镍含量对铜基复合材料力电性能的影响[J].稀有金属,2018,42(7):735-742.LIU Peng,YAN Cui-xia,LING Zi-cheng,et al.Strength and electrical properties of graphene reinforced copper matrix composites with different nickel contents[J].Rare Metal,2018,42(7):735-742.
[24] 李涛,闫翠霞,黄启祥,等.石墨烯-稀贵金属复合材料的制备及其研究进展[J].热加工工艺,2016,45(2):23-27.LI Tao,YAN Cui-xia,HUANG Qi-xiang,et al.Research progess and preparation of graphene-rare metal composite[J].Hot Working Technology,2016,45(2):23-27.
[25] Wang L D,Yang Z Y,Cui Y,et al.Graphene-copper composite with micro-layered grains and ultrahigh strength[J].Scientific Reports,2017,7:1-10.
[26] Hwang B,Kim W,Kim J,et al.Role of graphene in reducing fatigue damage in Cu/Gr nanolayered composite[J].Nano Letters,2017,17(8):4740-4745.
[27] 独涛.化学气相沉积法制备石墨烯铜复合材料[D].上海:上海交通大学,2015.DU Tao.Preparation of graphene copper composite by chemical vapoe[D].Shanghai:Shanghai Jiaotong University,2015.
[28] Chen F Y,Ying J M,Wang Y F,et al.Effects of graphene content on the microstructure and properties of copper matrix composites[J].Carbon,2016,96:836-842.
[29] Cao M,Xiong D B,Tan Z Q,et al.Aligning graphene in bulk copper:nacre-inspired nanolaminated architecture coupled with in-situ processing for enhanced mechanical properties and high electrical conductivity[J].Carbon,2017,117:65-74.
[30] Yang M,Weng L,Zhu H X,et al.Simultaneously enhancing the strength,ductility and conductivity of copper matrix composites with graphene nanoribbons[J].Carbon,2017,118:250-260.
[31] 匡达.石墨烯/镍基复合材料的制备和性能研究[D].上海:上海交通大学,2015.KUANG Da.Fabrication and properties of the nickel matrix graphene composites[D].Shanghai:Shanghai Jiaotong University,2012.
[32] 张兴普.石墨烯-纳米晶镍基复合材料的制备及性能研究[D].长春:吉林大学,2015.ZHANG Xing-pu.Fabrication and properties of graphene reinforced NC Ni matrix composites[D].Changchun:Jilin University,2015.
[33] Ren Z,Meng K,Shehzad K,et al.Mechanical properties of nickel-graphene composites synthesized by electrochemical deposition[J].Nanotechnology,2015,26(6):1-8.
[34] 杜金芳.石墨烯/镍基复合材料的原位制备与性能研究[D].兰州:兰州理工大学,2015.DU Jin-fang.In-situ fabrication and properties of graphene/nickel matrix composites[D].Lanzhou:Lanzhou University of Technology,2015.
[35] 吉传波,王晓峰,邹金文,等.石墨烯增强镍基粉末高温合金复合材料的力学性能[J].材料工程,2017,45(3):1-6.JI Chuan-bo,WANG Xiao-feng,ZOU Jin-wen,et al.Mechanical properties of graphene reinforced nickel-based P/M superalloy[J].Materials Engineering,2017,45(3):1-6.
[36] 张丽萍.体育器材用石墨烯镁基复合材料的制备与性能分析[J].热加工工艺,2015,44(12):140-142.ZHANG Li-ping.Properties analysis and preparation with grapheme magnesiummatrix composite in sports equipment[J].Hot Working Technology,2015,44(12):140-142.
[37] Rashad M,Pan F S,Hu H H,et al.Enhanced tensile properties of magnesium composites reinforced with graphene nanoplatelets[J].Materials Science and Engineering A,2015,630:36-44.
[38] Xiang S L,Gupta M,Wang X J,et al.Enhanced overall strength and ductility of magnesium matrix composites by low content of graphene nanoplatelets[J].Composites:Part A,2017,100:183-193.
[39] Du X,Du W B,Wang Z H,et al.Ultra-high strengthening efficiency of graphene nanoplatelets reinforced magnesium matrix composites[J].Materials Science and Engineering A,2018,711:633-642.
[40] 袁秋红,曾效舒,吴俊斌.石墨烯增强AZ91镁基复合材料的力学性能[J].机械工程材料,2016,40(8):43-48.YUAN Qiu-hong,ZENG Xiao-shu,WU Jun-bin,et al.Mechanical properties of graphene reinforced AZ91 Mg alloy based composite[J].Mechanical Engineering Materials,2016,40(8):43-48.