Fast, green microwave-assisted synthesis of single crystalline Sb_2Se_3 nanowires towards promising lithium storage

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英文篇名：Fast, green microwave-assisted synthesis of single crystalline Sb_2Se_3 nanowires towards promising lithium storage 作者：Wen ; Luo ; Jean-Jacques ; Gaumet ; Pierre ; Magri ; Sébastien ; Diliberto ; Feng ; Li ; Pascal ; Franchetti ; Jaafar ; Ghanbaja ; Liqiang ; Mai 英文作者：Wen Luo;Jean-Jacques Gaumet;Pierre Magri;Sébastien Diliberto;Feng Li;Pascal Franchetti;Jaafar Ghanbaja;Liqiang Mai;State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology;Laboratoire de Chimie et Physique: Approche Multi-échelles des Milieux Complexes, Institut Jean Barriol, Université de Lorraine;Institut Jean Lamour, UMR CNRS 7198, Université de Lorraine, Campus Artem; 英文关键词：Microwave synthesis;;Sb_2Se_3 nanowires;;Solvent-mediated process;;Lithium-ion battery;;High-performance anode 中文刊名：TRQZ 英文刊名：能源化学(英文版) 机构：State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology;Laboratoire de Chimie et Physique: Approche Multi-échelles des Milieux Complexes, Institut Jean Barriol, Université de Lorraine;Institut Jean Lamour, UMR CNRS 7198, Université de Lorraine, Campus Artem; 出版日期：2019-03-15 出版单位：Journal of Energy Chemistry 年：2019 期：v.30 基金：supported by the National Key Research and Development Program of China(2016YFA0202603);; the National Basic Research Program of China(2013CB934103);; the National Natural Science Foundation of China(51521001,51602239);; the National Natural Science Fund for Distinguished Young Scholars(51425204);; Yellow Crane Talent(Science&Technology)Program of Wuhan City;; the Fundamental Research Funds for the Central Universities(WUT:2016III001,2016III003,2016IVA090);; the Programme of Introducing Talents of Discipline to Universities(B17034);; support from the Lorraine Region(nowpart of Grand Est Region)Cooperation Research Lorraine/Hubei Program 2015/2017 语种：英文; 页：TRQZ201903004 页数：7 CN：03 ISSN：10-1287/O6 分类号：35-41

摘要

In this work, a fast(0.5 h), green microwave-assisted synthesis of single crystalline Sb_2Se_3 nanowires was developed. For the first time we demonstrated a facile solvent-mediated process, whereby intriguing nanostructures including antimony selenide(Sb_2Se_3) nanowires and selenium(Se) microrods can be achieved by merely varying the volume ratio of ethylene glycol(EG) and H_2O free from expensive chemical and additional surfactant. The achieved uniform Sb_2Se_3 nanowire is single crystalline along [001]growth direction with a diameter of 100 nm and a length up to tens of micrometers. When evaluated as an anode of lithium-ion battery, Sb_2Se_3 nanowire can deliver a high reversible capacity of 650.2 m Ah g~(-1) at 100 mA g~(-1) and a capacity retention of 63.8% after long-term 1000 cycles at 1000 mA g~(-1), as well as superior rate capability(389.5 m Ah g~(-1) at 2000 mA g~(-1)). This easy solvent-mediated microwave synthesis approach exhibits its great universe and importance towards the fabrication of high-performance metal chalcogenide electrode materials for future low-cost, large-scale energy storage systems.
        In this work, a fast(0.5 h), green microwave-assisted synthesis of single crystalline Sb_2Se_3 nanowires was developed. For the first time we demonstrated a facile solvent-mediated process, whereby intriguing nanostructures including antimony selenide(Sb_2Se_3) nanowires and selenium(Se) microrods can be achieved by merely varying the volume ratio of ethylene glycol(EG) and H_2O free from expensive chemical and additional surfactant. The achieved uniform Sb_2Se_3 nanowire is single crystalline along [001]growth direction with a diameter of 100 nm and a length up to tens of micrometers. When evaluated as an anode of lithium-ion battery, Sb_2Se_3 nanowire can deliver a high reversible capacity of 650.2 m Ah g~(-1) at 100 mA g~(-1) and a capacity retention of 63.8% after long-term 1000 cycles at 1000 mA g~(-1), as well as superior rate capability(389.5 m Ah g~(-1) at 2000 mA g~(-1)). This easy solvent-mediated microwave synthesis approach exhibits its great universe and importance towards the fabrication of high-performance metal chalcogenide electrode materials for future low-cost, large-scale energy storage systems.

引文

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