矿化剂H_3BO_3对黑色颜料SrFeO_3合成温度与性能的影响
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摘要
采用传统的固相合成法制备了一种新型无毒黑色无机颜料SrFeO_3,通过热重-示差扫描量热仪、X-射线衍射仪、紫外-可见-近红外分光光度计和Color CIE 1976 L~*a~*b~*色度分析软件等对所制备的粉末样品进行了综合分析。研究了矿化剂H_3BO_3对颜料样品合成温度及光学性能的影响,同时也对颜料样品的热稳定性及化学稳定性进行了分析。结果表明,这种SrFeO_3粉体作为颜料在涂料领域具有广阔的应用前景。
A novel non-toxic black inorganic pigment SrFeO_3 was synthesized by the traditional solid state method. Comprehensive analyses were carried out to characterize the resulting powders including thermo gravimetry and differential scanning calorimetry,X-ray diffraction,UV-Vis-NIR spectrophotometry,and color CIE 1976 chromaticity analysis software. The influence of H_3BO_3 mineralizer on the synthesis temperature and optical properties of the pigment has been evaluated. The thermal and chemical stabilities of the pigment have also been examined. The result indicating that this SrFeO_3 powder has great potential in serving as pigment for coating.
A novel non-toxic black inorganic pigment SrFeO_3 was synthesized by the traditional solid state method. Comprehensive analyses were carried out to characterize the resulting powders including thermo gravimetry and differential scanning calorimetry,X-ray diffraction,UV-Vis-NIR spectrophotometry,and color CIE 1976 chromaticity analysis software. The influence of H_3BO_3 mineralizer on the synthesis temperature and optical properties of the pigment has been evaluated. The thermal and chemical stabilities of the pigment have also been examined. The result indicating that this SrFeO_3 powder has great potential in serving as pigment for coating.
引文
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[15]李慧琴,陈敏璇,韩强,等.矿化剂对黄色颜料Sm0.3Ce0.66Mo0.04O(1.85+δ)光学性能影响[J].稀土,2014,35(6):62-66.
[2]JANSEN M,LETSCHERT H P.Inorganic yellow-red pigments without toxic metals[J].Nature,2000,404(6781):980-982.
[3]SAMEERA S,RAO P P,JAMES V,et al.Influence of(Li La)1/2Mo O4substitution on the pigmentary properties of Bi VO4[J].Dyes and Pigments,2014,104(1):41-47.
[4]FERNNDEZ-OSORIO A,PINEDA-VILLANUEVA E,CHVEZ-FERNNDEZ J.Synthesis of nanosized(Zn1-xCox)Al2O4spinels:New pink ceramic pigments[J].Materials Research Bulletin,2012,47(2):445-452.
[5]MELO D,VIEIRA F T G,COSTA T C C,et al.Lanthanum cobaltite black pigments with perovskite structure[J].Dyes and Pigments,2013,98(3):459-463.
[6]KIM J H,SON B R,YOON D H,et al.Characterization of blue Co Al2O4nano-pigment synthesized by ultrasonic hydrothermal method[J].Ceramics International,2012,38(7):5707-5712.
[7]LI Y Q,MEI S G,BYON Y J,et al.Highly Solar Radiation Reflective Cr2O3-3Ti O2Orange Nanopigment Prepared by a Polymer-Pyrolysis Method[J].ACS Sustainable Chemistry&Engineering,2014,2(2):318-321.
[8]张潇予,张玉军,龚红宇,等.溶胶-凝胶法制备纳米近红外高反射率黑色陶瓷颜料[J].功能材料,2013,3(44):417-420.
[9]王伟文,郑晓丹,李平,等.高能球磨高温度固相法制备尖晶石型铜铬黑颜料[J].化工进展,2013,32(8):1876-1880.
[10]王伟文,郑晓丹,李平,等.十二烷基苯磺酸钠辅助尿素共沉淀制备超细铜铬黑颜料[J].化工学报,2013,64(5):1847-1854.
[11]ELIZIRIO S A,ANDRADE J M,LIMA S J G,et al.Black and green pigments based on chromium-cobalt spinels[J].Materials Chemistry and Physics,2011,129(1/2):619-624.
[12]CALBO J,MESTRE A,GARCIA A,et al.Multicomponent black coloured spinels from alkoxides[J].Journal of Sol-Gel Science and Technology,2003,26(1/2/3):191-194.
[13]黄钢,卢西龙,曾信谦,等.矿化剂对钙铬榴石陶瓷绿色料性能的影响[J].陶瓷学报,2014,35(1):32-36.
[14]MESIKOV,ULCOVP,TROJAN M,et al.Synthesis and description of Sr Sn0.6Ln0.4O3perovskite pigments[J].Journal of Thermal Analysis and calorimetry,2008,91(1):163-166.
[15]李慧琴,陈敏璇,韩强,等.矿化剂对黄色颜料Sm0.3Ce0.66Mo0.04O(1.85+δ)光学性能影响[J].稀土,2014,35(6):62-66.