Zirconyl schiff base complex-functionalized MCM-41 catalyzes dehydration of fructose into 5-hydroxymethylfurfural in organic solvents

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英文篇名：Zirconyl schiff base complex-functionalized MCM-41 catalyzes dehydration of fructose into 5-hydroxymethylfurfural in organic solvents 作者：Yongdi ; Xie ; Wenwen ; Yuan ; Yi ; Huang ; Chunyan ; Wu ; Haijun ; Wang ; Yongmei ; Xia ; Xiang ; Liu 英文作者：Yongdi Xie;Wenwen Yuan;Yi Huang;Chunyan Wu;Haijun Wang;Yongmei Xia;Xiang Liu;Key Laboratory of Synthetic and Biological Colloids,Ministry of Education, School of Chemical and Material Engineering,Jiangnan University;State Key Laboratory of Food Science ξ Technology; 英文关键词：Fructose;;5-Hydroxymethylfurfural;;Zirconyl Schiff base complex;;MCM-41 中文刊名：FXKB 英文刊名：中国化学快报(英文版) 机构：Key Laboratory of Synthetic and Biological Colloids,Ministry of Education, School of Chemical and Material Engineering,Jiangnan University;State Key Laboratory of Food Science ξ Technology; 出版日期：2019-02-15 出版单位：Chinese Chemical Letters 年：2019 期：v.30 基金：financial supported by MOE & SAFEA,111 Project (No. B13025) 语种：英文; 页：FXKB201902017 页数：4 CN：02 ISSN：11-2710/O6 分类号：109-112

摘要

A novel catalyst, Zr (IV)-salen-MCM-41 with Lewis acid and base sites, was prepared and characterized by FT-IR, TG, XRD, SEM, TEM, BET, NH3-TPD, and CO_2-TPD. The as-synthesized catalyst was applied to the conversion of fructose into 5-hydroxymethylfurfural (HMF). In this work, the heterogeneous catalyst had a superior activity for the dehydration of fructose into HMF. 92,0% HMF yield was obtained from fructose at 140 ℃ for 4 h in dimethyl sulfoxide (DMSO), In addition, the effect of reaction temperature, reaction time, solvents and catalyst dosages were also investigated in detail. Meanwhile, the Zr (IV)-salen-MCM-41 could be reused four times with a slight decrease in catalytic activity
        A novel catalyst, Zr (IV)-salen-MCM-41 with Lewis acid and base sites, was prepared and characterized by FT-IR, TG, XRD, SEM, TEM, BET, NH3-TPD, and CO_2-TPD. The as-synthesized catalyst was applied to the conversion of fructose into 5-hydroxymethylfurfural (HMF). In this work, the heterogeneous catalyst had a superior activity for the dehydration of fructose into HMF. 92,0% HMF yield was obtained from fructose at 140 ℃ for 4 h in dimethyl sulfoxide (DMSO), In addition, the effect of reaction temperature, reaction time, solvents and catalyst dosages were also investigated in detail. Meanwhile, the Zr (IV)-salen-MCM-41 could be reused four times with a slight decrease in catalytic activity

引文

[1] Z.Z. Yang, J. Deng, T. Pan, Q.X. Guo, Y. Fu, Green Chem. 14(2012)2986-2989.
    [2] Q.D. Hou, W.Z. Li, M.T. Ju, et al., RSC Adv. 6(2016)104016-104024.
    [3] P. Maki-Arvela, I.L. Simakova, T. Salmi, D.Y. Murzin, Chem. Rev. 114(2014)1909-1971.
    [4] N.N. Wang, Y. Yao, W. Li, et al., RSC Adv. 4(2014)57164-57172.
    [5] F.D. Pileidis, M.M. Titirici, ChemSusChem 9(2016)562-582.
    [6] Y.L Yang, Z.T. Du, Y.Z. Huang, et al., Green Chem. 15(2013)1932-1940.
    [7] G. Yong, Y.G. Zhang, J.Y. Ying, Angew. Chem. Int. Ed. 47(2008)9485-9488.
    [8] B. Liu, Z.H. Zhang, Chemsuschem 47(2016)2015-2036.
    [9] J. Wang, T. Qu, M.S. Liang, Z.B. Zhao, RSC Adv. 5(2015)106053-106060.
    [10] T.S. Deng, J.G. Li, Q.Q. Yang, et al., RSC Adv. 6(2016)30160-30165.
    [11] Z.H. Zhang, J.D. Zhen, B. Liu, K.L. Lv, K.J. Deng, Green Chem. 17(2015)1308-1317.
    [12] X.W. Han, L Geng, Y. Guo, et al., Green Chem. 18(2016)1597-1604.
    [13] D.W. Gardner, J.J. Huo, T.C. Hoff, et al., ACS Catal. 5(2015)4418-4422.
    [14] J.B. Binder, A.V. Cefali, J.J. Blank, R.T. Raines, Energ. Environ. Sci. 3(2010)765-771.
    [15] H.B. Zhao, J.E. Holladay, H. Brown, Z.C. Zhang, Science 316(2007)1597-1600.
    [16] X.H. Yi, I. Delidovich, Z. Sun, et al., Catal. Sci. Technol. 5(2015)2496-2502.
    [17] P. Zhou, Z.H. Zhang, Catal. Sci. Technol. 6(2016)3694-3712.
    [18] R.J. van Putten,J.C. van der Waal, E. de Jong, et al., Chem. Rev. 113(2013)1499-1597.
    [19] F.C. de Melo, R.F. de Souza, P.L.A. Coutinho, M.O. de Souza, J. Brazil Chem. Soc.25(2014)2378-2384.
    [20] A.H. Jadhav, A. Chinnappan, R.H. Patil, S.V. Kostjuk, H. Kim, Chem. Eng. J. 243(2014)92-98.
    [21] H.T. Han, H.Y. Zhao, Y. Liu, et al., RSC Adv. 7(2017)3790-3795.
    [22] B. Liu, Z.Z. Gou, A.Q. Liu, Z.H. Zhang, J. Ind. Eng. Chem. 21(2015)338-339.
    [23] A. Jain, A.M. Shore, S.C. Jonnalagadda, K.V. Ramanujachary, A. Mugweru, Appl.Catal. A:Gener. 489(2015)72-76.
    [24] S. Narang, R. Mehta, S.N. Upadhyay, Ind. Eng. Chem. Res. 52(2013)3967-3973.
    [25] C.G. Arellano, A. Corma, M. Iglesias, F. Sanchez, Eur. J. Inorg. Chem. 7(2008)1107-1115.
    [26] C.G. Arellano, A. Corma, M. Iglesias, F. Sanchez, Adv. Synth. Catal. 346(2004)1758-1764.
    [27] A.Jafarzadeh, S.Sohrabnezhad,M.A. Zanjanchi, M. Arvand, Micropor. Mesopor.Mat. 236(2016)109-119.
    [28] X. Yuan, G.F. Shan, L.X. Li, J. Wu, H.A. Luo, Catal. Lett. 145(2015)868-874.
    [29] M. Hajjami, F. Ghorbani, S. Roshani, S. Rahimipanah, J. Porous. Mat. 23(2016)689-699.
    [30] M. Hajjami, F. Ghorbani, S. Roshani, S. Rahimipanah, Chin. J. Catal. 36(2015)1852-1860.
    [31] M. Fadhli, I. Khedher, J.M. Fraile, J. Mol. Catal. A:Chem. 420(2016)282-289.
    [32] M. Hajjami, Z. Yousofvand, Catal. Lett. 145(2015)1733-1740.
    [33] Y.Y. Wang, L.H. Zhang, D.D. Wang, X.Y. Guo, S.H. Wu, J. Chromatogr. A 1478(2016)26-34.
    [34] Z. Zhang, B. Du, L.J. Zhang, et al., RSC Adv. 3(2013)9201-9205.
    [35] Z. Zhang, B. Du, Z.J. Quan, Y.X. Da, X.C. Wang, Catal. Sci. Technol. 4(2014)633-638.
    [36] T.Y. Cheng, P.Y. Chao, Y.H. Huang, et al., Micropor. Mesopor. Mat. 233(2016)148-153.
    [37] C.H. Song, H. Liu, Y. Li, et al., Chin. J. Chem. 32(2014)434-442.