农业废弃物活性炭制备及其对染料废水的吸附研究进展
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摘要
介绍了农业废弃物的化学组成,综述了农业废弃物活性炭的制备方法以及制备过程中的影响因素,分析讨论了其在染料吸附过程中的应用,以及影响活性炭对染料吸附作用的主要因素,指出以农业废弃物为前驱体制备活性炭是目前的研究热点,并已经在颜料脱除方面取得了大量进展。
The chemical composition of agricultural wastes was introduced; the preparation method of activated carbon by agricultural wastes and the influencing factors were summarized. The application of the said kind of activated carbon for dyestuff adsorption and the main influencing factors were analyzed and discussed. It was pointed out that, using agricultural wastes as the precursor to prepare activated carbon was the hotspot of current research, which has already obtained great progress in field of pigment removal.
The chemical composition of agricultural wastes was introduced; the preparation method of activated carbon by agricultural wastes and the influencing factors were summarized. The application of the said kind of activated carbon for dyestuff adsorption and the main influencing factors were analyzed and discussed. It was pointed out that, using agricultural wastes as the precursor to prepare activated carbon was the hotspot of current research, which has already obtained great progress in field of pigment removal.
引文
[1]DEMIRBAS A.Agricultural based activated carbons for the removal of dyes from aqueous solutions:A review[J].Journal of Hazardous Materials,2009,167(1-3):1-9.
[2]CHAKRABARTI T,SUBRAHMANYAM P V R,SUNDARESAN B B,et al.Biodegradation of recalcitrant industrial wastes.In Wise,D,Biotreatment Systems,Vol 2[M].Florida:CRC Press,1988:172-234.
[3]ESSAWY A A,ALI A E,ABDEL-MOTTALEB M S A.Application of novel copolymer-Ti O2membranes for some textile dyes adsorptive removal from aqueous solution and photocatalytic decolorization[J].Journal of Hazardous Materials,2008,157(2-3):547-552.
[4]马新芳.煤基活性炭和果胶/钛柱撑膨润土的制备及吸附性能研究[D].石河子:石河子大学,2014.
[5]SUN Y,LI H,LI G,et al.Characterization and ciprofloxacin adsorption properties of activated carbons prepared from biomass wastes by H3PO4activation[J].Bioresource technology,2016,217:239-244.
[6]LI D,YAN J,LIU Z,et al.Adsorption kinetic studies for removal of methylene blue using activated carbon prepared from sugar beet pulp[J].International Journal of Environmental Science and Technology,2016,13(7):1815-1822.
[7]DEMIRBAS A.Effects of temperature and particle size on bio-char yield from pyrolysis of agricultural residues[J].Journal of Analytical and Applied Pyrolysis,2004,72(2):243-248.
[8]CRINI G.Non-conventional low-cost adsorbents for dye removal:a review[J].Bioresource technology,2006,97(9):1061-1085.
[9]CHEN C,FU Y,YU L,et al.Removal of methylene blue by seed-watermelon pulp based low-cost adsorbent:Study of adsorption isotherms and kinetic models[J].Journal of Dispersion Science and Technology,2016,38(8):1142-1146.
[10]MOHAMAD N N,LAU L C,LEE K T,et al.Synthesis of activated carbon from lignocellulosic biomass and its applications in air pollution control-a review[J].Journal of Environmental Chemical Engineering,2013,1(4):658-666.
[11]ARAMI-NIYA A,WAN MOHD ASHRI W D,FAROUQ S M.Using granular activated carbon prepared from oil palm shell by Zn Cl2and physical activation for methane adsorption[J].Journal of Analytical and Applied Pyrolysis,2010,89(2):197-203.
[12]SUHAS,CARROTT P J,RIBEIRO C M M.Lignin-from natural adsorbent to activated carbon:a review[J].Bioresource Technology,2007,98(12):2301-2312.
[13]MENDES F M,MARQUES A C,MENDON覶A D L,et al.High surface area activated carbon from sugar cane straw[J].Waste and Biomass Valorization,2015,6(3):433-440.
[14]KUNDU A,GUPTA B S,HASHIM M,et al.Taguchi optimization approach for production of activated carbon from phosphoric acid impregnated palm kernel shell by microwave heating[J].Journal of Cleaner Production,2015,105:420-427.
[15]ELLO A M,DE SOUZA L K C,ALBERT T.Development of microporous carbons for CO2capture by KOH activation of African palm shells[J].Journal of CO2Utilization,2013,2(2):35-38.
[16]DURSUN A Y,TEPE O,USHU G,et al.Kinetics of Remazol Black B adsorption onto carbon prepared from sugar beet pulp[J].Environmental Science and Pollution Research,2013,20(4):2472-2483.
[17]GAO Y,XU S,ORTABOY S,et al.Preparation of welldeveloped mesoporous activated carbon with high yield by ammonium polyphosphate activation[J].Journal of the Taiwan Institute of Chemical Engineers,2016,66:394-399.
[18]AHMAD M A,RAHMAN N K.Equilibrium,kinetics and thermodynamic of Remazol Brilliant Orange 3R dye adsorption on coffee husk-based activated carbon[J].Chemical Engineering Journal,2011,170(1):154-161.
[19]杨蓉,赵芳,苏燕艳.果壳活性炭对废水中苯酚的吸附特性[J].工业用水与废水,2010,41(5):74-76.
[20]BALAT M.Mechanisms of thermochemical biomass conversion processes.Part 1:reactions of pyrolysis[J].Energy Sources,Part A,2008,30(7):620-635.
[21]HOKKANEN S,BHATNAGAR A,SILLAMP魧魧M.A review on modification methods to cellulose-based adsorbents to improve adsorption capacity[J].Water Research,2016,91:156-173.
[22]CHAN C H,CHIA C H,ZAKARIA S,et al.Cellulose nanofibrils:a rapid adsorbent for the removal of methylene blue[J].RSC Advances,2015,5(24):18204-18212.
[23]DAUD W M A W,ALI W S W.Comparison on pore development of activated carbon produced from palm shell and coconut shell[J].Bioresource Technology,2004,93(1):63-69.
[24]武颖杰.甜菜粕基活性炭的制备及吸附性能的研究[D].南京:南京林业大学,2013.
[25]NABAIS J M V,LAGINHAS C,CARROTT P J M,et al.Thermal conversion of a novel biomass agricultural residue(vine shoots)into activated carbon using activation with CO2[J].Journal of Analytical and Applied Pyrolysis,2010,87(1):8-13.
[26]LI L,LI X,LEE J,et al.The effect of surface properties in activated carbon on mercury adsorption[J].Industrial&Engineering Chemistry Research,2012,51(26):9136-9144.
[27]DAUD W M A W,ALI W S W,SULAIMAN M Z.The effects of carbonization temperature on pore development in palm-shell-based activated carbon[J].Carbon,2000,38(14):1925-1932.
[28]RUIZ-FERN魣DEZ M,ALEXANDRE-FRANCO M,FERN魣NDEZ-GONZ魣LEZ C,et al.Development of activated carbon from vine shoots by physical and chemical activation methods.Some insight into activation mechanisms[J].Adsorption,2011,17(3):621-629.
[29]胡立鹃,吴峰,彭善枝,等.生物质活性炭的制备及应用进展[J].化学通报,2016,79(3):205-212.
[30]MOCHIZUKI T,KUBOTA M,MATSUDA H,et al.Adsorption behaviors of ammonia and hydrogen sulfide on activated carbon prepared from petroleum coke by KOH chemical activation[J].Fuel Processing Technology,2016,144:164-169.
[31]FOO K,HAMEED B.Microwave-assisted preparation of oil palm fiber activated carbon for methylene blue adsorption[J].Chemical Engineering Journal,2011,166(2):792-795.
[32]LI G,LI J,TAN W,et al.Preparation and characterization of the hydrogen storage activated carbon from coffee shell by microwave irradiation and KOH activation[J].International Biodeterioration&Biodegradation,2016,113:386-390.
[33]SHORE J.Advances in direct dyes[J].Indian Journal of Fibre&Textile Research,1996,21(1):1-29.
[34]KUMAR A,JENA H M.Removal of methylene blue and phenol onto prepared activated carbon from Fox nutshell by chemical activation in batch and fixed-bed column[J].Journal of Cleaner Production,2016,137:1246-1259.
[35]HEIBATI B,RODRIGUEZ-COUTO S,AL-GHOUTI M A,et al.Kinetics and thermodynamics of enhanced adsorption of the dye AR 18 using activated carbons prepared from walnut and poplar woods[J].Journal of Molecular Liquids,2015,208:99-105.
[36]HAMEED B,EL-KHAIARY M.Equilibrium,kinetics and mechanism of malachite green adsorption on activated carbon prepared from bamboo by K2CO3activation and subsequent gasification with CO2[J].Journal of Hazardous Materials,2008,157(2):344-351.
[37]PEI Y,WU X,XU G,et al.Tannin-immobilized cellulose microspheres as effective adsorbents for removing cationic dye(Methylene Blue)from aqueous solution[J].Journal of Chemical Technology&Biotechnology,2016,92:1276-1284.
[38]AL-DEGS Y,KHRAISHEH M A M,ALLEN S J,et al.Effect of carbon surface chemistry on the removal of reactive dyes from textile effluent[J].Water Research,2000,34(3):927-935.
[39]SHAFEEYAN M S,DAUD W M A W,HOUSHMAND A,et al.A review on surface modification of activated carbon for carbon dioxide adsorption[J].Journal of Analytical and Applied Pyrolysis,2010,89(2):143-151.
[40]MEHTA D,MAZUMDAR S,SINGH S K.Magnetic adsorbents for the treatment of water/wastewater-A review[J].Journal of Water Process Engineering,2015,7:244-265.
[41]MEZOHEGYI G,VAN D Z F P,FONT J,et al.Towards advanced aqueous dye removal processes:A short review on the versatile role of activated carbon[J].Journal of Environmental Management,2012,102(14):148-164.
[42]HSIEH C,TENG H.Langmuir and Dubinin-Radushkevich analyses on equilibrium adsorption of activated carbon fabrics in aqueous solutions[J].Journal of Chemical Technology&Biotechnology,2015,75(11):1066-1072.
[43]ACEMIGLU B.Adsorption of Congo red from aqueous solution onto calcium-rich fly ash[J].Journal of Colloid&Interface Science,2004,274(2):371-379.
[2]CHAKRABARTI T,SUBRAHMANYAM P V R,SUNDARESAN B B,et al.Biodegradation of recalcitrant industrial wastes.In Wise,D,Biotreatment Systems,Vol 2[M].Florida:CRC Press,1988:172-234.
[3]ESSAWY A A,ALI A E,ABDEL-MOTTALEB M S A.Application of novel copolymer-Ti O2membranes for some textile dyes adsorptive removal from aqueous solution and photocatalytic decolorization[J].Journal of Hazardous Materials,2008,157(2-3):547-552.
[4]马新芳.煤基活性炭和果胶/钛柱撑膨润土的制备及吸附性能研究[D].石河子:石河子大学,2014.
[5]SUN Y,LI H,LI G,et al.Characterization and ciprofloxacin adsorption properties of activated carbons prepared from biomass wastes by H3PO4activation[J].Bioresource technology,2016,217:239-244.
[6]LI D,YAN J,LIU Z,et al.Adsorption kinetic studies for removal of methylene blue using activated carbon prepared from sugar beet pulp[J].International Journal of Environmental Science and Technology,2016,13(7):1815-1822.
[7]DEMIRBAS A.Effects of temperature and particle size on bio-char yield from pyrolysis of agricultural residues[J].Journal of Analytical and Applied Pyrolysis,2004,72(2):243-248.
[8]CRINI G.Non-conventional low-cost adsorbents for dye removal:a review[J].Bioresource technology,2006,97(9):1061-1085.
[9]CHEN C,FU Y,YU L,et al.Removal of methylene blue by seed-watermelon pulp based low-cost adsorbent:Study of adsorption isotherms and kinetic models[J].Journal of Dispersion Science and Technology,2016,38(8):1142-1146.
[10]MOHAMAD N N,LAU L C,LEE K T,et al.Synthesis of activated carbon from lignocellulosic biomass and its applications in air pollution control-a review[J].Journal of Environmental Chemical Engineering,2013,1(4):658-666.
[11]ARAMI-NIYA A,WAN MOHD ASHRI W D,FAROUQ S M.Using granular activated carbon prepared from oil palm shell by Zn Cl2and physical activation for methane adsorption[J].Journal of Analytical and Applied Pyrolysis,2010,89(2):197-203.
[12]SUHAS,CARROTT P J,RIBEIRO C M M.Lignin-from natural adsorbent to activated carbon:a review[J].Bioresource Technology,2007,98(12):2301-2312.
[13]MENDES F M,MARQUES A C,MENDON覶A D L,et al.High surface area activated carbon from sugar cane straw[J].Waste and Biomass Valorization,2015,6(3):433-440.
[14]KUNDU A,GUPTA B S,HASHIM M,et al.Taguchi optimization approach for production of activated carbon from phosphoric acid impregnated palm kernel shell by microwave heating[J].Journal of Cleaner Production,2015,105:420-427.
[15]ELLO A M,DE SOUZA L K C,ALBERT T.Development of microporous carbons for CO2capture by KOH activation of African palm shells[J].Journal of CO2Utilization,2013,2(2):35-38.
[16]DURSUN A Y,TEPE O,USHU G,et al.Kinetics of Remazol Black B adsorption onto carbon prepared from sugar beet pulp[J].Environmental Science and Pollution Research,2013,20(4):2472-2483.
[17]GAO Y,XU S,ORTABOY S,et al.Preparation of welldeveloped mesoporous activated carbon with high yield by ammonium polyphosphate activation[J].Journal of the Taiwan Institute of Chemical Engineers,2016,66:394-399.
[18]AHMAD M A,RAHMAN N K.Equilibrium,kinetics and thermodynamic of Remazol Brilliant Orange 3R dye adsorption on coffee husk-based activated carbon[J].Chemical Engineering Journal,2011,170(1):154-161.
[19]杨蓉,赵芳,苏燕艳.果壳活性炭对废水中苯酚的吸附特性[J].工业用水与废水,2010,41(5):74-76.
[20]BALAT M.Mechanisms of thermochemical biomass conversion processes.Part 1:reactions of pyrolysis[J].Energy Sources,Part A,2008,30(7):620-635.
[21]HOKKANEN S,BHATNAGAR A,SILLAMP魧魧M.A review on modification methods to cellulose-based adsorbents to improve adsorption capacity[J].Water Research,2016,91:156-173.
[22]CHAN C H,CHIA C H,ZAKARIA S,et al.Cellulose nanofibrils:a rapid adsorbent for the removal of methylene blue[J].RSC Advances,2015,5(24):18204-18212.
[23]DAUD W M A W,ALI W S W.Comparison on pore development of activated carbon produced from palm shell and coconut shell[J].Bioresource Technology,2004,93(1):63-69.
[24]武颖杰.甜菜粕基活性炭的制备及吸附性能的研究[D].南京:南京林业大学,2013.
[25]NABAIS J M V,LAGINHAS C,CARROTT P J M,et al.Thermal conversion of a novel biomass agricultural residue(vine shoots)into activated carbon using activation with CO2[J].Journal of Analytical and Applied Pyrolysis,2010,87(1):8-13.
[26]LI L,LI X,LEE J,et al.The effect of surface properties in activated carbon on mercury adsorption[J].Industrial&Engineering Chemistry Research,2012,51(26):9136-9144.
[27]DAUD W M A W,ALI W S W,SULAIMAN M Z.The effects of carbonization temperature on pore development in palm-shell-based activated carbon[J].Carbon,2000,38(14):1925-1932.
[28]RUIZ-FERN魣DEZ M,ALEXANDRE-FRANCO M,FERN魣NDEZ-GONZ魣LEZ C,et al.Development of activated carbon from vine shoots by physical and chemical activation methods.Some insight into activation mechanisms[J].Adsorption,2011,17(3):621-629.
[29]胡立鹃,吴峰,彭善枝,等.生物质活性炭的制备及应用进展[J].化学通报,2016,79(3):205-212.
[30]MOCHIZUKI T,KUBOTA M,MATSUDA H,et al.Adsorption behaviors of ammonia and hydrogen sulfide on activated carbon prepared from petroleum coke by KOH chemical activation[J].Fuel Processing Technology,2016,144:164-169.
[31]FOO K,HAMEED B.Microwave-assisted preparation of oil palm fiber activated carbon for methylene blue adsorption[J].Chemical Engineering Journal,2011,166(2):792-795.
[32]LI G,LI J,TAN W,et al.Preparation and characterization of the hydrogen storage activated carbon from coffee shell by microwave irradiation and KOH activation[J].International Biodeterioration&Biodegradation,2016,113:386-390.
[33]SHORE J.Advances in direct dyes[J].Indian Journal of Fibre&Textile Research,1996,21(1):1-29.
[34]KUMAR A,JENA H M.Removal of methylene blue and phenol onto prepared activated carbon from Fox nutshell by chemical activation in batch and fixed-bed column[J].Journal of Cleaner Production,2016,137:1246-1259.
[35]HEIBATI B,RODRIGUEZ-COUTO S,AL-GHOUTI M A,et al.Kinetics and thermodynamics of enhanced adsorption of the dye AR 18 using activated carbons prepared from walnut and poplar woods[J].Journal of Molecular Liquids,2015,208:99-105.
[36]HAMEED B,EL-KHAIARY M.Equilibrium,kinetics and mechanism of malachite green adsorption on activated carbon prepared from bamboo by K2CO3activation and subsequent gasification with CO2[J].Journal of Hazardous Materials,2008,157(2):344-351.
[37]PEI Y,WU X,XU G,et al.Tannin-immobilized cellulose microspheres as effective adsorbents for removing cationic dye(Methylene Blue)from aqueous solution[J].Journal of Chemical Technology&Biotechnology,2016,92:1276-1284.
[38]AL-DEGS Y,KHRAISHEH M A M,ALLEN S J,et al.Effect of carbon surface chemistry on the removal of reactive dyes from textile effluent[J].Water Research,2000,34(3):927-935.
[39]SHAFEEYAN M S,DAUD W M A W,HOUSHMAND A,et al.A review on surface modification of activated carbon for carbon dioxide adsorption[J].Journal of Analytical and Applied Pyrolysis,2010,89(2):143-151.
[40]MEHTA D,MAZUMDAR S,SINGH S K.Magnetic adsorbents for the treatment of water/wastewater-A review[J].Journal of Water Process Engineering,2015,7:244-265.
[41]MEZOHEGYI G,VAN D Z F P,FONT J,et al.Towards advanced aqueous dye removal processes:A short review on the versatile role of activated carbon[J].Journal of Environmental Management,2012,102(14):148-164.
[42]HSIEH C,TENG H.Langmuir and Dubinin-Radushkevich analyses on equilibrium adsorption of activated carbon fabrics in aqueous solutions[J].Journal of Chemical Technology&Biotechnology,2015,75(11):1066-1072.
[43]ACEMIGLU B.Adsorption of Congo red from aqueous solution onto calcium-rich fly ash[J].Journal of Colloid&Interface Science,2004,274(2):371-379.