有机液体吸附功能纤维研究进展
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摘要
有机液体吸附功能纤维是一类可吸附自身重量数十倍有机液体的新型纤维材料,具有吸附速率快、吸附量高、易回收及可重复使用等特点,在环境保护、水处理、有机液体分离与回收等领域具有广阔的应用前景,已成为近年来吸附材料研究领域的热点。本文回顾了有机液体吸附功能纤维的发展历史,介绍了所用聚合物种类、单体选用及其制备方法,分析比较了几种有机液体吸附功能纤维的纺丝成形原理,讨论了纺丝过程中各种参数对纤维结构与性能的影响,总结了有机液体吸附功能纤维的再生与应用等方面的研究进展,并对其发展趋势进行了展望。
Absorptive functional fiber for organic liquids is a kind of novel fiber material that can absorb certain organic liquids several times as its original weight.Absorptive functional fiber for organic liquids is characterized by its high absorptive rate,large saturated absorbency,easy recyclable and disposal,which makes it highly promising in the field of environmental protection,water treatment and separation of organic liquids.And it also has become a hot research topic in absorptive materials.In this paper,the history of absorptive functional fiber for organic liquids development has been reviewed;different types of polymers and monomers and preparation methods are introduced;the fiber forming mechanisms of absorptive functional fiber are investigated.In addition,this review illustrates the effects of spinning parameters on fiber structures and properties,and then summarizes the recent advances in regeneration and application field.At last,the promising approaches and developing direction are forecasted.
Absorptive functional fiber for organic liquids is a kind of novel fiber material that can absorb certain organic liquids several times as its original weight.Absorptive functional fiber for organic liquids is characterized by its high absorptive rate,large saturated absorbency,easy recyclable and disposal,which makes it highly promising in the field of environmental protection,water treatment and separation of organic liquids.And it also has become a hot research topic in absorptive materials.In this paper,the history of absorptive functional fiber for organic liquids development has been reviewed;different types of polymers and monomers and preparation methods are introduced;the fiber forming mechanisms of absorptive functional fiber are investigated.In addition,this review illustrates the effects of spinning parameters on fiber structures and properties,and then summarizes the recent advances in regeneration and application field.At last,the promising approaches and developing direction are forecasted.
引文
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[2]Haigh D H,Beaverton M.USP 3520806.1970-7-21.
[3]Fletcher J C,Marsh H E.USP 4039489.1977-8-2.
[4]Barby D,Haq Z.USP 4522953.1985-6-11.
[5]Hozumi Y,Inaoka T,Gomi T,Goto T,Uno T,Rakutani K.USP 5374600.1994-12-20.
[6]Hozumi Y,Inaoka T,Gomi T,Goto T.JP,04015286.1990-5-9.
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[8]路建美,朱秀林.高分子材料科学与工程,1995,11(2):41～43.
[9]朱秀林,徐冬梅,郦雅芳,庞爱东.高分子材料科学与工程,1995,11(1):19～23.
[10]蒋必彪,陈小严,朱亮.合成树脂及塑料,1996,13(2):37～39.
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[23]Zhou M-H,Kim S-H,Park J-G,Ha C-S,Cho W-J.Polym Bull,2000,44(1):17～24.
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[38]Fan L,Chen H,Hao Z,Tan Z.J Polym Sci Part A:Polym Chem,2012,50(23):4871～4878.
[39]Zhao J,Xiao C,Xu N,Feng Y.Polym-Plast Technol Eng,2011,50(8):818～824.
[40]肖长发,张燕,安树林,贾广霞.中国,200810053621.0.2009-12-30.
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[42]van Der Sanden M C M,Meijer H E H.Makromol Chem Macromol Symp,1993,75(1):115～125.
[43]Ge Z,Xiao C.J Appl Polym Sci,2010,115(6):3357～3364.
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[45]肖长发,赵健,徐乃库,封严,安树林.中国,201010164761.2.2011-8-31.
[46]Deschamps G,Caruel H,Borredon M-E,Bonnin C,Vignoles C.Environ Sci Technol,2003,37(5),1013～1015.
[47]Li S,Wei J.J Polym Res,2012,19(3):1～6.
[48]刘艳萍.三元乙丙超细纤维毡的制备及其处理油类污染物的机理研究.上海:东华大学,2009.
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[50]Zhu H,Qiu S,Jiang W,Wu D,Zhang C.Environ Sci Technol,2011,45(10):4527～4531.
[51]Zhao J,Xiao C F,Xu NK,Feng Y.J Macromol Sci Part B-Phys,2012,51(11):2297～2309.
[52]Ji F,Li C,Dong X,Li Y,Wang D.J Hazard Mater,2009,164(2):1346～1351.
[53]何月,凌旌瑾,陈业钢.环境科学与管理,2010,35(007):100～102.
[54]张玉婷,肖长发.天津工业大学学报,2009,28(2):1～4.
[55]张玉婷,肖长发.合成树脂及塑料,2009,26(2):38～42.
[56]Zhao J,Xiao C,Xu N.J Thermoplast Compo Mater,2013,In press.
[57]Zhao J,Xiao C,Xu N.Int J Polym Anal Charact,2012,17(8):557～567.
[58]Zhao J,Xiao C,Xu N.Environ Sci Pollut Res,2013,20(6):4137～4145.
[59]Lin C,Huang C-L,Shern C-C.Resour Conserv Recy,2008,52(10):1162～1166.
[60]文善雄,刘光利,赵保全,荣树茂.化工新型材料,2011,39(8):122～124.
[61]刘雪粉,俞云良,陆向红,徐之超,计建炳.化工进展,2006,25(6):639～645.