Syntheses,Structures,and Luminescent Properties of the Zn~Ⅱ and Cd~Ⅱ 1-D Chain Polymers Assembled by Salicylhydroxamic Acid
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摘要
Two complexes of compositions [Zn(H2shi)(CH3COO)]n(1) and [Cd(H2shi)2(H2O)]n(2)(H3shi = salicylhydroxamic acid) have been prepared under solvothermal conditions. They are characterized by X-ray single-crystal diffraction, IR and elemental analysis. The crystal of 1 belongs to the tetragonal system, space group I41/a with a = 18.972(3), b = 18.972(3), c = 10.938(2) ?, V = 3937.1(1) ?3, C9H9NO5 Zn, Mr = 276.54, Z = 16, Dc = 1.866 g/cm3, μ = 2.500 mm-1, F(000) = 2240, the final R = 0.0425 and w R = 0.123. The crystal of 2 belongs to the monoclinic system, space group P2/c with a = 16.647(3), b = 6.4577(1), c = 6.5623(1) ?, V = 702.4(2) ?3, C14H14Cd2N2O7, Mr = 434.68, Z = 2, Dc = 2.055 g/cm3, μ = 1.599 mm-1, F(000) = 432, the final R = 0.0211 and w R = 0.0761. They both possess 1-D polymeric chain structures. The luminescent properties of complexes 1 and 2 have been investigated.
Two complexes of compositions [Zn(H2shi)(CH3COO)]n(1) and [Cd(H2shi)2(H2O)]n(2)(H3shi = salicylhydroxamic acid) have been prepared under solvothermal conditions. They are characterized by X-ray single-crystal diffraction, IR and elemental analysis. The crystal of 1 belongs to the tetragonal system, space group I41/a with a = 18.972(3), b = 18.972(3), c = 10.938(2) ?, V = 3937.1(1) ?3, C9H9NO5 Zn, Mr = 276.54, Z = 16, Dc = 1.866 g/cm3, μ = 2.500 mm-1, F(000) = 2240, the final R = 0.0425 and w R = 0.123. The crystal of 2 belongs to the monoclinic system, space group P2/c with a = 16.647(3), b = 6.4577(1), c = 6.5623(1) ?, V = 702.4(2) ?3, C14H14Cd2N2O7, Mr = 434.68, Z = 2, Dc = 2.055 g/cm3, μ = 1.599 mm-1, F(000) = 432, the final R = 0.0211 and w R = 0.0761. They both possess 1-D polymeric chain structures. The luminescent properties of complexes 1 and 2 have been investigated.
Two complexes of compositions [Zn(H2shi)(CH3COO)]n(1) and [Cd(H2shi)2(H2O)]n(2)(H3shi = salicylhydroxamic acid) have been prepared under solvothermal conditions. They are characterized by X-ray single-crystal diffraction, IR and elemental analysis. The crystal of 1 belongs to the tetragonal system, space group I41/a with a = 18.972(3), b = 18.972(3), c = 10.938(2) ?, V = 3937.1(1) ?3, C9H9NO5 Zn, Mr = 276.54, Z = 16, Dc = 1.866 g/cm3, μ = 2.500 mm-1, F(000) = 2240, the final R = 0.0425 and w R = 0.123. The crystal of 2 belongs to the monoclinic system, space group P2/c with a = 16.647(3), b = 6.4577(1), c = 6.5623(1) ?, V = 702.4(2) ?3, C14H14Cd2N2O7, Mr = 434.68, Z = 2, Dc = 2.055 g/cm3, μ = 1.599 mm-1, F(000) = 432, the final R = 0.0211 and w R = 0.0761. They both possess 1-D polymeric chain structures. The luminescent properties of complexes 1 and 2 have been investigated.
引文
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(28)Meng,X.R.;Song,Y.L.;Hou,H.W.;Han,H.Y.;Xiao,B.;Fan,Y.T.;Zhu,Y.Hydrothermal syntheses,crystal structures,and characteristics of a series of Cd-btx coordination polymers(btx=1,4-bis(triazol-1-ylmethyl)benzene).Inorg.Chem.2004,43,3528–3536.
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(31)Brown,D.A.;Fitzpatrick,N.J.;Müller-Bunz,H.;Ryan,A.T.Di-,tri-,and tetranuclear zinc hydroxamate complexes as structural models for the inhibition of zinc hydrolases by hydroxamic acids.Inorg.Chem.2006,45,4497–4507.
(32)Alexiou,M.;Dendrinou-Samara,C.;Raptopoulou,C.P.;Terzis,A.;Kessissoglou,D.P.From monomer zinc-oxamato complexes to tetranuclear inverse 12-membered and octanuclear 12-membered metallacrowns.Inorg.Chem.2002,41,4732–4738.
(33)Chen,Y.M.;Gao,Q.;Liu,Y.L.;Cao,Y.Y.;Gao,D.D.;Liu,J.N.;Zhao,J.J.;Li,Y.H.;Liu,W.;Li,W.Synthesis,crystal structures and luminescent properties of CdⅡ and ZnⅡ complexes assembled by 4-aminophenylhydroxamic acid.RSC Adv.2014,4,147–153.
(34)Chen,W.T.;Yi,X.G.;Wen,J.W.Synthesis,crystal structure and property of(Cd Cl3)n·n H3O with a one-dimensional infinite chain-like structure.Asian J.Chem.2014,26,1253–1254.
(35)Chen,W.T.;Hu,R.H.;Yi,X.G.;Wang,Y.F.;Luo,Z.G.;Fu,H.R.;Liu,J.;Chen,H.L.Synthesis,structure,properties and time-dependent density functional theory calculations of cadmium complex.Asian J.Chem.2014,26,4865–4867.
(36)Chen,W.T.;Hu,R.H.;Luo,Z.G.;Chen,H.L.;Zhang,X.;Liu,J.[N-ethyl-4,4?-bipyridinium][Zn X4](X=Cl or Br)with N-ethyl-4,4?-bipyridinium generated in situ:syntheses,structures,fluorescence and TDDFT calculations.Chin.J.Struct.Chem.2014,33,1141–1146.
(37)Zheng,S.L.;Yang,J.H.;Yu,X.L.;Chen,X.M.;Wong,W.T.Syntheses,structures,photoluminescence and theoretical studies of d10 metal complexes of 2,2?-dihydroxy-[1,1?]binaphthalenyl-3,3?-dicarboxylate.Inorg.Chem.2004,43,830–838.
(2)Gaynor,D.;Starikova,Z.A.;Ostrovsky,S.;Haase,W.;Nolan,K.B.Synthesis and structure of a heptanuclear nickel(Ⅱ)complex uniquely exhibiting four distinct binding modes,two of which are novel,for a hydroxamate ligand.Chem.Commun.2002,506–507.
(3)Jankolovits,J.;Andolina,C.M.;Kampf,J.W.;Raymond,K.N.;Pecoraro,V.L.Assembly of near-infrared luminescent lanthanide host(host-guest)complexes with a metallacrown sandwich motif.Angew.Chem.Int.Ed.2011,50,9660–9664.
(4)Eltayeb,A.Z.;Nimir,H.I.;Brown,D.A.;Lan,Y.;Anson,C.E.;Powell,A.K.Magnetic and structural studies of novel tetranickel hydroxamates.Inorg.Chim.Acta 2010,363,899–904.
(5)Bai,Y.;Guo,D.;Duan,C.Y.;Dang,D.B.;Pang,K.L.;Meng,Q.J.A three-dimensional porous metal-organic framework[Fe4L6·(DMF)3·(H2O)10]constructed from neutral discrete Fe4L6 pyramids(H2L=1,3-benzodihydroxamix acid).Chem.Commun.2004,186–187.
(6)Gajewska,M.;Luzyanin,K.V.;Guedes da Silva,M.F.C.;Li,Q.S.;Cui,J.R.;Pombeiro,A.J.L.The first tin compounds bearing oximehydroxamate ligands.Eur.J.Inorg.Chem.2009,3765–3769.
(7)Alagha,A.B.M.;Gaynor,D.;Muller-Bunz,H.;Nolan,K.B.;Parthasarathi,L.fac-Tris(4-amino-benzohydroxamato)iron(ⅡI)ethanol solvate.Acta Crystallogr.,Sect.E 2010,66,m853–854.
(8)Lah,M.S.;Pecoraro,V.L.A functional analogy between crown ethers and metallacrowns.Inorg.Chem.1991,30,878–880.
(9)Zaleski,C.M.;Kampf,J.W.;Mallah,T.;Kirk,M.;Pecoraro,V.L.Assessing the slow magnetic relaxation behavior of LnⅡI4MnⅡI6 metallacrowns.Inorg.Chem.2007,46,1954–1956.I
(10)Gibney,B.R.;Kessissoglou,D.P.;Kampf,J.W.;Pecoraro,V.L.Copper(Ⅱ)12-metallacrown-4:synthesis,structure,ligand variability,and solution dynamics in the 12-MC-4 structural motif.Inorg.Chem.1994,33,4840–4849.
(11)Liu,S.C.;Zhu,H.Z.;Zubieta,J.Reactions of polyoxomolybdates with oximes.The crystal and molecular structures of[(C4H9)4N]2[Mo2O5C6H4(O)CHNO2]·CH2Cl2 and[(C4H9)4N]2[Mo2O5C6H5CH(O)C(NO)C6H52].Polyhedron 1989,8,2473–2480.
(12)Si,e T.K.;Chakraborty,S.;Mukherjee,A.K.;Drew,M.G.B.;Bhattacharyy,R.Novel supramolecular network in tri-and mono-nuclear oxovanadium(V)-salicyl-hydroximate:synthesis,structure and catalytic oxidation of hydrocarbons using H2O2 as terminal oxidant..Polyhedron 2008,27,2233–2242.
(13)2Henderson,W.;Evans,C.;Nicholson,B.K.;Fawcett,J.Coordination isomerism in salicylhydroxamate complexes of platinum(Ⅱ)and palladium(Ⅱ).Dalton Tran.2003,2691–2697.
(14)Cornman,6C.R.;Colpas,G.J.;Hoeschele,J.D.;Kampf,J.;Pecoraro,V.L.Implications for the spectroscopic assignment of vanadium biomolecules:structural and spectroscopic characterization of monooxovanadium(V)complexes containing catecholate and hydroximate based noninnocent ligands.J.Am.Chem.Soc.1992,114,9925–9933.
(15)Stemmier,A.J.;Kampf,J.W.;Kirk,M.L.;Pecoraro,V.L.A model for the inhibition of urease by hydroxamates.1J.Am.Chem.Soc.1995,117,6368–6369.
(16)Centore,R.;Tommaso,G.D.;Iuliano,M.;Tuzi,A.An organouranium coordination polymer containing infinite metal oxide chains.5Acta Cryst.2007,C63,m253–m255.
(17)Tekeste,T.;Vahrenkamp,H.Enzyme inhibitor modeling with Tp Zn complexes of functional hydroxamates and oximates.5Inorg.Chim.Acta 2007,360,1523–1528.
(18)Comiskey,J.;Farkas,E.;Krot-Lacina,K.A.;Pritchard,R.G.;Mc Auliffe,C.A.;Nolan,K.B.Synthesis,structures and speciation studies of ruthenium(ⅡI)hydroxamate/hydroximato complexes.Crystal and molecular structure of hydrated[Ru(H2edta)(2-methoxyphenylhydroxamate)],the first structurally characterised ruthenium(ⅡI)-hydroxamate complex.Dalton Tran.2003,4243–4249.
(19)Katsoulakou,E.;Bekiari,V.;Raptopoulou,C.P.;Terzis,A.;Manessi-Zoupa,E.;Powell,A.;Perlepes,S.P.Simultaneous coordination of a ketone by two cadmium(Ⅱ)ions and conversion to its gem-diolate(-1)form.Inorg.Chem.Commun.2011,14,1057–1060.
(20)Eom,G.H.;Park,H.M.;Hyun,M.Y.;Jang,S.P.;Kim,C.;Lee,J.H.;Lee,S.J.;Kim,S.J.;Kim,Y.Anion effects on the crystal structures of ZnⅡ complexes containing 2,2?-bipyridine:their photoluminescence and catalytic activities.Polyhedron 2011,30,1555–1564.
(21)Cui,P.;Chen,Z.;Gao,D.L.;Zhao,B.;Shi,W.;Cheng,P.Syntheses,structures,and photoluminescence of a series of three-dimensional CdⅡ frameworks with a flexible ligand,1,5-bis(5-tetrazolo)-3-oxapentane.Cryst.Growth&Des.2010,10,4370–4378.
(22)Wang,R.J.;Deng,L.J.;Fu,M.;Cheng,J.L.;Li,J.Y.Novel ZnⅡ complexes of 2-(2-hydroxyphenyl)benzothiazoles ligands:electroluminescence and application as host materials for phosphorescent organic light-emitting diodes.J.Mater.Chem.2012,22,23454–23460.
(23)Guha,A.;Chattopadhyay,T.;Paul,N.D.;Mukherjee,M.;Goswami,S.;Mondal,T.K.;Zangrando,E.;Das,D.Radical pathway in catecholase activity with zinc-based model complexes of compartmental ligands.Inorg.Chem.2012,51,8750–8759.
(24)Panja,A.;Matsuo,T.;Nagao,S.;Hirota,S.DNA cleavage by the photocontrolled cooperation of ZnⅡ centers in an azobenzene-linked dizinc complex.Inorg.Chem.2011,50,11437–11445.
(25)Feng,G.Q.;Natale,D.;Prabaharan,R.;Mareque-Rivas,J.C.;Williams,N.H.Efficient phosphodiester binding and cleavage by a ZnⅡ complex combining hydrogen-bonding interactions and double Lewis acid activation.Angew.Chem.,Int.Ed.2006,45,7056–7059.
(26)Scrimin,P.;Tecilla,P.;Tonellato,U.;Valle,G.;Veronese,A.A zinc(Ⅱ)-organized molecular receptor as a catalyst for the cleavage of amino acid esters.J.Chem.Soc.,Chem.Commun.1995,1163–1164.
(27)Jang,K.J.;Yeo,G.Y.;Cho,T.S.;Eom,G.H.;Kim,C.;Kim,S.K.Real-time detection of DNA cleavage induced by[M(2,2?-dipyridylamine)2(NO3)n]x+(M=Cd,Cu,Ni,Zn,n=1,2,x=0,1):effect of central metal ions.Biophy.Chem.2010,148,138–143.
(28)Meng,X.R.;Song,Y.L.;Hou,H.W.;Han,H.Y.;Xiao,B.;Fan,Y.T.;Zhu,Y.Hydrothermal syntheses,crystal structures,and characteristics of a series of Cd-btx coordination polymers(btx=1,4-bis(triazol-1-ylmethyl)benzene).Inorg.Chem.2004,43,3528–3536.
(29)Sheldrick,G.M.SHELXS-97,Program for Crystal Structure Solution.University of G?ttingen,Germany 1997.
(30)Sheldrick,G.M.SHELXL-97,Program for the Refinement of Crystal Structures from Diffraction Data.University of G?ttingen,Germany 1997.
(31)Brown,D.A.;Fitzpatrick,N.J.;Müller-Bunz,H.;Ryan,A.T.Di-,tri-,and tetranuclear zinc hydroxamate complexes as structural models for the inhibition of zinc hydrolases by hydroxamic acids.Inorg.Chem.2006,45,4497–4507.
(32)Alexiou,M.;Dendrinou-Samara,C.;Raptopoulou,C.P.;Terzis,A.;Kessissoglou,D.P.From monomer zinc-oxamato complexes to tetranuclear inverse 12-membered and octanuclear 12-membered metallacrowns.Inorg.Chem.2002,41,4732–4738.
(33)Chen,Y.M.;Gao,Q.;Liu,Y.L.;Cao,Y.Y.;Gao,D.D.;Liu,J.N.;Zhao,J.J.;Li,Y.H.;Liu,W.;Li,W.Synthesis,crystal structures and luminescent properties of CdⅡ and ZnⅡ complexes assembled by 4-aminophenylhydroxamic acid.RSC Adv.2014,4,147–153.
(34)Chen,W.T.;Yi,X.G.;Wen,J.W.Synthesis,crystal structure and property of(Cd Cl3)n·n H3O with a one-dimensional infinite chain-like structure.Asian J.Chem.2014,26,1253–1254.
(35)Chen,W.T.;Hu,R.H.;Yi,X.G.;Wang,Y.F.;Luo,Z.G.;Fu,H.R.;Liu,J.;Chen,H.L.Synthesis,structure,properties and time-dependent density functional theory calculations of cadmium complex.Asian J.Chem.2014,26,4865–4867.
(36)Chen,W.T.;Hu,R.H.;Luo,Z.G.;Chen,H.L.;Zhang,X.;Liu,J.[N-ethyl-4,4?-bipyridinium][Zn X4](X=Cl or Br)with N-ethyl-4,4?-bipyridinium generated in situ:syntheses,structures,fluorescence and TDDFT calculations.Chin.J.Struct.Chem.2014,33,1141–1146.
(37)Zheng,S.L.;Yang,J.H.;Yu,X.L.;Chen,X.M.;Wong,W.T.Syntheses,structures,photoluminescence and theoretical studies of d10 metal complexes of 2,2?-dihydroxy-[1,1?]binaphthalenyl-3,3?-dicarboxylate.Inorg.Chem.2004,43,830–838.