Simulation of Tensile Behaviors of Bamboo-like Carbon Nanotubes Based on Molecular Structural Mechanics Approach Combining with Finite Element Analysis
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摘要
A molecular structural mechanics approach combining with finite element analysis(MSM/FEA) was applied to study the microstructure and tensile behaviors of bamboo-like carbon nanotubes(BCNTs). The mathematical model of tensile behaviors of BCNTs was established based on molecular structural mechanics theory. The deformations of BCNTs, with different diameters and compartments set based on the experimental investigation on BCNT structures synthesized by chemical vapor depositon, under tensile load, were analyzed with ANSYS programmed. Results show that the BCNTs have good tensile properties, and those Young's modulus can reach 0.84 Tpa. Through the analysis, it can be found that the Young's modulus of BCNTs depends on the diameters and the length of compartment, which is in good agreement with our experimental tests for the tensile performances of individual BCNT.
A molecular structural mechanics approach combining with finite element analysis(MSM/FEA) was applied to study the microstructure and tensile behaviors of bamboo-like carbon nanotubes(BCNTs). The mathematical model of tensile behaviors of BCNTs was established based on molecular structural mechanics theory. The deformations of BCNTs, with different diameters and compartments set based on the experimental investigation on BCNT structures synthesized by chemical vapor depositon, under tensile load, were analyzed with ANSYS programmed. Results show that the BCNTs have good tensile properties, and those Young's modulus can reach 0.84 Tpa. Through the analysis, it can be found that the Young's modulus of BCNTs depends on the diameters and the length of compartment, which is in good agreement with our experimental tests for the tensile performances of individual BCNT.
A molecular structural mechanics approach combining with finite element analysis(MSM/FEA) was applied to study the microstructure and tensile behaviors of bamboo-like carbon nanotubes(BCNTs). The mathematical model of tensile behaviors of BCNTs was established based on molecular structural mechanics theory. The deformations of BCNTs, with different diameters and compartments set based on the experimental investigation on BCNT structures synthesized by chemical vapor depositon, under tensile load, were analyzed with ANSYS programmed. Results show that the BCNTs have good tensile properties, and those Young's modulus can reach 0.84 Tpa. Through the analysis, it can be found that the Young's modulus of BCNTs depends on the diameters and the length of compartment, which is in good agreement with our experimental tests for the tensile performances of individual BCNT.
引文
[1]Wang J, Yan S, Bao R, et al. Facile Fabrication of Multi-Walled Carbon Nanotubes and Its Enhancement on Thermally Conductive Adhesive Applied in Heat Dissipation Devices[J]. Mater. Design, 2013, 5:598-604
[2]Shulaker MM, Hills G, Patil N, et al. Carbon Nanotube Computer[J].Nature, 2013, 7 468:526
[3]Sun X, Xu Y, Ding P, et al. Superior Lithium Storage of the Carbon Modified Hybrid of Manganese Monoxide and Carbon Nanotubes[J].Mater. Lett., 2013, 24:186-189
[4]Yang M, Hong CK, Hong SH. DMMP Gas Sensing Behavior of ZnO-coated Single-Wall Carbon Nanotube Network Sensors[J]. Mater.Lett., 2012, 24:312-315
[5]Zare HR, Nasirizadeh N, Ajamain H, et al. Preparation, Electrochemical Behavior and Electrocatalytic Activity of Chlorogenic Acid MultiWall Carbon Nanotubes as a Hydroxylamine Sensor[J]. Materials Science&Engineering C., 2011, 5:975-982
[6]Qiang, Song, Kezhi, et al. Increasing the Tensile Property of Unidirectional Carbon/Carbon Composites by Grafting Carbon Nanotubes onto Carbon Fibers by Electrophoretic Deposition[J]. J. Mater. Sci. Technol., 2013, 8:711-714
[7]Liu ZY, Xiao BL, Wang WG, et al. Tensile Strength and Electrical Conductivity of Carbon Nanotube Reinforced Aluminum Matrix Composites Fabricated by Powder Metallurgy Combined with Friction Stir Processing[J]. J. Mater. Sci. Technol., 2014, 7:649-655
[8]Xu Y, Zhang D, Cai J, et al. Effects of Multi-Walled Carbon Nanotubes on the Electromagnetic Absorbing Characteristics of Composites Filled with Carbonyl Iron Particles[J]. J. Mater. Sci. Technol., 2012, 1:34-40
[9]Wang J, Xie H, Xin Z. Preparation and Thermal Properties of Grafted CNTs Composites[J]. J. Mater. Sci. Technol., 2011, 3:233-238
[10]Hone J, Batlogg B, Benes Z, et al. Quantized Phonon Spectrum of Single-Wall Carbon Nanotubes[J]. Science, 2000, 5 485:1 730-1 733
[11]Wang X, Li Q, Jing X, et al. Fabrication of Ultralong and Electrically Uniform Single-Walled Carbon Nanotubes on Clean Substrates.[J].Nano Lett., 2009, 9:3 137
[12]Maciej Olek, John Ostrander, Stefan Jurga et al. Layer-by-Layer Assembled Composites from Multiwall Carbon Nanotubes with Different Morphologies[J]. Nano Lett., 2004, 10:1 889-1 895
[13]Wu J, El Hamaoui B, Li J, et al. Solid-State Synthesis of&Ldquo;Bamboo-Like&Rdquo; and Straight Carbon Nanotubes by Thermolysis of Hexa-Peri-Hexabenzocoronene&Ndash;Cobalt Complexes[J]. Small, 2005:210-212
[14]Feng JM, Li YL, Hou F, et al. Controlled Growth of High Quality Bamboo Carbon Nanotube Arrays by the Double Injection Chemical Vapor Deposition Process[J]. Materials Science&Engineering A,2008, 1:238-243
[15]Sahoo RK, Daramalla V, Jacob C. Multiwall and Bamboo-Like Carbon Nanotube Growth by CVD Using a Semimetal as a Catalyst[J]. Materials Science&Engineering B, 2012, 1:79-85
[16]Lin CR, Su CH, Hung CH, et al. Characterization of Bamboo-Like CNTs Prepared Using Sol-Gel Catalyst[J]. Diamond&Related Materials, 2005, 3:794-797
[17]Jin C, Zou XP, Fei LI, et al. Synthesis of Bamboo-Like Carbon Nanotubes by Ethanol Catalytic Combustion Technique[J]. Nonferr Metal Soc., 2006, s1:s435-437
[18]Shanmugam S, Gedanken A. Electrochemical Properties of Bamboo-Shaped Multiwalled Carbon Nanotubes Generated by Solid State Pyrolysis[J]. Electrochem Commun., 2006, 7:1 099-1 105
[19]Erko??. Structural and Electronic Properties of Bamboo-Like Carbon Nanostructure[J]. Physica E:Low-dimensional Systems and Nanostructures, 2006, 1:62-66
[20]Lee WJ, Ramasamy E, Dong YL, et al. Efficient Dye-Sensitized Solar Cells with Catalytic Multiwall Carbon Nanotube Counter Electrodes[J]. Acs Appl. Mater. Interfaces, 2009, 6:1 145-1 149
[21]Li C, Chou TW. A Structural Mechanics Approach for the Analysis of Carbon Nanotubes[J]. International Journal of Solids&Structures,2003, 10:2 487-2 499
[22]Cornell WD, Cieplak P, Bayly CI et al. A Second Generation Force Field for the Simulation of Proteins, Nucleic Acids, and Organic Molecules[J]. J. Am. Chem. Soc., 1995, 117:5 179-5 197
[23]Jang JW, Lee CE, Lee TJ, et al. Lateral Force Microscopy of Bamboo-Shaped Multiwalled Carbon Nanotubes[J]. Curr. Appl. Phys.,2006, 2:141-144
[24]Glukhova OE, Kolesnikova AS, Torgashov GV, et al. Elastic and Electrostatic Properties of Bamboo-Shaped Carbon Nanotubes[J]. Phys.Solid State, 2010, 6:1 323-1 328
[25]Wang C, Li Y, Tong L, et al. The Role of Grafting Force and Surface Wettability in Interfacial Enhancement of Carbon Nanotube/Carbon Fiber Hierarchical Composites[J]. Carbon, 2014, 239-246
[26]Yu MF, Lourie O, Dyer MJ, et al. Strength and Breaking Mechanism of Multiwalled Carbon Nanotubes Under Tensile Load[J]. Science,2000, 5453:637-640
[2]Shulaker MM, Hills G, Patil N, et al. Carbon Nanotube Computer[J].Nature, 2013, 7 468:526
[3]Sun X, Xu Y, Ding P, et al. Superior Lithium Storage of the Carbon Modified Hybrid of Manganese Monoxide and Carbon Nanotubes[J].Mater. Lett., 2013, 24:186-189
[4]Yang M, Hong CK, Hong SH. DMMP Gas Sensing Behavior of ZnO-coated Single-Wall Carbon Nanotube Network Sensors[J]. Mater.Lett., 2012, 24:312-315
[5]Zare HR, Nasirizadeh N, Ajamain H, et al. Preparation, Electrochemical Behavior and Electrocatalytic Activity of Chlorogenic Acid MultiWall Carbon Nanotubes as a Hydroxylamine Sensor[J]. Materials Science&Engineering C., 2011, 5:975-982
[6]Qiang, Song, Kezhi, et al. Increasing the Tensile Property of Unidirectional Carbon/Carbon Composites by Grafting Carbon Nanotubes onto Carbon Fibers by Electrophoretic Deposition[J]. J. Mater. Sci. Technol., 2013, 8:711-714
[7]Liu ZY, Xiao BL, Wang WG, et al. Tensile Strength and Electrical Conductivity of Carbon Nanotube Reinforced Aluminum Matrix Composites Fabricated by Powder Metallurgy Combined with Friction Stir Processing[J]. J. Mater. Sci. Technol., 2014, 7:649-655
[8]Xu Y, Zhang D, Cai J, et al. Effects of Multi-Walled Carbon Nanotubes on the Electromagnetic Absorbing Characteristics of Composites Filled with Carbonyl Iron Particles[J]. J. Mater. Sci. Technol., 2012, 1:34-40
[9]Wang J, Xie H, Xin Z. Preparation and Thermal Properties of Grafted CNTs Composites[J]. J. Mater. Sci. Technol., 2011, 3:233-238
[10]Hone J, Batlogg B, Benes Z, et al. Quantized Phonon Spectrum of Single-Wall Carbon Nanotubes[J]. Science, 2000, 5 485:1 730-1 733
[11]Wang X, Li Q, Jing X, et al. Fabrication of Ultralong and Electrically Uniform Single-Walled Carbon Nanotubes on Clean Substrates.[J].Nano Lett., 2009, 9:3 137
[12]Maciej Olek, John Ostrander, Stefan Jurga et al. Layer-by-Layer Assembled Composites from Multiwall Carbon Nanotubes with Different Morphologies[J]. Nano Lett., 2004, 10:1 889-1 895
[13]Wu J, El Hamaoui B, Li J, et al. Solid-State Synthesis of&Ldquo;Bamboo-Like&Rdquo; and Straight Carbon Nanotubes by Thermolysis of Hexa-Peri-Hexabenzocoronene&Ndash;Cobalt Complexes[J]. Small, 2005:210-212
[14]Feng JM, Li YL, Hou F, et al. Controlled Growth of High Quality Bamboo Carbon Nanotube Arrays by the Double Injection Chemical Vapor Deposition Process[J]. Materials Science&Engineering A,2008, 1:238-243
[15]Sahoo RK, Daramalla V, Jacob C. Multiwall and Bamboo-Like Carbon Nanotube Growth by CVD Using a Semimetal as a Catalyst[J]. Materials Science&Engineering B, 2012, 1:79-85
[16]Lin CR, Su CH, Hung CH, et al. Characterization of Bamboo-Like CNTs Prepared Using Sol-Gel Catalyst[J]. Diamond&Related Materials, 2005, 3:794-797
[17]Jin C, Zou XP, Fei LI, et al. Synthesis of Bamboo-Like Carbon Nanotubes by Ethanol Catalytic Combustion Technique[J]. Nonferr Metal Soc., 2006, s1:s435-437
[18]Shanmugam S, Gedanken A. Electrochemical Properties of Bamboo-Shaped Multiwalled Carbon Nanotubes Generated by Solid State Pyrolysis[J]. Electrochem Commun., 2006, 7:1 099-1 105
[19]Erko??. Structural and Electronic Properties of Bamboo-Like Carbon Nanostructure[J]. Physica E:Low-dimensional Systems and Nanostructures, 2006, 1:62-66
[20]Lee WJ, Ramasamy E, Dong YL, et al. Efficient Dye-Sensitized Solar Cells with Catalytic Multiwall Carbon Nanotube Counter Electrodes[J]. Acs Appl. Mater. Interfaces, 2009, 6:1 145-1 149
[21]Li C, Chou TW. A Structural Mechanics Approach for the Analysis of Carbon Nanotubes[J]. International Journal of Solids&Structures,2003, 10:2 487-2 499
[22]Cornell WD, Cieplak P, Bayly CI et al. A Second Generation Force Field for the Simulation of Proteins, Nucleic Acids, and Organic Molecules[J]. J. Am. Chem. Soc., 1995, 117:5 179-5 197
[23]Jang JW, Lee CE, Lee TJ, et al. Lateral Force Microscopy of Bamboo-Shaped Multiwalled Carbon Nanotubes[J]. Curr. Appl. Phys.,2006, 2:141-144
[24]Glukhova OE, Kolesnikova AS, Torgashov GV, et al. Elastic and Electrostatic Properties of Bamboo-Shaped Carbon Nanotubes[J]. Phys.Solid State, 2010, 6:1 323-1 328
[25]Wang C, Li Y, Tong L, et al. The Role of Grafting Force and Surface Wettability in Interfacial Enhancement of Carbon Nanotube/Carbon Fiber Hierarchical Composites[J]. Carbon, 2014, 239-246
[26]Yu MF, Lourie O, Dyer MJ, et al. Strength and Breaking Mechanism of Multiwalled Carbon Nanotubes Under Tensile Load[J]. Science,2000, 5453:637-640