Electrosynthesis of hierarchical NiLa-layered double hydroxide electrode for efficient oxygen evolution reaction
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  • 英文篇名:Electrosynthesis of hierarchical NiLa-layered double hydroxide electrode for efficient oxygen evolution reaction
  • 作者:Shan ; Jiang ; Yunke ; Liu ; Wenfu ; Xie ; Mingfei ; Shao
  • 英文作者:Shan Jiang;Yunke Liu;Wenfu Xie;Mingfei Shao;State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology;
  • 英文关键词:Layered double hydroxides;;Oxygen evolution reaction;;Lanthanides;;Electrosynthesis
  • 中文刊名:TRQZ
  • 英文刊名:能源化学(英文版)
  • 机构:State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology;
  • 出版日期:2019-06-15
  • 出版单位:Journal of Energy Chemistry
  • 年:2019
  • 期:v.33
  • 基金:supported by the National Natural Science Foundation of China (21601011 and 21521005);; the National Key Research and Development Programme (2017YFA0206804);; the Fundamental Research Funds for the Central Universities (buctrc201506 and buctylkxj01)
  • 语种:英文;
  • 页:TRQZ201906014
  • 页数:5
  • CN:06
  • ISSN:10-1287/O6
  • 分类号:133-137
摘要
Oxygen evolution reaction(OER) is a key process for electrochemical water splitting due to its intrinsic large overpotential. Recently, layered double hydroxides(LDHs), especially Ni Fe-LDH, have been regarded as highly performed electrocatalysts for OER in alkaline condition. Here we first present a new class of Ni La-LDH electrocatalyst synthesized by an electrochemical process for efficient water splitting. The as-prepared NiL a-LDH nanosheet arrays(NSAs) give remarkable electrochemical activity and durability under alkaline environments, with a low overpotential of 209 mV for OER to deliver a current density of 10 mA cm~(-2), surpassing most of previous reported LDHs eletrocatalysts. The presence of NiLa-LDH in this work extends the studies about LDHs-based electrocatalysts, which will benefit the development of electrochemical energy storage and conversion systems.
        Oxygen evolution reaction(OER) is a key process for electrochemical water splitting due to its intrinsic large overpotential. Recently, layered double hydroxides(LDHs), especially Ni Fe-LDH, have been regarded as highly performed electrocatalysts for OER in alkaline condition. Here we first present a new class of Ni La-LDH electrocatalyst synthesized by an electrochemical process for efficient water splitting. The as-prepared NiL a-LDH nanosheet arrays(NSAs) give remarkable electrochemical activity and durability under alkaline environments, with a low overpotential of 209 mV for OER to deliver a current density of 10 mA cm~(-2), surpassing most of previous reported LDHs eletrocatalysts. The presence of NiLa-LDH in this work extends the studies about LDHs-based electrocatalysts, which will benefit the development of electrochemical energy storage and conversion systems.
引文
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