Preparation of Ce~(3+)doped Bi_2O_3 hollow needle-shape with enhanced visible-light photocatalytic activity
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摘要
Ce~(3+) doped Bi_2O_3 hollow needle-shape with enhanced visible-light photocatalytic activity was successfully prepared via the method of chemical precipitation using Bi(NO_3)·5H_2O and Ce(NO_3)_3·6H_2O as the source of bismuth and cerium, HNO_3 as solvent and NaOH as precipitants, respectively and after calcination at 500 ℃ for 2 h. The morphology and elemental composition,crystal form,purity and specific surface area of the hollow needle Bi_2O_3 were characterized by SEM-EDS, XRD, BET and FT-IR. The photocatalytic properties of the as-obtained samples were measured by UV-vis diffuse reflection spectroscopy and photochemical reactor. As a result, the obtained Bi_2O_3 hollow needle-shape doped with 5 wt% Ce shows good morphology, α-phase, stronger absorbent for visible light and good photocatalytic property. Under the simulated visible light of 300 W, the photodegradation rate of tetracycline over HNBCe can reach to 89.1%,which is higher than that of commercial Bi_2O_3 nanoparticles and Bi_2O_3 hollow needle-shape.
Ce~(3+) doped Bi_2O_3 hollow needle-shape with enhanced visible-light photocatalytic activity was successfully prepared via the method of chemical precipitation using Bi(NO_3)·5H_2O and Ce(NO_3)_3·6H_2O as the source of bismuth and cerium, HNO_3 as solvent and NaOH as precipitants, respectively and after calcination at 500 ℃ for 2 h. The morphology and elemental composition,crystal form,purity and specific surface area of the hollow needle Bi_2O_3 were characterized by SEM-EDS, XRD, BET and FT-IR. The photocatalytic properties of the as-obtained samples were measured by UV-vis diffuse reflection spectroscopy and photochemical reactor. As a result, the obtained Bi_2O_3 hollow needle-shape doped with 5 wt% Ce shows good morphology, α-phase, stronger absorbent for visible light and good photocatalytic property. Under the simulated visible light of 300 W, the photodegradation rate of tetracycline over HNBCe can reach to 89.1%,which is higher than that of commercial Bi_2O_3 nanoparticles and Bi_2O_3 hollow needle-shape.
Ce~(3+) doped Bi_2O_3 hollow needle-shape with enhanced visible-light photocatalytic activity was successfully prepared via the method of chemical precipitation using Bi(NO_3)·5H_2O and Ce(NO_3)_3·6H_2O as the source of bismuth and cerium, HNO_3 as solvent and NaOH as precipitants, respectively and after calcination at 500 ℃ for 2 h. The morphology and elemental composition,crystal form,purity and specific surface area of the hollow needle Bi_2O_3 were characterized by SEM-EDS, XRD, BET and FT-IR. The photocatalytic properties of the as-obtained samples were measured by UV-vis diffuse reflection spectroscopy and photochemical reactor. As a result, the obtained Bi_2O_3 hollow needle-shape doped with 5 wt% Ce shows good morphology, α-phase, stronger absorbent for visible light and good photocatalytic property. Under the simulated visible light of 300 W, the photodegradation rate of tetracycline over HNBCe can reach to 89.1%,which is higher than that of commercial Bi_2O_3 nanoparticles and Bi_2O_3 hollow needle-shape.
引文
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10.Brezesinski K, Ostermann R, Hartmann P, Perlich J, Brezesinski T.Exceptional photocatalytic activity of ordered mesoporousβ-Bi_2O_3 thin Films and electrospun nanofiber mats.Chem Mater.2010;22(22):3079.
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13.Huang YC, Fan WJ, Bei L, Li HB, Zhao FY, Liu ZL, et al.Visible light Bi2S3/Bi2O3/Bi_2O_2CO_3 photocatalyst for effective degradation of organic pollution.Appl Catal B.2016;185(15):68.
14.Hanggara S.Template-free, simple fabrication of C/N-doped Bi_2O_3 nanospheres with appreciable photocatalytic activity under visible light.Superlattice Microst.2017;109:3079.
15.Zhang L, Hashimoto Y, Taishi T, Nakamura I, Ni QQ, Fabrication of flowershaped Bi_2O_3 superstructure by a facile template-free process.Appl Sci.2011;257(15):6577.
16.Sood S, Umar A, Mehta SK, Kansal SK.α-Bi_2O_3 nanorods:an efficient sunlight active photocatalyst for degradation of Rhodamine B and 2,4,6-trichlorophenol.Ceram Int.2015;41:3355.
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19.Li CR, Chen R, Zhang XQ, Shu SX, Xiong J, Zheng YY, et al.Electro spinning of CeO_2-ZnO composite nanofibers and their photocatalytic property.Mater Lett.2011;65(9):1327.
20.Huang YF, Wei YL, Wang J, Luo D, Fan LQ, Wu JH.Controllable fabrication of Bi_2O_3/TiO_2 heterojunction with excellent visible-light responsive photocatalytic performance.Appl Sci.2017;423(30):119.
21.Liu H, Wang MY, Wang Y, Liang YG, Cao WR, Su Y.Ionic liquid-templated synthesis of mesoporous CeO_2-TiO_2 nanoparticles and their enhanced photocatalytic activities under UV or visible light.J Photochem Photobiol A.2011;223(2):157.
22.Jiang LB, Yuan XZ, Zeng GM, Liang J, Chen XH, Yu HB, et al.In-situ synthesis of direct solid-state dual Z-scheme WO_3/g-C_3N_4/Bi_2O_3, photocatalyst for the degradation of refractory pollutant.Appl Catal B Environ.2018;227(5):376.
23.Monte RD, Fornasiero P, Graziani M, Kaspar J.Oxygen storage and catalytic NO removal promoted by CeO_2-containing mixed oxides.J Alloys Compd.1998;275-277:877.
24.Laoued NJ, Elaziouti AK, Benhadria N, Bekka A.CeO_2, nanoscale particles:synthesis, characterization and photocatalytic activity under UVA light irradiation.J Rare Earths.2018;36(6):575.
25.Jun K, Shinichi H, Shindo T, Keiji Y, Toshiaki M, Yamaji K, et al.Self-modification of Ni metal surfaces with CeO_2 to suppress carbon deposition at solid oxide fuel cell anodes.Fuel Cells.2017;17(3):402.
26.Zhang WW, Chen DH.Preparation and performance of CeO_2 hollow spheres and nanoparticles.J Rare Earths.2016;34(3):295.
27.Gao SH, Zhang WW, Zhou HP, Chen DH.Magnetic composite Fe_3O_4/CeO_2 for adsorption of azo dye.J Rare Earths.2018;36(9):986.
28.Chaudhary YS, Panigrahi S, Nayak S, Satpati B, Bhattacharjee S, Kulkarni N.Facile synthesis of ultra-small monodisperse ceria nanocrystals at room temperature and their catalytic activity under visible light.J Mater Chem.2010;20(2):2381.
29.Cao TP, Li YJ, Wang CH, Wei LM, Shao CL, Liu YC.Fabrication, structure, and enhanced photocatalytic properties of hierarchical CeO_2 nanostructures/TiO_2nanofibers heterostructures.Mater Res Bull.2010;45(10):1406.
30.Hu SC, Zhou F, Wang LZ, Zhang JL.Preparation of Cu_2O/CeO_2 heterojunction photocatalyst for the degradation of Acid Orange 7 under visible light irradiation.Catal Commun.2011;12(9):794.
31.Tian J, Sang YH, Zhao ZH, Zhou WJ, Wang DZ, Kang XL, et al.Enhanced photocatalytic performances of CeO_2/TiO_2 nanobelt heterostructures.Small.2013;9(22):3864.
32.Li LZ, Yan B.CeO_2-Bi_2O_3 nanocomposite:two step synthesis, micro structure and photocatalytic activity.J Non-Cryst Solids.2009;355:776.
33.Liew CW, Ramesh S, Ramesh K, Arof AK.Synthesis, characterization and photocatalytic activity ofα-Bi_2O_3 nanoparticles.J Taibah Univer.2015;9(4):508.
34.Umar K, Haque MM, Muneer M, Harada T, Mo Matsumura M.Mn and La doped TiO_2:synthesis, characterization and photocatalytic activity for the decolourization of three different chromophoric dyes.J Alloys Compd.2013;578:431.
35.Raza W, Haque MM, Muneer M, Harada T, Matsumura M.Synthesis, characterization and photocatalytic performance of visible light induced bismuth oxide nanoparticle.J Alloys Compd.2015;648(5):641.
36.Ai ZH, Huang Y, Lee SC, Zhang LZ.Monoclinicα-Bi_2O_3 photocatalyst for efficient removal of gaseous NO and HCHO under visible light irradiation.J Alloys Compd.2011;509(5):2044.
37.Yan W, Wen YY, Ding HM, Shan YK, Improved structural stability of titaniumdopedβ-Bi_2O_3 during visible-light-activated photocatalytic processes.J Mater Sci.2010;45(5):1385.
38.Fu HB, Pan CS, Yao WQ, Zhu YF.Visible-light-induced degradation of rhodamine B by nanosized Bi_2WO_6.J Phys Chem B.2005;109(47):22432.
39.Li BX, Shao LZ, Zhang BS, Wang RS, Zhu M, Gu XW.Understanding sizedependent properties of BiOCl nanosheets and exploring more catalysis.J Colloid Interface Sci.2017;505(1):653.
40.Wang QH, Yu SY, Tan ZB, Zhang RF, Li Z, Gao XC, et al.Synthesis of monodisperse Bi_2O_3-modified CeO_2 nanospheres with excellent photocatalytic activity under visible light.CrystEngComm.2014;17(3):671.
41.Westerhoff P, Yoon Y, Snyder S, Wert E.Fate of endocrine-disruptor, pharmaceutical, and personal care product chemicals during simulated drinking water treatment processes.Environ Sci Technol.2005;39(17):6649.
42.Orge CA, Orfao JJM, Pereira MFR, Farias AMDD, Neto RCR, Fraga MA.Ozonation of model organic compounds catalysed by nanostructured cerium oxides.Appl Catal B Environ.2011;103(1):190.
43.Zhong LS, Hu JS, Cao AM, Liu Q, Song WG, Wan LJ.3D flowerlike ceria micro/nanocomposite structure and its application for water treatment and CO removal.Chem Mater.2007;19(7):1648.
2.Owen SF, Giltrow E, Huggett DB, Hutchinson TH, Saye J, Winter MJ, et al.Comparative physiology, pharmacology and toxicology of beta-blockers:mammals versus fish.Aquat Toxicol.2007;82(3):145.
3.Lang XM, Wei DZ, Cui ZQ, Gan LH.Optimization of pharmaceutical wastewater treatment with combined anaerobic hydrolysis-UNITANK process.J Northeast Univ(Nat Sci).2005;26(9):904.
4.Oktem YA, Ince O, Sallis P, Donnelly T, Ince BK.Anaerobic treatment of a chemical synthesis-based pharmaceutical wastewater in a hybrid upflow anaerobic sludge blanket reactor.Bio Technol.2008;99(5):1089.
5.Enick OV, Moore MM.Assessing the assessments:pharmaceuticals in the environment.Environ Impact Assess Rev.2007;27(8):707.
6.Czech B, Buda W.Photocatalytic treatment of pharmaceutical wastewater using new multiwall-carbon nanotubes/TiO_2/SiO_2 nanocomposites.Environ Res.2015;137:176.
7.Vinoth R, Neppolian B.Visible light photocatalysts Bi_2O_3 with graphene oxide support for the effective degradation of organic compound.Mater Focus.2014;3(6):485.
8.Xekoukoulotakis NP, Drosou C, Brebou C, Chatzisymeon E, Hapeshi E, FattaKassinos D, et al.Kinetics of UV-A/TiO_2 photocatalytic degradation and mineralization of the antibiotic sulfamethoxazole in aqueous matrices.Catal Today.2011;161(1):163.
9.Harriman A, Thomas JM, Zhou W, Jefferson DA.A new family of photocatalysts based on Bi_2O_3.J Solid State Chem.1988;72(1):126.
10.Brezesinski K, Ostermann R, Hartmann P, Perlich J, Brezesinski T.Exceptional photocatalytic activity of ordered mesoporousβ-Bi_2O_3 thin Films and electrospun nanofiber mats.Chem Mater.2010;22(22):3079.
11.Chen R, Shen ZR, Wang H, Zhou HJ, Liu YP, Ding DT, et al.Fabrication of meshlike bismuth oxide single crystalline nanoflakes and their visible light photocatalytic activity.J Alloys Compd.2011;509(5):2588.
12.Shi YY, Luo LJ, Zhang YF, Chen Y, Wang SX, Li LJ, et al.Synthesis and characterization of porous platelet-shapedα-Bi_2O_3 with enhanced photocatalytic activity for 17α-ethynylestradiol.Ceram Int.2017;53(2):1049.
13.Huang YC, Fan WJ, Bei L, Li HB, Zhao FY, Liu ZL, et al.Visible light Bi2S3/Bi2O3/Bi_2O_2CO_3 photocatalyst for effective degradation of organic pollution.Appl Catal B.2016;185(15):68.
14.Hanggara S.Template-free, simple fabrication of C/N-doped Bi_2O_3 nanospheres with appreciable photocatalytic activity under visible light.Superlattice Microst.2017;109:3079.
15.Zhang L, Hashimoto Y, Taishi T, Nakamura I, Ni QQ, Fabrication of flowershaped Bi_2O_3 superstructure by a facile template-free process.Appl Sci.2011;257(15):6577.
16.Sood S, Umar A, Mehta SK, Kansal SK.α-Bi_2O_3 nanorods:an efficient sunlight active photocatalyst for degradation of Rhodamine B and 2,4,6-trichlorophenol.Ceram Int.2015;41:3355.
17.Qiu YF, Yang ML, Fan HB, Zuo YZ, Shao YU, Xu YJ, et al.Nanowires ofα-andβ-Bi_2O_3:phase-selective synthesis and application in photocatalysis.CrystEngComm.2011:13(6):1843.
18.Stengl V, Henych J, Slusna M, Tolasz J, Zetkova K.ZnO/Bi_2O_3 nanowire composites as a new family of photocatalysts.Powder Technol.2015;270(A):83.
19.Li CR, Chen R, Zhang XQ, Shu SX, Xiong J, Zheng YY, et al.Electro spinning of CeO_2-ZnO composite nanofibers and their photocatalytic property.Mater Lett.2011;65(9):1327.
20.Huang YF, Wei YL, Wang J, Luo D, Fan LQ, Wu JH.Controllable fabrication of Bi_2O_3/TiO_2 heterojunction with excellent visible-light responsive photocatalytic performance.Appl Sci.2017;423(30):119.
21.Liu H, Wang MY, Wang Y, Liang YG, Cao WR, Su Y.Ionic liquid-templated synthesis of mesoporous CeO_2-TiO_2 nanoparticles and their enhanced photocatalytic activities under UV or visible light.J Photochem Photobiol A.2011;223(2):157.
22.Jiang LB, Yuan XZ, Zeng GM, Liang J, Chen XH, Yu HB, et al.In-situ synthesis of direct solid-state dual Z-scheme WO_3/g-C_3N_4/Bi_2O_3, photocatalyst for the degradation of refractory pollutant.Appl Catal B Environ.2018;227(5):376.
23.Monte RD, Fornasiero P, Graziani M, Kaspar J.Oxygen storage and catalytic NO removal promoted by CeO_2-containing mixed oxides.J Alloys Compd.1998;275-277:877.
24.Laoued NJ, Elaziouti AK, Benhadria N, Bekka A.CeO_2, nanoscale particles:synthesis, characterization and photocatalytic activity under UVA light irradiation.J Rare Earths.2018;36(6):575.
25.Jun K, Shinichi H, Shindo T, Keiji Y, Toshiaki M, Yamaji K, et al.Self-modification of Ni metal surfaces with CeO_2 to suppress carbon deposition at solid oxide fuel cell anodes.Fuel Cells.2017;17(3):402.
26.Zhang WW, Chen DH.Preparation and performance of CeO_2 hollow spheres and nanoparticles.J Rare Earths.2016;34(3):295.
27.Gao SH, Zhang WW, Zhou HP, Chen DH.Magnetic composite Fe_3O_4/CeO_2 for adsorption of azo dye.J Rare Earths.2018;36(9):986.
28.Chaudhary YS, Panigrahi S, Nayak S, Satpati B, Bhattacharjee S, Kulkarni N.Facile synthesis of ultra-small monodisperse ceria nanocrystals at room temperature and their catalytic activity under visible light.J Mater Chem.2010;20(2):2381.
29.Cao TP, Li YJ, Wang CH, Wei LM, Shao CL, Liu YC.Fabrication, structure, and enhanced photocatalytic properties of hierarchical CeO_2 nanostructures/TiO_2nanofibers heterostructures.Mater Res Bull.2010;45(10):1406.
30.Hu SC, Zhou F, Wang LZ, Zhang JL.Preparation of Cu_2O/CeO_2 heterojunction photocatalyst for the degradation of Acid Orange 7 under visible light irradiation.Catal Commun.2011;12(9):794.
31.Tian J, Sang YH, Zhao ZH, Zhou WJ, Wang DZ, Kang XL, et al.Enhanced photocatalytic performances of CeO_2/TiO_2 nanobelt heterostructures.Small.2013;9(22):3864.
32.Li LZ, Yan B.CeO_2-Bi_2O_3 nanocomposite:two step synthesis, micro structure and photocatalytic activity.J Non-Cryst Solids.2009;355:776.
33.Liew CW, Ramesh S, Ramesh K, Arof AK.Synthesis, characterization and photocatalytic activity ofα-Bi_2O_3 nanoparticles.J Taibah Univer.2015;9(4):508.
34.Umar K, Haque MM, Muneer M, Harada T, Mo Matsumura M.Mn and La doped TiO_2:synthesis, characterization and photocatalytic activity for the decolourization of three different chromophoric dyes.J Alloys Compd.2013;578:431.
35.Raza W, Haque MM, Muneer M, Harada T, Matsumura M.Synthesis, characterization and photocatalytic performance of visible light induced bismuth oxide nanoparticle.J Alloys Compd.2015;648(5):641.
36.Ai ZH, Huang Y, Lee SC, Zhang LZ.Monoclinicα-Bi_2O_3 photocatalyst for efficient removal of gaseous NO and HCHO under visible light irradiation.J Alloys Compd.2011;509(5):2044.
37.Yan W, Wen YY, Ding HM, Shan YK, Improved structural stability of titaniumdopedβ-Bi_2O_3 during visible-light-activated photocatalytic processes.J Mater Sci.2010;45(5):1385.
38.Fu HB, Pan CS, Yao WQ, Zhu YF.Visible-light-induced degradation of rhodamine B by nanosized Bi_2WO_6.J Phys Chem B.2005;109(47):22432.
39.Li BX, Shao LZ, Zhang BS, Wang RS, Zhu M, Gu XW.Understanding sizedependent properties of BiOCl nanosheets and exploring more catalysis.J Colloid Interface Sci.2017;505(1):653.
40.Wang QH, Yu SY, Tan ZB, Zhang RF, Li Z, Gao XC, et al.Synthesis of monodisperse Bi_2O_3-modified CeO_2 nanospheres with excellent photocatalytic activity under visible light.CrystEngComm.2014;17(3):671.
41.Westerhoff P, Yoon Y, Snyder S, Wert E.Fate of endocrine-disruptor, pharmaceutical, and personal care product chemicals during simulated drinking water treatment processes.Environ Sci Technol.2005;39(17):6649.
42.Orge CA, Orfao JJM, Pereira MFR, Farias AMDD, Neto RCR, Fraga MA.Ozonation of model organic compounds catalysed by nanostructured cerium oxides.Appl Catal B Environ.2011;103(1):190.
43.Zhong LS, Hu JS, Cao AM, Liu Q, Song WG, Wan LJ.3D flowerlike ceria micro/nanocomposite structure and its application for water treatment and CO removal.Chem Mater.2007;19(7):1648.