微量分析法用于电感耦合等离子发射光谱法测定含硼键合剂中硼含量
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摘要
将微量分析方法与电感耦合等离子发射光谱法结合用于测定含硼键合剂中的硼含量。通过改良取样及称量方法,简化样品前处理过程,建立了适合三氟化硼醇胺络合物类键合剂中硼含量的测定方法。方法的检出限为0. 0012 mg/L,定量限为0. 0039 mg/L (相当于硼含量0. 02%),相对标准偏差(RSD)为2. 8%,回收率为99. 3%。
A new method combining microanalysis with inductively coupled plasma-optical emission spectrometer to determine the content of boron in organic boron bonding agent was developed.Weighing sample was optimized and the pre-treatment method was evaluated. The limit of detection was0. 0012 mg/L. The limit of quantitation was 0. 0039 mg/L( 0. 02% of boron in sample),the RSD was2. 8%,and the recovery was 99. 3%.
A new method combining microanalysis with inductively coupled plasma-optical emission spectrometer to determine the content of boron in organic boron bonding agent was developed.Weighing sample was optimized and the pre-treatment method was evaluated. The limit of detection was0. 0012 mg/L. The limit of quantitation was 0. 0039 mg/L( 0. 02% of boron in sample),the RSD was2. 8%,and the recovery was 99. 3%.
引文
[1] Wang D J. Sichuan Ordnance J,2009(4):33王敦举.四川兵工学报,2009(4):33
[2] Liu X. Chin. J. Energ. Mater.,2000,8(3):135刘学.含能材料,2000,8(3):135
[3] An H M,Li J J. Chin. J. Expl. Propell.,1998(2):47安红梅,李建军.火炸药学报,1998(2):47
[4] Pang W Q,Zhang J Q,Liu H,Guo J Y,Zhu F. Chem. Propell. Polym. Mater.,2005(6):10庞维强,张教强,刘何,国际英,朱峰.化学推进剂与高分子材料,2005(6):10
[5] Yang H X,Li B. Chem. Bull.,2005(6):479杨红霞,李冰.化学通报,2005(6)479
[6] Chi W T. Occupation and Health,2010,26(3):335池卫廷.职业与健康,2010,26(3):335
[7] Luo M B,Liu S J,Li J Q,Xing X F. J. Analyt. Sci.,18(3):226罗明标,刘淑娟,李建强,邢新芳.分析科学学报,2002,18(3):226
[8] Li L,Cao B S,Cao H,Zhou A F,Yang Y L,Chen Y H. Chin J Health Lab Tech,2006,16(11):1337林立,曹宝森,曹红,周谙非,杨彦丽,陈玉红.中国卫生检验杂志,2006,16(11):1337
[9] Chi H T,Xu C,Le S F,Wang W,Zhao T,Zhao Y,He J Z. Anal Instr,2018(2):43池海涛,徐聪,乐胜锋,王尉,赵婷,赵毅,贺俊智.分析仪器,2018(2):43
[10] Li A,Zhao D,Li P. Anal Instr,2009(1):37李安,赵彤,李鹏.分析仪器,2009(1):37
[11] Gu J L. Chin J Spectr Lab,2007,24(3):614顾佳丽.光谱实验室,2007,24(3):614
[12] Li X M,Deng Y F,Lu G H. PTCA(Part B:Chem Anal),1994,30(5):288李晓明,邓毓芳,陆光汉.理化检验(化学分册),1994,30(5):288
[13] Chemistry Department of Lanzhou University,Shanghai Institute of Materia Medica,Chinese Academy of Sicences,Quantitative Methods of Organic Microanalysis,Beijing:Science Press,1978:2兰州大学化学系,中科院上海药物所.有机微量定量分析.北京:科学出版社,1978:2
[14] Dai Y T,Gao M,Dai J X. Anal. Test. Technol. Instr.,2013(1):24戴钰婷,高敏,戴俊晓.分析测试技术与仪器,2013(1):24
[15] Q/Rs 101-2005,Speicification of boron trifluoride ethanolamine complex.Q/Rs 101-2005,三氟化硼络醇胺规范.
[2] Liu X. Chin. J. Energ. Mater.,2000,8(3):135刘学.含能材料,2000,8(3):135
[3] An H M,Li J J. Chin. J. Expl. Propell.,1998(2):47安红梅,李建军.火炸药学报,1998(2):47
[4] Pang W Q,Zhang J Q,Liu H,Guo J Y,Zhu F. Chem. Propell. Polym. Mater.,2005(6):10庞维强,张教强,刘何,国际英,朱峰.化学推进剂与高分子材料,2005(6):10
[5] Yang H X,Li B. Chem. Bull.,2005(6):479杨红霞,李冰.化学通报,2005(6)479
[6] Chi W T. Occupation and Health,2010,26(3):335池卫廷.职业与健康,2010,26(3):335
[7] Luo M B,Liu S J,Li J Q,Xing X F. J. Analyt. Sci.,18(3):226罗明标,刘淑娟,李建强,邢新芳.分析科学学报,2002,18(3):226
[8] Li L,Cao B S,Cao H,Zhou A F,Yang Y L,Chen Y H. Chin J Health Lab Tech,2006,16(11):1337林立,曹宝森,曹红,周谙非,杨彦丽,陈玉红.中国卫生检验杂志,2006,16(11):1337
[9] Chi H T,Xu C,Le S F,Wang W,Zhao T,Zhao Y,He J Z. Anal Instr,2018(2):43池海涛,徐聪,乐胜锋,王尉,赵婷,赵毅,贺俊智.分析仪器,2018(2):43
[10] Li A,Zhao D,Li P. Anal Instr,2009(1):37李安,赵彤,李鹏.分析仪器,2009(1):37
[11] Gu J L. Chin J Spectr Lab,2007,24(3):614顾佳丽.光谱实验室,2007,24(3):614
[12] Li X M,Deng Y F,Lu G H. PTCA(Part B:Chem Anal),1994,30(5):288李晓明,邓毓芳,陆光汉.理化检验(化学分册),1994,30(5):288
[13] Chemistry Department of Lanzhou University,Shanghai Institute of Materia Medica,Chinese Academy of Sicences,Quantitative Methods of Organic Microanalysis,Beijing:Science Press,1978:2兰州大学化学系,中科院上海药物所.有机微量定量分析.北京:科学出版社,1978:2
[14] Dai Y T,Gao M,Dai J X. Anal. Test. Technol. Instr.,2013(1):24戴钰婷,高敏,戴俊晓.分析测试技术与仪器,2013(1):24
[15] Q/Rs 101-2005,Speicification of boron trifluoride ethanolamine complex.Q/Rs 101-2005,三氟化硼络醇胺规范.