鄱阳湖流域赣江水系溶解态金属元素空间分布特征及污染来源
|
摘要
于2015年1月和7月在赣江干流和主要支流37个采样点共采集74个水样,分析赣江水系15种溶解态金属元素(Be、Al、V、Mn、Fe、Co、Ni、Cu、As、Mo、Cd、Sb、Tl、Pb、U)的空间分布特征和污染来源的贡献率.结果表明:多数水样的溶解态金属元素浓度符合水质标准,主要的超标元素是Fe,样品超标率为21.60%,其次为As(8.10%)、Mn(4.05%)、Tl(4.05%)和Al(1.35%).Be、Al、V、Fe、Co、Ni、Cu、U浓度在枯水期显著高于丰水期,其他元素差异不显著.依据溶解态金属元素的空间分布特征,赣江流域可分为3个区域:湘水、章水和赣江赣州市段(C1),桃江、袁水和锦江(C2),其他区域(C3);溶解态金属元素水平大小排序为C1>C2>C3,其中Be、Al、Cu、Mo、Sb、As浓度在C1最高,V、Mn、Fe、Ni、Cd浓度在C2最高.采矿废水、矿渣和农田土壤降雨淋滤、钢铁冶炼废水是赣江溶解金属元素的主要来源;Be、Al、Cu、Pb、U的污染源超过40%来自采矿废水,Cu、As、Mo、Cd的污染源超过35%来自矿渣和农田土壤降雨淋滤,V、Mn、Co、Ni的污染源超过41%来自钢铁冶炼废水.
We collected 74 water samples from 37 sites along the Ganjiang River and its tributaries in January and July,2015 to analyze the spatial distribution of dissolved metals( Be,Al,V,Mn,Fe,Co,Ni,Cu,As,Mo,Cd,Sb,Tl,Pb and U),and to estimate the contributions of pollution sources in Lake Poyang Basin. The results showed that the concentrations of dissolved metals in most water samples met the national water quality standards,and Fe is the primary trace metal beyond the national standard,i.e. 21. 60% of water samples had higher Fe concentrations than the national drinking water quality standard,followed by As( 8.10%),Mn( 4. 05%),Tl( 4. 05%) and Al( 1. 35%). In addition,the concentrations of Be,Al,V,Fe,Co,Ni,Cu and U during the dry season were significantly higher than those during the wet season,while others had no significant difference. Based on the spatial distribution of dissolved metals,three spatial regions were identified: C1( Xiangshui River Basin,Zhangshui River Basin and Ganzhou section of Ganjiang River),C2( Taojiang River Basin,Yuanshui River Basin and Jinjiang River Basin),and C3( the other regions beyond C1 and C2). The contamination order in the three regions was C1 > C2 > C3. The highest concentrations of Be,Al,Cu,Mo,Sb and As occurred in C1; while V,Mn,Fe,Ni and Cd in C2. The primary sources of dissolved metals in the Ganjiang River were mining waste water,leaching water of slag and agricultural soils,and steel industry waste water. We estimated that more than 40% of Be,Al,Cu,Pb and U were from mining waste water,more than 35% of Cu,As,Mo and Cd from leaching water of slag and agricultural soils,and more than 41% of V,Mn,Co and Ni from the steel industry waste water.
We collected 74 water samples from 37 sites along the Ganjiang River and its tributaries in January and July,2015 to analyze the spatial distribution of dissolved metals( Be,Al,V,Mn,Fe,Co,Ni,Cu,As,Mo,Cd,Sb,Tl,Pb and U),and to estimate the contributions of pollution sources in Lake Poyang Basin. The results showed that the concentrations of dissolved metals in most water samples met the national water quality standards,and Fe is the primary trace metal beyond the national standard,i.e. 21. 60% of water samples had higher Fe concentrations than the national drinking water quality standard,followed by As( 8.10%),Mn( 4. 05%),Tl( 4. 05%) and Al( 1. 35%). In addition,the concentrations of Be,Al,V,Fe,Co,Ni,Cu and U during the dry season were significantly higher than those during the wet season,while others had no significant difference. Based on the spatial distribution of dissolved metals,three spatial regions were identified: C1( Xiangshui River Basin,Zhangshui River Basin and Ganzhou section of Ganjiang River),C2( Taojiang River Basin,Yuanshui River Basin and Jinjiang River Basin),and C3( the other regions beyond C1 and C2). The contamination order in the three regions was C1 > C2 > C3. The highest concentrations of Be,Al,Cu,Mo,Sb and As occurred in C1; while V,Mn,Fe,Ni and Cd in C2. The primary sources of dissolved metals in the Ganjiang River were mining waste water,leaching water of slag and agricultural soils,and steel industry waste water. We estimated that more than 40% of Be,Al,Cu,Pb and U were from mining waste water,more than 35% of Cu,As,Mo and Cd from leaching water of slag and agricultural soils,and more than 41% of V,Mn,Co and Ni from the steel industry waste water.
引文
[1]Sin SN,Chua H,Lo W et al.Assessment of heavy metal cations in sediments of Shing Mun River,Hong Kong.Environment International,2001,26(5):297-301.
[2]Yuan G,Liu C,Chen L et al.Inputting history of heavy metals into the inland lake recorded in sediment profiles:Poyang Lake in China.Journal of hazardous materials,2011,185(1):336-345.
[3]Armitage PD,Bowes MJ,Vincent HM.Long-term changes in macroinvertebrate communities of a heavy metal polluted stream:The river Nent(Cumbria,UK)after 28 years.River Research and Applications,2007,23(9):997-1015.
[4]Bo L,Wang D,Li T et al.Accumulation and risk assessment of heavy metals in water,sediments,and aquatic organisms in rural rivers in the Taihu Lake region,China.Environmental Science and Pollution Research,2015,22(9):6721.
[5]Palma P,Ledo L,Alvarenga P.Assessment of trace element pollution and its environmental risk to freshwater sediments influenced by anthropogenic contributions:The case study of Alqueva reservoir(Guadiana Basin).Catena,2015,128:174-184.
[6]Zhao SN,Shi XH,Li CY et al.Distribution characteristics of mercury and pollution risk assessment in the water of Lake Ulansuhai.J Lake Sci,2014,26(2):221-227.DOI:10.18307/2014.0208.[赵胜男,史小红,李畅游等.乌梁素海水体汞的分布特征及污染风险评估.湖泊科学,2014,26(2):221-227.]
[7]Licheng Z,Kezhun Z.Background values of trace elements in the source area of the Yangtze River.Science of the Total Environment,1992,125:391-404.
[8]Dahlem Workshop on Changing Metal Cycles,Human Health ed.Changing metal cycles and human health:Report of the Dahlem Workshop on Changing Metal Cycles and.Springer-Verlag,1984.
[9]Chapman DV ed.Water quality assessments:A guide to the use of biota,sediments,and water in environmental monitoring.London:CRC Press,1996.
[10]Zhang DW,Zhang L,He JH et al.Spatial distributions and risk assessment of dissolved heavy metals in Poyang Lake.Acta Ecologica Sinica,2015,35(24):8028-8035.[张大文,张莉,何俊海等.鄱阳湖溶解态重金属空间分布格局及风险评估.生态学报,2015,35(24):8028-8035.]
[11]Li WM,Yang ZF,Zhou L et al.Geochemical characteristic and fluxes of heavy metals in water system of the Poyang Lake.Geoscience,2014,28(3):512-536.[李文明,杨忠芳,周雷等.鄱阳湖水系重金属元素地球化学特征及入湖通量.现代地质,2014,28(3):512-536.]
[12]Zhang BJ,Zhu MN,Wang P et al.Spatial and temporal distribution of dissolved cadmium and water quality assessment of the water body of the Ganjiang River Catchment.Journal of Ecology and Rural Environment,2014,30(4):495-499.[张宝军,朱蒙曼,王鹏等.赣江流域水体中可溶态镉的时空分布特征及水质评价.生态与农村环境学报,2014,30(4):495-499.]
[13]Ji Y,Zhang J,Fan HB et al.Distribution characteristics of heavy metal and environmental assessment in the mid-lower reaches of the Ganjiang River.China Rural Water and Hydropower,2013,4(5):42-45.[计勇,张洁,樊后保等.赣江中下游城市断面重金属分布特征及生态风险评价.中国农村水利水电,2013,4(5):42-45.]
[14]Ji Y,Zhang J,Huang X et al.Investigation and assessment of heavy metals in surface sediments of Ganjiang River,China.Journal of Environmental Biology,2014,35(6):1173-1179.
[15]Wang P,Chen DD,Chen B.The distribution characters and pollution sources of nitrogen and phosphorus nutrients in Ganjiang River.Journal of Jiangxi Normal University:Natural Science,2015,39(4):435-440.[王鹏,陈多多,陈波.赣江水体氮磷营养盐分布特征与污染来源.江西师范大学学报:自然科学版,2015,39(4):435-440.]
[16]Zhao ZG.Researches on development pattern of agriculture in the forest areas of Jiangxi Province based on land suitability evaluation.Hubei Agricultural Sciences,2013,52(22):5634-5638.[赵志刚.江西省林耕地适宜性评价与农业发展格局探讨.湖北农业科学,2013,52(22):5634-5638.]
[17]Zhang CH.Statistical analysis of industrial agglomeration in Jiangxi Province.Times Finance,2016,(17):71-72.[张丛煌.江西省工业集聚情况统计分析.时代金融,2016,(17):71-72.]
[18]Huang CG,Liu CG,Ding SH et al.Prediction type and characteristics of main mineral resources in Jiangxi Province.Resources Survey and Environment,2015,36(3):196-202.[黄传冠,刘春根,丁少辉等.江西省主要矿产预测类型及其地质特征.资源调查与环境,2015,36(3):196-202.]
[19]Compilation Committee of geological and mineral records of Jiangxi ed.Chronicles of Jiangxi Province 4.Beijing:China Local Records Publishing,1998.[江西省地质矿产志编纂委员会编.江西省志4.北京:方志出版社,1998.]
[20]Li S,Gu S,Liu W et al.Water quality in relation to land use and land cover in the upper Han River Basin,China.Catena,2008,75(2):216-222.
[21]Thurston GD,Spengler JD.A quantitative assessment of source contributions to inhalable particulate matter pollution in metropolitan Boston.Atmospheric Environment,1985,19(1):9-25.
[22]Gholizadeh MH,Melesse A,Reddi L.Water quality assessment and apportionment of pollution sources using APCS-MLR and PMF receptor modeling techniques in three major rivers of South Florida.Science of the total Environment,2016,566:1552-1567.
[23]Nazeer S,Ali Z,Malik RN.Water quality assessment of River Soan(Pakistan)and source apportionment of pollution sources through receptor modeling.Archives of Environmental Contamination and Toxicology,2016,71(1):97-112.
[24]Su S L,Li D,Zhang Q et al.Temporal trend and source apportionment of water pollution in different functional zones of Qiantang River,China.Water Research,2011,45(4):1781-1795.
[25]Zhou F,Huang GH,Guo HC et al.Spatio-temporal patterns and source apportionment of coastal water pollution in easternHong Kong.Water Research,2007,41(15):3429-3439.
[26]Organization WH ed.Guidelines for drinking-water quality:Recommendations.World Health Organization,2004.
[27]State Environmental Protection Administration,General Administration of Quality Supervision,Inspection and Quarantine of the People’s Republic of China eds.State Standard of the People’s Republic of China GB 3838-2002,2002.[国家环境保护总局,国家质量监督检验检疫总局.中华人民共和国国家标准GB 3838 2002,2002.]
[28]Wan JB,Yan WW,Xie T.Research on heavy metals pollution status of Le’an Rier,Lake Poyang Basin.J Lake Sci,2007,19(4):421-427.DOI:10.18307/2007.0410.[万金保,闫伟伟,谢婷.鄱阳湖流域乐安河重金属污染水平.湖泊科学,2007,19(4):421-427.]
[29]Wang L,Wang Y,Xu C et al.Analysis and evaluation of the source of heavy metals in water of the River Changjiang.Environmental Monitoring and Assessment,2011,173(1/2/3/4):301-313.
[30]Zeng X,Liu Y,You S et al.Spatial distribution,health risk assessment and statistical source identification of the trace elements in surface water from the Xiangjiang River,China.Environmental Science and Pollution Research,2015,22(12):9400-9412.
[31]Li S,Zhang Q.Spatial characterization of dissolved trace elements and heavy metals in the upper Han River(China)using multivariate statistical techniques.Journal of Hazardous Materials,2010,176(1):579-588.
[32]Jing L,Fadong L,Qiang L et al.Spatial distribution and sources of dissolved trace metals in surface water of the Wei River,China.Water Science&Technology,2013,67(4):817.
[33]Wang Z,Sun R,Zhang H et al.Analysis and assessment of heavy metal contamination in surface water and sediments:A case study from Luan River,Northern China.Frontiers of Environmental Science&Engineering,2015,9(2):240-249.
[34]Giri S,Singh AK.Risk assessment,statistical source identification and seasonal fluctuation of dissolved metals in the Subarnarekha River,India.Journal of Hazardous Materials,2014,265:305-314.
[35]Saiful IM,Kawser AM,Mohammad R et al.Heavy metal pollution in surface water and sediment:A preliminary assessment of an urban river in a developing country.Ecological Indicators,2015,48:282-291.
[36]Devic'G,Sakan S,-Dor?evic'D.Assessment of the environmental significance of nutrients and heavy metal pollution in the river network of Serbia.Environmental Science and Pollution Research,2016,23(1):282-297.
[37]Simeonov V,Stratis JA,Samara C et al.Assessment of the surface water quality in Northern Greece.Water Research,2003,37(17):4119-4124.
[38]Lu N.Comprehensive benefits of tin ores.Geology and Exploration,1980,(4):43.[鲁宁.锡矿石的综合利用.地质勘探,1980,(4):43.]
[39]Deng AT.Opinions on reserves calculation of associated beneficial components of tungsten ore in central south China.Geology and Exploration,1957,(16):4-5.[邓安太.对中南钨矿伴生有益组份储量计算的意见.地质与勘探,1957,(16):4-5.]
[40]Peng Y,He JG,Zhang ZM et al.Eco-environmental dynamic monitoring and assessment of rare earth mining area in southern Ganzhou using remote sensing.Acta Ecologica Sinica,2016,36(6):1676-1685.[彭燕,何国金,张兆明等.赣南稀土矿开发区生态环境遥感动态监测与评估.生态学报,2016,36(6):1676-1685.]
[41]Dudka S,Adriano DC.Environmental impacts of metal ore mining and processing:A review.Journal of Environmental Quality,1997,26(3):590-602.
[42]Wang F,Huang ZY,Wang XL et al.Ecological risk assessment of heavy metals in surrounding soils of tungsten ores:Comparison of different evaluation methods.Environmental Chemistry,2015,34(2):225-233.[王斐,黄益宗,王小玲等.江西钨矿周边土壤重金属生态风险评价:不同评价方法的比较.环境化学,2015,34(2):225-233.]
[43]Franklin RSCE,Duis L,Brown R et al.Trace element content of selected fertilizers and micronutrient source materials.Communications in Soil Science and Plant Analysis,2005,36(11/12):1591-1609.
[44]Krishna AK,Satyanarayanan M,Govil PK.Assessment of heavy metal pollution in water using multivariate statistical techniques in an industrial area:A case study from Patancheru,Medak District,Andhra Pradesh,India.Journal of Hazardous Materials,2009,167(1):366-373.
[45]Kalogeropoulos N,Scoullos M,Vassilaki-Grimani M et al.Vanadium in particles and sediments of the northern Saronikos Gulf,Greece.Science of the Total Environment,1989,79(3):241-252.
[46]Miller SLSM,Anderson MJ,Daly EP et al.Source apportionment of exposures to volatile organic compounds.I.Evaluation of receptor models using simulated exposure data.Atmospheric Environment,2002,36(22):3629-3641.
[2]Yuan G,Liu C,Chen L et al.Inputting history of heavy metals into the inland lake recorded in sediment profiles:Poyang Lake in China.Journal of hazardous materials,2011,185(1):336-345.
[3]Armitage PD,Bowes MJ,Vincent HM.Long-term changes in macroinvertebrate communities of a heavy metal polluted stream:The river Nent(Cumbria,UK)after 28 years.River Research and Applications,2007,23(9):997-1015.
[4]Bo L,Wang D,Li T et al.Accumulation and risk assessment of heavy metals in water,sediments,and aquatic organisms in rural rivers in the Taihu Lake region,China.Environmental Science and Pollution Research,2015,22(9):6721.
[5]Palma P,Ledo L,Alvarenga P.Assessment of trace element pollution and its environmental risk to freshwater sediments influenced by anthropogenic contributions:The case study of Alqueva reservoir(Guadiana Basin).Catena,2015,128:174-184.
[6]Zhao SN,Shi XH,Li CY et al.Distribution characteristics of mercury and pollution risk assessment in the water of Lake Ulansuhai.J Lake Sci,2014,26(2):221-227.DOI:10.18307/2014.0208.[赵胜男,史小红,李畅游等.乌梁素海水体汞的分布特征及污染风险评估.湖泊科学,2014,26(2):221-227.]
[7]Licheng Z,Kezhun Z.Background values of trace elements in the source area of the Yangtze River.Science of the Total Environment,1992,125:391-404.
[8]Dahlem Workshop on Changing Metal Cycles,Human Health ed.Changing metal cycles and human health:Report of the Dahlem Workshop on Changing Metal Cycles and.Springer-Verlag,1984.
[9]Chapman DV ed.Water quality assessments:A guide to the use of biota,sediments,and water in environmental monitoring.London:CRC Press,1996.
[10]Zhang DW,Zhang L,He JH et al.Spatial distributions and risk assessment of dissolved heavy metals in Poyang Lake.Acta Ecologica Sinica,2015,35(24):8028-8035.[张大文,张莉,何俊海等.鄱阳湖溶解态重金属空间分布格局及风险评估.生态学报,2015,35(24):8028-8035.]
[11]Li WM,Yang ZF,Zhou L et al.Geochemical characteristic and fluxes of heavy metals in water system of the Poyang Lake.Geoscience,2014,28(3):512-536.[李文明,杨忠芳,周雷等.鄱阳湖水系重金属元素地球化学特征及入湖通量.现代地质,2014,28(3):512-536.]
[12]Zhang BJ,Zhu MN,Wang P et al.Spatial and temporal distribution of dissolved cadmium and water quality assessment of the water body of the Ganjiang River Catchment.Journal of Ecology and Rural Environment,2014,30(4):495-499.[张宝军,朱蒙曼,王鹏等.赣江流域水体中可溶态镉的时空分布特征及水质评价.生态与农村环境学报,2014,30(4):495-499.]
[13]Ji Y,Zhang J,Fan HB et al.Distribution characteristics of heavy metal and environmental assessment in the mid-lower reaches of the Ganjiang River.China Rural Water and Hydropower,2013,4(5):42-45.[计勇,张洁,樊后保等.赣江中下游城市断面重金属分布特征及生态风险评价.中国农村水利水电,2013,4(5):42-45.]
[14]Ji Y,Zhang J,Huang X et al.Investigation and assessment of heavy metals in surface sediments of Ganjiang River,China.Journal of Environmental Biology,2014,35(6):1173-1179.
[15]Wang P,Chen DD,Chen B.The distribution characters and pollution sources of nitrogen and phosphorus nutrients in Ganjiang River.Journal of Jiangxi Normal University:Natural Science,2015,39(4):435-440.[王鹏,陈多多,陈波.赣江水体氮磷营养盐分布特征与污染来源.江西师范大学学报:自然科学版,2015,39(4):435-440.]
[16]Zhao ZG.Researches on development pattern of agriculture in the forest areas of Jiangxi Province based on land suitability evaluation.Hubei Agricultural Sciences,2013,52(22):5634-5638.[赵志刚.江西省林耕地适宜性评价与农业发展格局探讨.湖北农业科学,2013,52(22):5634-5638.]
[17]Zhang CH.Statistical analysis of industrial agglomeration in Jiangxi Province.Times Finance,2016,(17):71-72.[张丛煌.江西省工业集聚情况统计分析.时代金融,2016,(17):71-72.]
[18]Huang CG,Liu CG,Ding SH et al.Prediction type and characteristics of main mineral resources in Jiangxi Province.Resources Survey and Environment,2015,36(3):196-202.[黄传冠,刘春根,丁少辉等.江西省主要矿产预测类型及其地质特征.资源调查与环境,2015,36(3):196-202.]
[19]Compilation Committee of geological and mineral records of Jiangxi ed.Chronicles of Jiangxi Province 4.Beijing:China Local Records Publishing,1998.[江西省地质矿产志编纂委员会编.江西省志4.北京:方志出版社,1998.]
[20]Li S,Gu S,Liu W et al.Water quality in relation to land use and land cover in the upper Han River Basin,China.Catena,2008,75(2):216-222.
[21]Thurston GD,Spengler JD.A quantitative assessment of source contributions to inhalable particulate matter pollution in metropolitan Boston.Atmospheric Environment,1985,19(1):9-25.
[22]Gholizadeh MH,Melesse A,Reddi L.Water quality assessment and apportionment of pollution sources using APCS-MLR and PMF receptor modeling techniques in three major rivers of South Florida.Science of the total Environment,2016,566:1552-1567.
[23]Nazeer S,Ali Z,Malik RN.Water quality assessment of River Soan(Pakistan)and source apportionment of pollution sources through receptor modeling.Archives of Environmental Contamination and Toxicology,2016,71(1):97-112.
[24]Su S L,Li D,Zhang Q et al.Temporal trend and source apportionment of water pollution in different functional zones of Qiantang River,China.Water Research,2011,45(4):1781-1795.
[25]Zhou F,Huang GH,Guo HC et al.Spatio-temporal patterns and source apportionment of coastal water pollution in easternHong Kong.Water Research,2007,41(15):3429-3439.
[26]Organization WH ed.Guidelines for drinking-water quality:Recommendations.World Health Organization,2004.
[27]State Environmental Protection Administration,General Administration of Quality Supervision,Inspection and Quarantine of the People’s Republic of China eds.State Standard of the People’s Republic of China GB 3838-2002,2002.[国家环境保护总局,国家质量监督检验检疫总局.中华人民共和国国家标准GB 3838 2002,2002.]
[28]Wan JB,Yan WW,Xie T.Research on heavy metals pollution status of Le’an Rier,Lake Poyang Basin.J Lake Sci,2007,19(4):421-427.DOI:10.18307/2007.0410.[万金保,闫伟伟,谢婷.鄱阳湖流域乐安河重金属污染水平.湖泊科学,2007,19(4):421-427.]
[29]Wang L,Wang Y,Xu C et al.Analysis and evaluation of the source of heavy metals in water of the River Changjiang.Environmental Monitoring and Assessment,2011,173(1/2/3/4):301-313.
[30]Zeng X,Liu Y,You S et al.Spatial distribution,health risk assessment and statistical source identification of the trace elements in surface water from the Xiangjiang River,China.Environmental Science and Pollution Research,2015,22(12):9400-9412.
[31]Li S,Zhang Q.Spatial characterization of dissolved trace elements and heavy metals in the upper Han River(China)using multivariate statistical techniques.Journal of Hazardous Materials,2010,176(1):579-588.
[32]Jing L,Fadong L,Qiang L et al.Spatial distribution and sources of dissolved trace metals in surface water of the Wei River,China.Water Science&Technology,2013,67(4):817.
[33]Wang Z,Sun R,Zhang H et al.Analysis and assessment of heavy metal contamination in surface water and sediments:A case study from Luan River,Northern China.Frontiers of Environmental Science&Engineering,2015,9(2):240-249.
[34]Giri S,Singh AK.Risk assessment,statistical source identification and seasonal fluctuation of dissolved metals in the Subarnarekha River,India.Journal of Hazardous Materials,2014,265:305-314.
[35]Saiful IM,Kawser AM,Mohammad R et al.Heavy metal pollution in surface water and sediment:A preliminary assessment of an urban river in a developing country.Ecological Indicators,2015,48:282-291.
[36]Devic'G,Sakan S,-Dor?evic'D.Assessment of the environmental significance of nutrients and heavy metal pollution in the river network of Serbia.Environmental Science and Pollution Research,2016,23(1):282-297.
[37]Simeonov V,Stratis JA,Samara C et al.Assessment of the surface water quality in Northern Greece.Water Research,2003,37(17):4119-4124.
[38]Lu N.Comprehensive benefits of tin ores.Geology and Exploration,1980,(4):43.[鲁宁.锡矿石的综合利用.地质勘探,1980,(4):43.]
[39]Deng AT.Opinions on reserves calculation of associated beneficial components of tungsten ore in central south China.Geology and Exploration,1957,(16):4-5.[邓安太.对中南钨矿伴生有益组份储量计算的意见.地质与勘探,1957,(16):4-5.]
[40]Peng Y,He JG,Zhang ZM et al.Eco-environmental dynamic monitoring and assessment of rare earth mining area in southern Ganzhou using remote sensing.Acta Ecologica Sinica,2016,36(6):1676-1685.[彭燕,何国金,张兆明等.赣南稀土矿开发区生态环境遥感动态监测与评估.生态学报,2016,36(6):1676-1685.]
[41]Dudka S,Adriano DC.Environmental impacts of metal ore mining and processing:A review.Journal of Environmental Quality,1997,26(3):590-602.
[42]Wang F,Huang ZY,Wang XL et al.Ecological risk assessment of heavy metals in surrounding soils of tungsten ores:Comparison of different evaluation methods.Environmental Chemistry,2015,34(2):225-233.[王斐,黄益宗,王小玲等.江西钨矿周边土壤重金属生态风险评价:不同评价方法的比较.环境化学,2015,34(2):225-233.]
[43]Franklin RSCE,Duis L,Brown R et al.Trace element content of selected fertilizers and micronutrient source materials.Communications in Soil Science and Plant Analysis,2005,36(11/12):1591-1609.
[44]Krishna AK,Satyanarayanan M,Govil PK.Assessment of heavy metal pollution in water using multivariate statistical techniques in an industrial area:A case study from Patancheru,Medak District,Andhra Pradesh,India.Journal of Hazardous Materials,2009,167(1):366-373.
[45]Kalogeropoulos N,Scoullos M,Vassilaki-Grimani M et al.Vanadium in particles and sediments of the northern Saronikos Gulf,Greece.Science of the Total Environment,1989,79(3):241-252.
[46]Miller SLSM,Anderson MJ,Daly EP et al.Source apportionment of exposures to volatile organic compounds.I.Evaluation of receptor models using simulated exposure data.Atmospheric Environment,2002,36(22):3629-3641.