摘要
在中性水溶液中合成了Keggin型铜取代磷钨杂多阴离子PW11O39Cu(II)(H2O)5-(PW11Cu),并对其进行IR、UV-Vis和循环伏安表征.实验结果表明,PW11Cu在700~1100 cm-1的指纹区内有四个特征振动吸收峰,分别对应于P-Oa、W=Od、W-Ob-W和W-Oc-W的反对称伸缩振动吸收.在200nm和249 nm处有两个很强的紫外吸收,在650~800 nm的可见光区有一个较强的连续吸收带.循环伏安显示W-O骨架波和一对Cu的氧化-还原波.
Keggin-type Cu(II)-substituted heteropolyanion PW11O39Cu(II)(H2O)5-(PW11Cu) was synthesized in neutral aqueous solution and characterized by IR, UV-Vis and cyclic voltammetry. Experimental results showed that in the 700-1100cm-1 fingerprint area PW11 Cu exhibits five characteristic absorption peaks, corresponding to the anti-symmetric stretching vibration of P-Oa, W=Od, W-Ob-W and W-Oc-W, respectively. There are two strong UV absorptions at near 200 nm and249 nm and a continuous visible absorption band in the district of 650~800 nm for PW11 Cu. In addition to W-O skeletonwaves a pair of Cu(II)/Cu(I) redox wave appears in the cyclic voltammograms.
引文
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