锂离子电池磷负极材料的研究进展
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摘要
磷因兼具高储锂容量和高倍率性能的优点而被认为是一种具有巨大发展潜力的锂离子电池负极材料。综述了锂离子电池磷和磷/碳复合负极材料的研究进展。主要介绍了黑磷的基本结构性质,制备方法及其作为锂离子电极材料的综合电化学性能,并对目前存在的一些问题和亟待进行的研究工作进行了分析。
Phosphorus with advantages of super-high specific capacity and rate capability was considered as a promising anode material of lithium ion batteries. The research progress of the phosphorus anode materials of lithium-ion battery was summarized. Basic physical property of black phosphorus, synthesis methods and electrochemical performance of black phosphorus and phosphorus/carbon composite system were introduced. The key problems and the future work of black phosphorus were also analyzed and proposed.
Phosphorus with advantages of super-high specific capacity and rate capability was considered as a promising anode material of lithium ion batteries. The research progress of the phosphorus anode materials of lithium-ion battery was summarized. Basic physical property of black phosphorus, synthesis methods and electrochemical performance of black phosphorus and phosphorus/carbon composite system were introduced. The key problems and the future work of black phosphorus were also analyzed and proposed.
引文
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[16]其鲁,胡晓光,晨辉,等.黑磷作为锂离子蓄电池负极材料的应用及其制成的蓄电池:中国,03153105.9[P].2004-03-10.
[17]LANGE S,SCHMIDT P,NILGES T.Au3SnP7@black phosphorus:an easy acess to black phosphorus[J].Inorg Chem,2007,46:4028-4035.
[18]NILGES T,KERSTING M,PFEIFER T.A fast low-pressure transport route to large black phosphorus single crystals[J].J Solid State Chem,2008,181:1707-1711.
[19]QIAN J,QIAO D,AI X,et al.Reversible 3-Li storage reactions of amorphous phosphorus as high capacity and cycling-stable anodes for Li-ion batteries[J].Chem Commun,2012,48:8931-8933.
[20]NAGAO M,HAYASHI A,TATSUMISAGO M.All-solid-state lithium secondary batteries with high capacity using black phosphorus negative electrode[J].J Power Sources,2011,196:6902-6905.
[21]SUN L Q,LI M-J,SUN K,et al.Electrochemical activity of black phosphorus as an anode material for lithium-ion batteries[J].J Phys Chem,2012,116:14772-14779.
[22]陈军,陶占良,袁华堂.锂离子二次电池电极材料的研究进展[J].电源技术,2007,31(12):A 946-A 950.
[23]MARINO C,DEBENEDETTI A,FRAISSE B,et al.Activatedphosphorus as new electrode material for Li-ion batteries[J].Electrochem Commun,2011,13:346-349.
[2]乐毅诚,石磊,吴飞.锂离子电池负极材料的研究进展[J].船电技术,2011,31(6):10-13.
[3]SOUZA D C S,PRALONG V,JACOBSON A,et al.A reversible solid-state crystalline transformation in a metal phosphide induced by redox chemistry[J].Science,2002,296:2012-2015.
[4]PARK C M,SOHN H J.Black phosphours and its composite for lithium rechargeable batteries[J].Adv Mater,2007,19:2465-2468.
[5]PRALONG V,SOUZA D C S,LEUNG K T,et al.Reversible lithium uptake by CoP3at low potential:role of the anion[J].Electrochem Commun,2002,4:516-520.
[6]ZHANG C D,LIAN J C,YI W,et al.Surface structures of black phosphorus investigated with scanning tunneling microscopy[J].J Phys Chem C,2009,113:18823-18826.
[7]GAGARIN S G,TETERIN Y A.Relation between the structure of black phosphorus and the structure of its photoelectron spectrum,due to the electrons of the inner valence bonds,and their role in the chemical bond[J].Plenum Publishing Corporation,1986,26:535-540.
[8]孙立群,谢海明,王荣顺.一种高容量锂离子电池负极材料的制备方法:中国,201110398730.8[P].2012-06-13.
[9]BRIDGEMAN P W.Two new modifications of phosphorus[J].J Am Chem Soc,1914,36:1344-1363.
[10]BRIDGEMAN P W.The compression of 39 substances to 100 000kg/cm2[J].Proc Am Acad Art Sci,1948,76:55-70.
[11]BRIDGEMAN P W.Effects of high shearing stress combined with high hydrostatic press[J].Phys Rev,1935,48:825-847.
[12]BRIDGEMAN P W.Shearing phenomena at high pressures,particularly in inorganic compound[J].Proc Am Acad Art Sci,1937,71:387-460.
[13]MARUYAMA Y,SUZUKI S,KOBAYASHI K,et al.Synthesis and some properties of black phosphorus single crystals[J].Physica,1981,105B:99-102.
[14]ENDO S,AKAHAMA Y,TERADA S,et al.Growth of large single crystals of black phosphorus under high pressure[J].Jpn J Appl Phys,1982,21:L482-L484.
[15]MORITA A.Semiconducting black phosphorus[J].Appl Phys A,1986,39:227-242.
[16]其鲁,胡晓光,晨辉,等.黑磷作为锂离子蓄电池负极材料的应用及其制成的蓄电池:中国,03153105.9[P].2004-03-10.
[17]LANGE S,SCHMIDT P,NILGES T.Au3SnP7@black phosphorus:an easy acess to black phosphorus[J].Inorg Chem,2007,46:4028-4035.
[18]NILGES T,KERSTING M,PFEIFER T.A fast low-pressure transport route to large black phosphorus single crystals[J].J Solid State Chem,2008,181:1707-1711.
[19]QIAN J,QIAO D,AI X,et al.Reversible 3-Li storage reactions of amorphous phosphorus as high capacity and cycling-stable anodes for Li-ion batteries[J].Chem Commun,2012,48:8931-8933.
[20]NAGAO M,HAYASHI A,TATSUMISAGO M.All-solid-state lithium secondary batteries with high capacity using black phosphorus negative electrode[J].J Power Sources,2011,196:6902-6905.
[21]SUN L Q,LI M-J,SUN K,et al.Electrochemical activity of black phosphorus as an anode material for lithium-ion batteries[J].J Phys Chem,2012,116:14772-14779.
[22]陈军,陶占良,袁华堂.锂离子二次电池电极材料的研究进展[J].电源技术,2007,31(12):A 946-A 950.
[23]MARINO C,DEBENEDETTI A,FRAISSE B,et al.Activatedphosphorus as new electrode material for Li-ion batteries[J].Electrochem Commun,2011,13:346-349.