摘要
The recent development of Cu-based electrocatalysts for electrochemical reduction of carbon dioxide(CO_2) has attracted much attention due to their unique activity and selectivity compared to other metal catalysts. Particularly, Cu is the unique electrocatalyst for CO_2 electrochemical reduction with high selectivity to generate a variety of hydrocarbons. In this review, we mainly summarize the recent advances on the rational design of Cu nanostructures, the composition regulation of Cu-based alloys, and the exploitation of advanced supports for improving the catalytic activity and selectivity toward electrochemical reduction of CO_2. The special focus is to demonstrate how to enhance the activity and selectivity of Cubased electrocatalyst for CO_2 reduction. The perspectives and challenges for the development of Cu-based electrocatalysts are also addressed. We hope this review can provide timely and valuable insights into the design of advanced electrocatalytic materials for CO_2 electrochemical reduction.
The recent development of Cu-based electrocatalysts for electrochemical reduction of carbon dioxide(CO_2) has attracted much attention due to their unique activity and selectivity compared to other metal catalysts. Particularly, Cu is the unique electrocatalyst for CO_2 electrochemical reduction with high selectivity to generate a variety of hydrocarbons. In this review, we mainly summarize the recent advances on the rational design of Cu nanostructures, the composition regulation of Cu-based alloys, and the exploitation of advanced supports for improving the catalytic activity and selectivity toward electrochemical reduction of CO_2. The special focus is to demonstrate how to enhance the activity and selectivity of Cubased electrocatalyst for CO_2 reduction. The perspectives and challenges for the development of Cu-based electrocatalysts are also addressed. We hope this review can provide timely and valuable insights into the design of advanced electrocatalytic materials for CO_2 electrochemical reduction.
引文
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