植物基活性炭的制备及吸附应用研究进展
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  • 英文篇名:Review on preparation of plant-based activated carbon and its adsorption application
  • 作者:申朋飞 ; 朱颖颖 ; 李信宝 ; 夏振国 ; 陈耿
  • 英文作者:SHEN Pengfei;ZHU Yingying;LI Xinbao;XIA Zhenguo;CHEN Geng;Faculty of Maritime and Transportation, Ningbo University;
  • 关键词:生物质 ; 活性炭 ; 制备 ; 吸附 ; 应用
  • 英文关键词:biomass;;activated carbon;;preparation;;adsorption;;application
  • 中文刊名:HGJZ
  • 英文刊名:Chemical Industry and Engineering Progress
  • 机构:宁波大学海运学院;
  • 出版日期:2019-08-05
  • 出版单位:化工进展
  • 年:2019
  • 期:v.38;No.335
  • 基金:国家自然科学基金(51406093)
  • 语种:中文;
  • 页:HGJZ201908031
  • 页数:11
  • CN:08
  • ISSN:11-1954/TQ
  • 分类号:272-282
摘要
从植物基活性炭的制备及其吸附应用两个部分对国内外的研究进行了综述。介绍了不同生物质原料对活性炭品质和用途的影响,总结了常用活性炭炭化方法,着重阐述了不同活化方法的优缺点和研究现状,并对不同活性炭改性技术的特点和应用进行了比较。植物基活性炭的应用主要包括对硫化氢等工业废气和甲醛等室内废气的吸附净化,对废水中有机染料、有机药物、小分子有机化合物和重金属的吸附,以及被用于制作超级电容器电极材料等。最后针对目前研究中对植物原料的特点考虑不足、制备过程存在环境污染等问题,指出根据植物前体的性质优化制备方法、开发绿色高效制备技术、提高活性炭回收再利用效率将是今后的主要研究方向。
        The preparation of plant-based activated carbon and its application are reviewed in this paper. The effects of different carbon resource on the characteristics and application of activated carbon were summarized. Features of common carbonization methods, activation methods and modification methods were discussed. The use of different preparing methods and related research progress were summarized as well. The general use of plant-based activated carbon includes decontamination of industrial and indoor waste gas, such as hydrogen sulfide and formaldehyde, adsorption of organic dyes,organic drugs, small molecular organic compounds and heavy metals in wastewater, and use as supercapacitor electrode materials. According to the limitations of current research, such as characteristics of plant raw materials being not adequately considered for single preparation process and pollution emission during preparation, future perspectives of plant-based active preparation research were provided as follows: preparation method optimization according the nature of plant precursors, environmental-friendly preparation methods development and improvement of activated carbon reuse ratio.
引文
[1]宇鹏,赵树青,黄魁.固体废弃物处理与处置[M].北京:北京大学出版社, 2016.YU Peng, ZHAO Shuqing, HUANG Kui. Solid waste treatment and disposal[M]. Beijing:Peking University Press, 2016.
    [2]许伟,刘军利,孙康.活性炭吸附法在挥发性有机物治理中的应用研究进展[J].化工进展, 2016, 35(4):1223-1229.XU Wei, LIU Junli, SUN Kang. Application progresses in the treatment of volatile organic compounds by adsorption on activated carbon[J]. Chemical Industry and Engineering Progress, 2016, 35(4):1223-1229.
    [3]刘琼,李涛,支娟娟,等.生物质基活性炭处理重金属废水研究进展[J].现代化工, 2017, 37(1):18-22.LIU Qiong, LI Tao, ZHI Juanjuan, et al. Research progress of treatment of heavy metal containing wastewater by biomass based activated carbon[J]. Modern Chemical Industry, 2017, 37(1):18-22.
    [4]方梦祥,姚鹏,岑建孟,等.活性炭吸附处理含酚废水的研究进展[J].化工进展, 2018, 37(2):744-751.FANG Mengxiang, YAO Peng, CEN Jianmeng, et al. Adsorption treatment of phenolic wastewater by activated carbon:a review[J].Chemical Industry and Engineering Progress, 2018, 37(2):744-751.
    [5]王勋,曾丹林,陈诗渊,等.生物质活性炭的研究进展[J].化工新型材料, 2018, 46(6):27-30.WANG Xun, ZENG Danlin, CHEN Shiyuan, et al. Research progress of activated carbon from biomass[J]. New Chemical Materials, 2018, 46(6):27-30.
    [6]李栋,汪印,杨娟,等.生物质和煤基活性炭制备过程的活化特性比较[J].化工学报, 2013, 64(9):3338-3347.LI Dong, WANG Ying, YANG Juan, et al. Comparison of activation characteristics of biomass and coal-based activated carbon preparation process[J]. CIESC Journal, 2013, 64(9):3338-3347.
    [7]解炜.我国煤基活性炭的应用现状及发展趋势[J].煤炭科学技术,2017, 45(10):16-23.XIE Wei. Application status and development trend of coal-based activated carbon in China[J]. Coal Science and Technology, 2017, 45(10):16-23.
    [8] OU Y J, P C, LANG J W, et al. Hierarchical porous activated carbon produced from spinach leaves as an electrode material for an electric double layer capacitor[J]. New Carbon Materials, 2014, 77(3):1196-1196.
    [9]曹国飞,廖奕,张小华,等.电化学双电层电容器电极材料——豌豆荚基活性炭的制备与表征[J].物理化学学报, 2011, 27(2):1679-1684.CAO Guofei, LIAO Yi, ZHANG Xiaohua, et al. Preparation and characterization of peasecod—Based activated carbons as electrode materials for electrochemical double-layer capacitors[J]. Acta Physico-Chimica Sinica, 2011, 27(2):1679-1684.
    [10] CHAITRA K, VINNY R T, SIVARAMAN P, et al. KOH activated carbon derived from biomass-banana fibers as an efficient negative electrode in high performance asymmetric super capacitor[J]. Journal of Energy Chemistry, 2017, 26(1):56-62.
    [11]王玉新,时志强,周亚平.孔隙发达竹质活性炭的制备及其电化学性能[J].化工进展, 2008, 27(3):399-403.WANG Yunxin, SHI Zhiqiang, ZHOU Yaping. Preparation of bamboo activated carbon with high porosity and its electrochemical applications[J]. Chemical Industry and Engineering Progress, 2008, 27(3):399-403.
    [12] CHEN C J, ZHAO P C, HUANG Y M, et, al. Preparation and characterization of activated carbon from eucalyptus sawdustⅠ.Activated by NaOH[J]. Journal of Inorganic and Organometallic Polymers and Materials, 2013, 23(5):1201-1209.
    [13]仲兆平,张居兵,郭厚焜,等. KOH活化制备直接碳燃料电池用竹炭[J].工程热物理学报, 2011, 32(12):2156-2159.ZHONG Zhaoping, ZHANG Jubing, GUO Houkun, et al. Bamboobased activated carbon for DCFC prepared by KOH activation[J].Journal of Engineering Thermophysics, 2011, 32(12):2156-2159.
    [14]李勇,张宏,李庆,等.几种干果核壳活性炭的表征与性能比较[J].生物质化学工程, 2014, 48(3):25-29.LI Yong, ZHANG Hong, LI Qing, et al. Characterization and properties of activated carbon from several nut shells[J]. Biomass Chemical Engineering, 2014, 48(3):25-29.
    [15]杨晓霞,郑小峰,郭延红.枣核基活性炭的制备及其对亚甲基蓝的吸附性能[J].过程工程学报, 2016, 16(6):1075-1080.YANG Xiaoxia, ZHENG Xiaofeng, GUO Yanhong. Preparation of meso-activated carbon from jujube stone and its adsorption of methylene blue[J]. The Chinese Journal of Process Engineering, 2016,16(6):1075-1080.
    [16] CAZETTA A L, VARGAS A M M, NOGAMI E M, et al. NaOHactivated carbon of high surface area produced from coconut shell:kinetics and equilibrium studies from the methylene blue adsorption[J]. Chemical Engineering Journal, 2011,174(1):117-125.
    [17]张利波,彭金辉,涂建华,等.氢氧化钾活化烟杆制造活性炭及表征[J].化工进展, 2006, 25(4):415-419.ZHANG Libo, PENG Jinhui, TU Jianhua, et al. Production and characterization of activated carbon from tobacco stems by potassium hydroxide activation[J]. Chemical Industry and Engineering Progress,2006, 25(4):415-419.
    [18] XIAO Gang, WU Rongbing, ZHOU Huilong, et al. Preparation and characterization of activated carbons based alkali lignin by KOH chemical activation[J]. Journal of Combustion Science and Technology,2014, 21(1):14-20.
    [19] WANG X, WANG M J, ZHANG X M, et al. Low-cost, green synthesis of highly porous carbons derived from lotus root shell as superior performance electrode materials in supercapacitor[J]. Journal of Energy Chemistry, 2016, 25(1):26-34.
    [20]王昀,贲腾,裘式纶.自活化乌拉草基多孔碳的制备和电化学性质[J].高等学校化学学报, 2016, 37(6):1042-1049.WANG Yun, BI Teng, QIU Shilun. Self-activated carex meyeriana kunth-based porous carbon prepared by direct carbonization and its electrochemical properties[J]. Chemical Journal of Chinese Universities, 2016, 37(6):1042-1049.
    [21]黄彪,陈学榕,江茂生,等.不同炭化条件下炭化物的结构与性能表征[J].光谱学与光谱分析, 2006, 26(3):455-459.HUANG Biao, CHEN Xuerong, JIANG Maosheng, et al. Structural and property characteristics of Chinese fir wood charcoal prepared under various conditions[J]. Spectroscopy and Spectral Analysis, 2006, 26(3):455-459.
    [22]曲先锋,彭辉,毕继诚,等.生物质在超临界水中热解行为的初步研究[J].燃料化学学报, 2003, 31(3):230-233.QU Xianfeng, PENG Hui, BI Jicheng, et al. Pyrolysis behavior of biomass in supercritical water[J]. Journal of Fuel Chemistry and Technology, 2003, 31(3):230-233.
    [23] ROMAN S, NABAIS J M V, LAGINHAS C, et al. Hydrothermal carbonization as an effective way of densifying the energy conten of biomass[J]. Fuel Processing Technology, 2012,103:78-83.
    [24]董向元,郭淑青,吴婷婷,等.液固比对生物质水热炭化产物结构演变的影响[J].太阳能学报, 2017, 38(7):2005-2011.DONG Xiangyuan, GUO Shuqing, WU Tingting, et al. Influence of liquid to biomass ratio on structural evolution of products derived from biomass hydrothermal carbonization[J]. Acta Energiae Solaris Sinica,2017, 38(7):2005-2011.
    [25] ZHANG Y J, XING Z J, DUAN Z K, et al. Effects of steam activation on the pore structure and surface chemistry of activated carbon derived from bamboo waste[J]. Applied Surface Science, 2014, 315:279-286.
    [26] CHEN W, HE F, ZHANG S, et al. Development of porosity and surface chemistry of textile waste jute-based activated carbon by physical activation[J]. Environmental Science&Pollution Research International, 2018, 25(10):9840-9848.
    [27] YANG K B, PENG J H, SRINIVASAKANNAN C, et al. Preparation of high surface area activated carbon from coconut shells using microwave heating[J]. Bioresource Technology, 2010, 101(15):6163-6169.
    [28]陈诚,任庆功,徐庆瑞,等.板栗壳活性炭对重金属离子吸附性能研究[J].离子交换与吸附, 2014, 30(1):29-38.CHEN Cheng, REN Qinggong, XU Qingrui, et al. Adsorption of heavy metal ions by chestnut shell activated carbon[J]. Ion Exchange and Adsorption, 2014, 30(1):29-38.
    [29]马承愚,张晏静,查向浩,等. KOH活化咖啡渣制备活性炭及其孔结构的影响[J].应用化工, 2017, 46(12):2412-2415.MA Chengyu, ZHANG Yanjing, ZHA Xianghao, et al. Research of pore structure of activated carbon from KOH-activated coffee grounds[J]. Applied Chemical Industry, 2017, 46(12):2412-2415.
    [30]李园园,陈少华,张召基,等. KOH活化丝瓜络制备高比表面积活性炭[J].化工进展, 2012, 31(6):1274-1279.LI Yuanyuan, CHEN Shaohua, ZHANG Zhaoji, et al. Preparation of high surface area activated carbons from luffa cylindrical sponge by KOH activation[J]. Chemical Industry and Engineering Progress, 2012,31(6):1274-1279.
    [31] XU J, CHEN L, QU H, et al. Preparation and characterization of activated carbon from reedy grass leaves by chemical activation with H3PO4[J]. Applied Surface Science, 2014, 320:674-680.
    [32]熊道陵,许光辉,张团结,等.油茶壳残渣制备活性炭的工艺[J].化工进展, 2015, 34(12):4280-4284.XIONG Daoling, XU Guanghui, ZHANG Tuanjie, et al. Activated carbon prepared from camellia oleifera shell residue after alcohol extraction[J]. Chemical Industry and Engineering Progress, 2015, 34(12):4280-4284.
    [33] TSUBOTA T, MORITA M, KAMIMURA S, et al. New approach for synthesis of activated carbon from bamboo[J]. Journal of Porous Materials, 2016, 23(2):349-355.
    [34]付国家,张建社,郭庆杰.核桃壳化学-物理耦合活化法制备活性炭及其表征[J].青岛科技大学学报(自然科学版), 2012, 33(2):126-130.FU Guojia, ZHANG Jianshe, GUO Qingjie. Preparation and characterization of activated carbon from walnut shell by coupled physiochemical activation[J]. Journal of Qingdao University of Science and Technology(Natural Science Edition), 2012, 33(2):126-130.
    [35] WU J, XIA H, ZHANG L, et al. Effect of microwave heating conditions on the preparation of high surface area activated carbon from waste bamboo[J]. High Temperature Materials&Processes, 2015, 82(7):1-8.
    [36]张利波,彭金辉,夏洪应,等.微波加热制备烟杆基高比面积活性炭的研究[J].武汉理工大学学报, 2008, 30(12):76-79.ZHANG Libo, PENG Jinhui, XIA Hongying, et al. Research on preparation of high specific surface area activated carbon from tobacco stem by microwave heating[J]. Journal of Wuhan University of Technology, 2008, 30(12):76-79.
    [37]宋磊,张彬,陈家元,等.废茶活性炭的制备及其孔径结构的控制[J].化工进展, 2014, 33(6):1496-1505.SONG Lei, ZHANG Bin, CHEN Jiayuan, et al. Preparation of activated carbon from waste tea and its porosity control[J]. Chemical Industry and Engineering Progress, 2014, 33(6):1496-1505.
    [38] SEPúLVEDA-CERVANTES CYNTHIA V, SOTO-REGALADO E,RIVAS-GARCIA P, et al. Technical-environmental optimisation of the activated carbon production of an agroindustrial waste by means response surface and life cycle assessment[J]. Waste Management&Research, 2018, 36(2):121-130.
    [39] ALSLAIBI T M, ABUSTAN I, AHMAD M A, et al. A review:production of activated carbon from agricultural byproducts via conventional and microwave heating[J]. Journal of Chemical Technology&Biotechnology, 2013, 88(7):1183-1190.
    [40]朱光真,邓先伦,郭昊,等.催化活化法制备杉木基超高比表面积颗粒活性炭[J].林产化学与工业, 2014, 34(1):113-116.ZHU Guangzhen, DENG Xianlun, GUO Hao, et al. Preparation of granular activated carbon from China fir with super-high surface area by catalysis activation[J]. Chemistry and Industry of Forest Products,2014, 34(1):113-116.
    [41]黄帮福,耿朝阳,施哲,等.酸碱改性及负载镍对活性炭脱硫性能影响研究[J].硅酸盐通报,2018, 37(11):3617-3622, 3636.HUANG Bangfu, GENG Chaoyang, SHI Zhe, et al. Desulfurizing property of activated carbon modified by acid and alkali and nickel[J].Bulletin of the Chinese Ceramic Society, 2018, 37(11):3617-3622,3636.
    [42] CHEUNG W H, LAU S S Y, LEUNG S Y, et al. Characteristics of chemical modified activated carbons from bamboo scaffolding[J].Chinese Journal of Chemical Engineering, 2012, 20(3):515-523.
    [43]汪婷,高谨,金晓英,等.纳米四氧化三铁同步去除水中的Pb(Ⅱ)和Cr(Ⅲ)离子[J].环境工程学报, 2013,7(9):3476-3482.WANG Ting, GAO Jin, JIN Xiaoying, et al. Simultaneous removal of Pb(Ⅱ)and Cr(Ⅲ)from wastewater by magnetite nanoparticles[J].Chinese Journal of Environmental Engineering, 2013, 7(9):3476-3482.
    [44]王贵珍,李丽欣,李永真.毛竹活性炭制备及其对含苯酚废水吸附的研究[J].高校化学工程学报, 2010, 24(4):700-704.WANG Guihzhen, LI Lixin, LI Yongzhen. Study on the preparation of bamboo activated carbon and its phenol adsorption properties[J].Journal of Chemical Engineering of Chinese Universities, 2010, 24(4):700-704.
    [45]李立清,顾庆伟,石瑞,等.热改性活性炭吸附有机气体的性能[J].化工学报, 2012, 63(6):1749-1756.LI Liqing, GU Qingwei, SHI Rui, et al. Adsorption of VOCs onto activated carbons with thermal treatment[J]. CIESC Journal, 2012, 63(6):1749-1756.
    [46]李洲,建伟伟,贾冯睿,等.微波与氧化剂改性活性炭及SO2吸附实验[J].应用化工, 2018, 47(4):703-707.LI Zhou, JIAN Weiwei, JIA Fengrui, et al. Activated carbon modified by microwave and oxidant for flue gas desulfurization[J]. Applied Chemical Industry, 2018, 47(4):703-707.
    [47]孙康,蒋剑春,卢辛成,等.表面掺氮活性炭的制备及其甲醛吸附性能研究[J].林产化学与工业, 2014, 34(4):77-82.SUN Kang, JIANG Jianchun, LU Xincheng, et al. Preparation of Ndoped activated carbon and effects of N-doping on formaldehyde adsorption[J]. Chemistry and Industry of Forest Products, 2014, 34(4):77-82.
    [48] ZHANG X L, ZHANG Y, WANG S S, et al. Effect of activation agents on the surface chemical properties and desulphurization performance of activated carbon[J]. Science in China Series E:Technological Sciences, 2010, 53(9):2515-2520.
    [49] SUMATHI S. BHATIA S. LEE K T,et al. Cerium impregnated palm shell activated carbon(Ce/PSAC)sorbent for simultaneous removal of SO2and NO—Process study[J]. Chemical Engineering Journal, 2010,162(1):51-57.
    [50]顾恒星,董朔,陈华,等.铁水脱硫渣-生物质活性炭的烟气脱硫性能研究[J].硅酸盐通报, 2017, 36(1):385-390.GU Hengxing, DONG Shuo, CHEN Hua, et al. Performance of flue gas desulfurization by desulfurized slag-novel biomass activated carbon[J].Bulletin of the Chinese Ceramic Society, 2017, 36(1):385-390.
    [51]刘晓敏,邓先伦,朱光真.活性炭吸附挥发性有机物的影响因素研究进展[J].生物质化学工程, 2010, 44(6):52-58.LIU Xiaomin, DENG Xianlun, ZHU Guangzhen. Research progress in the activated carbon adsorption on volatile organic compounds[J].Biomass Chemical Engineering, 2010, 44(6):52-58.
    [52]许伟,刘军利,孙康.活性炭吸附法在挥发性有机物治理中的应用研究进展[J].化工进展, 2016, 35(4):1223-1229.XU Wei, LIU Junli, SUN Kang. Application progresses in the treatment of volatile organic compounds by adsorption on activated carbon[J]. Chemical Industry and Engineering Progress, 2016, 35(4):1223-1229.
    [53]周剑峰,吴祖成.不同条件对活性炭吸附挥发性有机物的影响[J].浙江大学学报(理学版), 2013, 40(2):201-206.ZHOU Jianfeng, WU Zucheng. The study of effect of activated carbon adsorbing volatile organic compounds under different conditions[J].Journal of Zhejiang University(Science Edition), 2013, 40(2):201-206.
    [54]李桥,雍毅,丁文川,等.紫外辐照改性生物炭对VOCs的动态吸附[J].环境科学, 2016, 37(6):2065-2072.LI Qiao, YONG Yi, DING Wenchuan, et al. Studies of dynamic adsorption behavior of VOCs on biochar modified by ultraviolet irradiation[J]. Environmental Science, 2016, 37(6):2065-2072.
    [55]湛世界,孟海波,程红胜,等.生物质活性炭理化特性对挥发性有机物吸附性能影响的研究进展[J].中国农业科技导报, 2018, 20(3):132-138.ZHAN Shijie, MENG Haibo, CHENG Hongsheng, et al. Research progress on the effect of physical and chemical properties of biomass activated carbon on the adsorption properties of VOCs[J]. Journal of Agricultural Science and Technology, 2018, 20(3):132-138.
    [56]武瑞燕,薛小艳,王勇,等.莲藕基活性炭对Fe(Ⅲ)的识别及去除性能研究[J].功能材料, 2017, 48(9):9074-9079.WU Ruiyan, XUE Xiaoyan, WANG Yong, et al. Recognitions and removal performance of lotus root-based activated carbon towards Fe(Ⅲ)[J]. Journal of Functional Materials, 2017, 48(9):9074-9079.
    [57]邓志华,刘佩琪,邓清,等.椰壳活性炭对水中重金属离子的吸附研究[J].化工新型材料, 2018, 46(3):273-276.DENG Zhihua, LIU Peiqi, DENG Qing, et al. Research on the adsorption of coconut shell activated carbon for heavy metal ion in the water[J]. New Chemical Materials, 2018, 46(3):273-276.
    [58] GHOSH S K, HAJR A K, BANDYOPADHYAY A, et al. Air agitated tapered bubble column adsorber for hazardous dye(crystal violet)removal onto activated(ZnCl2)carbon prepared from bamboo leaves[J].Journal of Molecular Liquids, 2017(240):313-321.
    [59] GARCíA Juan Rafael, SEDRAN Ulises, ZAINI Muhammad Abbas Ahmad, et al. Preparation, characterization, and dye removal study of activated carbon prepared from palm kernel shell[J]. Environmental Science and Pollution Research International, 2018, 25(6):5076-5085.
    [60]邓隐北,谢志平,赖正泷,等.作为车载用蓄电系统的双电层电容器[J].电源世界, 2017(2):29-33.DENG Yinbei, XIE Zhiping, LAI Zhenglong, et al. EDLC used as electric storage system for cars[J]. The World of Power Supply, 2017(2):29-33.
    [61]黎先发,罗学刚.制备活性炭负载K2CO3用于催化餐饮废油合成生物柴油[J].化工进展, 2015, 34(2):376-380.LI Xianfa, LUO Xuegang. Preparation of K2CO3supported activated carbon for the transesterification of waste cooking oil to biodiesel[J].Chemical Industry and Engineering Progress, 2015, 34(2):376-380.
    [62]荣常如,韩金磊,陈书礼,等.活性炭在汽车上的应用及展望[J].汽车工艺与材料, 2017(11):55-59.RONG Changru, HAN Jinlei, CHEN Shuli, et al. Application and prospect of activated carbon in automobiles[J]. Automobile Technology&Material, 2017(11):55-59.
    [63]彭韬,邢学刚,蔡先立,等.保水剂与活性炭改良白云岩石漠化坡地土壤促进植物生长的盆栽试验研究[J].中国岩溶, 2016, 35(5):525-532.PENG Tao, XING Xuegang, CAI Xianli, et al. Pot experiment research on the effects of water retaining agent and activated carbon as soil amendments for plant growing on dolomitic rocky desertification slopes[J]. Carsologica Sinica, 2016, 35(5):525-532.
    [64]方孟,张新军,曹志勇,等.活性炭对土壤氡吸附饱和性能研究[J].核电子学与探测技术, 2017, 37(4):364-368.FANG Meng, ZHANG Xinjun, CAO Zhiyong, et al. The study on adsorption saturation of activated carbon to soil radon[J]. Nuclear Electronics&Detection Technology, 2017, 37(4):364-368.

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