石榴石型固体电解质Li_7La_3Zr_2O_(12)的研究进展
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摘要
固态电解质主要包括聚合物固态电解质、无机固体电解质、薄膜固态电解质。简单介绍了无机固体电解质的分类,着重阐述了无机固体电解质锂镧锆氧(Li_7La_3Zr_2O_(12))的合成方法、掺杂和表面修饰研究进展,并展望了研究前景。
Solid electrolyte mainly included polymer solid electrolyte,inorganic solid electrolyte and thin film solid electrolyte,and the classification of inorganic solid electrolyte was briefly introduced.The synthesis of inorganic solid electrolyte was reviewed,and the research results of synthesis,doping and surface modification were reviewed,and the research prospect was also discussed.
Solid electrolyte mainly included polymer solid electrolyte,inorganic solid electrolyte and thin film solid electrolyte,and the classification of inorganic solid electrolyte was briefly introduced.The synthesis of inorganic solid electrolyte was reviewed,and the research results of synthesis,doping and surface modification were reviewed,and the research prospect was also discussed.
引文
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[15]Lee C H,Park G J,Choi J H,et al.Low temperature synthesis of garnet type solid electrolyte by modified polymer complex process and its characterization[J].Materials Research Bulletin,2016,83:309-315.
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[17]Chen R J,Huang M,Huang W Z,et al.Effect of calcining and Al doping on structure and conductivity of Li7La3Zr2O12[J].Solid State Ionics,2014,265(6):7-12.
[18]Hu Z,Liu H,Ruan H,et al.High Li-ion conductivity of Aldoped Li7La3Zr2O12,synthesized by solid-state reaction[J].Ceramics International,2016,42(10):12156-12160.
[19]Xia W,Xu B,Duan H,et al.Ionic conductivity and air stability of Al-doped Li7La3Zr2O12sintered in alumina and Pt crucibles[J].Acs Applied Materials&Interfaces,2016,8(8):5335-5342.
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[21]Elshinawi H,Paterson G W,Maclaren D A,et al.Low-temperature densification of Al-doped Li7La3Zr2O12:a reliable and controllable synthesis of fast-ion conducting garnets[J].Journal of Materials Chemistry A,2016,5(1):319-329.
[22]Deviannapoorani C,Dhivya L,Ramakumar S,et al.Lithium ion transport properties of high conductive tellurium substituted Li7La3Zr2O12,cubic lithium garnets[J].Journal of Power Sources,2013,240(1):18-25.
[23]Howard M A,Clemens O,Kendrick E,et al.Effect of Ga incorpo-ration on the structure Li ion conductivity of La3Zr2Li7O12[J].Dalton Transactions,2012,41(39):12048-12053.
[24]Rettenwander D,Geiger C A,Amthauer G.Synthesis and crystal chemistry of the fast Li-ion conductor Li7La3Zr2O12doped with Fe[J].ChemInform,2013,52(14):8005-8009.
[25]Sudo R,Nakata Y,Ishiguro K,et al.Interface behavior between garnet-type lithium-conducting solid electrolyte and lithium metal[J].Solid State Ionics,2014,262(1):151-154.
[26]Ohta S,Komagata S,Seki J,et al.All-solid-state lithium ion battery using garnet-type oxide and Li3BO3,solid electrolytes fabricated by screen-printing[J].Journal of Power Sources,2013,238(28):53-56.
[27]Shin R H,Son S I,Han Y S,et al.Sintering behavior of garnet-type Li7La3Zr2O12-Li3BO3,composite solid electrolytes for all-solid-state lithium batteries[J].Solid State Ionics,2017,301:10-14.
[2]Manthiram A,Yu X,Wang S.Lithium battery chemistries enabled by solid-state electrolytes[J].Nature Reviews Materials,2017,3(2):1-16.
[3]张金华,潘继民.无机固态电解质研究现状与应用展望[J].科技展望,2017,27(25):159-260.
[4]许阳阳,李全国,梁成都,等.硫化物固体电解质的研究进展[J].储能科学与技术,2016(5):649-658.
[5]Murugan R,Thangadurai V,Weppner W.Fast lithium ion conduction in garnet-type Li7La3Zr2O12[J].Angewandte Chemie,2007,34(27):437-440.
[6]Ohta S,Kobayashi T,Asaoka T.High lithium ionic conductivity in the garnet-type oxide Li7-XLa3(Zr2-XNbX)O12,(X=0-2)[J].Journal of Power Sources,2011,196(6):3342-3345.
[7]Murugan R,Thangadurai V,Weppner W.Fast lithium ion conduction in garnet-type Li7La3Zr2O12[J].Angewandte Chemie International Edition,2007,46(41):7778-7781.
[8]Cao Z,Cao X,Liu X,et al.Effect of Sb-Ba codoping on the ionic conductivity of Li7La3Zr2O12ceramic[J].Ceramics International,2015,41(5):6232-6236.
[9]Toda S,Ishiguro K,Shimonishi Y,et al.Low temperature cubic garnet-type CO2-doped Li7La3Zr2O12[J].Solid State Ionics,2013,233(7):102-106.
[10]Beak S W,Lee J M,Kim T Y,et al.Garnet related lithium-ion conductor processed by spark plasm sinte ring for all solid state batteries[J].J Power Sources,2014,249:197-206.
[11]Han X,Gong Y,Fu K,et al.Negating interfacial impedance in garnet-based solid-state Li metal batteries[J].Nature Materials,2017,16(5):572-579.
[12]Cao Z,Cao X,Liu X,et al.Effect of Sb-Ba codoping on the ionic conductivity of Li7La3Zr2O12ceramic[J].Ceramics International,2015,41(5):6232-6236.
[13]Beak S W,Lee J M,Kim T Y,et al.Garnet related lithium-ion conductor processed by spark plasm sinte ring for all solid state batteries[J].J Power Sources,2014,249(1):197-206.
[14]Zhao P,Wen Y,Cheng J,et al.A novel method for preparation of high dense tetragonal Li7La3Zr2O12[J].Journal of Power Sources,2017,344:56-61.
[15]Lee C H,Park G J,Choi J H,et al.Low temperature synthesis of garnet type solid electrolyte by modified polymer complex process and its characterization[J].Materials Research Bulletin,2016,83:309-315.
[16]Dermenci K B,eki9E,Turan S.Al stabilized Li7La3Zr2O12,solid electrolytes for all-solid state Li-ion batteries[J].International Journal of Hydrogen Energy,2016,41(23):9860-9867.
[17]Chen R J,Huang M,Huang W Z,et al.Effect of calcining and Al doping on structure and conductivity of Li7La3Zr2O12[J].Solid State Ionics,2014,265(6):7-12.
[18]Hu Z,Liu H,Ruan H,et al.High Li-ion conductivity of Aldoped Li7La3Zr2O12,synthesized by solid-state reaction[J].Ceramics International,2016,42(10):12156-12160.
[19]Xia W,Xu B,Duan H,et al.Ionic conductivity and air stability of Al-doped Li7La3Zr2O12sintered in alumina and Pt crucibles[J].Acs Applied Materials&Interfaces,2016,8(8):5335-5342.
[20]Djenadic R,Botros M,Benel C,et al.Nebulized spray pyrolysis of Al-doped Li7La3Zr2O12,solid electrolyte for battery applications[J].Solid State Ionics,2014,263(10):49-56.
[21]Elshinawi H,Paterson G W,Maclaren D A,et al.Low-temperature densification of Al-doped Li7La3Zr2O12:a reliable and controllable synthesis of fast-ion conducting garnets[J].Journal of Materials Chemistry A,2016,5(1):319-329.
[22]Deviannapoorani C,Dhivya L,Ramakumar S,et al.Lithium ion transport properties of high conductive tellurium substituted Li7La3Zr2O12,cubic lithium garnets[J].Journal of Power Sources,2013,240(1):18-25.
[23]Howard M A,Clemens O,Kendrick E,et al.Effect of Ga incorpo-ration on the structure Li ion conductivity of La3Zr2Li7O12[J].Dalton Transactions,2012,41(39):12048-12053.
[24]Rettenwander D,Geiger C A,Amthauer G.Synthesis and crystal chemistry of the fast Li-ion conductor Li7La3Zr2O12doped with Fe[J].ChemInform,2013,52(14):8005-8009.
[25]Sudo R,Nakata Y,Ishiguro K,et al.Interface behavior between garnet-type lithium-conducting solid electrolyte and lithium metal[J].Solid State Ionics,2014,262(1):151-154.
[26]Ohta S,Komagata S,Seki J,et al.All-solid-state lithium ion battery using garnet-type oxide and Li3BO3,solid electrolytes fabricated by screen-printing[J].Journal of Power Sources,2013,238(28):53-56.
[27]Shin R H,Son S I,Han Y S,et al.Sintering behavior of garnet-type Li7La3Zr2O12-Li3BO3,composite solid electrolytes for all-solid-state lithium batteries[J].Solid State Ionics,2017,301:10-14.