二维晶体材料MXenes的合成、性能和应用研究进展
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摘要
近年来,MXene材料因具有独特的结构和优异的特性越来越受到研究人员的关注,对其研究也不断深入。MXene材料是由M_(n+1)AX_n(n=1,2,3…)相刻蚀得到,目前已有化学液相常压刻蚀法、水热刻蚀法和高温分解等制备方法。研究发现MXene拥有优良的导电性、稳定性、磁性能以及力学性能,被广泛的应用于储能、催化、吸附等应用领域。本文主要综述了MXene的基础理论、制备方法、结构性能以及其在各领域的应用研究进展,并对以后的发展和面临的问题做出了展望。
MXene materials have attracted more and more attention and researched also more in-depth because of their unique structure and excellent properties in recent years. MXene is etched by the M_(n+1)AX_n( n = 1,2,3…) phase. At present,there have chemical liquid etching,hydrothermal etching and high temperature decomposition synthetic methods. MXene has been found to have good electrical conductivity,stability,magnetic and mechanical properties,and thus they are promising in many fields,including energy storage,catalysis and adsorption. There mainly summarize the theoretical study,preparation method,structural properties and applications of MXene materials,and predict the problems in the future development.
MXene materials have attracted more and more attention and researched also more in-depth because of their unique structure and excellent properties in recent years. MXene is etched by the M_(n+1)AX_n( n = 1,2,3…) phase. At present,there have chemical liquid etching,hydrothermal etching and high temperature decomposition synthetic methods. MXene has been found to have good electrical conductivity,stability,magnetic and mechanical properties,and thus they are promising in many fields,including energy storage,catalysis and adsorption. There mainly summarize the theoretical study,preparation method,structural properties and applications of MXene materials,and predict the problems in the future development.
引文
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[2]李正阳,周爱国,王李波,等.二维晶体MXene的制备与性能研究进展[J].硅酸盐通报,2013,32(8):1562-1566.
[3]孙正明.《MAX相与MXene专辑》序[J].现代技术陶瓷,2017,38(1):1-2.
[4]郑伟,杨丽,张培根,等.二维材料MXene的储能性能与应用[J].材料导报,2018,32(15):2513-2537.
[5] Lipatov A,Lu H,Alhabeb M,et al. Elastic Properties of 2D Ti3C2TXMXene Monolayers and Bilayers[J]. Science Advances,2018,4(6):1-7.
[6] Wang C,Xie H,Chen S,et al. Atomic Cobalt Covalently Engineered Interlayers for Superior Lithium-Ion Storage[J]. Advanced Materials,2018,30(32):1802525.
[7] Zhang H,Wang L B,Shen C J,et al. Synthesis of Na V6O15Nanorods via Thermal Oxidation of Sodium-intercalated 2D V2CTXand Their ElectrochemicalProperties as Anode for Lithium-ion Batteries[J]. Electrochimica Acta,2017,248:178-187.
[8] Kent P,Anasori B,Xie Y,et al. Two-dimensional,Ordered,DoubleTransition Metals Carbides(MXenes)[J]. Acs Nano,2015,9(10):9507-9516.
[9] Novoselov K S,Geim A K,Morozov S V,et al. Electric Field Effect in Atomically Thin Carbon Films[J]. Science,2004,306(5696):666-669.
[10] Naguib M,Kurtoglu M,Presser V,et al. Two-Dimensional Nanocrystals Produced by Exfoliation of Ti3Al C2[J]. Advanced Materials,2011,42(52):4248-4253.
[11] Tran M H,Schfer T,Shahraei A,et al. Adding a New Member to the MXene Family:Synthesis,Structure and Electrocatalytic Activity for the Hydrogen Evolution Reaction of V4C3TX[J]. Acs Applied Materials&Interfaces,2018,1(8):3908-3914.
[12] Naguib M,MochalinV N,Barsoum M W,et al. Two-Dimensional Materials:25th Anniversary Article:MXenes:A New Family of TwoDimensional Materials[J]. Advanced Materials,2014,26(7):982-982.
[13] Naguib M,Mashtalir O,Carle,J,et al. Two-Dimensional Transition Metal Carbides[J]. Acs Nano,2012,6(2):1322-1331.
[14] Naguib M,Halim J,Lu J,et al. New Two-dimensional Niobium and Vanadium Carbides as Promising Materials for Li-ion a Btteries[J]. Journal of the American Chemical Society,2013,135(43):15966-15969.
[15] Tahatijerina J,Narayanan T N,Gao G H,et al. Electrically Insulating Thermal Nano-Oils Using 2D Fillers[J]. Acs Nano,2012,6(2):1214-1220.
[16]申长洁,王李波,张恒,等.二维晶体材料MXene的电化学应用研究进展[J].材料导报,2016,30(19):148-153.
[17] Sun D D,Hu Q K,Li Z Y,et al. Research Progress of New Two-dimensional MXene Crystals[J]. Journal of Synthetic Crystals,2014,43(11):2950-2956.
[18] Ghidiu M,Lukatskaya M R,Zhao M Q,et al. Conductive Two-dimensional Titanium Carbide/`Clay/'with High Volumetric Capacitance[J].Nature,2014,516(7529):78-81.
[19] Hu M,Hu T,Li Z,et al. Surface Functional Groups and Interlayer Water Determine the Electrochemical Capacitance of Ti3C2TXMXene[J].Acs Nano,2018,12(4):3578-3586.
[20] Maleski K,Ren C E,Zhao M Q,et al. Size-Dependent Physical and Electrochemical Properties of Two-Dimensional MXene Flakes[J]. Acs Applied Materials&Interfaces,2018,10(29):24491-24498.
[21] Xie J,Wang X H,Li A J,et al. Corrosion Behavior of Selected Mn+1AXnPhases in Hot Concentrated HCl Solution:Effect of A element and MX layer[J]. Corrosion Science,2012,60(7):129-135.
[22] Wang L B,Zhang H,Wang B,et al. Synthesis and Electrochemical Performance of Ti3C2TXwith Hydrothermal Process[J]. Electronic Materials Letters,2016,12(5):1-9.
[23] Peng J,Chen X Z,Ong Wee-Jun,et al. Surface and Heterointerface Engineering of 2D MXenes and Their Nanocomposites:Insights into Electroand Photocatalysis[J]. Chem,2019,5(1):18-50.
[24] Li T F,Yao L L,Liu Q L,et al. Fluorine-Free Synthesis of High-Purity Ti3C2TX(T=OH,O)via Alkali Treatment[J]. Angew Chem Int Ed Engl,2018,57(21):6115-6119.
[25] Naguib M,Presser V,Tallman D,et al. On the Topotactic Transformation of Ti2Al C into a Ti-C-O-F Cubic Phase by Heating in Molten Lithium Fluoride in Air[J]. Journal of the American Ceramic Society,2011,94(12):4556-4561.
[26] Naguib M,Unocic R R,Armstrong B L,et al. Large-scale Delamination of Multi-layers Transition Metal Carbides and Carbonitrides"MXenes"[J]. Dalton Transactions,2015,44(20):9353-9358.
[27] Barsoum,M W. The Topotactic Transformation of Ti[sub 3]SiC[sub 2]into a Partially Ordered Cubic Ti(C[sub 0. 67]Si[sub 0. 06])Phase by the Diffusion of Si into Molten Cryolite[J]. Journal of the Electrochemical Society,1999,146(10):3919-3923.
[28] Shein I R,Ivanovskii A L. Graphene-like Titanium Carbides and Nitrides Tin+1Cn,Tin+1Nn(n=1,2,and 3)from De-intercalated MAX Phases:First-principles Probing of Their Structural,Electronic Properties and Relative Stability[J]. Computational Materials Science,2012,65:104-114.
[29] Michael N,Mashtalir L,Maria R,et al. One-step Synthesis of Nanocrystalline Transition Metal Oxides on Thin Sheets of Disordered Graphitic Carbon by Oxidation of MXenes[J]. Chemical Communications,2014,50(56):7420-7423.
[30]刘凡凡,周爱国,陈进峰,等.二维结构MXene温和制备及吸附催化领域的应用[J].兵器材料科学与工程[J],2016,39(1):120-124.
[31] Kurtoglu M,Naguib M,Gogotsi Y,et al. First Principles Study of Two-dimensional Early Transition Metal Carbides[J]. Mrs Communications,2012,2(4):133-137.
[32] Zha X H,Huang Q,He Jian,et al. Promising Electron Mobility and High Thermal Conductivity in Sc2CT2(T=F,OH)MXenes[J].Nanoscale,2016,8(11):6110-6117.
[33] Khazaei M,Ranjbar A,Ghorbaniasl M,et al. Nearly Free Electron States in MXenes[J]. Physical Review B,2016,93(20):205125.
[34] Zha X H,Huang Q,He Jian,et al. The Thermal and Electrical Properties of the Promising Semiconductor MXene Hf2CO2[J]. Scientific Reports,2016,6:27971.
[35] Khazaei M,Arai M,Sasaki T,et al. Novel Electronic and Magnetic Properties of Two-Dimensional Transition Metal Carbides and Nitrides[J].Advanced Functional Materials,2013,23(17):2185-2192.
[36] Wang H,Wu Y,Yuan X Z,et al. Clay-Inspired MXene-Based Electrochemical Devices and Photo-Electrocatalyst:State-of-the-Art Progresses and Challenges[J]. Advanced Materials,2018,30(12):1704561.
[37] Lukatskaya M R,Mashtalir O,Ren C E,et al. Cation Intercalation and Hhigh Volumetric Capacitance of Two-dimensional Titanium Carbide[J]. Science,2013,341(6153):1502-1505.
[38] Mashtalir O, Naguib M, Mochalin V N, et al. Intercalation and Delamination of Layered Carbides and Carbonitrides[J]. Nature Communications,2013,4:1716.
[39] Naguib M,Come J,Dyatkin B,et al. MXene:A Promising Transition Metal Carbide Anode for Lithium-ion Batteries[J]. Electrochemistry Communications,2012,16(1):61-64.
[40] Sun D D,Wang M S,Li Z Y,et al. Two-dimensional Ti3C2as Anode Material for Li-ion Batteries[J]. Electrochemistry Communications,2014,47(10):80-83.
[41] Kent P,Xie Yu,Zhuang H L,et al. Prediction and Characterization of MXenes for Non-lithium Ion Battery Anodes[J]. Acs Nano,2014,8(9):9606-9615.
[42] Dall'Agnese Y,Lukatskaya M R,Cook,Kevin M,et al. High Capacitance of Surface-modified 2D Titanium Carbide in Acidic Electrolyte[J].Electrochemistry Communications,2014,48(48):118-122.
[43] Tang Y,Zhu J F,Wu W L,et al. Synthesis of Nitrogen-Doped Two-Dimensional Ti3C2with Enhanced Electrochemical Performance[J]. Journal of the Electrochemical Society,2017,164(4):A923-A929.
[44] Mashtalir O,Cook K M,Mochalin V N,et al. Dye Adsorption and Decomposition on Two-dimensional Titanium Carbide in Aqueous Media[J].Journal of Materials Chemistry A,2014,2(35):14334-14338.
[45]彭超.二维过渡金属碳化物(MXene)基光催化剂的制备、性能与催化机理研究[D].华南理工大学,2017.
[46] Li X J,Fan G Y,Zeng C M,et al. Synthesis of Ruthenium Nanoparticles Deposited on Graphene-like Transition Metal Carbide as An Effective Catalyst for the Hydrolysis of Sodium Borohydride[J]. International Journal of Hydrogen Energy,2014,39(27):14927-14934.
[47] Peng Q,Guo J,Zhang Q,et al. Unique Lead Adsorption Behavior of Activated Hydroxyl Group in Two-dimensional Titanium Carbide[J].Journal of the American Chemical Society,2014,136(11):4113-4116.
[48]申长洁,高誉鹏,王李波,等.二维晶体Ti3C2的制备及其对有机染料的吸附性能研究[J].人工晶体学报,2016,45(7):1812-1819.
[49] Sobolciak P,Ali A,Hassan M K,et al. 2D Ti3C2TX(MXene)-reinforced Polyvinyl Alcohol(PVA)Nanofibers with Enhanced Mechanical and Eelectrical Properties[J]. Plos One,2017,12(8):e0183705.
[50] Ling Z,Ren C E,Zhao M Q,et al. Flexible and Conductive MXene Films and Nanocomposites with High Capacitance[J]. Proceedings of the National Academy of Science,2014,111(47):16676-16681.
[51] Zhang H,Wang L B,Chen Q,et al. Preparation,Mechanical and Anti-friction Performance of MXene/Polymer Composites[J]. Materials&Design,2016,92(11):682-689.
[52] Yuan W,Cheng L F,Zhang B X,et al. 2D-Ti3C2as Hard,Conductive Substrates to Enhance the Electrochemical Performance of MnO2for Supercapacitor Applications[J]. Ceramics International,2018,44(14):17539-17543.
[53]朱元元,王李波,张恒,等. MXene材料的制备及其对液体石蜡润滑性能的研究[J].硅酸盐通报,2015,34(10):2940-2944.
[54] Fang Y F,Yang X C,Chena T,et al. Two-dimensional titanium carbide(MXene)-based solid-state electrochemiluminescent sensor for label-free single-nucleotide mismatch discrimination in human urine[J]. Sensors and Actuators B:Chemical,2018,263:400-407.
[55] Liu F F,Zhou A G,Chen J F,et al. Preparation of Ti3C2and Ti2C MXenes by Fluoride Salts Etching and Methane Adsorptive Properties[J].Applied Surface Science,2017,416:781-789.
[56] Ran J,Gao G,Li F T,et al. Ti3C2MXene Co-catalyst on Metal Sulfide Photo-absorbers for Enhanced Visible-light Photocatalytic Hydrogen Production[J]. Nature Communications,2017,8:13907.
[57] Kim S J,Koh H J,Ren C E,et al. Metallic Ti3C2TXMXene Gas Sensors with Ultrahigh Signal-to-oise Ratio[J]. Acs Nano,2018,12(2):986-993.
[58] Lee E,Vahidmohammadi A,Prorok B C,et al. Room Temperature Gas-Sensing of Two-Dimensional Titanium Carbide(MXene). Acs Applied Materials&Interfaces,2017,9(42):37184-37190.
[2]李正阳,周爱国,王李波,等.二维晶体MXene的制备与性能研究进展[J].硅酸盐通报,2013,32(8):1562-1566.
[3]孙正明.《MAX相与MXene专辑》序[J].现代技术陶瓷,2017,38(1):1-2.
[4]郑伟,杨丽,张培根,等.二维材料MXene的储能性能与应用[J].材料导报,2018,32(15):2513-2537.
[5] Lipatov A,Lu H,Alhabeb M,et al. Elastic Properties of 2D Ti3C2TXMXene Monolayers and Bilayers[J]. Science Advances,2018,4(6):1-7.
[6] Wang C,Xie H,Chen S,et al. Atomic Cobalt Covalently Engineered Interlayers for Superior Lithium-Ion Storage[J]. Advanced Materials,2018,30(32):1802525.
[7] Zhang H,Wang L B,Shen C J,et al. Synthesis of Na V6O15Nanorods via Thermal Oxidation of Sodium-intercalated 2D V2CTXand Their ElectrochemicalProperties as Anode for Lithium-ion Batteries[J]. Electrochimica Acta,2017,248:178-187.
[8] Kent P,Anasori B,Xie Y,et al. Two-dimensional,Ordered,DoubleTransition Metals Carbides(MXenes)[J]. Acs Nano,2015,9(10):9507-9516.
[9] Novoselov K S,Geim A K,Morozov S V,et al. Electric Field Effect in Atomically Thin Carbon Films[J]. Science,2004,306(5696):666-669.
[10] Naguib M,Kurtoglu M,Presser V,et al. Two-Dimensional Nanocrystals Produced by Exfoliation of Ti3Al C2[J]. Advanced Materials,2011,42(52):4248-4253.
[11] Tran M H,Schfer T,Shahraei A,et al. Adding a New Member to the MXene Family:Synthesis,Structure and Electrocatalytic Activity for the Hydrogen Evolution Reaction of V4C3TX[J]. Acs Applied Materials&Interfaces,2018,1(8):3908-3914.
[12] Naguib M,MochalinV N,Barsoum M W,et al. Two-Dimensional Materials:25th Anniversary Article:MXenes:A New Family of TwoDimensional Materials[J]. Advanced Materials,2014,26(7):982-982.
[13] Naguib M,Mashtalir O,Carle,J,et al. Two-Dimensional Transition Metal Carbides[J]. Acs Nano,2012,6(2):1322-1331.
[14] Naguib M,Halim J,Lu J,et al. New Two-dimensional Niobium and Vanadium Carbides as Promising Materials for Li-ion a Btteries[J]. Journal of the American Chemical Society,2013,135(43):15966-15969.
[15] Tahatijerina J,Narayanan T N,Gao G H,et al. Electrically Insulating Thermal Nano-Oils Using 2D Fillers[J]. Acs Nano,2012,6(2):1214-1220.
[16]申长洁,王李波,张恒,等.二维晶体材料MXene的电化学应用研究进展[J].材料导报,2016,30(19):148-153.
[17] Sun D D,Hu Q K,Li Z Y,et al. Research Progress of New Two-dimensional MXene Crystals[J]. Journal of Synthetic Crystals,2014,43(11):2950-2956.
[18] Ghidiu M,Lukatskaya M R,Zhao M Q,et al. Conductive Two-dimensional Titanium Carbide/`Clay/'with High Volumetric Capacitance[J].Nature,2014,516(7529):78-81.
[19] Hu M,Hu T,Li Z,et al. Surface Functional Groups and Interlayer Water Determine the Electrochemical Capacitance of Ti3C2TXMXene[J].Acs Nano,2018,12(4):3578-3586.
[20] Maleski K,Ren C E,Zhao M Q,et al. Size-Dependent Physical and Electrochemical Properties of Two-Dimensional MXene Flakes[J]. Acs Applied Materials&Interfaces,2018,10(29):24491-24498.
[21] Xie J,Wang X H,Li A J,et al. Corrosion Behavior of Selected Mn+1AXnPhases in Hot Concentrated HCl Solution:Effect of A element and MX layer[J]. Corrosion Science,2012,60(7):129-135.
[22] Wang L B,Zhang H,Wang B,et al. Synthesis and Electrochemical Performance of Ti3C2TXwith Hydrothermal Process[J]. Electronic Materials Letters,2016,12(5):1-9.
[23] Peng J,Chen X Z,Ong Wee-Jun,et al. Surface and Heterointerface Engineering of 2D MXenes and Their Nanocomposites:Insights into Electroand Photocatalysis[J]. Chem,2019,5(1):18-50.
[24] Li T F,Yao L L,Liu Q L,et al. Fluorine-Free Synthesis of High-Purity Ti3C2TX(T=OH,O)via Alkali Treatment[J]. Angew Chem Int Ed Engl,2018,57(21):6115-6119.
[25] Naguib M,Presser V,Tallman D,et al. On the Topotactic Transformation of Ti2Al C into a Ti-C-O-F Cubic Phase by Heating in Molten Lithium Fluoride in Air[J]. Journal of the American Ceramic Society,2011,94(12):4556-4561.
[26] Naguib M,Unocic R R,Armstrong B L,et al. Large-scale Delamination of Multi-layers Transition Metal Carbides and Carbonitrides"MXenes"[J]. Dalton Transactions,2015,44(20):9353-9358.
[27] Barsoum,M W. The Topotactic Transformation of Ti[sub 3]SiC[sub 2]into a Partially Ordered Cubic Ti(C[sub 0. 67]Si[sub 0. 06])Phase by the Diffusion of Si into Molten Cryolite[J]. Journal of the Electrochemical Society,1999,146(10):3919-3923.
[28] Shein I R,Ivanovskii A L. Graphene-like Titanium Carbides and Nitrides Tin+1Cn,Tin+1Nn(n=1,2,and 3)from De-intercalated MAX Phases:First-principles Probing of Their Structural,Electronic Properties and Relative Stability[J]. Computational Materials Science,2012,65:104-114.
[29] Michael N,Mashtalir L,Maria R,et al. One-step Synthesis of Nanocrystalline Transition Metal Oxides on Thin Sheets of Disordered Graphitic Carbon by Oxidation of MXenes[J]. Chemical Communications,2014,50(56):7420-7423.
[30]刘凡凡,周爱国,陈进峰,等.二维结构MXene温和制备及吸附催化领域的应用[J].兵器材料科学与工程[J],2016,39(1):120-124.
[31] Kurtoglu M,Naguib M,Gogotsi Y,et al. First Principles Study of Two-dimensional Early Transition Metal Carbides[J]. Mrs Communications,2012,2(4):133-137.
[32] Zha X H,Huang Q,He Jian,et al. Promising Electron Mobility and High Thermal Conductivity in Sc2CT2(T=F,OH)MXenes[J].Nanoscale,2016,8(11):6110-6117.
[33] Khazaei M,Ranjbar A,Ghorbaniasl M,et al. Nearly Free Electron States in MXenes[J]. Physical Review B,2016,93(20):205125.
[34] Zha X H,Huang Q,He Jian,et al. The Thermal and Electrical Properties of the Promising Semiconductor MXene Hf2CO2[J]. Scientific Reports,2016,6:27971.
[35] Khazaei M,Arai M,Sasaki T,et al. Novel Electronic and Magnetic Properties of Two-Dimensional Transition Metal Carbides and Nitrides[J].Advanced Functional Materials,2013,23(17):2185-2192.
[36] Wang H,Wu Y,Yuan X Z,et al. Clay-Inspired MXene-Based Electrochemical Devices and Photo-Electrocatalyst:State-of-the-Art Progresses and Challenges[J]. Advanced Materials,2018,30(12):1704561.
[37] Lukatskaya M R,Mashtalir O,Ren C E,et al. Cation Intercalation and Hhigh Volumetric Capacitance of Two-dimensional Titanium Carbide[J]. Science,2013,341(6153):1502-1505.
[38] Mashtalir O, Naguib M, Mochalin V N, et al. Intercalation and Delamination of Layered Carbides and Carbonitrides[J]. Nature Communications,2013,4:1716.
[39] Naguib M,Come J,Dyatkin B,et al. MXene:A Promising Transition Metal Carbide Anode for Lithium-ion Batteries[J]. Electrochemistry Communications,2012,16(1):61-64.
[40] Sun D D,Wang M S,Li Z Y,et al. Two-dimensional Ti3C2as Anode Material for Li-ion Batteries[J]. Electrochemistry Communications,2014,47(10):80-83.
[41] Kent P,Xie Yu,Zhuang H L,et al. Prediction and Characterization of MXenes for Non-lithium Ion Battery Anodes[J]. Acs Nano,2014,8(9):9606-9615.
[42] Dall'Agnese Y,Lukatskaya M R,Cook,Kevin M,et al. High Capacitance of Surface-modified 2D Titanium Carbide in Acidic Electrolyte[J].Electrochemistry Communications,2014,48(48):118-122.
[43] Tang Y,Zhu J F,Wu W L,et al. Synthesis of Nitrogen-Doped Two-Dimensional Ti3C2with Enhanced Electrochemical Performance[J]. Journal of the Electrochemical Society,2017,164(4):A923-A929.
[44] Mashtalir O,Cook K M,Mochalin V N,et al. Dye Adsorption and Decomposition on Two-dimensional Titanium Carbide in Aqueous Media[J].Journal of Materials Chemistry A,2014,2(35):14334-14338.
[45]彭超.二维过渡金属碳化物(MXene)基光催化剂的制备、性能与催化机理研究[D].华南理工大学,2017.
[46] Li X J,Fan G Y,Zeng C M,et al. Synthesis of Ruthenium Nanoparticles Deposited on Graphene-like Transition Metal Carbide as An Effective Catalyst for the Hydrolysis of Sodium Borohydride[J]. International Journal of Hydrogen Energy,2014,39(27):14927-14934.
[47] Peng Q,Guo J,Zhang Q,et al. Unique Lead Adsorption Behavior of Activated Hydroxyl Group in Two-dimensional Titanium Carbide[J].Journal of the American Chemical Society,2014,136(11):4113-4116.
[48]申长洁,高誉鹏,王李波,等.二维晶体Ti3C2的制备及其对有机染料的吸附性能研究[J].人工晶体学报,2016,45(7):1812-1819.
[49] Sobolciak P,Ali A,Hassan M K,et al. 2D Ti3C2TX(MXene)-reinforced Polyvinyl Alcohol(PVA)Nanofibers with Enhanced Mechanical and Eelectrical Properties[J]. Plos One,2017,12(8):e0183705.
[50] Ling Z,Ren C E,Zhao M Q,et al. Flexible and Conductive MXene Films and Nanocomposites with High Capacitance[J]. Proceedings of the National Academy of Science,2014,111(47):16676-16681.
[51] Zhang H,Wang L B,Chen Q,et al. Preparation,Mechanical and Anti-friction Performance of MXene/Polymer Composites[J]. Materials&Design,2016,92(11):682-689.
[52] Yuan W,Cheng L F,Zhang B X,et al. 2D-Ti3C2as Hard,Conductive Substrates to Enhance the Electrochemical Performance of MnO2for Supercapacitor Applications[J]. Ceramics International,2018,44(14):17539-17543.
[53]朱元元,王李波,张恒,等. MXene材料的制备及其对液体石蜡润滑性能的研究[J].硅酸盐通报,2015,34(10):2940-2944.
[54] Fang Y F,Yang X C,Chena T,et al. Two-dimensional titanium carbide(MXene)-based solid-state electrochemiluminescent sensor for label-free single-nucleotide mismatch discrimination in human urine[J]. Sensors and Actuators B:Chemical,2018,263:400-407.
[55] Liu F F,Zhou A G,Chen J F,et al. Preparation of Ti3C2and Ti2C MXenes by Fluoride Salts Etching and Methane Adsorptive Properties[J].Applied Surface Science,2017,416:781-789.
[56] Ran J,Gao G,Li F T,et al. Ti3C2MXene Co-catalyst on Metal Sulfide Photo-absorbers for Enhanced Visible-light Photocatalytic Hydrogen Production[J]. Nature Communications,2017,8:13907.
[57] Kim S J,Koh H J,Ren C E,et al. Metallic Ti3C2TXMXene Gas Sensors with Ultrahigh Signal-to-oise Ratio[J]. Acs Nano,2018,12(2):986-993.
[58] Lee E,Vahidmohammadi A,Prorok B C,et al. Room Temperature Gas-Sensing of Two-Dimensional Titanium Carbide(MXene). Acs Applied Materials&Interfaces,2017,9(42):37184-37190.