聚合物共混物及纳米粒子选择性分布研究进展
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摘要
随着世界经济的进步与发展,社会对材料性能的要求也越来越高,复合材料已经逐渐取代单一聚合物材料。自20世纪60年代以来,纳米材料因其优异的性能,得到广泛人们关注,使得纳米复合材料成为了科学研究的新宠。然而,在不相容共混物中,纳米粒子的加入会存在选选择性分布的问题。本文综述了国内外聚合物纳米复合材料以及以及纳米粒子选择性分布研究,并对其发展趋势进行了展望。
With the progress and development of the world economy,the social requirements of the material performance are getting higher and higher,the composite material has gradually replaced single polymer material.Since the 1990 s,nano-materials,because of its excellent performance,has been widespread concern,making nanocomposites become the new darling of scientific research.However,in the incompatible blends,the addition of nanoparticles will have a problem of selective distribution.The polymer nanocomposites and the selective distribution of nanoparticles were reviewed,and the development trend of polymer nanocomposites was discussed.
With the progress and development of the world economy,the social requirements of the material performance are getting higher and higher,the composite material has gradually replaced single polymer material.Since the 1990 s,nano-materials,because of its excellent performance,has been widespread concern,making nanocomposites become the new darling of scientific research.However,in the incompatible blends,the addition of nanoparticles will have a problem of selective distribution.The polymer nanocomposites and the selective distribution of nanoparticles were reviewed,and the development trend of polymer nanocomposites was discussed.
引文
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[3]Zou Hao,Ning Nanying,Su Run,et al.Manipulating the phase morphology in PPS/PA66 blends using clay[J].Journal of Applied Polymer Science,2007,106(4):2238-2250.
[4]Jarnthong Methakarn,Nakason Charoen,Lopattananon Natinee,et al.Influence of incorporation sequence of silica nanoparticles on morphology,crystallization behavior,mechanical properties,and thermal resistance of melt blended thermoplastic natural rubber[J].Polymer Composites,2012,33(11):1911-1920.
[5]Khare Rupesh A,Bhattacharyya Arup R,Panwar Ajay S,et al.Dispersion of multiwall carbon nanotubes in blends of polypropylene and acrylonitrile butadiene styrene[J].Polymer Engineering&Science,2011,51(9):1891-1905.
[6]Filippone G,Dintcheva N,Acierno D,et al.The role of organoclay in promoting co-continuous morphology in high-density poly(ethylene)/poly(amide)6 blends[J].Polymer,2008,49(5):1312-1322.
[7]Newnham R E,Skinner D P,Cross L E.Connectivity and piezoelectricpyroelectric composites[J].Mater Res.Bul.,1978,13(5):525-536.
[8]王树彬,徐廷献,韩杰才,等.PZT/PVDF压电复合材料的制备及其性能研究[J].复合材料学报,2000,17(4):1-5.
[9]Hu G,Lijowski M,Zhang H,et al.Imaging of Vx-2 rabbit tumors withανβ3-integrin-targeted111In nanoparticles[J].Int J Cancer.,2007,120(9):1951-1957.
[10]Gupya AK,Srinivasan KR.Melt rheology and morphology of PP/SEBS/PC ternary blend[J].J Appl.Polym.Sci.,1993,47(1):167-184.
[11]Gubbels F,Jerome R,Teyssie P,et al.Selective Localization of Carbon Black in Immiscible Polymer Blends:A Useful Tool To Design Electrical Conductive Composites[J].Macromolecules,1994,27:1972-1974.
[12]Bose Suryasarathi,Bhattacharyya Arup R,Khare Rupesh A,et al.The role of specific interaction and selective localization of multiwall carbon nanotubes on the electrical conductivity and phase morphology of multicomponent polymer blends[J].Polymer Engineering&Science,2011,51(10):1987-2000.
[13]Xu Z H,Zhang Y,Wang Z,et al.Enhancement of Electrical Conductivity by Changing phase Morphology for Composites Consisting of Polylactide and Poly(ε-caprolactone)Filled with Acid-Oxidized Multiwalled Carbon Nanotubes[J].ACS Appl Mater Interfaces,2011,3(12):4858-4864.
[14]Wu Defeng,Zhang Yisheng,Zhang Ming,et al.Selective Localization of Multiwalled Carbon Nanotubes in Poly(ε-caprolactone)/Polylactide Blend[J].Biomacromolecules,2009,10:417-424.
[15]杨波,陈晓浪,陈光顺,等.导电炭黑填充PP-EAA复合材料的形态及电性能[J].复合材料学报,2007,24(3):78-83.
[16]Cayla A,Campagne C,Rochery M,et al.Melt spun multifilament yarns of carbon nanotubes-based polymeric blends:Electrical,mechanical and thermal properties[J].Synthetic Metals,2012,162(9-10):759-767.