金属有机骨架材料MOF-808(Zr)的制备与表征
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摘要
文章主要阐述了用微波辐射晶化法合成Zr_6O_4(BTC)_2(HCOO)_6(MOF-808(Zr))纳米颗粒。并通过XRD、N_2吸脱附、FT-IR和SEM等表征技术进行了系统地表征。表征结果:证明该方法能成功地合成出MOF-808(Zr)。
The paper reviews a metal-organic framework Zr_6O_4(BTC)_2(HCOO)_6(MOF-808(Zr)) nanoparticles by using a microwave irradiation method. The obtained MOF-808(Zr) was systematically characterized by XRD, N_2 adsorption-desorption, FT-IR, and SEM techniques. The method has been tested to be feasible by the results of simulation.
The paper reviews a metal-organic framework Zr_6O_4(BTC)_2(HCOO)_6(MOF-808(Zr)) nanoparticles by using a microwave irradiation method. The obtained MOF-808(Zr) was systematically characterized by XRD, N_2 adsorption-desorption, FT-IR, and SEM techniques. The method has been tested to be feasible by the results of simulation.
引文
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[2]Furukawa H,Gandara F,Zhang Y B,et al.Water adsorption in porous metal-organic frameworks and related materials[J].Journal of the American Chemical Society,2014,136(11):4369-4381.
[3]Abid H R,Tian H,Ang H-M,et al.Nanosize Zr-metal organic framework(Ui O-66)for hydrogen and carbon dioxide storage[J].Chemical Engineering Journal,2012,187:415-420.
[4]Ebrahim A M,Bandosz T J.Ce(III)doped Zr-based MOFs as excellent NO2adsorbents at ambient conditions[J].ACS Applied Materials&Interfaces,2013,5(21):10565-10573.
[5]Shi J,Hei S,Liu H,et al.Synthesis of MIL-100(Fe)at Low Temperature and Atmospheric Pressure[J].Journal of Chemistry,2013,2013:1-4.
[6]Dipendu Saha S D.Structural Stability of Metal Organic Framework MOF-177[J].The Journal of Physical Chemistry Letters,2010,1:73-78.
[7]Moon S Y,Liu Y,Hupp J T,et al.Instantaneous hydrolysis of nerve-agent simulants with a six-connected zirconium-based metal-organic framework[J].Angewandte Chemie International Edition,2015,54(23):6795-6799.
[8]Zongqun Li N J Y,Kewen Sui,Na Yin.Facile synthesis of metal-organic framework MOF-808 for arsenic removal[J].Materials Letters,2015,160:412-414.