基于碱金属的金属-有机框架(MOFs)研究进展
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摘要
综述了近十几年来基于碱金属的金属-有机框架(metal-organic frameworks,MOFs)研究进展.由于碱金属MOFs在气体吸附相关方面拥有优异性能,近年来引起了研究者的广泛关注.主要介绍了碱金属MOFs的合成、结构、性质和潜在应用.其中,着重介绍了碱金属MOFs的结构以及在氢气(H_2)和二氧化碳(CO_2)等气体吸附储存方面的研究,简要介绍了碱金属MOFs在气体分离与荧光检测等方面的潜在应用,还阐述了掺杂碱金属后的MOFs对H_2吸附性能的影响.最后,对碱金属MOFs今后的发展进行了展望.
The research progress of alkali metal-based metal-organic frameworks( MOFs) in recent years is summarized in this paper. Alkali metal-based MOFs have attracted considerable attention due to their excellent performance in gas adsorption related field. In this review,the synthesis,structure,properties,and potential applications of alkali metal-based MOFs were introduced. Among them,the structure of the MOFs and the research on gas adsorption and storage including H_2 and CO_2 were emphasized and the gas separation and fluorescence detection were briefly reviewed. In addition,MOFs doped with alkali metal for H_2 sorption was also introduced. At the same time,the development trend of alkali metal-based MOFs was prospected.
The research progress of alkali metal-based metal-organic frameworks( MOFs) in recent years is summarized in this paper. Alkali metal-based MOFs have attracted considerable attention due to their excellent performance in gas adsorption related field. In this review,the synthesis,structure,properties,and potential applications of alkali metal-based MOFs were introduced. Among them,the structure of the MOFs and the research on gas adsorption and storage including H_2 and CO_2 were emphasized and the gas separation and fluorescence detection were briefly reviewed. In addition,MOFs doped with alkali metal for H_2 sorption was also introduced. At the same time,the development trend of alkali metal-based MOFs was prospected.
引文
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[19] TAYLOR K M,RIETER W J,LIN W. Manganese-based nanoscale metal-organic frameworks for magnetic resonance imaging[J]. Journal of the American Chemical Society,2008,130(44):14358-14359.
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