MOFs作为催化剂在乙烯选择性齐聚中的应用进展
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摘要
随着MOFs在催化领域的蓬勃发展,已有MOFs作为催化剂用于乙烯选择性齐聚中。根据乙烯齐聚活性中心与MOFs骨架的联接方式,MOFs乙烯选择性齐聚催化剂可分为接枝型、负载型和本体型三类,分别综述了它们的应用。同时介绍了MOFs乙烯选择性齐聚遵循的两种催化机理:金属环机理和单金属机理,最后对MOFs乙烯选择性齐聚催化剂进行了总结和展望。
With the rapid development of MOFs in the ?eld of catalysis,MOFs have been used as catalysts for the selective ethylene oligomerization. In this article,according to the connection types of ethylene oligomerization active center and MOFs' framework,the selective ethylene oligomerization MOFs catalysts are classified into three types:graft type,supported type and bulk type,which are introduced one by one. Subsequently,the two catalytic mechanisms followed by selective ethylene oligomerization over MOFs are briefly introduced:metallacyclic mechanism and Cossee-Arlman mechanism. Finally,the selective ethylene oligomerization MOFs catalysts are summarized and prospected.
With the rapid development of MOFs in the ?eld of catalysis,MOFs have been used as catalysts for the selective ethylene oligomerization. In this article,according to the connection types of ethylene oligomerization active center and MOFs' framework,the selective ethylene oligomerization MOFs catalysts are classified into three types:graft type,supported type and bulk type,which are introduced one by one. Subsequently,the two catalytic mechanisms followed by selective ethylene oligomerization over MOFs are briefly introduced:metallacyclic mechanism and Cossee-Arlman mechanism. Finally,the selective ethylene oligomerization MOFs catalysts are summarized and prospected.
引文
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[21]张乐,黄永旺,陈延辉,等.乙烯选择性齐聚机理研究进展[J].石油化工,2017,46(6):791-800.
[22]Manyik R M,Walker W E,Wilson T P.A soluble chromiumbased catalyst for ethylene trimerization and polymerization[J].J Catal,1977,47(2):197-209.
[23]Briggs J R.The selective trimerization of ethylene to hex-1-ene[J].J Chem Soc,Chem Commun,1989(11):674-675.
[24]Peitz S,Aluri B R,Peulecke N,et al.An alternative mechanistic concept for homogeneous selective ethylene oligomerization of chromium-based catalysts:Binuclear metallacycles as a reason for 1-octene selectivity?[J].Chem Eur J,2010,16(26):7670-7676.
[25]Britovsek G J P,McGuinness D S,Wierenga T S,et al.Single-and double-coordination mechanism in ethylene tri-and tetramerization with Cr/PNP catalysts[J].ACS Catal,2015,5(7):4152-4166.
[26]Metzger E D,Comito R J,Hendon C H,et al.Mechanism of single-site molecule-like catalytic ethylene dimerization in Ni-MFU-4l[J].J Am Chem Soc,2017,139(2):757-762.
[2]王如文,赵丹平,郑来昌,等.乙烯齐聚制线性α-烯烃的应用和研究现状[J].甘肃科技,2017,33(22):29-31,24.
[3]刘素丽,袁炜,罗春桃.α-烯烃的生产及应用[J].合成材料老化与应用,2016,45(3):132-135.
[4]Lee J Y,Farha O K,Roberts J.Metal-organic framework materials as catalysts[J].Chem Soc Rev,2009,38(5):1450-1459.
[5]Liu Bing,Jie Suyun,Bu Zhiyang,et al.Postsynthetic modification of mixed-linker metal-organic frameworks for ethylene oligomerization[J].RSC Adv,2014,4(107):62343-62346.
[6]Canivet J,Aguado S,Schuurman Y,et al.MOF-supported selective ethylene dimerization single-site catalysts through onepot postsynthetic modification[J].J Am Chem Soc,2013,135(11):4195-4198.
[7]Madrahimov S T,Gallagher J R,Zhang Guanghui,et al.Gas-phase dimerization of ethylene under mild conditions catalyzed by MOF materials containing(bpy)NiⅡcomplexes[J].ACS Catal,2015,5(11):6713-6718.
[8]Meilikhocv M,Yusenko K,Esken D,et al.Metals@MOFs-loading MOFs with metal nanoparticles for hybrid functions[J].Eur J Inorg Chem,2010(24):3701-3714.
[9]Li Zhangyong,Schweitzer N M,League A B,et al.Sinteringresistant single-site nickel catalyst supported by metal-organic framework[J].J Am Chem Soc,2016,138(6):1977-1982.
[10]Ye Jingyun,Gagliardi L,Ctamer C J,et al.Single Ni atoms and Ni4 clusters have similar catalytic activity for ethylene dimerization[J].J Catal,2017,354:278-286.
[11]Liu Suyan,Zhang Ying,Huo Quan,et al.Synthesis and catalytic performances of a novel Zn-MOF catalyst bearing nickel chelating diimine carboxylate ligands for ethylene oligomerization[J].Doi:10.1155/2015/310162.
[12]Bernales V,League A B,Li Zhangyong,et al.Computationally guided discovery of a catalytic cobalt-decorated metal-organic framework for ethylene dimerization[J].J Phys Chem C,2016,120(41):23576-23583.
[13]Bernales V,Yang D,Yu J,et al.Molecular rhodium complexes supported on the metal-oxide-like nodes of metal organic frameworks and on zeolite HY:Catalysts for ethylene hydrogenation and dimerization[J].ACS Appl Mater Interfaces,2017,9(39):33511-33520.
[14]Yang Dong,Odoh S O,Borycz J,et al.Tuning Zr6 MOFnodes as catalyst supports:Site densities and electron-donor properties influence molecular iridium complexes as ethylene conversion catalysts[J].ACS Catal,2015,6(1):235-247.
[15]Liu Suyan,Zhang Ying,Han Yang,et al.Selective ethylene oligomerization with chromium-based metal-organic framework MIL-100 evacuated under different temperatures[J].Organometallics,2017,36(3):632-638.
[16]Metzger E C,Brozek C K,Comito R J,et al.Selective dimerization of ethylene to 1-butene with a porous catalyst[J].ACS Central Sci,2016,2(3):148-153.
[17]Comito R J,Metzger E C,Wu Zhenwei,et al.Selective dimerization of propylene with Ni-MFU-4l[J].Organometallics,2017,36(9):1681-1683.
[18]Mlinar A N,Keitz B K,Gygi D,et al.Selective propene oligomerization with Nickel(Ⅱ)-based metal-organic frameworks[J].ACS Catal,2014,4(3):717-721.
[19]程阿超,韩阳,冯光亮,等.一维金属铁有机配位聚合物的乙烯选择性四聚催化性能研究[J].中国科学:化学,2017,47(10):1218-1225.
[20]Rozhko E,Bavykina A,Osadchii D,et al.Covalent organic frameworks as supports for a molecular Ni based ethylene oligomerization catalyst for the synthesis of long chain olefins[J].J Catal,2017,345:270-280.
[21]张乐,黄永旺,陈延辉,等.乙烯选择性齐聚机理研究进展[J].石油化工,2017,46(6):791-800.
[22]Manyik R M,Walker W E,Wilson T P.A soluble chromiumbased catalyst for ethylene trimerization and polymerization[J].J Catal,1977,47(2):197-209.
[23]Briggs J R.The selective trimerization of ethylene to hex-1-ene[J].J Chem Soc,Chem Commun,1989(11):674-675.
[24]Peitz S,Aluri B R,Peulecke N,et al.An alternative mechanistic concept for homogeneous selective ethylene oligomerization of chromium-based catalysts:Binuclear metallacycles as a reason for 1-octene selectivity?[J].Chem Eur J,2010,16(26):7670-7676.
[25]Britovsek G J P,McGuinness D S,Wierenga T S,et al.Single-and double-coordination mechanism in ethylene tri-and tetramerization with Cr/PNP catalysts[J].ACS Catal,2015,5(7):4152-4166.
[26]Metzger E D,Comito R J,Hendon C H,et al.Mechanism of single-site molecule-like catalytic ethylene dimerization in Ni-MFU-4l[J].J Am Chem Soc,2017,139(2):757-762.