我国耕地土壤重金属污染的阻控技术研究进展
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摘要
随着人口数量的增长,工业化、城市化的快速发展,我国很多地区已经普遍存在严重的耕地土壤重金属污染和农产品重金属超标等问题,这直接威胁农产品安全和人体健康,影响土地资源的可持续利用和农业的可持续发展。耕地土壤重金属污染阻控以及农作物安全生产已经成为农业生态环境治理的重点研究项目之一,研究土壤重金属污染的阻控技术是消除或控制土壤重金属污染,实现农产品质量安全的重要措施和有效途径。本文就土壤重金属环境行为特征、阻控机理和方法等进行综述,为重金属污染耕地土壤修复提供借鉴,从而促进农业生产的绿色、健康和可持续发展。
With the increase of population and the rapid development of industrialization and urbanization, serious soil heavy metal pollution and excessive heavy metals in agricultural products have been widespread in many areas of China.Heavy metal pollution in cultivated soil threatens the safety of agricultural products and human health directly, and affects the sustainable utilization of land resources and the sustainable development of agriculture. Prevention and control of heavy metal pollution in farmland soil and the safety production of agricultural products have become one of the key research projects in the agricultural eco-environmental governance. Thus, the research on the prevention and control technology of heavy metal pollution in soil is an important measure and effective way to eliminate or control soil heavy metal contamination, and realize the quality and safety of agricultural products. In the paper, the behavioral characteristics of heavy metals in soil, the methods and mechanisms of pollution control are reviewed. The purpose of the paper is to provide practical reference for remediation of cultivated land contaminated by heavy metal, thereby promoting the green, health and sustainable development of agricultural production.
With the increase of population and the rapid development of industrialization and urbanization, serious soil heavy metal pollution and excessive heavy metals in agricultural products have been widespread in many areas of China.Heavy metal pollution in cultivated soil threatens the safety of agricultural products and human health directly, and affects the sustainable utilization of land resources and the sustainable development of agriculture. Prevention and control of heavy metal pollution in farmland soil and the safety production of agricultural products have become one of the key research projects in the agricultural eco-environmental governance. Thus, the research on the prevention and control technology of heavy metal pollution in soil is an important measure and effective way to eliminate or control soil heavy metal contamination, and realize the quality and safety of agricultural products. In the paper, the behavioral characteristics of heavy metals in soil, the methods and mechanisms of pollution control are reviewed. The purpose of the paper is to provide practical reference for remediation of cultivated land contaminated by heavy metal, thereby promoting the green, health and sustainable development of agricultural production.
引文
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[3]LI Z,MA Z,VAN DER KUIJP T J,et al.A review of soil heavy metal pollution from mines in China:pollution and health risk assessment[J].Science of the Total Environment,2014,468-469:843-853.
[4]ADAMO P,IAVAZZO P,ALBANESE S,et al.Bioavailability and soil-to-plant transfer factors as indicators of potentially toxic element contamination in agricultural soils[J].Science of the Total Environment,2014,500-501:11-22.
[5]王敬国,林杉,李保国.氮循环与中国农业氮管理[J].中国农业科学,2016(3):503-517.
[6]LIU L,LI W,SONG W,et al.Remediation techniques for heavy metal-contaminated soils:Principles and applicability[J].Science of the Total Environment,2018,633:206-219.
[7]GUAN Q,WANG F,XU C,et al.Source apportionment of heavy metals in agricultural soil based on PMF:A case study in Hexi Corridor,northwest China[J].Chemosphere,2017,193:189-197.
[8]郑顺安,郑向群,张铁亮,等.土壤重金属形态研究动态及展望[C].2011中国环境科学学会学术年会论文集(第二卷),2011.
[9]URE A M,QUEVAUVILLER P,MUNTAU H,et al.Speciation of heavy metals in soils and sediments.An account of the improvement and harmonization of extraction techniques undertaken under the auspices of the BCR of the commission of the european communities[J].International Journal of Environmental Analytical Chemistry,1993,51(1-4):135-151.
[10]TESSIER A,CAMPBELLl P G C,BISSON M.Sequential extraction procedure for the speciation of particulate trace metals[J].Analytical Chemistry,1979,51(7):844-851.
[11]孙海,张亚玉,孙长伟,等.林下参土壤中重金属形态分布及生态风险评估[J].农业环境科学学报,2014,33(5):928-934.
[12]李文博,廖超,石建凡.浅谈影响重金属元素在土壤中迁移转化的因素[J].地质论评,2015,61(z1):20-21.
[13]韦朝阳,陈同斌.重金属超富集植物及植物修复技术研究进展[J].生态学报,2001,21(7):1196-1203.
[14]薛生国,陈英旭,林琦,等.中国首次发现的锰超积累植物-商陆[J].生态学报,2003,23(5):935-937.
[15]张学洪,罗亚平,黄海涛,等.一种新发现的湿生铬超积累植物--李氏禾(Leersia hexandra Swartz)[J].生态学报,2006,26(3):950-953.
[16]万敏,周卫,林葆.不同镉积累类型小麦根际土壤低分子量有机酸与镉的生物积累[J].植物营养与肥料学报,2003,9(3):331-336.
[17]WELCH R M,NORVELL W A,SCHAEFER S C,et al.Induction of iron(III)and copper(II)reduction in pea(Pisum sativum L.)roots by Fe and Cu status:Does the root-cell plasmalemma Fe(III)-chelate reductase perform a general role in regulating cation uptake?[J]Planta1993;190:555-61.
[18]丁竹红,胡忻,尹大强.螯合剂在重金属污染土壤修复中应用研究进展[J].生态环境学报,2009,18(2):777-782.
[19]BAI W.Effects of application of NTA and EDTA on accumulation of soil heavy metals in chrysanthemum[C].IOP Conference Series:Earth and Environmental Science,IOP Publishing,2018.
[20]LUO C L,SHEN Z G,LI X D,et al.Enhanced phytoextraction of Pb and other metals from contaminated soils through the combined application of EDTA and EDDS[J].Chemosphere,2005,63(10):1773-1784.
[21]王立群,罗磊,马义兵,等.重金属污染土壤原位钝化修复研究进展[J].应用生态学报,2009,20(5):1214-1222.
[22]YANG J,MOSBY D.Field assessment of treatment efficacy by three methods of phosphoric acid application in lead-contaminated urban soil[J].Science of the Total Environment,2006,366(1):136-142.
[23]DEBALA F,AROCENA J M,THRING R W,et al.Organic acids inhibit the formation of pyromorphite and Zn-phosphate in phosphorous amended Pb-and Zn-contaminated soil[J].Journal of Environmental Management,2013,116:156-162.
[24]夏鹏,王学江,张晶,等.生物质炭对单一与复合污染土壤中铜、铅、铬的钝化作用[J].土壤通报,2016,47(1):192-197.
[25]LUO X,LIU H,HUANG G,et al.Remediation of arsenic-contaminated groundwater using media-injected permeable reactive barriers with a modified montmorillonite:sand tank studies[J].Environmental Science and Pollution Research,2016,23:870-7.
[26]LIU L,CHEN H,CAI P,et al.Immobilization and phytotoxicity of Cd in contaminated soil amended with chicken manure compost[J].Journal of Hazardous Materials,2009,163(2-3):563-567.
[27]张会敏,袁艺,焦慧,等.相思谷尾矿8种定居植物对重金属吸收及富集特性[J].生态环境学报,2015(5):886-891.
[28]焦位雄,杨虎德,冯丹妮,等.Cd Hg Pb胁迫下不同作物可食部分重金属含量及累积特征研究[J].农业环境科学学报,2017,36(9):1726-1733.
[29]赵云云,钟彩霞,方小龙,等.华南地区11个春播大豆品种抗镉性的差异[J].华南农业大学学报,2014(3):111-113.
[30]伍钧,吴传星,孟晓霞,等.重金属低积累玉米品种的稳定性和环境适应性分析[J].农业环境科学学报,2011,30(11):2160-2167.
[31]WANG X,CHEN T,LEI M,et al.Selection of sugar cane varieties with a low heavy metal accumulation ability for the ecological remediation of contaminated farmland[J].Journal of Resources and Ecology,2012,3(4):373-378.
[32]LI D,YANG K,FAN M.Research progress on heavy metal pollution control and remediation[J].Research Journal of Chemistry&Environment,2013,17(2):76-83.
[33]MEIER S,BORIE F,BOLAN N,et al.Phytoremediation of metal-polluted soils by arbuscular mycorrhizal fungi[J].Critical Reviews in Environmental Science and Technology,2012,42(7):741-775.
[34]LIU H,YUAN M,TAN S,et al.Enhancement of arbuscular mycorrhizal fungus(Glomus versiforme)on the growth and Cd uptake by Cdhyperaccumulator Solanum nigrum[J].Applied Soil Ecology,2015,89:44-49.
[35]GRAW C W,DUNHAM S J,DENNIS P G,et al.Field evaluation of in situ remediation of a heavy metal contaminated soil using lime and red-mud[J].Environmental Pollution,2006,142(3):530-539.
[36]SINGH A,PRASAD S M.Effect of agro-industrial waste amendment on Cd uptake in Amaranthus caudatus grown under contaminated soil:an oxidative biomarker response[J].Ecotoxicology&Environmental Safety,2014,100(3):105-113.
[37]高瑞丽,唐茂,付庆灵,等.生物炭、蒙脱石及其混合添加对复合污染土壤中重金属形态的影响[J].环境科学,2017,38(1):361-367.
[38]武成辉,李亮,雷畅,等.硅酸盐钝化剂在土壤重金属污染修复中的研究与应用[J].土壤,2017,49(3):446-452.
[39]杜彩艳,段宗颜,曾民,等.田间条件下不同组配钝化剂对玉米(Zea mays)吸收Cd、As和Pb影响研究[J].生态环境学报,2015(10):1731-1738.
[40]李剑睿,徐应明,林大松,等.农田重金属污染原位钝化修复研究进展[J].生态环境学报,2014(4):721-728.
[41]孙约兵,王朋超,徐应明,等.海泡石对镉-铅复合污染钝化修复效应及其土壤环境质量影响研究[J].环境科学,2014(12):4720-4726.
[42]殷飞,王海娟,李燕燕,等.不同钝化剂对重金属复合污染土壤的修复效应研究[J].农业环境科学学报,2015,34(3):438-448.
[43]孙媛媛,曾希柏,白玲玉,等.双金属氧化物和改性赤泥对潮褐土中外源砷的调控研究[J].农业环境科学学报,2013,32(8):1545-1551.
[44]JING Y X,YAN J L,HE H D,et al.Characterization of bacteria in the rhizosphere soils of Polygonum pubescens and their potential in promoting growth and Cd,Pb,Zn uptake by Brassica napus[J].International Journal of Phytoremediation,2014,16(4):321-333.
[45]MNASRI M,JANOU?KOVáM,RYALOVáJ,et al.Comparison of arbuscular mycorrhizal fungal effects on the heavy metal uptake of a host and a non-host plant species in contact with extraradical mycelial network[J].Chemosphere,2017,171:476-484.
[46]王林,秦旭,徐应明,等.污灌区镉污染菜地的植物阻隔和钝化修复研究[J].农业环境科学学报,2014,33(11):2111-2117.
[47]崔俊义,马友华,陈亮妹,等.原位钝化-低积累品种联合修复镉污染农田研究[J].环境科学与技术,2018(7):77-83.
[2]ZHANG J,LI H,ZHOU Y,et al.Bioavailability and soil-to-crop transfer of heavy metals in farmland soils:A case study in the Pearl River Delta,South China[J].Environmental Pollution,2018,235:710-719.
[3]LI Z,MA Z,VAN DER KUIJP T J,et al.A review of soil heavy metal pollution from mines in China:pollution and health risk assessment[J].Science of the Total Environment,2014,468-469:843-853.
[4]ADAMO P,IAVAZZO P,ALBANESE S,et al.Bioavailability and soil-to-plant transfer factors as indicators of potentially toxic element contamination in agricultural soils[J].Science of the Total Environment,2014,500-501:11-22.
[5]王敬国,林杉,李保国.氮循环与中国农业氮管理[J].中国农业科学,2016(3):503-517.
[6]LIU L,LI W,SONG W,et al.Remediation techniques for heavy metal-contaminated soils:Principles and applicability[J].Science of the Total Environment,2018,633:206-219.
[7]GUAN Q,WANG F,XU C,et al.Source apportionment of heavy metals in agricultural soil based on PMF:A case study in Hexi Corridor,northwest China[J].Chemosphere,2017,193:189-197.
[8]郑顺安,郑向群,张铁亮,等.土壤重金属形态研究动态及展望[C].2011中国环境科学学会学术年会论文集(第二卷),2011.
[9]URE A M,QUEVAUVILLER P,MUNTAU H,et al.Speciation of heavy metals in soils and sediments.An account of the improvement and harmonization of extraction techniques undertaken under the auspices of the BCR of the commission of the european communities[J].International Journal of Environmental Analytical Chemistry,1993,51(1-4):135-151.
[10]TESSIER A,CAMPBELLl P G C,BISSON M.Sequential extraction procedure for the speciation of particulate trace metals[J].Analytical Chemistry,1979,51(7):844-851.
[11]孙海,张亚玉,孙长伟,等.林下参土壤中重金属形态分布及生态风险评估[J].农业环境科学学报,2014,33(5):928-934.
[12]李文博,廖超,石建凡.浅谈影响重金属元素在土壤中迁移转化的因素[J].地质论评,2015,61(z1):20-21.
[13]韦朝阳,陈同斌.重金属超富集植物及植物修复技术研究进展[J].生态学报,2001,21(7):1196-1203.
[14]薛生国,陈英旭,林琦,等.中国首次发现的锰超积累植物-商陆[J].生态学报,2003,23(5):935-937.
[15]张学洪,罗亚平,黄海涛,等.一种新发现的湿生铬超积累植物--李氏禾(Leersia hexandra Swartz)[J].生态学报,2006,26(3):950-953.
[16]万敏,周卫,林葆.不同镉积累类型小麦根际土壤低分子量有机酸与镉的生物积累[J].植物营养与肥料学报,2003,9(3):331-336.
[17]WELCH R M,NORVELL W A,SCHAEFER S C,et al.Induction of iron(III)and copper(II)reduction in pea(Pisum sativum L.)roots by Fe and Cu status:Does the root-cell plasmalemma Fe(III)-chelate reductase perform a general role in regulating cation uptake?[J]Planta1993;190:555-61.
[18]丁竹红,胡忻,尹大强.螯合剂在重金属污染土壤修复中应用研究进展[J].生态环境学报,2009,18(2):777-782.
[19]BAI W.Effects of application of NTA and EDTA on accumulation of soil heavy metals in chrysanthemum[C].IOP Conference Series:Earth and Environmental Science,IOP Publishing,2018.
[20]LUO C L,SHEN Z G,LI X D,et al.Enhanced phytoextraction of Pb and other metals from contaminated soils through the combined application of EDTA and EDDS[J].Chemosphere,2005,63(10):1773-1784.
[21]王立群,罗磊,马义兵,等.重金属污染土壤原位钝化修复研究进展[J].应用生态学报,2009,20(5):1214-1222.
[22]YANG J,MOSBY D.Field assessment of treatment efficacy by three methods of phosphoric acid application in lead-contaminated urban soil[J].Science of the Total Environment,2006,366(1):136-142.
[23]DEBALA F,AROCENA J M,THRING R W,et al.Organic acids inhibit the formation of pyromorphite and Zn-phosphate in phosphorous amended Pb-and Zn-contaminated soil[J].Journal of Environmental Management,2013,116:156-162.
[24]夏鹏,王学江,张晶,等.生物质炭对单一与复合污染土壤中铜、铅、铬的钝化作用[J].土壤通报,2016,47(1):192-197.
[25]LUO X,LIU H,HUANG G,et al.Remediation of arsenic-contaminated groundwater using media-injected permeable reactive barriers with a modified montmorillonite:sand tank studies[J].Environmental Science and Pollution Research,2016,23:870-7.
[26]LIU L,CHEN H,CAI P,et al.Immobilization and phytotoxicity of Cd in contaminated soil amended with chicken manure compost[J].Journal of Hazardous Materials,2009,163(2-3):563-567.
[27]张会敏,袁艺,焦慧,等.相思谷尾矿8种定居植物对重金属吸收及富集特性[J].生态环境学报,2015(5):886-891.
[28]焦位雄,杨虎德,冯丹妮,等.Cd Hg Pb胁迫下不同作物可食部分重金属含量及累积特征研究[J].农业环境科学学报,2017,36(9):1726-1733.
[29]赵云云,钟彩霞,方小龙,等.华南地区11个春播大豆品种抗镉性的差异[J].华南农业大学学报,2014(3):111-113.
[30]伍钧,吴传星,孟晓霞,等.重金属低积累玉米品种的稳定性和环境适应性分析[J].农业环境科学学报,2011,30(11):2160-2167.
[31]WANG X,CHEN T,LEI M,et al.Selection of sugar cane varieties with a low heavy metal accumulation ability for the ecological remediation of contaminated farmland[J].Journal of Resources and Ecology,2012,3(4):373-378.
[32]LI D,YANG K,FAN M.Research progress on heavy metal pollution control and remediation[J].Research Journal of Chemistry&Environment,2013,17(2):76-83.
[33]MEIER S,BORIE F,BOLAN N,et al.Phytoremediation of metal-polluted soils by arbuscular mycorrhizal fungi[J].Critical Reviews in Environmental Science and Technology,2012,42(7):741-775.
[34]LIU H,YUAN M,TAN S,et al.Enhancement of arbuscular mycorrhizal fungus(Glomus versiforme)on the growth and Cd uptake by Cdhyperaccumulator Solanum nigrum[J].Applied Soil Ecology,2015,89:44-49.
[35]GRAW C W,DUNHAM S J,DENNIS P G,et al.Field evaluation of in situ remediation of a heavy metal contaminated soil using lime and red-mud[J].Environmental Pollution,2006,142(3):530-539.
[36]SINGH A,PRASAD S M.Effect of agro-industrial waste amendment on Cd uptake in Amaranthus caudatus grown under contaminated soil:an oxidative biomarker response[J].Ecotoxicology&Environmental Safety,2014,100(3):105-113.
[37]高瑞丽,唐茂,付庆灵,等.生物炭、蒙脱石及其混合添加对复合污染土壤中重金属形态的影响[J].环境科学,2017,38(1):361-367.
[38]武成辉,李亮,雷畅,等.硅酸盐钝化剂在土壤重金属污染修复中的研究与应用[J].土壤,2017,49(3):446-452.
[39]杜彩艳,段宗颜,曾民,等.田间条件下不同组配钝化剂对玉米(Zea mays)吸收Cd、As和Pb影响研究[J].生态环境学报,2015(10):1731-1738.
[40]李剑睿,徐应明,林大松,等.农田重金属污染原位钝化修复研究进展[J].生态环境学报,2014(4):721-728.
[41]孙约兵,王朋超,徐应明,等.海泡石对镉-铅复合污染钝化修复效应及其土壤环境质量影响研究[J].环境科学,2014(12):4720-4726.
[42]殷飞,王海娟,李燕燕,等.不同钝化剂对重金属复合污染土壤的修复效应研究[J].农业环境科学学报,2015,34(3):438-448.
[43]孙媛媛,曾希柏,白玲玉,等.双金属氧化物和改性赤泥对潮褐土中外源砷的调控研究[J].农业环境科学学报,2013,32(8):1545-1551.
[44]JING Y X,YAN J L,HE H D,et al.Characterization of bacteria in the rhizosphere soils of Polygonum pubescens and their potential in promoting growth and Cd,Pb,Zn uptake by Brassica napus[J].International Journal of Phytoremediation,2014,16(4):321-333.
[45]MNASRI M,JANOU?KOVáM,RYALOVáJ,et al.Comparison of arbuscular mycorrhizal fungal effects on the heavy metal uptake of a host and a non-host plant species in contact with extraradical mycelial network[J].Chemosphere,2017,171:476-484.
[46]王林,秦旭,徐应明,等.污灌区镉污染菜地的植物阻隔和钝化修复研究[J].农业环境科学学报,2014,33(11):2111-2117.
[47]崔俊义,马友华,陈亮妹,等.原位钝化-低积累品种联合修复镉污染农田研究[J].环境科学与技术,2018(7):77-83.