Magnetism tuned by intercalation of various metal ions in coordination polymer
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摘要
Incorporation of guest ions into porous frameworks changed magnetism of the host materials significantly.However,in most cases,the guest ions were monovalent due to lack of reliable method to insert divalent and trivalent guest ions.In this work,we demonstrated that divalent and trivalent metal ions could be inserted into frameworks of a coordinate polyme r,Cu_3[Fe(CN)_6]_2,through electrochemical intercalation.The magnetism of the host frameworks was changed among paramagnetic,superparamagnetic,and ferromagnetic as demonstrated by physical property measurement system(PPMS).Furthermo re,the magnetization of the framewo rks under low temperatures correlated to the guest ions significantly.The io nic radius and net charge of the guest ions influenced the intercalation amount of the guest ions,therefore affected the valence change of Fe~(3+)ions in the host frameworks,finally leading to variation of the magnetism of the host materials.
Incorporation of guest ions into porous frameworks changed magnetism of the host materials significantly.However,in most cases,the guest ions were monovalent due to lack of reliable method to insert divalent and trivalent guest ions.In this work,we demonstrated that divalent and trivalent metal ions could be inserted into frameworks of a coordinate polyme r,Cu_3[Fe(CN)_6]_2,through electrochemical intercalation.The magnetism of the host frameworks was changed among paramagnetic,superparamagnetic,and ferromagnetic as demonstrated by physical property measurement system(PPMS).Furthermo re,the magnetization of the framewo rks under low temperatures correlated to the guest ions significantly.The io nic radius and net charge of the guest ions influenced the intercalation amount of the guest ions,therefore affected the valence change of Fe~(3+)ions in the host frameworks,finally leading to variation of the magnetism of the host materials.
Incorporation of guest ions into porous frameworks changed magnetism of the host materials significantly.However,in most cases,the guest ions were monovalent due to lack of reliable method to insert divalent and trivalent guest ions.In this work,we demonstrated that divalent and trivalent metal ions could be inserted into frameworks of a coordinate polyme r,Cu_3[Fe(CN)_6]_2,through electrochemical intercalation.The magnetism of the host frameworks was changed among paramagnetic,superparamagnetic,and ferromagnetic as demonstrated by physical property measurement system(PPMS).Furthermo re,the magnetization of the framewo rks under low temperatures correlated to the guest ions significantly.The io nic radius and net charge of the guest ions influenced the intercalation amount of the guest ions,therefore affected the valence change of Fe~(3+)ions in the host frameworks,finally leading to variation of the magnetism of the host materials.
引文
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[2]H.J.Richter,A.Lyberatos,U.Nowak,R.F.L.Evans,R.W.Chantrell,J.Appl.Phys.111(2012)033909.
[3]S.Jadoon,A.Waseem,M.Yaqoob,A.Nabi,Chin.Chem.Lett.21(2010)712-715.
[4]H.Zhang,F.Huang,D.L. Liu,P.Shi,Chin.Chem.Lett 26(2015)1137-1143.
[5]P.A.Sundaram,R.Augustine,M.Kannan,Biotechnol.Bioprocess Eng.17(2012)835-840.
[6]S.Wu,A.Z.Sun,F.Zhai,A.A.Volinsky,et al.,Mater.Lett. 65(2011)1882-1884.
[7]M.Hu,J.S.Jiang,F.X.Bu,et al.,RSC Adv.2(2012)4782-4786.
[8]M.Darbandi,F.Stromberg,J.Landers,et al.,J.Phys.D Appl.Phys.45(2012)195001.
[9]O.M.Lemine,K.Omri,B.Zhang,et al.,Uperlattices Microstruct.52(2012)793-799.
[10]G.H.Gao,R.R.Shi,W.Q.Qin,et al.,J.Mater.Sci.45(2010)3483-3489.
[11]H.Xu,B.W.Zeiger,K.S.Suslick,Chem.Soc.Rev.42(2013)2555-2567.
[12]L.Wu,H.Yao,B.Hu,S.H.Yu,Chem.Mater.23(2011)3946-3952.
[13]D.P.Dong,J.Q.Xiao,P.F.Zhuang,et al.,Inorg.Chem.Commun.21(2012)84-87.
[14]D.P.Dong,H.Zheng,L.Zhao,et al.,Sci.China Chem.55(2012)1018-1021.
[15]R.M.Wen,S.D.Han,H.Wang,Y.H.Zhang,Chin.Chem.Lett.25(2014)854-858.
[16]S.Ohkoshi,T.Matsuda,H.Tokoro,K.Hashimoto,Chem.Mater.17(2005)81-84.
[17]C.Eugenio,G.L.M.Carmen,K.Tomasz,et al.,J.Am.Chem.Soc.130(2008)15519.
[18]K.Noriyuki,H.Masanori,K.Izuru,et al.,J.Am.Chem.Soc.131(2009)212.
[19]M.Nishino,K.Boukheddaden,S.Miyashita,F.Varret,Phys.Rev.B 72(2005)73-80.
[20]T.Liu,H.Zheng,S.Kang,et al.,Nat.Commun.4(2013)3826.
[21]B.Li,R.J.Wei,J.Tao,et al.,J.Am.Chem.Soc.132(2010)1558-1566.
[22]Q.Y.Zhang,X.Luo,LN.Wang,et al.,Nano Lett 16(2016)583.
[23]Y.N.Yan,X.J.Zhou,F.Li,et al.,Appl.Phys.Lett.107(2015)122407.
[24]X.J.Zhou,Y.N.Yan,M.Jiang,et al.,J.Phys.Chem.C 120(2016)1633-1639.
[25]D.A.Gilbert,J.Olamit,R.K.Dumas,et al.,Nat. Commun.7(2016)11050.
[26]M.Okubo.,K.Kagesawa,Y.Mizuno,et al.,Inorg.Chem.52(2013)3772-3779.
[27]K.Taniguchi,K.Narushima,J.Mahin,W.Kosaka,H.Miyasaka,Angew.Chem.Int Ed.55(2016)5238-5242.
[28]T.Tsuchiya,K.Terabe,M.Ochi,et al.,ACS Nano 10(2016)1655-1661.
[29]T.Yamada,K.Morita,K.Kume,H.Yoshikawa,K.Awaga,J.Mater.Chem.C 2(2014)5183-5188.
[30]K.Taniguchi,K. Narushima,H.Sagayama,et al.,Adv.Funct.Mater.27(2017)1604990.
[31]M.Okubo,D.Asakura,Y.Mizuno,et al.,Angew.Chem.Int Ed.50(2011)6269-6273.
[32]Y.Mizuno,M.Okubo,K.Kagesawa,et al.,Inorg.Chem.51(2012)10311-10316.
[33]C.H.Li,M.K.Peprah,D.Asakura,et al.,Chem.Mater.27(2015)1524-1530.
[34]W.Antje,K Heike,P.P.Irena,et al.,Inorg.Chem.41(2002)5706-5715.
[35]F.Q.Li,W.Zhang,A.Carné-Sánchez,et al.,Inorg.Chem.57(2018)8701-8704.
[36]W.Zhang,Y.Y.Zhao,V.Malgras,et al.,Angew.Chem,Int.Ed.55(2016)8228-8234.
[37]Y.J.Fang,C.X.Chen,X.P.Ai,H.X.Yang,Y.L.Cao,Acta Phys-Chim.Sin.33(2017)211-241.
[38]S.Liu,L.Y.Shao,X.J.Zhang,Z.L.Tao,J.Chen,Acta Phys.-Chim.Sin.34(2018)581-597.
[39]Y.Mizuno,M.Okubo,E.Hosono,et al.,J.Mater.Chem.A 1(2013)13055-13059.
[40]R.Y.Wang,B.Shyam,K.H.Stone,et al.,Adv.Energy Mater.5(2015)1401869.
[41]C.D.Wessells,R.A.Huggins,Y.Cui,Nat.Commun.2(2011)550.
[42]E.Reguera,J.Rodriguez-Hernandez,A.Champi,et al.,Z.Phys.Chem.220(2006)1609-1619.
[43]D.Asakura,Y.Nanba,M.Okubo,et al.,J.Phys.Chem.Lett.5(2014)4008-4013.
[44]M.Verdaguer,G.S.Girolami,Magnetic prussian blue analogs,in:J.S.Miller,M.Dorillon(Eds.),Magnetism:Molecules to Materials V,Wiley-VCH,New York,2005,pp.283-346.
[45]T.Yamashita,P.Hayes,Appl.Surf.Sci.254(2008)2441-2449.
[46]A.Lisowska-Oleksiak,M.Wilamowska,V.Jasulaitiene,Electrochim.Acta 56(2011)3626-3632.