透明涂饰对家具用温致变色饰面材料材色的影响
|
摘要
以热敏黑为隐色剂、双酚a为显色剂、十四醇为溶剂,制备温致变色复配物,通过超声浸渍法将其引入到家具表面装饰用的单板基材上,并对其进行透明涂饰处理,研究聚氨酯清漆透明涂饰对温致变色木材的材色、热变色性能和热稳定性能的影响。结果表明,清漆涂饰较未涂饰的温致变色木材而言,其表面色相向偏绿偏黄的方向变化,且材料表面的明度上升。清漆涂饰处理的材料颜色恢复存在迟滞现象,且材料表面消色和复色反应开始温度升高,复色速度加快。冷热循环处理后的温致变色胡桃楸、杨木和枫木涂饰材表面材色热稳定性较好,均优于素材,总色差值的波动区间分别为26.76～36.70、20.82～29.54、18.49～29.07。
In this study,thermochromic compounds were prepared with thermal black leuco agent,bisphenol a and tetradecyl alcohol.They were introduced into the decorative veneers by ultrasonic immersion for thermochromic veneers fabrication.The influence of polyurethane varnish coating on surface color change,thermal discoloration performance and thermal stability of thermochromic veneer were investigated.The results showed that the color of varnished thermochromic surface changed towards green and yellow,the brightness increased.In the view of thermochromic property,the varnished materials showed color recovery hysteretic.And they showed good thermal stability after cold and heat cycling treatment.Compared with untreated materials,the fluctuation ranges of △E of varnished juglans,poplar and maple were 26.76-36.70,20.82-29.54,18.49-29.07,respectively.
In this study,thermochromic compounds were prepared with thermal black leuco agent,bisphenol a and tetradecyl alcohol.They were introduced into the decorative veneers by ultrasonic immersion for thermochromic veneers fabrication.The influence of polyurethane varnish coating on surface color change,thermal discoloration performance and thermal stability of thermochromic veneer were investigated.The results showed that the color of varnished thermochromic surface changed towards green and yellow,the brightness increased.In the view of thermochromic property,the varnished materials showed color recovery hysteretic.And they showed good thermal stability after cold and heat cycling treatment.Compared with untreated materials,the fluctuation ranges of △E of varnished juglans,poplar and maple were 26.76-36.70,20.82-29.54,18.49-29.07,respectively.
引文
[1] 于海鹏,刘一星,罗光华.聚氨酯漆透明涂饰木材的视觉物理量变化规律[J].建筑材料学报,2007,10(4):463-468.YU H P,LIU Y X,LUO G H.Changing rules of visual physical parameters of wood coated by clear polyurethane lacquer [J].Journal of Building Materials,2007,10(4):463-468.(in Chinese)
[2] 崔蒙蒙,吴智慧.现代上蜡工艺对红木家具用木材材色及光泽的影响[J].涂料工业,2017,47(2):67-72.
[3] 关锦锦.深色名贵硬木家具主要用材材色及其表面涂饰研究[D].南京:南京林业大学,2013.
[4] 王泽坤,龙涛,夏俊伟,等.火力楠木材涂饰聚氨酯清漆工艺研究[J].西北林学院学报,2016,31(1):265-270.WANG Z K,LONG T,XIA J W,et al.Coating process of polyurethane varnish for Michelia macclurei timber[J].Journal of Northwest Forestry University2016,31(1):265-270.(in Chinese)
[5] 白鹭,宋孝周,肖建平,等.桑枝重组方材透明涂饰性能研究[J].西北林学院学报,2016,31(1):271-275.BAI L,SONG X Z,XIAO J P,et al.Clear painting properties of reconstituted square lumber made from mulberry branch[J].Journal of Northwest Forestry University,2016,31(1):271-275.(in Chinese)
[6] SANTAMOURIS M,SYNNEFA A,KARLESSI T.Using advanced cool materials in the urban built environment to mitigate heat islands and improve thermal comfort conditions [J].Solar Energy,2011,85:3085-3102.
[7] BURKINSHAW S M,GRIFFITHS J,TOWNS A D.Reversibly thermochromic systems based on pH-sensitive functional dyes [J].Journal of materials chemistry ,1998,8:2677-2683.
[8] LIU Z J,BAO F C.Study of manufacturing thermochromic wood [J].Wood and Fiber Science,2011,43:239-244.
[9] 刘志佳,鲍甫成,傅峰.温致变色杨木单板浸渍工艺[J].林业科学,2012,48(1):143-147.LIU Z J,BAO F C,FU F.Impregnation process of thermochromic functional poplar veneer [J].Scientia Silvae Sinicae,2012,48(1):143-147.(in Chinese)
[10] HU L LYU S Y,FENG F,HUNG J D.Development of photochromic wood material by microcapsules [J].Bioresources,2016,11:9547-9559.
[11] HU L,LYU S Y,FU,F,HUANG J D,et al.Preparation and properties of multifunctional thermochromic energy-storage wood materials [J].Journal of Materials Science ,2015,51:2716-2726.
[12] 蒋汇川,傅峰,卢克阳.温致变色木质材料的研究进展[J].木材工业,2013,27(4):9-12.
[13] 高力娇,朱晓冬,刘乾,等.改性热敏黑温致变色木材的耐老化性研究[J].森林工程,2018,34(4):63-69
[14] 王娜.家具用改性速生杨表面性能和透明涂饰的研究[D].北京:北京林业大学,2013.
[15] 刘一星,李坚.透明涂饰处理前后木材表面材色和光泽度的变化[J].家具,1995(3):3-5.
[16] 肖泽芳,袁沛沛,王清文,等.蔗糖/DMDHEU改性对木材涂饰和老化性能的影响[J].林业工程学报,2016,1(4):18-24.
[17] 杨雪莲,徐信武,吕吉宁,等.阻尼涂饰意杨胶合板的表面性能[J].林业工程学报,2016,1(1):25-30.YANG X L,XU X W,LV J N,et al.Surface properties of Populus euramevicana plywood painted with damping coating [J],Journal of Forestry Engineering,2016,1(1):25-30.(in Chinese)
[18] 崔蒙蒙,吴智慧,李兴畅.打磨方式对上蜡硬木家具表面装饰性能的影响[J].林业工程学报,2018,3(3):155-160.CUI M M,WU Z H,LI X C.Effect of polishing method on surface decorative properties of waxed hardwood furniture [J].Journal of Forestry Engineering,2018,3(3):155-160.(in Chinese)
[19] 潘亚东,李春风.三聚氰胺改性树脂涂饰薄木饰面板工艺研究[J].森林工程,2017,33(3):44-47.
[20] 张文秀,张琳,葛飞,等.热致可逆变色涂料的发展[J].现代涂料与涂装,2009,12(3):24-27.
[21] 周雪琴,王薇,刘东志,等.热敏黑可逆热致变色复配物及其微胶囊化研究[J].化学工业与工程,2017,34(1):36-41.ZHOU X Q,WANG W,LIU D Z,et al.Study on thermosensitive black ODB reversible thermochromic compounds and their microencapsulation [J].Chemical Industry and Engineering,2017,34(1):36-41.(in Chinese)
[22] PANAK O,DRZKOVA M,KAPLANOVA M.Insight into the evaluation of colour changes of leuco dye based thermochromic systems as a function of temperature [J].Dyes and Pigments,2015,120:279-287.
[23] PANAK O,DRZKOVA M,KAPLANOVA M,et al.The relation between colour and structural changes in thermochromic systems comprising crystal violet lactone,bisphenol A,and tetradecanol [J].Dyes and Pigments,2017,136:382-389.
[24] KULCAR R,FRISKOVEC M,HAUPTMAN N,et al Colorimetric properties of reversible thermochromic printing inks [J].Dyes and Pigments,2010,86:271-277.
[25] 崔晓亮.可逆热致变色材料及其微胶囊化的研究[D].沈阳:东北大学,2001.
[26] ZHU X D,LIU Y,DONG N W,et al.Fabrication and characterization of reversible thermochromic wood veneers[J].Sci Rep,2017,7(1).
[27] 贾天宇,牛晓霆.22种红木木材的色彩与视觉特性评价[J].西北林学院学报,2017,32(6):250-258,269.JIA T Y,NIU X T.Evaluation of color and visual characteristics of 22 kinds of mahogany wood[J].Journal of Northwest Forestry University,2017,32(6):250-258,269.(in Chinese)
[28] 刘宏达,高建民,陈瑶.预热处理对改善尾巨桉木材干缩性和材色的研究[J].西北林学院学报,2014,29(5):176-180,206.LIU H D,GAO J M,CHEN Y.Effects of pre-heat treatment on improving the shrinkage and color of Eucalyptus grandis×E.urophylla wood[J].Journal of Northwest Forestry University,2014,29(5):176-180,206.(in Chinese)
[2] 崔蒙蒙,吴智慧.现代上蜡工艺对红木家具用木材材色及光泽的影响[J].涂料工业,2017,47(2):67-72.
[3] 关锦锦.深色名贵硬木家具主要用材材色及其表面涂饰研究[D].南京:南京林业大学,2013.
[4] 王泽坤,龙涛,夏俊伟,等.火力楠木材涂饰聚氨酯清漆工艺研究[J].西北林学院学报,2016,31(1):265-270.WANG Z K,LONG T,XIA J W,et al.Coating process of polyurethane varnish for Michelia macclurei timber[J].Journal of Northwest Forestry University2016,31(1):265-270.(in Chinese)
[5] 白鹭,宋孝周,肖建平,等.桑枝重组方材透明涂饰性能研究[J].西北林学院学报,2016,31(1):271-275.BAI L,SONG X Z,XIAO J P,et al.Clear painting properties of reconstituted square lumber made from mulberry branch[J].Journal of Northwest Forestry University,2016,31(1):271-275.(in Chinese)
[6] SANTAMOURIS M,SYNNEFA A,KARLESSI T.Using advanced cool materials in the urban built environment to mitigate heat islands and improve thermal comfort conditions [J].Solar Energy,2011,85:3085-3102.
[7] BURKINSHAW S M,GRIFFITHS J,TOWNS A D.Reversibly thermochromic systems based on pH-sensitive functional dyes [J].Journal of materials chemistry ,1998,8:2677-2683.
[8] LIU Z J,BAO F C.Study of manufacturing thermochromic wood [J].Wood and Fiber Science,2011,43:239-244.
[9] 刘志佳,鲍甫成,傅峰.温致变色杨木单板浸渍工艺[J].林业科学,2012,48(1):143-147.LIU Z J,BAO F C,FU F.Impregnation process of thermochromic functional poplar veneer [J].Scientia Silvae Sinicae,2012,48(1):143-147.(in Chinese)
[10] HU L LYU S Y,FENG F,HUNG J D.Development of photochromic wood material by microcapsules [J].Bioresources,2016,11:9547-9559.
[11] HU L,LYU S Y,FU,F,HUANG J D,et al.Preparation and properties of multifunctional thermochromic energy-storage wood materials [J].Journal of Materials Science ,2015,51:2716-2726.
[12] 蒋汇川,傅峰,卢克阳.温致变色木质材料的研究进展[J].木材工业,2013,27(4):9-12.
[13] 高力娇,朱晓冬,刘乾,等.改性热敏黑温致变色木材的耐老化性研究[J].森林工程,2018,34(4):63-69
[14] 王娜.家具用改性速生杨表面性能和透明涂饰的研究[D].北京:北京林业大学,2013.
[15] 刘一星,李坚.透明涂饰处理前后木材表面材色和光泽度的变化[J].家具,1995(3):3-5.
[16] 肖泽芳,袁沛沛,王清文,等.蔗糖/DMDHEU改性对木材涂饰和老化性能的影响[J].林业工程学报,2016,1(4):18-24.
[17] 杨雪莲,徐信武,吕吉宁,等.阻尼涂饰意杨胶合板的表面性能[J].林业工程学报,2016,1(1):25-30.YANG X L,XU X W,LV J N,et al.Surface properties of Populus euramevicana plywood painted with damping coating [J],Journal of Forestry Engineering,2016,1(1):25-30.(in Chinese)
[18] 崔蒙蒙,吴智慧,李兴畅.打磨方式对上蜡硬木家具表面装饰性能的影响[J].林业工程学报,2018,3(3):155-160.CUI M M,WU Z H,LI X C.Effect of polishing method on surface decorative properties of waxed hardwood furniture [J].Journal of Forestry Engineering,2018,3(3):155-160.(in Chinese)
[19] 潘亚东,李春风.三聚氰胺改性树脂涂饰薄木饰面板工艺研究[J].森林工程,2017,33(3):44-47.
[20] 张文秀,张琳,葛飞,等.热致可逆变色涂料的发展[J].现代涂料与涂装,2009,12(3):24-27.
[21] 周雪琴,王薇,刘东志,等.热敏黑可逆热致变色复配物及其微胶囊化研究[J].化学工业与工程,2017,34(1):36-41.ZHOU X Q,WANG W,LIU D Z,et al.Study on thermosensitive black ODB reversible thermochromic compounds and their microencapsulation [J].Chemical Industry and Engineering,2017,34(1):36-41.(in Chinese)
[22] PANAK O,DRZKOVA M,KAPLANOVA M.Insight into the evaluation of colour changes of leuco dye based thermochromic systems as a function of temperature [J].Dyes and Pigments,2015,120:279-287.
[23] PANAK O,DRZKOVA M,KAPLANOVA M,et al.The relation between colour and structural changes in thermochromic systems comprising crystal violet lactone,bisphenol A,and tetradecanol [J].Dyes and Pigments,2017,136:382-389.
[24] KULCAR R,FRISKOVEC M,HAUPTMAN N,et al Colorimetric properties of reversible thermochromic printing inks [J].Dyes and Pigments,2010,86:271-277.
[25] 崔晓亮.可逆热致变色材料及其微胶囊化的研究[D].沈阳:东北大学,2001.
[26] ZHU X D,LIU Y,DONG N W,et al.Fabrication and characterization of reversible thermochromic wood veneers[J].Sci Rep,2017,7(1).
[27] 贾天宇,牛晓霆.22种红木木材的色彩与视觉特性评价[J].西北林学院学报,2017,32(6):250-258,269.JIA T Y,NIU X T.Evaluation of color and visual characteristics of 22 kinds of mahogany wood[J].Journal of Northwest Forestry University,2017,32(6):250-258,269.(in Chinese)
[28] 刘宏达,高建民,陈瑶.预热处理对改善尾巨桉木材干缩性和材色的研究[J].西北林学院学报,2014,29(5):176-180,206.LIU H D,GAO J M,CHEN Y.Effects of pre-heat treatment on improving the shrinkage and color of Eucalyptus grandis×E.urophylla wood[J].Journal of Northwest Forestry University,2014,29(5):176-180,206.(in Chinese)