新型碳材料及其复合物在推进剂催化中的应用
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摘要
针对不同碳材料拥有的特殊结构及性能,碳材料被越来越多地应用于推进剂催化中;总结碳材料在推进剂燃烧催化中的研究成果,可为进一步研究新型碳材料催化剂提供理论依据;以碳纳米管、石墨烯和氮化碳为新型碳材料代表,总结了新型碳材料及其复合物在推进剂催化中的应用研究进展,分析了3种碳材料的结构性质特点及其复合物对推进剂组分热分解的不同催化效果;大量研究表明:碳材料及其复合物等均对推进剂含能组分的热分解具有良好的催化作用,能有效改善推进剂的能量性能及燃烧性能;最后,总结了复合碳材料在催化领域的重要性,指出了今后碳材料在推进剂催化方面的研究方向。
With special structures and properties,carbon materials have been widely used for catalyzing in propellants. Reviews of catalyzing application of carbon materials and derivatives on propellants could provide theoretical support for further research. Represented by carbon nanotube,graphene and carbon nitride,application research progress of new carbon materials on propellants as catalysts was summarized.The structure characteristics and catalytic effects on the thermal decomposition properties of propellants were analyzed. It has shown that,most carbon materials and derivatives have distinct catalytic effect on propellants,either on energy or combustion properties. The significance of composite carbon materials in the field of catalysis was summarized,and the research directions were suggested.
With special structures and properties,carbon materials have been widely used for catalyzing in propellants. Reviews of catalyzing application of carbon materials and derivatives on propellants could provide theoretical support for further research. Represented by carbon nanotube,graphene and carbon nitride,application research progress of new carbon materials on propellants as catalysts was summarized.The structure characteristics and catalytic effects on the thermal decomposition properties of propellants were analyzed. It has shown that,most carbon materials and derivatives have distinct catalytic effect on propellants,either on energy or combustion properties. The significance of composite carbon materials in the field of catalysis was summarized,and the research directions were suggested.
引文
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[13]王建灵,刘海让,杨建,等.固体推进剂易损性试验研究[J].兵工自动化,2017(7):60-62.
[14]ALLEN M J,TUNG V C,KANER R B.Honeycomb carbon:A review of graphene[J].Chemical Reviews,2009,110(1):132-145.
[15]冯文成,徐旭冉,杨雅,等.石墨烯制备方法及其在推进剂应用中的研究进展[J].兵器装备工程学报,2016,37(4):89-94.
[16]LI N,CAO M,WU Q,et al.A Facile one-step method to produce Ni/graphene nanocomposites and their application to the thermal decomposition of ammonium perchlorate[J].Crystengcomm,2012,14(2):428-434.
[17]LI N,GENG Z,CAO M,et al.Well-dispersed ultrafine Mn3O4nanoparticles on graphene as a promising catalyst for the thermal decomposition of ammonium perchlorate[J].Carbon,2013,54:124-132.
[18]YUAN Y,JIANG W,WANG Y,et al.Hydrothermal preparation of Fe2O3/graphene nanocomposite and its enhanced catalytic activity on the thermal decomposition of ammonium perchlorate[J].Applied Surface Science,2014,303(10):354-359.
[19]朱东波.氮化碳等含氮碳材料的制备与表面性质研究[D].合肥:中国科学技术大学,2017.
[20]谈玲华,杭祖圣,寇波,等.类石墨型氮化碳的制备及其对AP热分解催化性能研究[J].功能材料,2015,46(20):20020-20023.
[21]李奇.石墨相氮化碳及其纳米复合材料的制备与其在催化高氯酸铵热分解中的应用研究[D].绵阳:西南科技大学,2016.
[2]裴江峰,赵凤起,宋秀铎,等.轻质碳材料及其复合物在固体推进剂中的应用研究进展[J].火炸药学报,2014,37(2):1-6.
[3]BOLDYREV V.Thermal decomposition of ammonium perchlorate[J].Thermochimica Acta,2006,443(1):1-36.
[4]SHUSSER M C,CULICK F E,COHEN N S.Combustion response of ammonium perchlorate[J].AIAA Journal,2002,40(4):722-730.
[5]庞爱民,马新刚,唐承志.固体火箭推进剂理论与工程[M].北京:中国宇航出版社,2014.
[6]ZHANG Y,LIU X,NIE J,et al.Improve the catalytic activity ofα-Fe2O3particles in decomposition of ammonium perchlorate by coating amorphous carbon on their surface[J].Journal of Solid State Chemistry,2011,184(2):387-390.
[7]YU C,ZHANG W,GAO Y,et al.Shape-controlled syntheses of Co3O4nanowires arrays with excellent catalytic performances upon ammonium perchlorate decomposition[J].Materials Research Bulletin,2018,97(7):483-489.
[8]SUN T,ZHANG Z,XIAO J,et al.Facile and green synthesis of palladium nanoparticles-graphene-carbon nanotube material with high catalytic activity[J].Scientific Reports,2013(3):2527.
[9]刘建勋.新型碳纳米管基复合燃烧催化剂的制备及其在固体推进剂中的应用[D].南京:南京理工大学,2008.
[10]崔平,李凤生,周建,等.铜/碳纳米管复合粒子的制备及其对高氯酸铵热分解性能研究[J].无机材料学报,2006,21(2):303-308.
[11]刘永,刘建勋,姜炜,等.纳米Ni/CNTs对AP/HTPB推进剂热分解及燃烧性能的影响[J].固体火箭技术,2008,31(4):363-367.
[12]王敬念,李晓东,杨荣杰.Fe2O3/CNTs纳米粒子的制备及其对高氯酸铵燃速的催化作用[J].火炸药学报,2006,29(2):44-47.
[13]王建灵,刘海让,杨建,等.固体推进剂易损性试验研究[J].兵工自动化,2017(7):60-62.
[14]ALLEN M J,TUNG V C,KANER R B.Honeycomb carbon:A review of graphene[J].Chemical Reviews,2009,110(1):132-145.
[15]冯文成,徐旭冉,杨雅,等.石墨烯制备方法及其在推进剂应用中的研究进展[J].兵器装备工程学报,2016,37(4):89-94.
[16]LI N,CAO M,WU Q,et al.A Facile one-step method to produce Ni/graphene nanocomposites and their application to the thermal decomposition of ammonium perchlorate[J].Crystengcomm,2012,14(2):428-434.
[17]LI N,GENG Z,CAO M,et al.Well-dispersed ultrafine Mn3O4nanoparticles on graphene as a promising catalyst for the thermal decomposition of ammonium perchlorate[J].Carbon,2013,54:124-132.
[18]YUAN Y,JIANG W,WANG Y,et al.Hydrothermal preparation of Fe2O3/graphene nanocomposite and its enhanced catalytic activity on the thermal decomposition of ammonium perchlorate[J].Applied Surface Science,2014,303(10):354-359.
[19]朱东波.氮化碳等含氮碳材料的制备与表面性质研究[D].合肥:中国科学技术大学,2017.
[20]谈玲华,杭祖圣,寇波,等.类石墨型氮化碳的制备及其对AP热分解催化性能研究[J].功能材料,2015,46(20):20020-20023.
[21]李奇.石墨相氮化碳及其纳米复合材料的制备与其在催化高氯酸铵热分解中的应用研究[D].绵阳:西南科技大学,2016.