连云港北部地区高氟地下水分布特征及成因
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摘要
为研究连云港北部地区地下水氟水文地球化学特征,采集测试了63件地下水样品,分析了高氟地下水的空间分布特征及其形成的水文地球化学过程。结果表明,地下水中氟的质量浓度呈现出随着地下水流动而逐渐升高的变化规律,高氟地下水分布于海湾低平原及平原洼地。HCO_3~-质量浓度高的弱碱性水化学环境是促进氟富集、并增强其从沉积物向地下水中转化的主要因素。高氟地下水的形成是长期地质作用和地球化学演化的结果,矿物溶解-沉淀作用、蒸发浓缩作用、阳离子交替吸附作用是控制地下水中氟富集的主要水文地球化学过程。
In order to study hydrogeochemistry of the fluoride in groundwater in northern Lianyungang area,the authors analyzed 63 groundwater samples and investigated the distribution and genesis of high- fluoride groundwater.The results show that the concentration of fluoride in groundwater tends to increase with the groundwater flow.The high- fluoride groundwater areas are distributed in low gulf plain and depression.The alkaline water environment with high concentrations of sodium and bicarbonate is the main factor responsible for fluoride enrichment and transfer of fluoride from sediments to groundwater.The formation of highfluoride groundwater results from prolonged geological and geochemical evolution.The hydrogeochemical processes including mineral dissolution and precipitation,evaporation and concentration,cation exchange and adsorption are the dominant factors for the enrichment of fluoride in groundwater.
In order to study hydrogeochemistry of the fluoride in groundwater in northern Lianyungang area,the authors analyzed 63 groundwater samples and investigated the distribution and genesis of high- fluoride groundwater.The results show that the concentration of fluoride in groundwater tends to increase with the groundwater flow.The high- fluoride groundwater areas are distributed in low gulf plain and depression.The alkaline water environment with high concentrations of sodium and bicarbonate is the main factor responsible for fluoride enrichment and transfer of fluoride from sediments to groundwater.The formation of highfluoride groundwater results from prolonged geological and geochemical evolution.The hydrogeochemical processes including mineral dissolution and precipitation,evaporation and concentration,cation exchange and adsorption are the dominant factors for the enrichment of fluoride in groundwater.
引文
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[5]汤洁,卞建民,李昭阳,等.松嫩平原氟中毒区地下水氟分布规律和成因研究[J].中国地质,2010,37(3):614-620.Tang Jie,Bian Jianmin,Li Zhaoyang,et al.The distribution regularity and causes of fluoride in groundwater of the fluorosis area,Songnen plain[J].Geology in China,2010,37(3):614-620(in Chinese with English abstract).
[6]蔡贺,王长琪,张梅桂,等.中国东北饮水型地方性氟中毒的地质环境特征及防治[J].中国地质,2010,37(3):645-650.Cai He,Wang Changqi,Zhang Meigui,et al.Geological environment characteristics of potable water endemic fluorosis areas in Northeast China and the prevention and control measures[J].Geology in China,2010,37(3):645-650(in Chinese with English abstract).
[7]李旭光,王长琪,郭常来,等.呼伦贝尔高原地下水氟分布特征及其开发利用建议[J].中国地质,2010,37(3):665-671.Li Xuguang,Wang Changqi,Guo Changlai,et al.Fluorine distribution characteristics of groundwater in Hulun Buir plateau and some suggestions for groundwater exploitation and application[J].Geology in China,2010,37(3):665-671(in Chinese with English abstract).
[8]曹玉和,齐佳伟,熊绍礼.吉林省氟中毒病区水文质地特征及防氟改水对策[J].中国地质,2010,37(3):690-695.Cao Yuhe,Qi Jiawei,Xiong Shaoli.Hydrogeological characteristics of endemic fluorine disease areas of Jilin Province and water source project countermeasures for fluorine prevention[J].Geology in China,2010,37(3):690-695(in Chinese with English abstract).
[9]鲁孟胜,韩宝平,武凡,等.鲁西南地区高氟地下水特征及成因探讨[J].中国地质,2014,41(1):294-302.Lu Mengsheng,Han Baoping,Wu Fan,et al.Characteristics and genesis of high-fluorine groundwater in southwestern Shandong Province[J].Geology in China,2014,41(1):294-302(in Chinese with English abstract).
[10]龚建师,叶念军,葛伟亚,等.淮河流域地氟病环境水文地质因素及防病方向的研究[J],中国地质,2010,37(3):633-639.Gong Jianshi,Ye Nianjun,Ge Weiya,et al.The relationship between fluorine in geological environment and endemic fluorosis in Huaihe River basin[J].Geology in China,2010,37(3):633-639(in Chinese with English abstract).
[11]高宗军,庞绪贵,王敏,等.山东省黄河下游部分县市地氟病与地质环境的关系[J].中国地质,2010,37(3):627-632.Gao Zongjun,Pang Xugui,Wang Min,et al.The relationship between endemic fluoride disease and geological environment of several cities in the lower Yellow River basin of Shandong Province[J].Geology in China,2010,37(3):627-632(in Chinese with English abstract).
[12]郭常来,李旭光,蔡贺,等.中国东北地氟病防病改水示范:以肇源县为例[J].中国地质,2010,37(3):651-656.Guo Changlai,Li Xuguang,Cai He,et al.Demonstration of the prevention of endemic fluorosis disease in drinking water supply in Northeast China:a case study of Zhaoyuan County[J].Geology in China,2010,37(3):651-656(in Chinese with English abstract).
[13]朱桦,杨炳超,赵阿宁,等.陕西省大荔县高氟地下水的形成条件分析[J].中国地质,2010,37(3):672-676.Zhu Hua,Yang Bingchao,Zhao Aning,et al.The formation regularity of high-fluorine groundwater in Dali County,Shaanxi Province[J].Geology in China,2010,37(3):672-676(in Chinese with English abstract).
[14]柯海玲,朱桦,董瑾娟,等.陕西大荔县地方性氟中毒与地质环境的关系及防治对策[J].中国地质,2010,37(3):677-685.Ke Hailing,Zhu Hua,Dong Jinjuan,et al.The relationship between the endemic fluorosis and the geological environment as well as the prevention measures in Dali County,Shaanxi Province[J].Geology in China,2010,37(3):677-685(in Chinese with English abstract).
[15]庞绪贵,高宗军,边建朝,等.山东省黄河下游流域地方病与生态地球化学环境相关性研究[J].中国地质,2010,37(3):824-830.Pang Xugui,Bian Jianchao,Gao Zongjun,et al.The correlation between endemic diseases and eco-geochemical environment in the lower Yellow River basin,Shandong Province[J].Geology in China,2010,37(3):824-830(in Chinese with English abstract).
[16]董建梅,周晓梅,吴同浩,等.连云港市降氟改水氟病区村8~12岁儿童氟斑牙调查分析[J].中国地方病防治杂志,2011,26(4):278-280.Dong Jianmei,Zhou Xiaomei,Wu Tonghao,et al.An analysis of the incidence of dental Fluorosis of children aged 8 to 12 years in endemic fluorosis villages that changed water in Lianyungang city[J].Chinese Journal of Control of Endemic Disenaces,2011,26(4):278-280(in Chinese with English abstract).
[17]夏玉婷,汪呖,王培桦,等.2008年江苏省苏北地区饮水型地方性氟中毒病情监测结果分析[J].中国地方病学杂志,2011,30(4):434-436.Xia Yuting,Wang Yang,Wang Peihua,et al.Drinking-water type endemic fluorosis in Northern Jiangsu Province in 2008:An analysis of survey results[J].Chinese Journal of Endemiology,2011,30(4):434-436(in Chinese with English abstract).
[18]刘文波,高存荣,刘滨,孥河套平原浅层地下水水化学成分及其相关性分析[J].中国地质,2010,37(3):816-823.Liu Wenbo,Gao Cunrong,Liu Bin,et al.Hydro-chemical constituents and correlation analysis of shallow groundwater in the Hetao Plain[J].Geology in China,2010,37(3):816-823(in Chinese with English abstract).
[19]郭晓东,赵海卿.珲春盆地地下水水化学特征分析[J].中国地质,2014,41(3):1010-1017.Guo Xiaodong,Zhao Haiqing.Hydrochemical characteristics and correlation analysis of groundwater in Hunchun Basin[J].Geology in China,2014,41(3):1010-1017(in Chinese with English abstract).
[20]Tahir R,Shahid N,Muhammad I,et al.Fluoride ion contamination in the groundwater of Mithi sub-district,the Thar Desert,Pakistan[J].Environmental Geology,2008,56:317-326.
[21]Singh C K,Rina K,Singh R P,et al.Geochemical modeling of high fluoride concentration in groundwater of Pokhran Area of Rajasthan,India[J].Bulletin of Environmental Contamination and Toxicology,2011,86(2):152-158.
[22]沈照理,郭华明,徐刚,等.地下水化学异常与地方病[J].自然杂志,2010,32(2):83-89.Shen Zhaoli,Guo Huaming,Xu Gang,et al.Abnormal groundwater chemistry and endemic disease[J].Chinese Journal of Nature,2010,32(2):83-89(in Chinese with English abstract).
[23]刘瑞平,朱桦,亢明仲,等.关中盆地大荔地区地下水氟水文地球化学规律[J].水文地质工程地质,2009,36(5):84-88,93.Liu Ruiping,Zhu Hua,Kang Mingzhong,et al.Hydrogeochemistry of the fluoride in groundwater in the Dali area of the Guanzhong Basin[J].Hydrogeology and Engineering Geology,2009,36(5):84-88,93(in Chinese with English abstract).
[24]邢丽娜,郭华明,魏亮,等.华北平原浅层含氟地下水演化特点及成因[J].地球科学与环境学报,2012,34(4):57-67.Xing Lina,Guo Huaming,Wei Liang,et al.Evolution feature and gensis of fluoride groundwater in shallow aquifer from North China Plain[J].Journal of Earth Sciences and Environment,2012,34(4):57-67(in Chinese with English abstract).
[25]Wang G X,Cheng G D.Fluoride distribution in water and the governing factors of environment in arid north-west China[J].Journal of Arid Environments,2001,49:601-614.
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