Solubility of the silver nitrate in supercritical carbon dioxide with ethanol and ethylene glycol as double cosolvents: Experimental determination and correlation
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摘要
Solubility of the silver nitrate in the supercritical carbon dioxide containing ethanol and ethylene glycol as double cosolvents was measured under certain pressure and temperature range(10–25 MPa, 323.15–333.15 K). The impact of the pressure and temperature on the solubility was also investigated. Based on the experiment data,a correlation model concerning solid's solubility in supercritical fluids was established by combining the solubility parameter with the thermodynamic equation when a binary interaction parameter and a mixed solvent solubility parameter were defined. Experiments show the solubility of AgNO_3 increases with the pressure at a certain temperature. However, the influence of temperature is related to a pressure defined as the turnover pressure(12.3 MPa). When the pressure is higher(or lower) than this turnover pressure, silver nitrate's solubility shows increasing(or decreasing) trend as the temperature rises. Satisfactory accuracy of our presented model was revealed by comparing experimental data with calculated results.
Solubility of the silver nitrate in the supercritical carbon dioxide containing ethanol and ethylene glycol as double cosolvents was measured under certain pressure and temperature range(10–25 MPa, 323.15–333.15 K). The impact of the pressure and temperature on the solubility was also investigated. Based on the experiment data,a correlation model concerning solid's solubility in supercritical fluids was established by combining the solubility parameter with the thermodynamic equation when a binary interaction parameter and a mixed solvent solubility parameter were defined. Experiments show the solubility of AgNO_3 increases with the pressure at a certain temperature. However, the influence of temperature is related to a pressure defined as the turnover pressure(12.3 MPa). When the pressure is higher(or lower) than this turnover pressure, silver nitrate's solubility shows increasing(or decreasing) trend as the temperature rises. Satisfactory accuracy of our presented model was revealed by comparing experimental data with calculated results.
Solubility of the silver nitrate in the supercritical carbon dioxide containing ethanol and ethylene glycol as double cosolvents was measured under certain pressure and temperature range(10–25 MPa, 323.15–333.15 K). The impact of the pressure and temperature on the solubility was also investigated. Based on the experiment data,a correlation model concerning solid's solubility in supercritical fluids was established by combining the solubility parameter with the thermodynamic equation when a binary interaction parameter and a mixed solvent solubility parameter were defined. Experiments show the solubility of AgNO_3 increases with the pressure at a certain temperature. However, the influence of temperature is related to a pressure defined as the turnover pressure(12.3 MPa). When the pressure is higher(or lower) than this turnover pressure, silver nitrate's solubility shows increasing(or decreasing) trend as the temperature rises. Satisfactory accuracy of our presented model was revealed by comparing experimental data with calculated results.
引文
[1]G.V.Amaral,E.K.Silva,R.N.Cavalcanti,C.P.C.Martins,L.Andrade,J.Moraes,V.O.Alvarenga,J.T.Guimaraes,E.A.Esmerino,M.Q.Freitas,M.C.Silva,R.S.L.Raices,A.S.Sant'Ana,M.A.A.Meireles,A.G.Cruz,Whey-grape juice drink processed by supercritical carbon dioxide technology:Physicochemical characteristics,bioactive compounds and volatile profile,Food Chem.239(2018)697-703.
[2]C.Dai,T.Wang,M.Zhao,X.Sun,M.Gao,Z.Xu,B.Guan,P.Liu,Impairment mechanism of thickened supercritical carbon dioxide fracturing fluid in tight sandstone gas reservoirs,Fuel 211(2018)60-66.
[3]J.C.W.Ouédraogo,C.Dicko,F.B.Kini,Y.L.Bonzi-Coulibaly,E.S.Dey,Enhanced extraction of flavonoids from Odontonema strictum leaves with antioxidant activity using supercritical carbon dioxide fluid combined with ethanol,J.Supercrit.Fluids131(2018)66-71.
[4]Y.Yokozaki,Y.Shimoyama,Loading of vitamin E into silicone hydrogel by supercritical carbon dioxide impregnation toward controlled release of timolol maleate,J.Supercrit.Fluids 131(2018)11-18.
[5]H.S.Lu,M.M.Ren,M.H.Zhang,Y.Chen,Pretreatment of corn stover using supercritical CO2with water-ethanol as CO-solvent,Chin.J.Chem.Eng.21(2013)551-557.
[6]Q.L.Ren,H.B.Xing,Z.B.Bao,B.G.Su,Q.W.Yang,Y.W.Yang,Z.G.Zhang,Recent advances in separation of bioactive natural products,Chin.J.Chem.Eng.21(2013)937-952.
[7]K.D.Bartle,A.A.Clifford,S.A.Jafar,G.F.Shilstone,Solubilities of solids and liquids of low volatility in supercritical carbon dioxide,J.Phys.Chem.Ref.Data 20(1991)713-756.
[8]F.P.Lucien,N.R.Foster,Solubilities of solid mixtures in supercritical carbon dioxide:A review,J.Supercrit.Fluids 17(2000)111-134.
[9]D.K.Joshi,J.M.Prausnitz,Supercritical fluid extraction with mixed-solvents,AICHE J.30(1984)522-525.
[10]R.G.Bitencourt,F.A.Cabral,A.J.A.Meirelles,Ferulic acid solubility in supercritical carbon dioxide,ethanol and water mixtures,J.Chem.Thermodyn.103(2016)285-291.
[11]S.Zhan,S.Li,Q.Zhao,W.Wang,J.Wang,Measurement and correlation of curcumin solubility in supercritical carbon dioxide,J.Chem.Eng.Data 62(2017)1257-1263.
[12]D.L.Gurina,M.L.Antipova,E.G.Odintsova,V.E.Petrenko,The study of peculiarities of parabens solvation in methanol-and acetone-modified supercritical carbon dioxide by computer simulation,J.Supercrit.Fluids 126(2017)47-54.
[13]D.L.Gurina,E.G.Odintsova,V.A.Golubev,M.L.Antipova,V.E.Petrenko,Features of solvation of phenolic acids in supercritical carbon dioxide modified by methanol and acetone,J.Supercrit.Fluids 124(2017)50-56.
[14]Y.-H.Ting,C.-M.Hsieh,Prediction of solid solute solubility in supercritical carbon dioxide with organic cosolvents from the PR+COSMOSAC equation of state,Fluid Phase Equilib.431(2017)48-57.
[15]M.P.Ekart,K.L.Bennett,S.M.Ekart,G.S.Gurdial,C.L.Liotta,C.A.Eckert,Cosolvent interactions in supercritical fluid solutions,AICHE J.39(1993)235-248.
[16]D.L.Tomasko,B.L.Knutson,F.Pouillot,C.L.Liotta,C.A.Eckert,Spectroscopic study of structure and interactions in cosolvent-modified supercritical fluids,J.Phys.Chem.97(1993)11823-11834.
[17]W.J.Schmitt,R.C.Reid,The use of entrainers in modifying the solubility of phenanthrene and benzoic-acid in supercritical carbon-dioxide and ethane,Fluid Phase Equilib.32(1986)77-99.
[18]J.M.Prausnitz,R.N.Lichtenthaler,E.G.de Azevedo,Molecular Thermodynamics of Fluid-phase Equilibria,Pearson Education,1998.
[19]M.E.Mackay,M.E.Paulaitis,Solid solubilities of heavy hydrocarbons in supercritical solvents,Ind.Eng.Chem.Fundam.18(1979)149-153.
[20]J.F.Brennecke,C.A.Eckert,Phase equilibria for supercritical fluid process design,AICHE J.35(1989)1409-1427.
[21]J.Chrastil,Solubility of solids and liquids in supercritical gases,J.Phys.Chem.86(1982)3016-3021.
[22]A.Martin,P.L.Wu,A.Adjei,A.Beerbower,J.M.Prausnitz,Extended Hansen solubility approach-Naphthalene in individual solvents,J.Pharm.Sci.70(1981)1260-1264.
[23]B.L.Karger,L.R.Snyder,C.Eon,An expanded solubility parameter treatment for classification and use of chromatographic solvents and adsorbents:Parameters for dispersion,dipole and hydrogen bonding interactions,J.Chromatogr.A 125(1976)71-88.
[24]Q.-Q.Xu,Y.-Q.Wang,A.-Q.Wang,J.-Z.Yin,Systematical study of depositing nanoparticles and nanowires in mesoporous silica using supercritical carbon dioxide and co-solvents:Morphology control,thermodynamics and kinetics of adsorption,Nanotechnology 23(2012)285602.
[25]Q.-Q.Xu,C.-J.Zhang,X.-Z.Zhang,J.-Z.Yin,Y.Liu,Controlled synthesis of Ag nanowires and nanoparticles in mesoporous silica using supercritical carbon dioxide and co-solvent,J.Supercrit.Fluids 62(2012)184-189.
[26]Q.-Q.Xu,Y.-L.Ma,G.Xu,J.-X.Ma,J.-Z.Yin,A.-Q.Wang,J.-J.Gao,Synthesis of highly dispersed silver nanoparticles or nano-network modified KIT-6 using supercritical carbon dioxide,J.Mater.Sci.50(2015)855-862.
[27]T.L.Braon,Determination of solubility parmeter values for pure solvents and binary mixtures,Drug Dev.Ind.Pharm.6(1980)87-98.
[28]J.C.Giddings,M.N.Myers,L.Mc Laren,R.A.Keller,High pressure gas chromatography of nonvolatile species,Science 162(1968)67-73.
[29]A.Beerbower,P.Wu,A.Martin,Expanded solubility parameter approach I:Naphthalene and benzoic acid in individual solvents,J.Pharm.Sci.73(1984)179-188.
[30]P.Bustamante,D.Hinkley,A.Martin,S.Shi,Statistical analysis of the extended Hansen method using the bootstrap technique,J.Pharm.Sci.80(1991)971-977.
[31]P.Bustamante,A.Martin,M.Gonzalez-Guisandez,Partial solubility parameters and solvatochromic parameters for predicting the solubility of single and multiple drugs in individual solvents,J.Pharm.Sci.82(1993)635-640.
[32]C.M.Hansen,Hansen Solubility Parameters:A User's Handbook,CRC Press,2007.
[33]H.Stephen,T.Stephen,Solubility of Inorganic and Organic Compounds,Vol 1,Part 1,Pergamon Press,Oxford,1963.
[34]Y.Hiraiwa,P.Boxer,D.Swinehart,The solubility of silver nitrate in glycerine,ethylene glycol and 1,3-propanediol at 25°C,Anal.Lett.21(1988)101-105.
[2]C.Dai,T.Wang,M.Zhao,X.Sun,M.Gao,Z.Xu,B.Guan,P.Liu,Impairment mechanism of thickened supercritical carbon dioxide fracturing fluid in tight sandstone gas reservoirs,Fuel 211(2018)60-66.
[3]J.C.W.Ouédraogo,C.Dicko,F.B.Kini,Y.L.Bonzi-Coulibaly,E.S.Dey,Enhanced extraction of flavonoids from Odontonema strictum leaves with antioxidant activity using supercritical carbon dioxide fluid combined with ethanol,J.Supercrit.Fluids131(2018)66-71.
[4]Y.Yokozaki,Y.Shimoyama,Loading of vitamin E into silicone hydrogel by supercritical carbon dioxide impregnation toward controlled release of timolol maleate,J.Supercrit.Fluids 131(2018)11-18.
[5]H.S.Lu,M.M.Ren,M.H.Zhang,Y.Chen,Pretreatment of corn stover using supercritical CO2with water-ethanol as CO-solvent,Chin.J.Chem.Eng.21(2013)551-557.
[6]Q.L.Ren,H.B.Xing,Z.B.Bao,B.G.Su,Q.W.Yang,Y.W.Yang,Z.G.Zhang,Recent advances in separation of bioactive natural products,Chin.J.Chem.Eng.21(2013)937-952.
[7]K.D.Bartle,A.A.Clifford,S.A.Jafar,G.F.Shilstone,Solubilities of solids and liquids of low volatility in supercritical carbon dioxide,J.Phys.Chem.Ref.Data 20(1991)713-756.
[8]F.P.Lucien,N.R.Foster,Solubilities of solid mixtures in supercritical carbon dioxide:A review,J.Supercrit.Fluids 17(2000)111-134.
[9]D.K.Joshi,J.M.Prausnitz,Supercritical fluid extraction with mixed-solvents,AICHE J.30(1984)522-525.
[10]R.G.Bitencourt,F.A.Cabral,A.J.A.Meirelles,Ferulic acid solubility in supercritical carbon dioxide,ethanol and water mixtures,J.Chem.Thermodyn.103(2016)285-291.
[11]S.Zhan,S.Li,Q.Zhao,W.Wang,J.Wang,Measurement and correlation of curcumin solubility in supercritical carbon dioxide,J.Chem.Eng.Data 62(2017)1257-1263.
[12]D.L.Gurina,M.L.Antipova,E.G.Odintsova,V.E.Petrenko,The study of peculiarities of parabens solvation in methanol-and acetone-modified supercritical carbon dioxide by computer simulation,J.Supercrit.Fluids 126(2017)47-54.
[13]D.L.Gurina,E.G.Odintsova,V.A.Golubev,M.L.Antipova,V.E.Petrenko,Features of solvation of phenolic acids in supercritical carbon dioxide modified by methanol and acetone,J.Supercrit.Fluids 124(2017)50-56.
[14]Y.-H.Ting,C.-M.Hsieh,Prediction of solid solute solubility in supercritical carbon dioxide with organic cosolvents from the PR+COSMOSAC equation of state,Fluid Phase Equilib.431(2017)48-57.
[15]M.P.Ekart,K.L.Bennett,S.M.Ekart,G.S.Gurdial,C.L.Liotta,C.A.Eckert,Cosolvent interactions in supercritical fluid solutions,AICHE J.39(1993)235-248.
[16]D.L.Tomasko,B.L.Knutson,F.Pouillot,C.L.Liotta,C.A.Eckert,Spectroscopic study of structure and interactions in cosolvent-modified supercritical fluids,J.Phys.Chem.97(1993)11823-11834.
[17]W.J.Schmitt,R.C.Reid,The use of entrainers in modifying the solubility of phenanthrene and benzoic-acid in supercritical carbon-dioxide and ethane,Fluid Phase Equilib.32(1986)77-99.
[18]J.M.Prausnitz,R.N.Lichtenthaler,E.G.de Azevedo,Molecular Thermodynamics of Fluid-phase Equilibria,Pearson Education,1998.
[19]M.E.Mackay,M.E.Paulaitis,Solid solubilities of heavy hydrocarbons in supercritical solvents,Ind.Eng.Chem.Fundam.18(1979)149-153.
[20]J.F.Brennecke,C.A.Eckert,Phase equilibria for supercritical fluid process design,AICHE J.35(1989)1409-1427.
[21]J.Chrastil,Solubility of solids and liquids in supercritical gases,J.Phys.Chem.86(1982)3016-3021.
[22]A.Martin,P.L.Wu,A.Adjei,A.Beerbower,J.M.Prausnitz,Extended Hansen solubility approach-Naphthalene in individual solvents,J.Pharm.Sci.70(1981)1260-1264.
[23]B.L.Karger,L.R.Snyder,C.Eon,An expanded solubility parameter treatment for classification and use of chromatographic solvents and adsorbents:Parameters for dispersion,dipole and hydrogen bonding interactions,J.Chromatogr.A 125(1976)71-88.
[24]Q.-Q.Xu,Y.-Q.Wang,A.-Q.Wang,J.-Z.Yin,Systematical study of depositing nanoparticles and nanowires in mesoporous silica using supercritical carbon dioxide and co-solvents:Morphology control,thermodynamics and kinetics of adsorption,Nanotechnology 23(2012)285602.
[25]Q.-Q.Xu,C.-J.Zhang,X.-Z.Zhang,J.-Z.Yin,Y.Liu,Controlled synthesis of Ag nanowires and nanoparticles in mesoporous silica using supercritical carbon dioxide and co-solvent,J.Supercrit.Fluids 62(2012)184-189.
[26]Q.-Q.Xu,Y.-L.Ma,G.Xu,J.-X.Ma,J.-Z.Yin,A.-Q.Wang,J.-J.Gao,Synthesis of highly dispersed silver nanoparticles or nano-network modified KIT-6 using supercritical carbon dioxide,J.Mater.Sci.50(2015)855-862.
[27]T.L.Braon,Determination of solubility parmeter values for pure solvents and binary mixtures,Drug Dev.Ind.Pharm.6(1980)87-98.
[28]J.C.Giddings,M.N.Myers,L.Mc Laren,R.A.Keller,High pressure gas chromatography of nonvolatile species,Science 162(1968)67-73.
[29]A.Beerbower,P.Wu,A.Martin,Expanded solubility parameter approach I:Naphthalene and benzoic acid in individual solvents,J.Pharm.Sci.73(1984)179-188.
[30]P.Bustamante,D.Hinkley,A.Martin,S.Shi,Statistical analysis of the extended Hansen method using the bootstrap technique,J.Pharm.Sci.80(1991)971-977.
[31]P.Bustamante,A.Martin,M.Gonzalez-Guisandez,Partial solubility parameters and solvatochromic parameters for predicting the solubility of single and multiple drugs in individual solvents,J.Pharm.Sci.82(1993)635-640.
[32]C.M.Hansen,Hansen Solubility Parameters:A User's Handbook,CRC Press,2007.
[33]H.Stephen,T.Stephen,Solubility of Inorganic and Organic Compounds,Vol 1,Part 1,Pergamon Press,Oxford,1963.
[34]Y.Hiraiwa,P.Boxer,D.Swinehart,The solubility of silver nitrate in glycerine,ethylene glycol and 1,3-propanediol at 25°C,Anal.Lett.21(1988)101-105.