粘土硅酸盐矿物改性技术研究现状
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摘要
粘土矿物资源储量丰富、颗粒微细、廉价易得且用途广泛。然而粘土矿物由于地质演变过程导致表面活性减弱或丧失,颗粒团聚或者体型化导致纳米化效应减弱或者丧失。未经功能化改性的粘土矿物不能满足当今新材料、新技术的发展要求,因此需要对粘土矿物材料进行物理、化学改造。该综述从适应不同的工业应用需求出发,总结了粘土硅酸盐矿物应用中的活化、接枝、插层等活性激发和功能化制备技术。
Clay minerals are abundant,cheap and readily available. The clay particles are fine and can be used in various industrial applications. However,due to the geological evolution,the surface activity is decreased or lost. The "nanometerization effect"is eliminated by particle aggregation and shaping. Clay minerals that have not been functionally modified cannot meet the requirements of current new materials and new technologies. Therefore,physical and chemical transformation of clay mineral materials is required. In view of different industrial applications,this review summarizes the active excitation and functionalization preparation techniques such as activation,grafting and intercalation in the application of clay silicate minerals.
Clay minerals are abundant,cheap and readily available. The clay particles are fine and can be used in various industrial applications. However,due to the geological evolution,the surface activity is decreased or lost. The "nanometerization effect"is eliminated by particle aggregation and shaping. Clay minerals that have not been functionally modified cannot meet the requirements of current new materials and new technologies. Therefore,physical and chemical transformation of clay mineral materials is required. In view of different industrial applications,this review summarizes the active excitation and functionalization preparation techniques such as activation,grafting and intercalation in the application of clay silicate minerals.
引文
[1]张汀兰,曾雄丰,张文丽.粘土插层研究进展[J].山东陶瓷,2015(3):8-12.
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[4]杨南如,徐玲玲.粘土的结构特点和开发利用[J].建筑材料学报,2003(4):337-344.
[5]徐小彬.偏高岭土的结构特点及其应用研究综述[J].大众科技,2012(6):129-130.
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[7]魏博,张一敏,包申旭.煅烧制度对高岭土活性及地聚物性能的影响[J].非金属矿,2016(4):31-34.
[8]Lin M,Liu Y Y,Lei S M,et al. High-efficiency extraction of al from coal-series kaolinite and its kinetics by calcination and pressure acid leaching[J]. Appl clay sci,2018,161:215-224.
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[11]孔德顺,宋说讲,王茜,等.基于碱融活化的高岭土水热法制备干燥剂NaP分子筛[J].硅酸盐通报,2017(11):3653-3658.
[12]Zhang J,He Y,Wang Y,et al. Synthesis of a self-supporting faujasite zeolite membrane using geopolymer gel for separation of alcohol/water mixture[J]. Mater lett,2014,116:167-170.
[13]多喜.高岭土改性吸附材料的制备表征及其吸附性能的研究[D].呼和浩特:内蒙古师范大学,2017.
[14]金敏丽.高岭土改性吸附材料的制备表征及其吸附性能[J].化工管理,2018(15):35-36.
[15]Komadel P. Acid activated clays:materials in continuous demand[J]. Appl clay sci,2016,131:84-99.
[16]Komadel P,MadejováJ. Acid activation of clay minerals[J].Developments in clay science,2006,1(5):263-287.
[17]Duan P,Yan C,Luo W. A novel waterproof,fast setting and high early strength repair material derived from metakaolin geopolymer[J]. Constr build mater,2016,124:69-73.
[18]Li X,Yan C,Luo W,et al. Exceptional cerium(iii)adsorption performance of poly(acrylic acid)brushes-decorated attapulgite with abundant and highly accessible binding sites[J]. Chem. eng. j.,2016,284:333-342.
[19]Aǐt Aghzzaf A,Rhouta B,Rocca E,et al. Grafted palygorskite as containers of heptanoate for corrosion protection of steel in nacl medium[J]. Corros sci,2017,114:88-95.
[20]Lei Z Q,Wen S X. Synthesis and decoloration capacity of well-defined and pmma-grafted palygorskite nanocomposites[J]. Eur. polym j.,2008,44(9):2845-2849.
[21]Molatlhegi O,Alagha L. Adsorption characteristics of chitosan grafted copolymer on kaolin[J]. Appl clay sci,2017,150:342-353.
[22] Taimur S,Yasin T. Influence of the synthesis parameters on the properties of amidoxime grafted sepiolite nanocomposites[J]. Appl surf sci,2017,422:239-246.
[23]梁学峰.黏土矿物表面修饰及其吸附重金属离子的性能规律研究[D].天津:天津大学,2015.
[24]张乾,张白梅,张玉德,等.机械力化学法制备硅烷接枝高岭石的研究[J].硅酸盐通报,2017(3):942-946.
[25]周奇.粘土矿物的有机功能化及其重金属吸附特性研究[D].武汉:中国地质大学,2016.
[26]林美群,马少健.偶联剂在非金属矿物改性中的应用[C].衢州:第十三届全国粉体工程及矿产资源高效开发利用研讨会,2007.
[27]赵丽颖,蒋引珊,王秀平.改性粘土矿物在橡胶中的应用[J].世界地质,2001(1):95-99.
[28]朱小燕,严春杰,陈洁渝.脲插层技术对茂名高岭土粘浓度的影响[J].非金属矿,2010(4):50-53.
[29]曹明礼,余永富,袁继祖,等.插层型粘土复合材料的制备与研究现状[J].非金属矿,2002(4):5-7.
[30]Wang Y,Shui Z,Huang Y,et al. Improving the pozzolanic activity of metakaolin by urea intercalation technique[J].Constr build mater,2018,172:19-28.
[31]马原野,王占红,侯贵华,等.插层改性膨润土对聚合物基摩擦材料摩擦性能的影响[J].工程塑料应用,2018(5):6-11.
[32]彭志刚,张博建,冯茜,等.聚合物插层蒙脱土复合型高温缓凝剂的制备及性能[J].硅酸盐学报,2018,46(8):1087-1094.
[33]Zhang Y,Tang A,Yang H,et al. Applications and interfaces of halloysite nanocomposites[J]. Appl clay sci,2016,119:8-17.
[2]姜腾达.粘土矿物对水中Pb2+、Cu2+、Cd2+的吸附及机理研究[D].长沙:中南大学,2014.
[3]易发成,王哲.粘土矿物在环境保护领域的应用现状和发展前景[C].桂林:proceedings of the全国非金属矿产地质学术研讨会,2005.
[4]杨南如,徐玲玲.粘土的结构特点和开发利用[J].建筑材料学报,2003(4):337-344.
[5]徐小彬.偏高岭土的结构特点及其应用研究综述[J].大众科技,2012(6):129-130.
[6]Huang Y,Deng J,Wang W,et al. Preliminary investigation of pozzolanic properties of calcined waste kaolin[J]. Mater sci,2018,24(2):181-192.
[7]魏博,张一敏,包申旭.煅烧制度对高岭土活性及地聚物性能的影响[J].非金属矿,2016(4):31-34.
[8]Lin M,Liu Y Y,Lei S M,et al. High-efficiency extraction of al from coal-series kaolinite and its kinetics by calcination and pressure acid leaching[J]. Appl clay sci,2018,161:215-224.
[9]Liew Y M,Heah C Y,Mohd Mustafa A B,et al. Structure and properties of clay-based geopolymer cements:a review[J].Prog mater sci,2016,83:595-629.
[10]Zhang Z H,Zhu H J,Zhou C H,et al. Geopolymer from kaolin in china:an overview[J]. Appl clay sci,2016,119:31-41.
[11]孔德顺,宋说讲,王茜,等.基于碱融活化的高岭土水热法制备干燥剂NaP分子筛[J].硅酸盐通报,2017(11):3653-3658.
[12]Zhang J,He Y,Wang Y,et al. Synthesis of a self-supporting faujasite zeolite membrane using geopolymer gel for separation of alcohol/water mixture[J]. Mater lett,2014,116:167-170.
[13]多喜.高岭土改性吸附材料的制备表征及其吸附性能的研究[D].呼和浩特:内蒙古师范大学,2017.
[14]金敏丽.高岭土改性吸附材料的制备表征及其吸附性能[J].化工管理,2018(15):35-36.
[15]Komadel P. Acid activated clays:materials in continuous demand[J]. Appl clay sci,2016,131:84-99.
[16]Komadel P,MadejováJ. Acid activation of clay minerals[J].Developments in clay science,2006,1(5):263-287.
[17]Duan P,Yan C,Luo W. A novel waterproof,fast setting and high early strength repair material derived from metakaolin geopolymer[J]. Constr build mater,2016,124:69-73.
[18]Li X,Yan C,Luo W,et al. Exceptional cerium(iii)adsorption performance of poly(acrylic acid)brushes-decorated attapulgite with abundant and highly accessible binding sites[J]. Chem. eng. j.,2016,284:333-342.
[19]Aǐt Aghzzaf A,Rhouta B,Rocca E,et al. Grafted palygorskite as containers of heptanoate for corrosion protection of steel in nacl medium[J]. Corros sci,2017,114:88-95.
[20]Lei Z Q,Wen S X. Synthesis and decoloration capacity of well-defined and pmma-grafted palygorskite nanocomposites[J]. Eur. polym j.,2008,44(9):2845-2849.
[21]Molatlhegi O,Alagha L. Adsorption characteristics of chitosan grafted copolymer on kaolin[J]. Appl clay sci,2017,150:342-353.
[22] Taimur S,Yasin T. Influence of the synthesis parameters on the properties of amidoxime grafted sepiolite nanocomposites[J]. Appl surf sci,2017,422:239-246.
[23]梁学峰.黏土矿物表面修饰及其吸附重金属离子的性能规律研究[D].天津:天津大学,2015.
[24]张乾,张白梅,张玉德,等.机械力化学法制备硅烷接枝高岭石的研究[J].硅酸盐通报,2017(3):942-946.
[25]周奇.粘土矿物的有机功能化及其重金属吸附特性研究[D].武汉:中国地质大学,2016.
[26]林美群,马少健.偶联剂在非金属矿物改性中的应用[C].衢州:第十三届全国粉体工程及矿产资源高效开发利用研讨会,2007.
[27]赵丽颖,蒋引珊,王秀平.改性粘土矿物在橡胶中的应用[J].世界地质,2001(1):95-99.
[28]朱小燕,严春杰,陈洁渝.脲插层技术对茂名高岭土粘浓度的影响[J].非金属矿,2010(4):50-53.
[29]曹明礼,余永富,袁继祖,等.插层型粘土复合材料的制备与研究现状[J].非金属矿,2002(4):5-7.
[30]Wang Y,Shui Z,Huang Y,et al. Improving the pozzolanic activity of metakaolin by urea intercalation technique[J].Constr build mater,2018,172:19-28.
[31]马原野,王占红,侯贵华,等.插层改性膨润土对聚合物基摩擦材料摩擦性能的影响[J].工程塑料应用,2018(5):6-11.
[32]彭志刚,张博建,冯茜,等.聚合物插层蒙脱土复合型高温缓凝剂的制备及性能[J].硅酸盐学报,2018,46(8):1087-1094.
[33]Zhang Y,Tang A,Yang H,et al. Applications and interfaces of halloysite nanocomposites[J]. Appl clay sci,2016,119:8-17.