Use of polymeric sub-micron ion-exchange resins for removal of lead,copper,zinc,and nickel from natural waters
|
摘要
This research investigated the removal capacity of polymeric sub-micron ion-exchange resins(SMR) for removal of lead, copper, zinc, and nickel from natural waters in competition with natural organic matter(NOM). Polymeric SMR particles were created and tested to ensure that they were adequately dispersed in the solution. They removed little NOM(10%or less) from river water and wastewater, indicating that competition from NOM was not a major concern. SMR were able to remove 82% ± 0.2% of lead, 46% ± 0.6% of copper, 55% ±20% of zinc, and 17% ± 2% of nickel from river water spiked with 500 μg/L of each. Similarly,in wastewater, they were able to remove 86% ± 0.1% of lead, 38% ± 0.8% of copper, 28% ± 1%of zinc, and 11% ± 1% of nickel.
This research investigated the removal capacity of polymeric sub-micron ion-exchange resins(SMR) for removal of lead, copper, zinc, and nickel from natural waters in competition with natural organic matter(NOM). Polymeric SMR particles were created and tested to ensure that they were adequately dispersed in the solution. They removed little NOM(10%or less) from river water and wastewater, indicating that competition from NOM was not a major concern. SMR were able to remove 82% ± 0.2% of lead, 46% ± 0.6% of copper, 55% ±20% of zinc, and 17% ± 2% of nickel from river water spiked with 500 μg/L of each. Similarly,in wastewater, they were able to remove 86% ± 0.1% of lead, 38% ± 0.8% of copper, 28% ± 1%of zinc, and 11% ± 1% of nickel.
This research investigated the removal capacity of polymeric sub-micron ion-exchange resins(SMR) for removal of lead, copper, zinc, and nickel from natural waters in competition with natural organic matter(NOM). Polymeric SMR particles were created and tested to ensure that they were adequately dispersed in the solution. They removed little NOM(10%or less) from river water and wastewater, indicating that competition from NOM was not a major concern. SMR were able to remove 82% ± 0.2% of lead, 46% ± 0.6% of copper, 55% ±20% of zinc, and 17% ± 2% of nickel from river water spiked with 500 μg/L of each. Similarly,in wastewater, they were able to remove 86% ± 0.1% of lead, 38% ± 0.8% of copper, 28% ± 1%of zinc, and 11% ± 1% of nickel.
引文
Arora,M.,Kiran,B.,Rani,S.,Rani,A.,Kaur,B.,Mittal,N.,2008.Heavy metal accumulation in vegetables irrigated with water from different sources.Food Chem.111(4),811-815.
Babel,S.,Kurniawan,T.A.,2003.Low-cost adsorbents for heavy metals uptake from contaminated water:a review.J.Hazard.Mater.97(1-3),219-243.
Badruddoza,A.Z.M.,Shawon,Z.B.Z.,Tay,W.J.D.,Hidajat,K.,Uddin,M.S.,2013.Fe3O4/cyclodextrin polymer nanocomposites for selective heavy metals removal from industrial wastewater.Carbohydr.Polym.91(1),322-332.
Baes,C.F.,Mesmer,R.E.,1976.The Hydrolysis of Cations.John Wiley and Sons,Toronto.
Barakat,M.A.,2011.New trends in removing heavy metals from industrial wastewater.Arab.J.Chem.4(4),361-377.
Benjamin,M.,2002.Water Chemistry.McGraw Hill,Boston.
Fu,F.,Wang,Q.,2011.Removal of heavy metal ions from wastewaters:a review.J.Environ.Manag.92(3),407-418.
Ge,F.,Li,M.-M.,Ye,H.,Zhao,B.-X.,2012.Effective removal of heavy metal ions Cd2+,Zn2+,Pb2+,Cu2+from aqueous solution by polymer-modified magnetic nanoparticles.J.Hazard.Mater.211-212,366-372.
Gupta,V.K.,Agarwal,S.,Saleh,T.A.,2011.Chromium removal by combining the magnetic properties of iron oxide with adsorption properties of carbon nanotubes.Water Res.45(6),2207-2212.
Huang,S.H.,Chen,D.H.,2009.Rapid removal of heavy metal cations and anions from aqueous solutions by an amino-functionalized magnetic nano-adsorbent.J.Hazard.Mater.163(1),174-179.
Kurniawan,T.A.,Chan,G.Y.S.,Lo,W.-H.,Babel,S.,2006.Physico-chemical treatment techniques for wastewater laden with heavy metals.Chem.Eng.J.118(1-2),83-98.
Lai,E.P.C.,De Maleki,Z.,Wu,S.,2010.Characterization of molecularly imprinted and nonimprinted polymer submicron particles specifically tailored for removal of trace 17b-estradiol in water treatment.J.Appl.Polym.Sci.116(3),1499-1508.
Liao,M.H.,Chen,D.H.,2002.Preparation and characterization of a novel magnetic nano-adsorbent.J.Mater.Chem.12(12),3654-3659.
Liu,B.,Wang,D.,Yu,G.,Meng,X.,2013.Adsorption of heavy metal ions,dyes and proteins by chitosan composites and derivatives-a review.J.Ocean Univ.China 12(3),500-508.
Mapanda,F.,Mangwayana,E.N.,Nyamangara,J.,Giller,K.E.,2005.The effect of long-term irrigation using wastewater on heavy metal contents of soils under vegetables in Harare,Zimbabwe Agric.Ecosyst.Environ.107(2-3),151-165.
Murray,A.,?rmeci,B.,2018.Competitive effects of humic acid and wastewater on adsorption of Methylene Blue dye by activated carbon and non-imprinted polymers.J.Environ.Sci.66,310-317.
Murray,A.,?rmeci,B.,Lai,E.P.C.,2016.Removal of endocrine disrupting compounds from wastewater using polymer particles.Water Sci.Technol.73(1),17-181.
Pan,B.,Qiu,H.,Pan,B.,Nie,G.,Xiao,L.,Lv,L.,et al.,2010.Highly efficient removal of heavy metals by polymer-supported nanosized hydrated Fe(III)oxides:behavior and XPS study.Water Res.44(3),815-824.
Pyrzyńska,K.,Bystrzejewski,M.,2010.Comparative study of heavy metal ions sorption onto activated carbon,carbon nanotubes,and carbon-encapsulated magnetic nanoparticles.Colloids Surf.A Physicochem.Eng.Asp.362(1-3),102-109.
Ryan,J.,Pahren,H.,Lucas,J.,1982.Controlling cadmium in the human food chain:a review and rationale based on health effects.Environ.Res.28(2),251-302.
SenGupta,A.K.,2002.Environmental Separation of Heavy Metals:Engineering Processes.Lewis Publishers,CRC Press,Washington,D.C.
Singh,A.,Sharma,R.K.,Agrawal,M.,Marshall,F.M.,2010.Health risk assessment of heavy metals via dietary intake of foodstuffs from the wastewater irrigated site of a dry tropical area of India.Food Chem.Toxicol.48(2),611-619.
Stumm,W.,Morgan,J.,1981.Aquatic Chemistry:An Introduction Emphasizing Chemical Equilibria in Natural Waters.2nd ed.Wiley-Interscience,New York.
Tofighy,M.A.,Mohammadi,T.,2011.Adsorption of divalent heavy metal ions from water using carbon nanotube sheets.J.Hazard.Mater.185(1),140-147.
Toze,S.,2006.Reuse of effluent water-benefits and risks.Agric.Water Manag.80(1-3 SPEC.ISS),147-159.
Wang,X.,Sato,T.,Xing,B.,Tao,S.,2005.Health risks of heavy metals to the general public in Tianjin,China via consumption of vegetables and fish.Sci.Total Environ.350(1-3),28-37.
Wei,S.,Molinelli,A.,Mizaikoff,B.,2006.Molecularly imprinted micro and nanospheres for the selective recognition of17beta-estradiol.Biosens.Bioelectron.21(10),1943-1951.
Xiao,B.,Thomas,K.M.,2004.Competitive adsorption of aqueous metal ions on an oxidized nanoporous activated carbon.Langmuir 20(11),4566-4578.
Zhao,X.,Lv,L.,Pan,B.,Zhang,W.,Zhang,S.,Zhang,Q.,2011.Polymer-supported nanocomposites for environmental application:a review.Chem.Eng.J.170(2-3),381-394.
Babel,S.,Kurniawan,T.A.,2003.Low-cost adsorbents for heavy metals uptake from contaminated water:a review.J.Hazard.Mater.97(1-3),219-243.
Badruddoza,A.Z.M.,Shawon,Z.B.Z.,Tay,W.J.D.,Hidajat,K.,Uddin,M.S.,2013.Fe3O4/cyclodextrin polymer nanocomposites for selective heavy metals removal from industrial wastewater.Carbohydr.Polym.91(1),322-332.
Baes,C.F.,Mesmer,R.E.,1976.The Hydrolysis of Cations.John Wiley and Sons,Toronto.
Barakat,M.A.,2011.New trends in removing heavy metals from industrial wastewater.Arab.J.Chem.4(4),361-377.
Benjamin,M.,2002.Water Chemistry.McGraw Hill,Boston.
Fu,F.,Wang,Q.,2011.Removal of heavy metal ions from wastewaters:a review.J.Environ.Manag.92(3),407-418.
Ge,F.,Li,M.-M.,Ye,H.,Zhao,B.-X.,2012.Effective removal of heavy metal ions Cd2+,Zn2+,Pb2+,Cu2+from aqueous solution by polymer-modified magnetic nanoparticles.J.Hazard.Mater.211-212,366-372.
Gupta,V.K.,Agarwal,S.,Saleh,T.A.,2011.Chromium removal by combining the magnetic properties of iron oxide with adsorption properties of carbon nanotubes.Water Res.45(6),2207-2212.
Huang,S.H.,Chen,D.H.,2009.Rapid removal of heavy metal cations and anions from aqueous solutions by an amino-functionalized magnetic nano-adsorbent.J.Hazard.Mater.163(1),174-179.
Kurniawan,T.A.,Chan,G.Y.S.,Lo,W.-H.,Babel,S.,2006.Physico-chemical treatment techniques for wastewater laden with heavy metals.Chem.Eng.J.118(1-2),83-98.
Lai,E.P.C.,De Maleki,Z.,Wu,S.,2010.Characterization of molecularly imprinted and nonimprinted polymer submicron particles specifically tailored for removal of trace 17b-estradiol in water treatment.J.Appl.Polym.Sci.116(3),1499-1508.
Liao,M.H.,Chen,D.H.,2002.Preparation and characterization of a novel magnetic nano-adsorbent.J.Mater.Chem.12(12),3654-3659.
Liu,B.,Wang,D.,Yu,G.,Meng,X.,2013.Adsorption of heavy metal ions,dyes and proteins by chitosan composites and derivatives-a review.J.Ocean Univ.China 12(3),500-508.
Mapanda,F.,Mangwayana,E.N.,Nyamangara,J.,Giller,K.E.,2005.The effect of long-term irrigation using wastewater on heavy metal contents of soils under vegetables in Harare,Zimbabwe Agric.Ecosyst.Environ.107(2-3),151-165.
Murray,A.,?rmeci,B.,2018.Competitive effects of humic acid and wastewater on adsorption of Methylene Blue dye by activated carbon and non-imprinted polymers.J.Environ.Sci.66,310-317.
Murray,A.,?rmeci,B.,Lai,E.P.C.,2016.Removal of endocrine disrupting compounds from wastewater using polymer particles.Water Sci.Technol.73(1),17-181.
Pan,B.,Qiu,H.,Pan,B.,Nie,G.,Xiao,L.,Lv,L.,et al.,2010.Highly efficient removal of heavy metals by polymer-supported nanosized hydrated Fe(III)oxides:behavior and XPS study.Water Res.44(3),815-824.
Pyrzyńska,K.,Bystrzejewski,M.,2010.Comparative study of heavy metal ions sorption onto activated carbon,carbon nanotubes,and carbon-encapsulated magnetic nanoparticles.Colloids Surf.A Physicochem.Eng.Asp.362(1-3),102-109.
Ryan,J.,Pahren,H.,Lucas,J.,1982.Controlling cadmium in the human food chain:a review and rationale based on health effects.Environ.Res.28(2),251-302.
SenGupta,A.K.,2002.Environmental Separation of Heavy Metals:Engineering Processes.Lewis Publishers,CRC Press,Washington,D.C.
Singh,A.,Sharma,R.K.,Agrawal,M.,Marshall,F.M.,2010.Health risk assessment of heavy metals via dietary intake of foodstuffs from the wastewater irrigated site of a dry tropical area of India.Food Chem.Toxicol.48(2),611-619.
Stumm,W.,Morgan,J.,1981.Aquatic Chemistry:An Introduction Emphasizing Chemical Equilibria in Natural Waters.2nd ed.Wiley-Interscience,New York.
Tofighy,M.A.,Mohammadi,T.,2011.Adsorption of divalent heavy metal ions from water using carbon nanotube sheets.J.Hazard.Mater.185(1),140-147.
Toze,S.,2006.Reuse of effluent water-benefits and risks.Agric.Water Manag.80(1-3 SPEC.ISS),147-159.
Wang,X.,Sato,T.,Xing,B.,Tao,S.,2005.Health risks of heavy metals to the general public in Tianjin,China via consumption of vegetables and fish.Sci.Total Environ.350(1-3),28-37.
Wei,S.,Molinelli,A.,Mizaikoff,B.,2006.Molecularly imprinted micro and nanospheres for the selective recognition of17beta-estradiol.Biosens.Bioelectron.21(10),1943-1951.
Xiao,B.,Thomas,K.M.,2004.Competitive adsorption of aqueous metal ions on an oxidized nanoporous activated carbon.Langmuir 20(11),4566-4578.
Zhao,X.,Lv,L.,Pan,B.,Zhang,W.,Zhang,S.,Zhang,Q.,2011.Polymer-supported nanocomposites for environmental application:a review.Chem.Eng.J.170(2-3),381-394.