界面剪切流变技术在化学驱油体系应用研究进展
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摘要
界面剪切流变技术可以提供化学驱油体系油水界面的结构和强度等信息,因此逐渐成为近年来研究化学驱油机理的重要方法。介绍了界面剪切流变技术的理论基础与测量方法,并对该技术在化学驱油体系的研究进展进行了综述,重点包括在驱油剂溶液、原油(模拟油)/水和原油(模拟油)/驱油剂三类体系中的应用现状。对界面剪切流变技术面临主要挑战和未来发展方向进行了展望。
Interfacial shear rheology technology can provide information about the structure and strength of oil-water interface in chemical flooding system.Therefore,this technology has gradually become an important method to study chemical flooding mechanism in recent years.In this paper,theoretical basis and measurement methods of interfacial shear rheology are introduced.In addition,research progress on the application of interfacial shear rheology in chemical displacement system is summarized with the emphasis on the application of three types of systems:oil displacement solution,crude oil(simulated oil)/water and crude oil(simulated oil)/oil displacement agent.The main challenges and development trends of interface shear rheology technology are also prospected.
Interfacial shear rheology technology can provide information about the structure and strength of oil-water interface in chemical flooding system.Therefore,this technology has gradually become an important method to study chemical flooding mechanism in recent years.In this paper,theoretical basis and measurement methods of interfacial shear rheology are introduced.In addition,research progress on the application of interfacial shear rheology in chemical displacement system is summarized with the emphasis on the application of three types of systems:oil displacement solution,crude oil(simulated oil)/water and crude oil(simulated oil)/oil displacement agent.The main challenges and development trends of interface shear rheology technology are also prospected.
引文
[1]Cao X L,Li J,Yang Y,et al.Effects of Surfactants on Interfacial Shear Rheological Properties of Polymers for Enhanced Oil Recovery[J].Acta Phys Chim Sin,2014,30(5),908-916(in Chinese).(曹绪龙,李静,杨勇,等.表面活性剂对驱油聚合物界面剪切流变性质的影响[J].物理化学学报,2014,30(5):908-916.)
[2]Zhan Y Q,Wan X Y,Wang Y J,et al.Research Progress of Nanoparticles in Oil Field Flooding[J].Mod Chem Ind,2016,(8):37-40(in Chinese).(詹迎青,万昕艺,王雅洁,等.纳米粒子在油田驱油中的研究进展[J].现代化工,2016,(8):37-40.)
[3]Shu N K,Xu Z C,Liu Z Y,et al.Effect of Short Alkyl Chain on Interfacial Properties of Poly-substituted Alkyl Benzene Sulfonate[J].Acta Phys-Chim Sin,2017,33(4),803-809(in Chinese).(束宁凯,徐志成,刘子瑜,等.短链烷基对多取代烷基苯磺酸盐界面性质的影响[J].物理化学学报,2017,33(4):803-809.)
[4]Zhao C Y,Tang S F,Tian L,et al.Study on Viscosity Behavior of Carboxylate Gemini Surfactant Solution[J].Mod Chem Ind,2017,32(2):125-128(in Chinese).(赵成洋,唐善法,田磊,等.羧酸盐双子表面活性剂溶液黏度行为研究[J].现代化工,2017,32(2):125-128.)
[5]Dhukin S,Kretzschmar G,Miller R.Dynamics of Adsorption at Liquid Interfaces[M].Amsterdam:Elsevier,1995:425-431.
[6]Soo-gun Oh,Slattery J.C.Disk and Biconical Interfacial Viscometer[J].J Colloid Interface Sci,1978,67(3):154-159.
[7]Ray Y C,Lee H O.Oscillatory Torsional Interfacial Viseometer[J].J Colloid Interface Sci,1987,119(1):81-99.
[8]Li J,Yang Y,Cao X L,et al.Interfacial Shear Rheological Properties of Enhanced Oil Recovery Polymers with Different Structures[J].Chem J Chin Univ,2014,35(4):791-797(in Chinese).(李静,杨勇,曹绪龙,等.不同结构驱油聚合物的界面剪切流变性质[J].高等学校化学学报,2014,35(4):791-797.)
[9]Briley P B,Deemer A R,Slattery J C.Blunt Knifeedge and Disk Surface Viseometers[J].J Colloid Interface Sci,1976,56(1):32-38.
[10]Liggieri L,Ferrari M,Mondelli D,et al.Surface Rheology as a Tool for the Investigation of Processes Internal to Surfactant Adsorption Layers[J].Faraday Discuss,2005,129(8):125-140.
[11]Mohan V.Effect of Aging on Surace Shear Vscosity of Surfactant Solutions[J].J Colloid Interface Sci,1976,57(3):197-202.
[12]Gupta L,Wasan D T.Surface Shear Viscosity and Related Properties of Adsorbed Surfactant Films[J].Ind Eng Chem Fundam,1974,13(1):26-33.
[13]Cicuta P.Compression and Shear Surface Rheology in Spread Layers ofβ-Casein andβ-Lactoglobulin[J].JColloid Interface Sci,2007,308(1):93-99.
[14]Peng J B,Barnes G T,Abraham B M.The Shear Viscoelastic Properties of Poly(Methyl Methacrylate)and Poly(vinyl Stearate)Monolayers on Water[J].Langmuir,1993,12(9):3 574-3 579.
[15]Benmekhbi M,Simon S.Limitations and Applicability of the Interfacial Shear Rheology in the Study of Monolayer Films at the Air-water Interface[J].JDispersion Sci Technol,2014,35(1):150-160.
[16]Mohan V,Gupta L,Wasan D T.Effect of Aging on Surface Shear Viscosity of Surfactant Solutions[J].JColloid Interface Sci,1976,57(3):496-503.
[17]Lee H O,Jiang T S,Avramidis K S.Measurements of Interfacial Shear Viscoelasticity with an Oscillatory Torsional Viscometer[J].J Colloid Interface Sci,1991,146(1):90-122.
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[19]Birbaum F C,Haavisto S,Koponen A,et al.Shear Localisation in Interfacial Particle Layers and Its Influence on Lissajous-plots[J].Rheol Acta,2016,55(4):1-12.
[20]Wüstneck R,Hermel H,Kretzschmar G.On the Relation between the Molecular Mass Distribution of Gelatin and Its Ability to Stabilize Emulsions[J].Colloid Polym Sci,1984,262(4):827-832.
[21]Hohnerfuss H.Surface Viscosity Measurementa Revival of a Nearly Forgotten Surface Chemical Method[J].J Colloid Interface Sci,1985,107(1):84-95.
[22]Hohnerfuss H,Lange P A,Walter W.Relaxation Effects in Monolayers and Their Contribution to Water Wave Damping.Ⅱ.The Marangoni Phenomenon and Gravity Wave Attenuation[J].J Colloid Interface Sci,1985,108(2):442-450.
[23]Fan Y R,Simon S,Sjoblom J.Interfacial Shear Rheology of Asphaltenes at Oil-water Interface and Its Relation to Emulsion Stability:Influence of Concentration,Solvent Aromaticity and Nonionic Surfactant[J].Colloids Surf A,2010,366(1):120-128.
[24]Xu M J,Li M Y,Peng B,et al.Effect of Molecular Parameters of Asphaltene and Resin from Saudi Arabia Crude Oil on Oil-water Interfacial Properties[J].Fine Chem,2007,24(5):462-465(in Chinese).(徐明进,李明远,彭勃,等.沙特原油活性组分的结构对油水界面性质的影响[J].精细化工,2007,24(5):462-465.)
[25]Yang X L,Lu W Z,Li M Y,et al.Study on Interfacial Properties of Asphaltenes and Resins from Liaohe Crude[J].Acta Pet Sin(Pet Process Sect),1999,15(4):1-6(in Chinese).(杨小莉,陆婉珍,李明远,等.辽河原油沥青质及胶质油水界面化学性质初探[J].石油学报(石油加工),1999,15(4):1-6.)
[26]Chang C C,Nowbahar A,Mansard V,et al.Interfacial Rheology and Heterogeneity of Aging Asphaltene Layers at the Water-oil Interface[J].Prog Polym Sci,2015,36(12):1 697-1 753.
[27]Wasan D T,Shah S,Aderangi N.Observation on the Coalescence Behavior of Oil Droplets and Emulsion Stability in En-hanced Oil Recovery[J].SPE J,1978,18(6):409-417.
[28]Dahami M A,Constant W D,Wolcott J M.Alcoholassisted Alkaline Flooding for Enhanced Oil Recovery[J].Fuel,1988,67(9):1 242-1 248.
[29]Gunning A P,Mackie A R,Wilde P J,et al.Atomic Force Microscopy of Emulsion Droplets:Probing Droplet-droplet Interactions[J].Langmuir,2004,20(1):116-122.
[30]Dickinsion E,Murray B S,Stainsby G.Mixed Protein Films Adsorbed at the Oil-water Interface[J].Chem Soc,1988,1(8):871-883.
[31]Zhao Y,Hu J L,Li H C,et al.Effect of Heavy Oil Constituents on the Oil-water Interfacial Properties and Emulsion Stability[J].J Petrochem Univ,2016,29(6):32-38(in Chinese).(赵毅,胡景磊,李浩程,等.塔河稠油活性组分对油水界面性质和乳状液稳定性的影响[J].石油化工高等学校学报,2016,29(6):32-38.)
[32]Yan F,Zhang J,Fu T Y.Properties and Demulsification Laws of Crude Oil Emulsions in Hydrophobically Associating Polymer Flooding System[J].Acta Pet Sin(Pet Process Sect),2016,32(3):546-555(in Chinese).(严峰,张建,付天宇.疏水缔合聚合物驱体系中原油乳状液性质及破乳规律[J].石油学报(石油加工),2016,32(3):546-555.)
[33]Hua Z,Zhang J,Hao L,et al.Effect of Active Components in Bohai Heavy Oil on Water-oil Interfacial Properties and Emulsion Stability[J].Oilfield Chem,2017,34(4):626-630(in Chinese).(华朝,张健,李浩,等.渤海典型稠油活性组分对油水界面性质及乳状液稳定性的影响[J].油田化学,2017,34(4):626-630.)
[34]Lin Y J,Sourav Barman,Peng he,et al.Combined Interfacial Shear Rheology and Microstructure Visualization of Aphaltenes at Air-water and Oil-water Interfaces[J].J Rheol,2018,62(1):1-10.
[35]Wasan D T,Shah S H,Aderangi N.Observation on the Coalescence Behavior of Oil Droplets and Emulsion Stability in Enhanced Oil Recovery[J].Soc Pet Eng J,1978,18(6):409-417.
[36]Lakatos-Szabo J,Lakatos I.Effect of Alkaline Material on Interfacial Rheological Properties of Oil-water Systems[J].Colloid Polym Sci,1999,277(1):41-47.
[37]Wang X P,Zhang J Y,Tang J A,et al.Interfacial Rheology Investigation of Polyacrylamide-surfactant Interactions[J].Acta Phys-Chim Sin,1998,14(1):88-92(in Chinese).(王新平,张嘉云,唐季安,等.表面活性剂与聚丙烯酰胺在油水界面的流变性[J].物理化学学报,1998,14(1):88-92.)
[38]Liu W D,Tong Z X,Li M Y,et al.Interfacial Viscosity for Crude Oil/Chemical Flooding Solution Systems[J].Oilfield Chem,2000,17(4):337-339(in Chinese).(刘卫东,童正新,李明远,等.化学驱油体系的油/水界面黏度[J].油田化学,2000,17(4):337-339.)
[39]Wang H Y,Fang H B,Wu Z L,et al.Influence of Petroleum Sulfonate on Interfacial Properties of Crude Oil,Resin and Asphaltene from Shengli Oilfield[J].J Univ Petrol China,2000,17(4):337-339(in Chinese).(王慧云,方洪波,吴肇亮,等.石油磺酸盐对胜利油田原油、胶质、沥青质界面性质的影响[J].石油大学学报(自然科学版),2005,29(2):112-116.)
[40]Lin M Q,Zhou L J,Li M Y,et al.Effect of Polymer on Interfacial Properties of Gudao Asphaltene Model Oil/Water[J].J Chin Univ Petrol(Ed Nat Sci),2007,31(4):126-129(in Chinese).(林梅钦,周立娟,李明远,等.聚合物对孤岛沥青质模拟油/水界面性质的影响[J].中国石油大学学报(自然科学版),2007,4(31):126-129.)
[41]Yang Y,Li J,Cao X L,et al.Interfacial Shear Rheological Properties of Diethylenetriamine-ling Chain Fatty Acids System[J].Acta Petrol Sin(Petrol Process Sec),2014,30(6):1 059-1 064(in Chinese).(杨勇,李静,曹绪龙,等.二乙烯三胺-长链脂肪酸体系的界面剪切流变性质[J].石油学报(石油加工),2014,30(6):1 059-1 064.)
[42]Hou J R,Xie Y Y,Zhao F L,et al.Effects of Components in Combination System on Oil-water Interfacial Shear Viscoelasticity[J].Petroleum Geology and Recovery Efficiency,2015,22(1):68-73.(侯吉瑞,谢玉银,赵凤兰,等.复合体系各组分对油水界面剪切黏弹性的影响规律[J].油气地质与采收率,2015,22(1):68-73.)
[43]Simon S,Subramanian S,Gao B C,et al.Interfacial Shear Rheology of Gels Formed at the Oil/Water Interface by Tetrameric Acid and Calcium Ion:Influence of Tetrameric Acid Structure and Oil Composition[J].Ind Eng Chem Res,2015,54(35):8 713-8 722.
[44]Pradilla D,Simon S,Sj9blom J.Sorption and Interfacial Rheology Study of Modelmasphaltene Compounds[J].Langmuir the Acs J Surf Colloids,2016,32(12):1-47.
[2]Zhan Y Q,Wan X Y,Wang Y J,et al.Research Progress of Nanoparticles in Oil Field Flooding[J].Mod Chem Ind,2016,(8):37-40(in Chinese).(詹迎青,万昕艺,王雅洁,等.纳米粒子在油田驱油中的研究进展[J].现代化工,2016,(8):37-40.)
[3]Shu N K,Xu Z C,Liu Z Y,et al.Effect of Short Alkyl Chain on Interfacial Properties of Poly-substituted Alkyl Benzene Sulfonate[J].Acta Phys-Chim Sin,2017,33(4),803-809(in Chinese).(束宁凯,徐志成,刘子瑜,等.短链烷基对多取代烷基苯磺酸盐界面性质的影响[J].物理化学学报,2017,33(4):803-809.)
[4]Zhao C Y,Tang S F,Tian L,et al.Study on Viscosity Behavior of Carboxylate Gemini Surfactant Solution[J].Mod Chem Ind,2017,32(2):125-128(in Chinese).(赵成洋,唐善法,田磊,等.羧酸盐双子表面活性剂溶液黏度行为研究[J].现代化工,2017,32(2):125-128.)
[5]Dhukin S,Kretzschmar G,Miller R.Dynamics of Adsorption at Liquid Interfaces[M].Amsterdam:Elsevier,1995:425-431.
[6]Soo-gun Oh,Slattery J.C.Disk and Biconical Interfacial Viscometer[J].J Colloid Interface Sci,1978,67(3):154-159.
[7]Ray Y C,Lee H O.Oscillatory Torsional Interfacial Viseometer[J].J Colloid Interface Sci,1987,119(1):81-99.
[8]Li J,Yang Y,Cao X L,et al.Interfacial Shear Rheological Properties of Enhanced Oil Recovery Polymers with Different Structures[J].Chem J Chin Univ,2014,35(4):791-797(in Chinese).(李静,杨勇,曹绪龙,等.不同结构驱油聚合物的界面剪切流变性质[J].高等学校化学学报,2014,35(4):791-797.)
[9]Briley P B,Deemer A R,Slattery J C.Blunt Knifeedge and Disk Surface Viseometers[J].J Colloid Interface Sci,1976,56(1):32-38.
[10]Liggieri L,Ferrari M,Mondelli D,et al.Surface Rheology as a Tool for the Investigation of Processes Internal to Surfactant Adsorption Layers[J].Faraday Discuss,2005,129(8):125-140.
[11]Mohan V.Effect of Aging on Surace Shear Vscosity of Surfactant Solutions[J].J Colloid Interface Sci,1976,57(3):197-202.
[12]Gupta L,Wasan D T.Surface Shear Viscosity and Related Properties of Adsorbed Surfactant Films[J].Ind Eng Chem Fundam,1974,13(1):26-33.
[13]Cicuta P.Compression and Shear Surface Rheology in Spread Layers ofβ-Casein andβ-Lactoglobulin[J].JColloid Interface Sci,2007,308(1):93-99.
[14]Peng J B,Barnes G T,Abraham B M.The Shear Viscoelastic Properties of Poly(Methyl Methacrylate)and Poly(vinyl Stearate)Monolayers on Water[J].Langmuir,1993,12(9):3 574-3 579.
[15]Benmekhbi M,Simon S.Limitations and Applicability of the Interfacial Shear Rheology in the Study of Monolayer Films at the Air-water Interface[J].JDispersion Sci Technol,2014,35(1):150-160.
[16]Mohan V,Gupta L,Wasan D T.Effect of Aging on Surface Shear Viscosity of Surfactant Solutions[J].JColloid Interface Sci,1976,57(3):496-503.
[17]Lee H O,Jiang T S,Avramidis K S.Measurements of Interfacial Shear Viscoelasticity with an Oscillatory Torsional Viscometer[J].J Colloid Interface Sci,1991,146(1):90-122.
[18]Guo Y M,Li M Y,He Z H,et al.The Effects of Polymer and Surfactant on the Interfacial Viscosity Between Crude Model Oil and Water[J].Appli Chem Ind,2009,38(9):1 300-1 303(in Chinese).(郭亚梅,李明远,贺宗辉,等.聚合物-表面活性剂对油/水界面剪切黏度的影响[J].应用化工,2009,38(9):1 300-1 303.)
[19]Birbaum F C,Haavisto S,Koponen A,et al.Shear Localisation in Interfacial Particle Layers and Its Influence on Lissajous-plots[J].Rheol Acta,2016,55(4):1-12.
[20]Wüstneck R,Hermel H,Kretzschmar G.On the Relation between the Molecular Mass Distribution of Gelatin and Its Ability to Stabilize Emulsions[J].Colloid Polym Sci,1984,262(4):827-832.
[21]Hohnerfuss H.Surface Viscosity Measurementa Revival of a Nearly Forgotten Surface Chemical Method[J].J Colloid Interface Sci,1985,107(1):84-95.
[22]Hohnerfuss H,Lange P A,Walter W.Relaxation Effects in Monolayers and Their Contribution to Water Wave Damping.Ⅱ.The Marangoni Phenomenon and Gravity Wave Attenuation[J].J Colloid Interface Sci,1985,108(2):442-450.
[23]Fan Y R,Simon S,Sjoblom J.Interfacial Shear Rheology of Asphaltenes at Oil-water Interface and Its Relation to Emulsion Stability:Influence of Concentration,Solvent Aromaticity and Nonionic Surfactant[J].Colloids Surf A,2010,366(1):120-128.
[24]Xu M J,Li M Y,Peng B,et al.Effect of Molecular Parameters of Asphaltene and Resin from Saudi Arabia Crude Oil on Oil-water Interfacial Properties[J].Fine Chem,2007,24(5):462-465(in Chinese).(徐明进,李明远,彭勃,等.沙特原油活性组分的结构对油水界面性质的影响[J].精细化工,2007,24(5):462-465.)
[25]Yang X L,Lu W Z,Li M Y,et al.Study on Interfacial Properties of Asphaltenes and Resins from Liaohe Crude[J].Acta Pet Sin(Pet Process Sect),1999,15(4):1-6(in Chinese).(杨小莉,陆婉珍,李明远,等.辽河原油沥青质及胶质油水界面化学性质初探[J].石油学报(石油加工),1999,15(4):1-6.)
[26]Chang C C,Nowbahar A,Mansard V,et al.Interfacial Rheology and Heterogeneity of Aging Asphaltene Layers at the Water-oil Interface[J].Prog Polym Sci,2015,36(12):1 697-1 753.
[27]Wasan D T,Shah S,Aderangi N.Observation on the Coalescence Behavior of Oil Droplets and Emulsion Stability in En-hanced Oil Recovery[J].SPE J,1978,18(6):409-417.
[28]Dahami M A,Constant W D,Wolcott J M.Alcoholassisted Alkaline Flooding for Enhanced Oil Recovery[J].Fuel,1988,67(9):1 242-1 248.
[29]Gunning A P,Mackie A R,Wilde P J,et al.Atomic Force Microscopy of Emulsion Droplets:Probing Droplet-droplet Interactions[J].Langmuir,2004,20(1):116-122.
[30]Dickinsion E,Murray B S,Stainsby G.Mixed Protein Films Adsorbed at the Oil-water Interface[J].Chem Soc,1988,1(8):871-883.
[31]Zhao Y,Hu J L,Li H C,et al.Effect of Heavy Oil Constituents on the Oil-water Interfacial Properties and Emulsion Stability[J].J Petrochem Univ,2016,29(6):32-38(in Chinese).(赵毅,胡景磊,李浩程,等.塔河稠油活性组分对油水界面性质和乳状液稳定性的影响[J].石油化工高等学校学报,2016,29(6):32-38.)
[32]Yan F,Zhang J,Fu T Y.Properties and Demulsification Laws of Crude Oil Emulsions in Hydrophobically Associating Polymer Flooding System[J].Acta Pet Sin(Pet Process Sect),2016,32(3):546-555(in Chinese).(严峰,张建,付天宇.疏水缔合聚合物驱体系中原油乳状液性质及破乳规律[J].石油学报(石油加工),2016,32(3):546-555.)
[33]Hua Z,Zhang J,Hao L,et al.Effect of Active Components in Bohai Heavy Oil on Water-oil Interfacial Properties and Emulsion Stability[J].Oilfield Chem,2017,34(4):626-630(in Chinese).(华朝,张健,李浩,等.渤海典型稠油活性组分对油水界面性质及乳状液稳定性的影响[J].油田化学,2017,34(4):626-630.)
[34]Lin Y J,Sourav Barman,Peng he,et al.Combined Interfacial Shear Rheology and Microstructure Visualization of Aphaltenes at Air-water and Oil-water Interfaces[J].J Rheol,2018,62(1):1-10.
[35]Wasan D T,Shah S H,Aderangi N.Observation on the Coalescence Behavior of Oil Droplets and Emulsion Stability in Enhanced Oil Recovery[J].Soc Pet Eng J,1978,18(6):409-417.
[36]Lakatos-Szabo J,Lakatos I.Effect of Alkaline Material on Interfacial Rheological Properties of Oil-water Systems[J].Colloid Polym Sci,1999,277(1):41-47.
[37]Wang X P,Zhang J Y,Tang J A,et al.Interfacial Rheology Investigation of Polyacrylamide-surfactant Interactions[J].Acta Phys-Chim Sin,1998,14(1):88-92(in Chinese).(王新平,张嘉云,唐季安,等.表面活性剂与聚丙烯酰胺在油水界面的流变性[J].物理化学学报,1998,14(1):88-92.)
[38]Liu W D,Tong Z X,Li M Y,et al.Interfacial Viscosity for Crude Oil/Chemical Flooding Solution Systems[J].Oilfield Chem,2000,17(4):337-339(in Chinese).(刘卫东,童正新,李明远,等.化学驱油体系的油/水界面黏度[J].油田化学,2000,17(4):337-339.)
[39]Wang H Y,Fang H B,Wu Z L,et al.Influence of Petroleum Sulfonate on Interfacial Properties of Crude Oil,Resin and Asphaltene from Shengli Oilfield[J].J Univ Petrol China,2000,17(4):337-339(in Chinese).(王慧云,方洪波,吴肇亮,等.石油磺酸盐对胜利油田原油、胶质、沥青质界面性质的影响[J].石油大学学报(自然科学版),2005,29(2):112-116.)
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