用于喷墨打印电子器件的石墨烯墨水的制备及应用进展研究
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摘要
喷墨打印技术具有低成本、环境友好、图案均匀、加工连续性好等优势,使生产大面积柔性电子器件成为可能,而喷墨打印导电墨水的制备是喷墨打印电子技术得以蓬勃发展的关键所在。石墨烯是由碳原子紧密堆积而成的二维晶体,具有超薄、超轻、超高强度、高的导电导热性和透光性,结构稳定等特点。现在大量的研究将石墨烯制成导电墨水用于喷墨打印技术中,本文主要介绍了应用在喷墨打印技术中的两类石墨烯墨水的制备方法,并结合国内外研究前沿介绍了这两种墨水在传感器、超级电容器、薄膜晶体管等方面的应用,并指出喷印石墨烯墨水的未来挑战。
Inkjet printing has lots of advantages,such as low cost,environment friendly,uniform pattern and processing continuity,which can be used to product large and flexible electronic devices.It is the key to prepare conductive inks in the inkjet printing.Graphene was a one-carbon atom-thick two-dimensional(2D) single layer,which has been used to make conductive ink for inkjet printing technology owing to itsperfect characteristics,such asultra-thin,ultra-light,high transmittance,high strength,high electrical and thermal conductivity.Now a lot of researches aboutgraphene has been introduced.In this article,two major synthesis methods of conductive graphene inksare introduced.And their application in inkjet printingsuch assensor,supercapacitors,thin-film transistorare briefly discussedcombine to the current research situation Finally,we present the challenges for conductive graphene inks.
Inkjet printing has lots of advantages,such as low cost,environment friendly,uniform pattern and processing continuity,which can be used to product large and flexible electronic devices.It is the key to prepare conductive inks in the inkjet printing.Graphene was a one-carbon atom-thick two-dimensional(2D) single layer,which has been used to make conductive ink for inkjet printing technology owing to itsperfect characteristics,such asultra-thin,ultra-light,high transmittance,high strength,high electrical and thermal conductivity.Now a lot of researches aboutgraphene has been introduced.In this article,two major synthesis methods of conductive graphene inksare introduced.And their application in inkjet printingsuch assensor,supercapacitors,thin-film transistorare briefly discussedcombine to the current research situation Finally,we present the challenges for conductive graphene inks.
引文
[1]邢汝博,丁艳,韩艳春.喷墨打印图案化高分子薄膜及其在有机电子器件加工中的应用[J].分子科学学报,2007,2:75-81.
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[8]Kosmala A,Zhang Q,Wright R,et al.Development of high concentrated aqueous silver nano-uid and inkjet printing on ceramic substrates[J].Materials Chemistry and Physics,2012,2:788-795.
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[11]Oh-Sun Kwona,Hansu Kima,Hyojin Koa,et al.Fabrication and characterization of inkjet-printed carbonnanotube electrode patterns on paper[J].CARBON,2013,58:116-127.
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[13]Bolotin,KI,et al.Ultrahigh electron mobility in suspended graphene[J].Solid State Commun.,2008,146:351-355.
[14]Novoselov,K.S.,Geim,A.K.,et al.Electric field effect in atomically thin carbon films[J].Science,2004,306:666-669.
[15]Kim,K.S.,Zhao,Y.,Jang,H.,et al.Large-scale pattern growth of graphene films for stretchable transparent electrodes[J].Nature,2009,457:706-710.
[16]Mattevi C,Kim H,Chhowalla M..A review of chemical vapour deposition of graphene on copper[J].Journal of Materials Chemistry,2011:3324-3334.
[17]Felice Torrisi,Tawfique Hasan,Weiping Wu et al.Inkjet-Printed Graphene Electronics[J].ACSNano 2012,6:2992-3006.
[18]Jiantong Li,Fei Ye,Sam Vaziri,et al.Efficient Inkjet Printing of Graphene[J].Adv.Mater.,2013,25:3985-3992.
[19]Ethan B.Secor,et al.Inkjet Printing of High Conductivity,Flexible Graphene Patterns[J].J.Phys.Chem.Lett.,2013,4(8):1347-1351.
[20]Vineet Dua,Sumedh P.Surwade,Srikanth Ammu,et al.All-Organic Vapor Sensor Using Inkjet-Printed Reduced Graphene Oxide[J].Angew.Chem.Int.Ed.,2010,49:1-5.
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[22]C.L.Lee,et al.Graphenenanosheets as ink particles for inkjet printing on flexible Board[J].Chemical Engineering Journal,2013,230:296-302.
[23]Yanfei Xu,Ingolf Hennig,Dieter Freyberg,et al.Inkjet-printed energy storage device using graphene/polyanilineinks[J].Journal of Power Sources,2014,248:483-488.
[24]G.Wang et al.Annealed graphene sheets decorated with silver nanoparticles for inkjet printing[J].Chemical Engineering Journal,2015,260:582-589.
[25]R.Giardi.S,Porro.A,Chiolerio.E,et al.Inkjet printed acrylic formulations based on UV-reduced graphene oxide nanocomposites[J].J Mater Sci,2013,48:1249-1255.
[26]M.Sangermano,M.Sturari,A.,et al.Study of Ink-Jet Printable Vinyl Ether-Graphene UV-Curable Formulations[J].Macromol.Mater.Eng.,2015,300:340-345.
[27]Lin,Z.,Yao,Y.,Li,Z.,et al.Solvent-assisted thermal reduction of graphite oxide[J],J.Phys.Chem.C,2010,114,(35):14819-14825.
[28]Fazel Yavari,Nikhil Koratkar.Graphene-Based Chemical Sensors[J].J.Phys.Chem.Lett.2012,3:1746-1753.
[29]Taoran Le,Vasileios Lakafosis,et al.Inkjet-Printed Graphene-Based Wireless Gas Sensor Modules[J],2012 IEEE:1003-1008.
[30]Le,T.,Lakafosis,V.,Thai,T.,et al.Inkjet printing of graphene thin films for wireless sensing applications[J].2012 ICEAA,2012:954-957.
[31]Lu Huang,Yi Huang,Jiajie Liang,et al.Graphene-Based Conducting Inks for Direct Inkjet Printing of Flexible Conductive Patterns and Their Applications in Electric Circuits and Chemical Sensors[J].Nano Res.,2011,4(7):675-684.
[32]Chakrit Sriprachuabwong,Chanpen Karuwan,Anurat Wisitsorrat,et al.Inkjet-printed graphene-PEDOT:PSS modified screen printed carbon electrode for biochemical sensing[J].J.Mater.Chem.,2012,22:5478.
[33]Qingsong Mei,Zhongping Zhang.Photoluminescent Graphene Oxide Ink to Print Sensors onto Microporous Membranes for Versatile Visualization Bioassays[J].Angew.Chem.Int.Ed.,2012,51:5602-5606.
[34]Hui Zhang,Anjian Xie,Yuhua Shen,et al.Layer-by-layer inkjet printing of fabricating reduced graphene-polyoxometalate composite film for chemical sensors[J].Phys.Chem.Chem.Phys.,2012,14:12757-12763.
[35]De Kong,Linh T.Le,Yue Li,James L.Zunino,et al.TemperatureDependent Electrical Properties of Graphene Inkjet-Printed on Flexible Materials[J].Langmuir,2012,28:13467-13472.
[36]Le L,Ervin M,Qiu H.Inkjet-printed graphene for flexible microsupercapacitors[J].Nanotechnology(IEEE-NANO),2011:67-71.
[37]Linh T.Le,Matthew H.Ervin,Hongwei Qiu,et al.Graphenesupercapacitor electrodes fabricated by inkjet printing and thermal reduction of graphene oxide[J].Electrochemistry Communications,2011(13):355-358.
[38]Yanfei Xu,Ingolf Hennig,Dieter Freyberg,et al.Inkjet-printed energy storage device using graphene/polyanilineinks[J].Journal of Power Sources,2014(248):483-488.
[39]Kai Chi,Zheye Zhang,Jiangbo Xi,et al.Freestanding Graphene Paper Supported Three-Dimensional Porous Graphen ePolyaniline Nanocomposite Synthesized by Inkjet Printing and in Flexible All-Solid-State Supercapacitor[J].ACS Appl.Mater.Interfaces,2014,6:16312-16319.
[40]Kiran Kumar Manga,Shuai Wang,Manu Jaiswal,et al.High-Gain Graphene-Titanium Oxide Photoconductor Made from Inkjet Printable Ionic Solution[J].Adv.Mater.,2010,22:5265-5270.
[41]Soojin Lim,Boseok Kang,Donghoon Kwak,et al.Inkjet-Printed Reduced Graphene Oxide/Poly(Vinyl Alcohol)Composite Electrodes for Flexible Transparent Organic Field-Effect Transistors[J].J.Phys.Chem.C,2012,116:7520-7525.
[42]Keun-Young Shin,Jin-Yong Hong,J yongsik Jang.Micropatterning of Graphene Sheets by Inkjet Printing and Its Wideband Dipole-Antenna Application[J].Adv.Mater.,2011,23:2113-2118.
[43]Keun-Young Shin,Jin-Yong Hong,Jyongsik Jang.Flexible and transparent graphene films as acoustic actuator electrodes using inkjet printing[J].Chem.Commun.,2011,47:8527-8529.
[44]Yang Su,Jinhong Du,Dongming Sun,et al.Reduced graphene oxide with a highly restoredπ-conjugated structure for inkjet printing and its use in all-carbon transistors[J].Nano Research,2013,6(11):842-852.
[45]Ethan B.Secor,Bok Y.Ahn,T heodore Z.Gao,et al.Rapid and Versatile Photonic Annealing of Graphene Inks for Flexible Printed Electronics[J].Adv.Mater.,2015,28:1-6.
[46]Jin-Yong Hong,Keun-Young Shin,Haeyoung Kang,et al.A strategy for fabricating single layer graphene sheets based on a layer-by-layer self-assembly[J].Chem.Commun.,2011,47:7182-7184.
[47]Kukjoo Kim,Sung Il Ahn,Kyung Cheol Choi.Simultaneous synthesis and patterning of graphene electrodes by reactive inkjet printing[J].CARBON,2014(66):172-177.
[48]林金堵.喷墨打印技术在PCB中的应用前景[J].印制电路信息,2008,4:9-13.
[2]Hennek,J.W.,Xia,Y.,Everaerts,K.,et al.Reduced Contact Resistance in Inkjet Printed High-Performance Amorphous Indium Gallium Zinc Oxide Transistors[J].ACS Appl.Mater.Interfaces.,2012,4:1614-1619.
[3]Hoth,C.N.Schilinsky,P.,Choulis,S.A.,et al.Printing Highly Efficient Organic Solar Cells[J].Nano Lett.,2008,8:2806-2813.
[4]Lavery,L.L.,Whiting,G.L.,Arias,A.C.All Ink-Jet Printed Polyfluorene Photosensor for High Illuminance Detection[J].Org.Electron.,2011,12:682-685.
[5]Li Y,Amin R,Rushi V,et al.RFID tag and RF structures on a paper substrate using inkjet printing technology[J].IEEE Transactions on Microwave Theory and Techniques,2007,12:2894-2901.
[6]Wood,V.,Panzer,M.J.,Chen,J.,et al.Inkjet-Printed Quantum Dot-Polymer Composites for Full-Color AC-Driven Displays[J].Adv.Mater.,2009,21:2151-2155.
[7]Peter Harrop,Harry Zervos.Batteries,Supercapacitors,Alternative Storage for Portable Devices 2009-2019[J].IDTech Ex,www.idtechex.com.
[8]Kosmala A,Zhang Q,Wright R,et al.Development of high concentrated aqueous silver nano-uid and inkjet printing on ceramic substrates[J].Materials Chemistry and Physics,2012,2:788-795.
[9]Arjun Singh,et al.Understanding the formation of PEDOT:PSS films by ink-jet printing for organic solar cell applications[J].RSC Adv.,2015,5:78677-78685.
[10]Z.Pan,et al.Recent development on preparation of ceramic inks in ink-jet printing[J].Ceramics International,2015,41:12515-12528.
[11]Oh-Sun Kwona,Hansu Kima,Hyojin Koa,et al.Fabrication and characterization of inkjet-printed carbonnanotube electrode patterns on paper[J].CARBON,2013,58:116-127.
[12]Huang Lu,Huang Yi,Liang Jiajie,et al.Graphene-based conducting inks for direct inkjet printing of flexible conductive patterns and their applications in electric circuits and chemical sensors[J].Nano Research,2011,7:675-684.
[13]Bolotin,KI,et al.Ultrahigh electron mobility in suspended graphene[J].Solid State Commun.,2008,146:351-355.
[14]Novoselov,K.S.,Geim,A.K.,et al.Electric field effect in atomically thin carbon films[J].Science,2004,306:666-669.
[15]Kim,K.S.,Zhao,Y.,Jang,H.,et al.Large-scale pattern growth of graphene films for stretchable transparent electrodes[J].Nature,2009,457:706-710.
[16]Mattevi C,Kim H,Chhowalla M..A review of chemical vapour deposition of graphene on copper[J].Journal of Materials Chemistry,2011:3324-3334.
[17]Felice Torrisi,Tawfique Hasan,Weiping Wu et al.Inkjet-Printed Graphene Electronics[J].ACSNano 2012,6:2992-3006.
[18]Jiantong Li,Fei Ye,Sam Vaziri,et al.Efficient Inkjet Printing of Graphene[J].Adv.Mater.,2013,25:3985-3992.
[19]Ethan B.Secor,et al.Inkjet Printing of High Conductivity,Flexible Graphene Patterns[J].J.Phys.Chem.Lett.,2013,4(8):1347-1351.
[20]Vineet Dua,Sumedh P.Surwade,Srikanth Ammu,et al.All-Organic Vapor Sensor Using Inkjet-Printed Reduced Graphene Oxide[J].Angew.Chem.Int.Ed.,2010,49:1-5.
[21]Keun Young Shin,Jin Yong Hong,J yongsik Jang.Micropatterning of Graphene Sheets by Inkjet Printing and Its Wideband DipoleAntenna Application[J].Adv.Mater.,2011,23:2113-2118.
[22]C.L.Lee,et al.Graphenenanosheets as ink particles for inkjet printing on flexible Board[J].Chemical Engineering Journal,2013,230:296-302.
[23]Yanfei Xu,Ingolf Hennig,Dieter Freyberg,et al.Inkjet-printed energy storage device using graphene/polyanilineinks[J].Journal of Power Sources,2014,248:483-488.
[24]G.Wang et al.Annealed graphene sheets decorated with silver nanoparticles for inkjet printing[J].Chemical Engineering Journal,2015,260:582-589.
[25]R.Giardi.S,Porro.A,Chiolerio.E,et al.Inkjet printed acrylic formulations based on UV-reduced graphene oxide nanocomposites[J].J Mater Sci,2013,48:1249-1255.
[26]M.Sangermano,M.Sturari,A.,et al.Study of Ink-Jet Printable Vinyl Ether-Graphene UV-Curable Formulations[J].Macromol.Mater.Eng.,2015,300:340-345.
[27]Lin,Z.,Yao,Y.,Li,Z.,et al.Solvent-assisted thermal reduction of graphite oxide[J],J.Phys.Chem.C,2010,114,(35):14819-14825.
[28]Fazel Yavari,Nikhil Koratkar.Graphene-Based Chemical Sensors[J].J.Phys.Chem.Lett.2012,3:1746-1753.
[29]Taoran Le,Vasileios Lakafosis,et al.Inkjet-Printed Graphene-Based Wireless Gas Sensor Modules[J],2012 IEEE:1003-1008.
[30]Le,T.,Lakafosis,V.,Thai,T.,et al.Inkjet printing of graphene thin films for wireless sensing applications[J].2012 ICEAA,2012:954-957.
[31]Lu Huang,Yi Huang,Jiajie Liang,et al.Graphene-Based Conducting Inks for Direct Inkjet Printing of Flexible Conductive Patterns and Their Applications in Electric Circuits and Chemical Sensors[J].Nano Res.,2011,4(7):675-684.
[32]Chakrit Sriprachuabwong,Chanpen Karuwan,Anurat Wisitsorrat,et al.Inkjet-printed graphene-PEDOT:PSS modified screen printed carbon electrode for biochemical sensing[J].J.Mater.Chem.,2012,22:5478.
[33]Qingsong Mei,Zhongping Zhang.Photoluminescent Graphene Oxide Ink to Print Sensors onto Microporous Membranes for Versatile Visualization Bioassays[J].Angew.Chem.Int.Ed.,2012,51:5602-5606.
[34]Hui Zhang,Anjian Xie,Yuhua Shen,et al.Layer-by-layer inkjet printing of fabricating reduced graphene-polyoxometalate composite film for chemical sensors[J].Phys.Chem.Chem.Phys.,2012,14:12757-12763.
[35]De Kong,Linh T.Le,Yue Li,James L.Zunino,et al.TemperatureDependent Electrical Properties of Graphene Inkjet-Printed on Flexible Materials[J].Langmuir,2012,28:13467-13472.
[36]Le L,Ervin M,Qiu H.Inkjet-printed graphene for flexible microsupercapacitors[J].Nanotechnology(IEEE-NANO),2011:67-71.
[37]Linh T.Le,Matthew H.Ervin,Hongwei Qiu,et al.Graphenesupercapacitor electrodes fabricated by inkjet printing and thermal reduction of graphene oxide[J].Electrochemistry Communications,2011(13):355-358.
[38]Yanfei Xu,Ingolf Hennig,Dieter Freyberg,et al.Inkjet-printed energy storage device using graphene/polyanilineinks[J].Journal of Power Sources,2014(248):483-488.
[39]Kai Chi,Zheye Zhang,Jiangbo Xi,et al.Freestanding Graphene Paper Supported Three-Dimensional Porous Graphen ePolyaniline Nanocomposite Synthesized by Inkjet Printing and in Flexible All-Solid-State Supercapacitor[J].ACS Appl.Mater.Interfaces,2014,6:16312-16319.
[40]Kiran Kumar Manga,Shuai Wang,Manu Jaiswal,et al.High-Gain Graphene-Titanium Oxide Photoconductor Made from Inkjet Printable Ionic Solution[J].Adv.Mater.,2010,22:5265-5270.
[41]Soojin Lim,Boseok Kang,Donghoon Kwak,et al.Inkjet-Printed Reduced Graphene Oxide/Poly(Vinyl Alcohol)Composite Electrodes for Flexible Transparent Organic Field-Effect Transistors[J].J.Phys.Chem.C,2012,116:7520-7525.
[42]Keun-Young Shin,Jin-Yong Hong,J yongsik Jang.Micropatterning of Graphene Sheets by Inkjet Printing and Its Wideband Dipole-Antenna Application[J].Adv.Mater.,2011,23:2113-2118.
[43]Keun-Young Shin,Jin-Yong Hong,Jyongsik Jang.Flexible and transparent graphene films as acoustic actuator electrodes using inkjet printing[J].Chem.Commun.,2011,47:8527-8529.
[44]Yang Su,Jinhong Du,Dongming Sun,et al.Reduced graphene oxide with a highly restoredπ-conjugated structure for inkjet printing and its use in all-carbon transistors[J].Nano Research,2013,6(11):842-852.
[45]Ethan B.Secor,Bok Y.Ahn,T heodore Z.Gao,et al.Rapid and Versatile Photonic Annealing of Graphene Inks for Flexible Printed Electronics[J].Adv.Mater.,2015,28:1-6.
[46]Jin-Yong Hong,Keun-Young Shin,Haeyoung Kang,et al.A strategy for fabricating single layer graphene sheets based on a layer-by-layer self-assembly[J].Chem.Commun.,2011,47:7182-7184.
[47]Kukjoo Kim,Sung Il Ahn,Kyung Cheol Choi.Simultaneous synthesis and patterning of graphene electrodes by reactive inkjet printing[J].CARBON,2014(66):172-177.
[48]林金堵.喷墨打印技术在PCB中的应用前景[J].印制电路信息,2008,4:9-13.