超弹性β-Ti合金研究进展
|
摘要
生物医用β-Ti合金因具有低弹性模量和超弹性的特点而备受关注。亚稳定β-Ti合金的超弹性来源于应力诱发的β→α″马氏体转变及其逆转变。以分析Ti-Nb基和Ti-Mo基两合金体系为基础,对β-Ti合金的研究现状进行了归纳总结,阐述了合金元素添加对β相马氏体转变和超弹性的影响,指出提高超弹性的关键是通过提高β相的屈服强度和调整成分获得合适的Ms点,随后介绍了超弹性β-Ti合金经不同热处理后能够获得更高的超弹性回复,最后对生物医用β-Ti合金的发展进行了展望。
Biomedical β-Ti alloys have attracted much attention owning to their noticeable characteristic including low modulus and super elasticity. Super-elasticity in metastable β-Ti alloys is caused by a stress-induced β→α″ martensite transformation and the reverse transformation. The research progress ofβ-Ti alloys is summarized by analyzing Ti-Nb-based and Ti-Mo-based alloys. The influence of alloying elements on martensitic transformation and super-elasticity of β phase are elaborated. It is pointed out that the key of improving super-elasticity is increasing the yield strength of β phase and obtaining proper Ms points by adjusting composition. Improvement in super-elasticity of β-Ti alloys by heat treatment is introduced subsequently. Finally, the development of biomedical β-Ti alloys is prospected.
Biomedical β-Ti alloys have attracted much attention owning to their noticeable characteristic including low modulus and super elasticity. Super-elasticity in metastable β-Ti alloys is caused by a stress-induced β→α″ martensite transformation and the reverse transformation. The research progress ofβ-Ti alloys is summarized by analyzing Ti-Nb-based and Ti-Mo-based alloys. The influence of alloying elements on martensitic transformation and super-elasticity of β phase are elaborated. It is pointed out that the key of improving super-elasticity is increasing the yield strength of β phase and obtaining proper Ms points by adjusting composition. Improvement in super-elasticity of β-Ti alloys by heat treatment is introduced subsequently. Finally, the development of biomedical β-Ti alloys is prospected.
引文
[1]宁聪琴,周玉.医用钛合金的发展及研究现状[J].材料科学与工艺,2002,10(1):100-106.
[2]王运锋,何蕾,郭薇.医用钛合金的研究及应用现状[J].钛工业进展,2015,32(1):1-6.
[3]SHABALOVSKAYA S,ANDEREGG J,VANHUMBEECK J.Critical overview of Nitinol surfaces and their modifications for medical applications[J].Acta Biomaterialia,2008,4(3):447-467.
[4]NIINOMI M.Recent metallic materials for biomedical applications[J].Metallurgical and Materials Transactions A,2002,33:477.
[5]KIM H Y,OHMATSU Y,KIM J I,et al.Mechanical properties and shape memory behavior of Ti-Mo-Ga alloys[J].Materials Science and Engineering A,2006,438-440(7):839-843.
[6]KIM H Y,IKEHARA Y,KIM J I,et al.Martensitic transformation,shape memory effect and superelasticity of Ti-Nb binary alloys[J].Acta Materialia,2006,54(9):2419-2429.
[7]BAKER C.The shape-memory effect in a titanium-35wt.%niobium alloy[J].Metal Science Journal,1971,5(1):92-100.
[8]KIM H Y,HASHIMOTO S,KIM J I,et al.Effect of Ta addition on shape memory behavior of Ti-22Nb alloy[J].Materials Science and Engineering A,2006,417(1):120-128.
[9]KIM J I,KIM H Y,INAMURA T,et al.Shape memory characteristics of Ti-22Nb-(2-8)Zr(at.%)biomedical alloys[J].Materials Science and Engineering A,2005,403(1/2):334-339.
[10]LAI M,GAO Y,YUAN B,et al.Indirect determination of martensitic transformation temperature of sintered nickel-free Ti-22Nb-6Zr alloy by low temperature compression test[J].Materials&Design,2014,60:193-197.
[11]TAKAHASHI E,SAKURAI T,WATANABE S,et al.Effect of heat treatment and Sn content on superelasticity in biocompatible TiNbSn alloys[J].Materials Transactions,2002,43(12):2978-2983.
[12]NOZOE F,MATSUMOTO H,JUNG T K,et al.Effect of low temperature aging on superelastic behavior in biocompatibleβTiNbSn alloy[J].Materials Transactions,2007,48(11):3007-3013.
[13]KUBOTA I,INAMURA T,KIM H Y,et al.Texture in cold-drawn wire of Ti-Nb-Al shape memory alloy[M].Materials Park:ASM International,2008.
[14]INAMURA T,YAMAMOTO Y,HOSODA H,et al.Crystallographic orientation and stress-amplitude dependence of damping in the martensite phase in textured Ti-Nb-Al shape memory alloy[J].Acta Materialia,2010,58(7):2535-2544.
[15]KIM J I,KIM H Y,HOSODA H,et al.Shape memory behavior of Ti-22Nb-(0.5-2.0)O(at%)biomedical alloys[J].Materials Transactions,2005,46(4):852-857.
[16]TAHARA M,KIM H Y,HOSODA H,et al.Shape memory effect and cyclic deformation behavior of TiNb-N Alloys[J].Functional Materials Letters,2009,2(2):79-82.
[17]ZHANG D C,LIN J G,JIANG W J,et al.Shape memory and superelastic behavior of Ti-7.5Nb-4Mo-1Sn alloy[J].Materials&Design,2011,32(8/9):4614-4617.
[18]ZHANG D C,YANG S,WEI M,et al.Effect of Sn addition on the microstructure and superelasticity in TiNb-Mo-Sn Alloys[J].Journal of the Mechanical Behavior of Biomedical Materials,2012,13:156-165.
[19]TADA H,YAMAMOTO T,WANG X M,et al.Effect of al addition on superelastic properties of aged Ti-Nb-ZrAl quaternary alloys[J].Materials Transactions,2012,53(11):1981-1985.
[20]MAESHIMA T,NISHIDA M.Shape memory properties of biomedical Ti-Mo-Ag and Ti-Mo-Sn alloys[J].Materials Transactions,2005,45(4):1096-1100.
[21]MAESHIMA T,USHIMARU S,YAMAUCHI K,et al.Effect of heat treatment on shape memory effect and superelasticity in Ti-Mo-Sn alloys[J].Materials Science and Engineering A,2006,438-440:844-847.
[22]MAESHIMA T,NISHIDA M.Shape memory and mechanical properties of biomedical Ti-Sc-Mo alloys[J].Materials Transactions,2005,45(4):1101-1105.
[23]CAI S,BAILEY D M,KAY L E.Effect of annealing and cold work on mechanical properties of beta IIItitanium[J].Journal of Materials Engineering and Performance,2012,21(12):2559-2565.
[24]ZHANG D C,LIN J G,WEN C E.Influences of recovery and recrystallization on the superelastic behavior of aβtitanium alloy made by suction casting[J].Journal of Materials Chemistry B,2014,2(36):5972-5981.
[25]TAHARA M,KIM H Y,HOSODA H,et al.Effect of nitrogen addition and annealing temperature on superelastic properties of Ti-Nb-Zr-Ta alloys[J].Materials Science and Engineering A,2010,527(26):6844-6852.
[26]XIONG C Y,XUE P F,SUN B H,et al.Effect of annealing temperature on the microstructure and superelasticity of Ti-19Zr-10Nb-1Fe alloy[J].Materials Science and Engineering A,2017,688:464-469.
[27]李强.超弹性TiNbZr合金的设计与性能研究[D].天津:天津大学,2011.
[28]LI Q,NIINOMI M,NAKAI M,et al.Effect of Zr on super-elasticity and mechanical properties of Ti-24 at%Nb-(0,2,4)at%Zr alloy subjected to aging treatment[J].Materials Science and Engineering A,2012,536(3):197-206.
[29]SUN F,HAO Y L,NOWAK S,et al.A thermomechanical treatment to improve the superelastic performances of biomedical Ti-26Nb and Ti-20Nb-6Zr(at.%)alloys[J].Journal of the Mechanical Behavior of Biomedical Materials,2011,4(8):1864-1872.
[2]王运锋,何蕾,郭薇.医用钛合金的研究及应用现状[J].钛工业进展,2015,32(1):1-6.
[3]SHABALOVSKAYA S,ANDEREGG J,VANHUMBEECK J.Critical overview of Nitinol surfaces and their modifications for medical applications[J].Acta Biomaterialia,2008,4(3):447-467.
[4]NIINOMI M.Recent metallic materials for biomedical applications[J].Metallurgical and Materials Transactions A,2002,33:477.
[5]KIM H Y,OHMATSU Y,KIM J I,et al.Mechanical properties and shape memory behavior of Ti-Mo-Ga alloys[J].Materials Science and Engineering A,2006,438-440(7):839-843.
[6]KIM H Y,IKEHARA Y,KIM J I,et al.Martensitic transformation,shape memory effect and superelasticity of Ti-Nb binary alloys[J].Acta Materialia,2006,54(9):2419-2429.
[7]BAKER C.The shape-memory effect in a titanium-35wt.%niobium alloy[J].Metal Science Journal,1971,5(1):92-100.
[8]KIM H Y,HASHIMOTO S,KIM J I,et al.Effect of Ta addition on shape memory behavior of Ti-22Nb alloy[J].Materials Science and Engineering A,2006,417(1):120-128.
[9]KIM J I,KIM H Y,INAMURA T,et al.Shape memory characteristics of Ti-22Nb-(2-8)Zr(at.%)biomedical alloys[J].Materials Science and Engineering A,2005,403(1/2):334-339.
[10]LAI M,GAO Y,YUAN B,et al.Indirect determination of martensitic transformation temperature of sintered nickel-free Ti-22Nb-6Zr alloy by low temperature compression test[J].Materials&Design,2014,60:193-197.
[11]TAKAHASHI E,SAKURAI T,WATANABE S,et al.Effect of heat treatment and Sn content on superelasticity in biocompatible TiNbSn alloys[J].Materials Transactions,2002,43(12):2978-2983.
[12]NOZOE F,MATSUMOTO H,JUNG T K,et al.Effect of low temperature aging on superelastic behavior in biocompatibleβTiNbSn alloy[J].Materials Transactions,2007,48(11):3007-3013.
[13]KUBOTA I,INAMURA T,KIM H Y,et al.Texture in cold-drawn wire of Ti-Nb-Al shape memory alloy[M].Materials Park:ASM International,2008.
[14]INAMURA T,YAMAMOTO Y,HOSODA H,et al.Crystallographic orientation and stress-amplitude dependence of damping in the martensite phase in textured Ti-Nb-Al shape memory alloy[J].Acta Materialia,2010,58(7):2535-2544.
[15]KIM J I,KIM H Y,HOSODA H,et al.Shape memory behavior of Ti-22Nb-(0.5-2.0)O(at%)biomedical alloys[J].Materials Transactions,2005,46(4):852-857.
[16]TAHARA M,KIM H Y,HOSODA H,et al.Shape memory effect and cyclic deformation behavior of TiNb-N Alloys[J].Functional Materials Letters,2009,2(2):79-82.
[17]ZHANG D C,LIN J G,JIANG W J,et al.Shape memory and superelastic behavior of Ti-7.5Nb-4Mo-1Sn alloy[J].Materials&Design,2011,32(8/9):4614-4617.
[18]ZHANG D C,YANG S,WEI M,et al.Effect of Sn addition on the microstructure and superelasticity in TiNb-Mo-Sn Alloys[J].Journal of the Mechanical Behavior of Biomedical Materials,2012,13:156-165.
[19]TADA H,YAMAMOTO T,WANG X M,et al.Effect of al addition on superelastic properties of aged Ti-Nb-ZrAl quaternary alloys[J].Materials Transactions,2012,53(11):1981-1985.
[20]MAESHIMA T,NISHIDA M.Shape memory properties of biomedical Ti-Mo-Ag and Ti-Mo-Sn alloys[J].Materials Transactions,2005,45(4):1096-1100.
[21]MAESHIMA T,USHIMARU S,YAMAUCHI K,et al.Effect of heat treatment on shape memory effect and superelasticity in Ti-Mo-Sn alloys[J].Materials Science and Engineering A,2006,438-440:844-847.
[22]MAESHIMA T,NISHIDA M.Shape memory and mechanical properties of biomedical Ti-Sc-Mo alloys[J].Materials Transactions,2005,45(4):1101-1105.
[23]CAI S,BAILEY D M,KAY L E.Effect of annealing and cold work on mechanical properties of beta IIItitanium[J].Journal of Materials Engineering and Performance,2012,21(12):2559-2565.
[24]ZHANG D C,LIN J G,WEN C E.Influences of recovery and recrystallization on the superelastic behavior of aβtitanium alloy made by suction casting[J].Journal of Materials Chemistry B,2014,2(36):5972-5981.
[25]TAHARA M,KIM H Y,HOSODA H,et al.Effect of nitrogen addition and annealing temperature on superelastic properties of Ti-Nb-Zr-Ta alloys[J].Materials Science and Engineering A,2010,527(26):6844-6852.
[26]XIONG C Y,XUE P F,SUN B H,et al.Effect of annealing temperature on the microstructure and superelasticity of Ti-19Zr-10Nb-1Fe alloy[J].Materials Science and Engineering A,2017,688:464-469.
[27]李强.超弹性TiNbZr合金的设计与性能研究[D].天津:天津大学,2011.
[28]LI Q,NIINOMI M,NAKAI M,et al.Effect of Zr on super-elasticity and mechanical properties of Ti-24 at%Nb-(0,2,4)at%Zr alloy subjected to aging treatment[J].Materials Science and Engineering A,2012,536(3):197-206.
[29]SUN F,HAO Y L,NOWAK S,et al.A thermomechanical treatment to improve the superelastic performances of biomedical Ti-26Nb and Ti-20Nb-6Zr(at.%)alloys[J].Journal of the Mechanical Behavior of Biomedical Materials,2011,4(8):1864-1872.